Motorola RMU2040, RMU2080, SL300-HK2091, SL300-HK2090, SL300-HK2088 User Manual

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Motorola RMU2040, RMU2080, SL300-HK2091, SL300-HK2090, SL300-HK2088 User Manual

SAFETY DATA SHEET

1. Identification

Product identifier

Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries)

Other means of identification

None.

 

Recommended use

Lithium ion battery.

 

Recommended restrictions

None known.

 

Manufacturer/Importer/Supplier/Distributor information

 

Company Name

Motorola Solutions, Inc.

 

Address

1303 E. Algonquin Road

 

 

Schaumburg, Illinois 60196 U.S.A.

 

General information

1-847-576-5000

 

Emergency phone number

 

 

CHEMTREC

1-800-424-9300

 

2. Hazard(s) identification

 

 

Physical hazards

Not classified.

 

Health hazards

Acute toxicity, oral

Category 4

 

Skin corrosion/irritation

Category 1B

 

Serious eye damage/eye irritation

Category 1

 

Sensitization, skin

Category 1

 

Carcinogenicity

Category 1A

OSHA defined hazards

Not classified.

 

Under normal conditions of processing and use, exposure to the chemical constituents in this product is unlikely. The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. Hazards shown here apply to exposure that may occur from damaged or leaking batteries or under extreme heat conditions such as fire.

Label elements

Signal word

Danger

Hazard statement

Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin

 

reaction. May cause cancer.

Precautionary statement

 

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read

 

and understood. Avoid breathing fume/mist/vapors/spray. Wash thoroughly after handling. Do not

 

eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out

 

of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.

Response

If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all

 

contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and

 

keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.

 

Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison

 

center/doctor. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated

 

clothing before reuse.

Storage

Store locked up.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

None known.

classified (HNOC)

Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries)

SDS US

933626 Version #: 01 Revision date: - Issue date: 08-June-2016

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Supplemental information None.

3. Composition/information on ingredients

Mixtures

 

 

 

Chemical name

CAS number

%

 

Positive electrode (One of the

12190-79-3, 12057-17-9,

20-40

 

following: Lithiated cobalt

NA

 

 

oxides, Lithiated manganese

 

 

 

oxides, Proprietary lithiated

 

 

 

nickel-manganese-cobalt

 

 

 

oxides)

 

 

 

 

 

 

 

Negative electrode (Graphite)

7782-42-5

10-20

 

 

 

 

 

Binders (Polyvinylidene

24937-79-9, 9002-84-0

0-3

 

difluoride and/or

 

 

 

polytetrafluoroethylene)

 

 

 

 

 

 

 

Electrolyte salt (Lithium salt:

21324-40-3, 14283-07-9

1-5

 

one or more of lithium

 

 

 

hexafluorophosphate and

 

 

 

lithium tetrafluoroborate)

 

 

 

 

 

 

 

Electrolyte solvent (Organic

96-49-1, 105-58-8,

5-20

 

solvents including one or more

616-38-6, 623-53-0,

 

 

of the following: Ethylene

108-32-7

 

 

carbonate, Diethyl carbonate,

 

 

 

Dimethyl carbonate, Ethyl

 

 

 

methyl carbonate, and

 

 

 

Propylene carbonate.)

 

 

 

 

 

 

 

Other components (Copper)

7440-50-8

5-10

 

 

 

 

 

Other components (Aluminum)

7429-90-5

5-40

 

 

 

 

 

Other components (Nickel)

7440-02-0

0-5

 

 

 

 

 

Other components

9002-88-4, 9003-07-0

1-3

 

(Polyethylene and/or

 

 

 

polypropylene)

 

 

 

 

 

 

 

All concentrations are in percent by weight unless otherwise indicated.

 

 

 

Ingredients shown are major constituents representative of various compositions for lithium ion cells.

Exposure to hazardous ingredients is not anticipated under normal conditions of use. For further information please refer to Section 8.

