Xylem PH3110 User Manual

Download

pH 3110

Operating manual

ba75791e02 11/2008

pH meter

pH 3110

Accuracy when

going to press

The use of advanced technology and the high quality standard of our instruments are the result of a continuous development. This may result in differences between this operating manual and your meter. Also, we cannot guarantee that there are absolutely no errors in this manual. Therefore, we are sure you will understand that we cannot accept any legal claims resulting from the data, figures or descriptions.

Reproduction in whole - or even in part - is prohibited without the express written permission of WTW GmbH, Weilheim. Printed in Germany.

ba75791e02 11/2008

pH 3110 Contents

pH 3110 - Contents

1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

1.3 Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 10

3 Commissioning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.1 Scope of delivery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.2 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.2.1 Inserting the batteries. . . . . . . . . . . . . . . . . . . . . 13

3.2.2 Switching on the meter. . . . . . . . . . . . . . . . . . . . 14

4 Operation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

4.1 General operating principles . . . . . . . . . . . . . . . . . . . . . . 15

4.1.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . 15

4.1.2 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

4.2 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

4.2.1 Measuring the pH value . . . . . . . . . . . . . . . . . . . 17

4.2.2 Measuring the ORP . . . . . . . . . . . . . . . . . . . . . . 18

4.3 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

4.3.1 Calibration interval (Int.C) . . . . . . . . . . . . . . . . . 21

4.3.2 Automatic calibration (AutoCal) . . . . . . . . . . . . . 22

4.3.3 Conventional calibration (ConCal) . . . . . . . . . . . 24

4.4 Downloading calibration data . . . . . . . . . . . . . . . . . . . . . 27

4.5 Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

4.5.1 System settings . . . . . . . . . . . . . . . . . . . . . . . . . 29

4.5.2 Measurement settings . . . . . . . . . . . . . . . . . . . . 30

4.6 Reset. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

4.6.1 Resetting calibration values . . . . . . . . . . . . . . . . 34

4.6.2 Resetting all meter settings . . . . . . . . . . . . . . . . 35

5 Maintenance, cleaning, disposal. . . . . . . . . . . . . . . . . 37

5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

5.1.1 Replacing the batteries . . . . . . . . . . . . . . . . . . . 37

5.2 Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

5.3 Packing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

ba75791e02 11/2008

Contents pH 3110

5.4 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39

7 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

7.1 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

7.2 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . 44

8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45

ba75791e02 11/2008

pH 3110 Overview

1Overview

The compact pH 3110 precision pH meter enables you to perform pH measurements rapidly and reliably. The pH 3110 provides the maximum degree of operating comfort, reliability and measuring certainty for all applications. The proven calibration procedures and automatic stability control function (AR) support your work with the pH meter.

1 Keypad

2 Display

3 Socket field

ba75791e02 11/2008

Overview pH 3110

pH 3110

1.1 Keypad

In this operating manual, keys are indicated by brackets <..> . The key symbol (e.g. <ENTER>) generally indicates a short keystroke (under 2 sec) in this operating manual. A long keystroke (approx. 2 sec) is indicated by the underscore behind the key symbol (e.g.

<ENTER

_>).

<On/Off>: <On/Off

<M>: <M

<CAL>: <CAL

<▲>: Increments values, scrolls

<▼>: Decrements values, scrolls

_>:

Switches the meter on/off Resets calibration data

Selects the measured parameter Opens the setting menu for calibration and measurements

Calls up the calibration procedure Displays the calibration data

<ENTER>: <ENTER

Confirms entries Opens the setting menu for system settings

ba75791e02 11/2008

pH 3110 Overview

Status display

Sensor symbol

(calibration

evaluation)

Measured value display

Function and temperature display indicators

1.2 Display

Function display

indicators

AutoCal TEC Calibration with automatic buffer recognition

(buffer set: Technical buffers )

AutoCal DIN Calibration with automatic buffer recognition

(buffer set: DIN buffers )

ConCal Calibration with any buffers

CalError An error occurred during calibration

LoBat With battery operation: Batteries almost empty

AR Stability control (AutoRead) is active

TP Temperature measurement active

TIME Setting of calibration interval

ba75791e02 11/2008

Overview pH 3110

1.3 Socket field

Connectors:

1 pH electrode

2 Reference electrode

3 Temperature sensor

4 Service interface

Caution

Only connect sensors to the meter that cannot return any voltages or currents that are not allowed (> SELV and > current circuit with current limiting). Almost all customary sensors fulfill these conditions.

ba75791e02 11/2008

pH 3110 Safety

2 Safety

This operating manual contains basic instructions that you must follow during the commissioning, operation and maintenance of the meter. Consequently, all responsible personnel must read this operating manual before working with the meter. The operating manual must always be available within the vicinity of the meter.

