SAFETY DATA SHEET
1. Identification
Product identifier |
Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries) |
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Other means of identification |
None. |
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Recommended use |
Lithium ion battery. |
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Recommended restrictions |
None known. |
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Manufacturer/Importer/Supplier/Distributor information |
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Company Name |
Motorola Solutions, Inc. |
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Address |
1303 E. Algonquin Road |
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Schaumburg, Illinois 60196 U.S.A. |
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General information |
1-847-576-5000 |
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Emergency phone number |
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CHEMTREC |
1-800-424-9300 |
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2. Hazard(s) identification |
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Physical hazards |
Not classified. |
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Health hazards |
Acute toxicity, oral |
Category 4 |
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Skin corrosion/irritation |
Category 1B |
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Serious eye damage/eye irritation |
Category 1 |
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Sensitization, skin |
Category 1 |
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Carcinogenicity |
Category 1A |
OSHA defined hazards |
Not classified. |
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Under normal conditions of processing and use, exposure to the chemical constituents in this product is unlikely. The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. Hazards shown here apply to exposure that may occur from damaged or leaking batteries or under extreme heat conditions such as fire.
Label elements
Signal word |
Danger |
Hazard statement |
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin |
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reaction. May cause cancer. |
Precautionary statement |
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Prevention |
Obtain special instructions before use. Do not handle until all safety precautions have been read |
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and understood. Avoid breathing fume/mist/vapors/spray. Wash thoroughly after handling. Do not |
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eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out |
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of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. |
Response |
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all |
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contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and |
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keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. |
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Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison |
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center/doctor. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated |
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clothing before reuse. |
Storage |
Store locked up. |
Disposal |
Dispose of contents/container in accordance with local/regional/national/international regulations. |
Hazard(s) not otherwise |
None known. |
classified (HNOC)
Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries) |
SDS US |
933626 Version #: 01 Revision date: - Issue date: 08-June-2016 |
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Supplemental information None.
3. Composition/information on ingredients
Mixtures |
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Chemical name |
CAS number |
% |
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Positive electrode (One of the |
12190-79-3, 12057-17-9, |
20-40 |
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following: Lithiated cobalt |
NA |
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oxides, Lithiated manganese |
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oxides, Proprietary lithiated |
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nickel-manganese-cobalt |
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oxides) |
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Negative electrode (Graphite) |
7782-42-5 |
10-20 |
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Binders (Polyvinylidene |
24937-79-9, 9002-84-0 |
0-3 |
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difluoride and/or |
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polytetrafluoroethylene) |
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Electrolyte salt (Lithium salt: |
21324-40-3, 14283-07-9 |
1-5 |
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one or more of lithium |
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hexafluorophosphate and |
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lithium tetrafluoroborate) |
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Electrolyte solvent (Organic |
96-49-1, 105-58-8, |
5-20 |
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solvents including one or more |
616-38-6, 623-53-0, |
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of the following: Ethylene |
108-32-7 |
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carbonate, Diethyl carbonate, |
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Dimethyl carbonate, Ethyl |
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methyl carbonate, and |
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Propylene carbonate.) |
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Other components (Copper) |
7440-50-8 |
5-10 |
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Other components (Aluminum) |
7429-90-5 |
5-40 |
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Other components (Nickel) |
7440-02-0 |
0-5 |
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Other components |
9002-88-4, 9003-07-0 |
1-3 |
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(Polyethylene and/or |
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polypropylene) |
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All concentrations are in percent by weight unless otherwise indicated. |
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Ingredients shown are major constituents representative of various compositions for lithium ion cells.
Exposure to hazardous ingredients is not anticipated under normal conditions of use. For further information please refer to Section 8.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
Exposure to contents of an open or damaged battery: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician or poison control center immediately.
Exposure to contents of an open or damaged battery: Remove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Call a physician or poison control center immediately. Chemical burns must be treated by a physician.
Exposure to contents of an open or damaged battery: Immediately flush eyes with plenty of water for at least 15 minutes. Provide eyewash station. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Exposure to contents of an open or damaged battery: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Exposure to contents of an open or damaged battery: Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause allergic skin reaction. Difficulty in breathing. Coughing. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries) |
SDS US |
933626 Version #: 01 Revision date: - Issue date: 08-June-2016 |
2 / 9 |
General information |
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware |
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of the material(s) involved, and take precautions to protect themselves. Show this safety data |
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sheet to the doctor in attendance. Wash contaminated clothing before reuse. |
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Fire fighting equipment/instructions
Specific methods General fire hazards
Use fire-extinguishing media appropriate for surrounding materials.
Leak from a damaged or opened battery: Do not use water unless flooding amounts are available.
In the event of fire and/or explosion do not breathe fumes. The evolved combustion products may contain carbon oxides, metal oxides, hydrogen fluoride, and should be considered hazardous.
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask.
Fight fire from protected location or safe distance. Keep upwind. Move containers from fire area if you can do so without risk. Avoid discharge into drains, water courses or onto the ground.
Use standard firefighting procedures and consider the hazards of other involved materials.
Under normal use, the battery does not exhibit flammable properties. In the event that the battery is abused and disassembly of the battery occurs resulting in exposure of internal components, the exposed solution, may be flammable and/or corrosive. Exposure to excessive heat may lead to venting or rupture of the sealed battery, exposing the internal components which may be corrosive and/or flammable. Vented gas would be flammable when in sufficient concentration.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Environmental precautions
None under normal use conditions. In the event of damage resulting in a leak or exposed materials, avoid contact with contents of an open or damaged cell or battery. Wear protective clothing as described in Section 8 of this safety data sheet.
Leak from a damaged or opened battery: Contain spillage with sand or earth. Collect with absorbent, non-combustible material into suitable containers. For waste disposal, see Section 13 of the SDS.
Avoid allowing material from exposed battery to contaminate soil, sanitary sewers, or waterways.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage, including any incompatibilities
Do not open, disassemble, crush or burn battery. Protect against physical damage. Do not expose battery to extreme heat or fire. Do not allow conductive material to touch the battery terminals. A dangerous short-circuit may occur and cause battery failure and fire.
Keep out of reach of children. Prevent short circuits. Store in original packaging. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Store away from incompatible materials (See Section 10).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) |
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Components |
Type |
Value |
Form |
Aluminum (CAS 7429-90-5) |
PEL |
5 mg/m3 |
Respirable dust. |
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15 mg/m3 |
Total dust. |
COBALT LITHIUM NICKEL |
Ceiling |
5 mg/m3 |
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OXIDE (CAS 182442-95-1) |
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Copper (CAS 7440-50-8) |
PEL |
1 mg/m3 |
Dust and mist. |
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0.1 mg/m3 |
Fume. |
Graphite (CAS 7782-42-5) |
PEL |
5 mg/m3 |
Respirable fraction. |
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15 mg/m3 |
Total dust. |
Lithium manganese oxide |
Ceiling |
5 mg/m3 |
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(CAS 12057-17-9) |
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Nickel (CAS 7440-02-0) |
PEL |
1 mg/m3 |
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US. OSHA Table Z-3 (29 CFR 1910.1000) |
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Components |
Type |
Value |
Graphite (CAS 7782-42-5) |
TWA |
15 mppcf |
Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries) |
SDS US |
933626 Version #: 01 Revision date: - Issue date: 08-June-2016 |
3 / 9 |