4. First-aid measures

Inhalation

Skin contact

Eye contact

Ingestion

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed

Exposure to contents of an open or damaged battery: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician or poison control center immediately.

Exposure to contents of an open or damaged battery: Remove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Call a physician or poison control center immediately. Chemical burns must be treated by a physician.

Exposure to contents of an open or damaged battery: Immediately flush eyes with plenty of water for at least 15 minutes. Provide eyewash station. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.

Exposure to contents of an open or damaged battery: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Exposure to contents of an open or damaged battery: Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause allergic skin reaction. Difficulty in breathing. Coughing. Prolonged exposure may cause chronic effects.

Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim under observation. Symptoms may be delayed.

Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries)

SDS US

933626 Version #: 01 Revision date: - Issue date: 08-June-2016

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General information

IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware

 

of the material(s) involved, and take precautions to protect themselves. Show this safety data

 

sheet to the doctor in attendance. Wash contaminated clothing before reuse.

5. Fire-fighting measures

Suitable extinguishing media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Special protective equipment and precautions for firefighters

Fire fighting equipment/instructions

Specific methods General fire hazards

Use fire-extinguishing media appropriate for surrounding materials.

Leak from a damaged or opened battery: Do not use water unless flooding amounts are available.

In the event of fire and/or explosion do not breathe fumes. The evolved combustion products may contain carbon oxides, metal oxides, hydrogen fluoride, and should be considered hazardous.

Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask.

Fight fire from protected location or safe distance. Keep upwind. Move containers from fire area if you can do so without risk. Avoid discharge into drains, water courses or onto the ground.

Use standard firefighting procedures and consider the hazards of other involved materials.

Under normal use, the battery does not exhibit flammable properties. In the event that the battery is abused and disassembly of the battery occurs resulting in exposure of internal components, the exposed solution, may be flammable and/or corrosive. Exposure to excessive heat may lead to venting or rupture of the sealed battery, exposing the internal components which may be corrosive and/or flammable. Vented gas would be flammable when in sufficient concentration.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Environmental precautions

None under normal use conditions. In the event of damage resulting in a leak or exposed materials, avoid contact with contents of an open or damaged cell or battery. Wear protective clothing as described in Section 8 of this safety data sheet.

Leak from a damaged or opened battery: Contain spillage with sand or earth. Collect with absorbent, non-combustible material into suitable containers. For waste disposal, see Section 13 of the SDS.

Avoid allowing material from exposed battery to contaminate soil, sanitary sewers, or waterways.

7. Handling and storage

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Do not open, disassemble, crush or burn battery. Protect against physical damage. Do not expose battery to extreme heat or fire. Do not allow conductive material to touch the battery terminals. A dangerous short-circuit may occur and cause battery failure and fire.

Keep out of reach of children. Prevent short circuits. Store in original packaging. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Store away from incompatible materials (See Section 10).

8. Exposure controls/personal protection

Occupational exposure limits

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

 

 

Components

Type

Value

Form

Aluminum (CAS 7429-90-5)

PEL

5 mg/m3

Respirable dust.

 

 

15 mg/m3

Total dust.

COBALT LITHIUM NICKEL

Ceiling

5 mg/m3

 

OXIDE (CAS 182442-95-1)

 

 

 

Copper (CAS 7440-50-8)

PEL

1 mg/m3

Dust and mist.

 

 

0.1 mg/m3

Fume.

Graphite (CAS 7782-42-5)

PEL

5 mg/m3

Respirable fraction.

 

 

15 mg/m3

Total dust.

Lithium manganese oxide

Ceiling

5 mg/m3

 

(CAS 12057-17-9)

 

 

 

Nickel (CAS 7440-02-0)

PEL

1 mg/m3

 

US. OSHA Table Z-3 (29 CFR 1910.1000)

 

 

 

Components

Type

Value

Graphite (CAS 7782-42-5)

TWA

15 mppcf

Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries)

SDS US

933626 Version #: 01 Revision date: - Issue date: 08-June-2016

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