Target group The meter was developed for work in the field and in the laboratory.

Thus, we assume that, as a result of their professional training and experience, the operators will know the necessary safety precautions to take when handling chemicals.

Safety instructions Safety instructions in this operating manual are indicated by the

warning symbol (triangle) in the left column. The signal word (e.g. "Caution") indicates the level of danger:

Further notes

Warning

indicates instructions that must be followed precisely in order to avoid possibly great dangers to personnel.

Caution

indicates instructions that must be followed precisely in order to avoid the possibility of slight injuries or damage to the meter or the environment.

Note

indicates notes that draw your attention to special features.

Note

indicates cross-references to other documents, e.g. operating manuals.

ba75791e02 11/2008

Safety pH 3110

2.1 Authorized use

This meter is authorized exclusively for pH and ORP measurements in a laboratory or field environment. The technical specifications as given in chapter 7 T

ECHNICAL DATA must

be observed. Only the operation and running of the meter according to the instructions given in this operating manual is authorized. Any other use is considered unauthorized.

2.2 General safety instructions

This meter is constructed and tested in compliance with the IEC 1010 safety regulations for electronic measuring instruments. It left the factory in a safe and secure technical condition.

Function and

operational safety

The smooth functioning and operational safety of the meter can only be guaranteed if the generally applicable safety measures and the specific safety instructions in this operating manual are followed during operation.

The smooth functioning and operational safety of the meter can only be guaranteed under the environmental conditions that are specified in chapter 7 T

ECHNICAL DATA.

If the meter was transported from a cold environment to a warm environment, the formation of condensate can lead to the faulty functioning of the meter. In this event, wait until the temperature of the meter reaches room temperature before putting the meter back into operation.

Caution

The meter is only allowed to be opened by authorized personnel.

ba75791e02 11/2008

pH 3110 Safety

Safe operation If safe operation is no longer possible, the meter must be taken out of

service and secured against inadvertent operation! Safe operation is no longer possible if the meter:

z has been damaged in transport

z has been stored under adverse conditions for a lengthy period of

time

z is visibly damaged

z no longer operates as described in this manual.

If you are in any doubt, please contact the supplier of the meter.

Obligations of the

purchaser

The purchaser of this meter must ensure that the following laws and guidelines are observed when using dangerous substances:

z EEC directives for protective labor legislation

z National protective labor legislation

z Safety regulations

z Safety datasheets of the chemical manufacturers.

Caution

In addition to the safety instructions mentioned here, also follow the safety instructions of the sensors used. The operating manuals of the sensors are available on the supplied CD and on the Internet under www.WTW.com.

ba75791e02 11/2008

Safety pH 3110

ba75791e02 11/2008

pH 3110 Commissioning

3 Commissioning

3.1 Scope of delivery

z Handheld meter, pH 3110

z 4 batteries 1.5 V Mignon type AA

z Operating manual

3.2 Initial commissioning

Perform the following activities:

z Insert the supplied batteries

z Switch on the meter

3.2.1 Inserting the batteries

1 Unscrew the two screws (1) on the underside of the meter.

2 Open the battery compartment (2) on the underside of the

meter.

ba75791e02 11/2008

3 Place four batteries (type Mignon AA) in the battery

compartment.

Commissioning pH 3110

Note

Alternatively, you can also use Ni-MH rechargeable batteries (type Mignon AA). In order to charge the batteries, an external charging device is required.

Caution

Make sure that the poles of the batteries are positioned correctly. The

± signs on the batteries must correspond to the ± signs in the

battery compartment.

4 Close the battery compartment (2) and tighten the screws (1).

3.2.2 Switching on the meter

1 Place the meter on a flat surface and protect it from intense

light and heat.

2 Press the <On/Off>

key.

A display test is briefly displayed. Subsequently, the meter switches to the measuring mode (measured value display).

Note

The meter has an energy saving feature to avoid unnecessary battery depletion during battery operation. The energy saving feature switches off the meter if no key was pressed during the specified interval (setting the switch-off interval see section

4.5.1).

ba75791e02 11/2008

pH 3110 Operation

4 Operation

4.1 General operating principles

This section contains basic information on the operation of the pH 3110.

4.1.1 Operating modes

The meter has the following operating modes:

z Measurement

The display indicates the measurement data in the measured value display

z Calibration

The display guides you through a calibration procedure with calibration information

z Configuration

The system menu or a sensor menu with submenus, settings and functions is displayed

4.1.2 Operation

Keys The meter is operated via keys. The keys can have different functions

with long or short keystrokes.

Functions Generally, with a short keystroke a function is carried out. A long

keystroke opens a setting menu.

In a setting menu, settings are selected with the <▲><▼> keys. A setting is confirmed with <ENTER>. With confirming, the setting is finished and the next setting is displayed.

Representation In this operating manual, keys are indicated by brackets <..> .

The key symbol (e.g. <ENTER>) generally indicates a short keystroke (under 2 sec) in this operating manual. A long keystroke (approx. 2 sec) is indicated by the underscore behind the key symbol (e.g.

<ENTER

_>).

ba75791e02 11/2008

Operation pH 3110

4.2 Measuring

Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect the pH combination electrode to the meter.

2 Adjust the temperature of the buffer solutions or test solutions,

or measure the current temperature, if you measure without a temperature sensor.

3 Calibrate or check the meter with the combination electrode.

4 Select the measured parameter with <M>.

Note

Incorrect calibration of pH combination electrodes leads to incorrect measured values. Calibrate regularly before measuring.

Stability control

AutoRead

During the measuring procedure, the stability control function is automatically activated. The stability control function (drift control) checks the stability of the measured pH signal and the stability of the measured temperature signal. The stability has a considerable effect on the reproducibility of the measured value.

For identical measurement conditions, the following applies:

Measured

Reproducibility Response time

parameter

pH value < 0.02 pH units > 15 seconds

Temperature < 0.3 °C of temperature value > 15 seconds

Temperature sensor You can measure with or without a temperature sensor. If a

temperature sensor is connected, it is indicated on the display by TP.

Note

The pH meter automatically recognizes the type of the temperature sensor used. Therefore, you can connect combination electrodes with an NTC30 or Pt1000.

The temperature measurement is absolutely essential for a reproducible pH measurement. If the measurement is made without a temperature sensor, proceed as follows:

1 Measure the current temperature using a thermometer.

2 Set the temperature value with <▲><▼>.

ba75791e02 11/2008

pH 3110 Operation

Note

When calibrating without temperature sensor, also set the current temperature of each buffer solution manually with the <▲><▼> keys.

4.2.1 Measuring the pH value

1 Perform the preparatory activities according to section 4.2.

2 Immerse the pH combination electrode in the test sample.

3 Using <M>, scroll as necessary until the measured parameter

pH is displayed.

4 Wait for a stable measured value.

The AR display indicator flashes as long as the measured value is not yet stable.

ba75791e02 11/2008

Operation pH 3110

4.2.2 Measuring the ORP

The meter can, in conjunction with an ORP electrode, measure the ORP (mV) of a solution.

1 Perform the preparatory activities according to section 4.2.

2 Immerse the ORP electrode in the test sample.

3 If necessary, call up the measured parameter U with <M>.

4 Wait for a stable measured value.

The AR display indicator flashes as long as the measured value is not yet stable.

Note

ORP electrodes are not calibrated. However, you can check ORP electrodes using a test solution.

ba75791e02 11/2008

pH 3110 Operation

4.3 Calibration

Why calibrate? pH combination electrodes age. This changes the zero point

(asymmetry) and slope of the pH combination electrode. As a result, an inexact measured value is displayed. Calibration determines the current values of the zero point and slope of the combination electrode and stores them in the measuring instrument. Thus, you should calibrate at regular intervals.

When do you have to

calibrate?

z After connecting another combination electrode

z When the sensor symbol flashes on the display:

– e.g. after the calibration interval has expired

AutoCal is adapted to the permanently programmed buffer solutions as a fully

automatic single-point, two-point or three-point calibration. The buffer solutions are automatically recognized by the meter. The following buffer sets are suitable:

z Technical buffers (AutoCal TEC)

z DIN buffers (AutoCal DIN)

Calibration points Calibration can be performed using one, two or three buffer solutions in

any order (single-point, two-point or three-point calibration). The meter determines the following values and calculates the calibration line as follows:

Determined values Displayed calibration data

1-point ASY z Zero point = ASY

z Slope = Nernst slope

(-59.16 mV/pH at 25 °C)

ConCal This function is a conventional two-point calibration using two buffer

Stability control

AutoRead

ba75791e02 11/2008

2-point 3-point

ASY SLO

z Zero point = ASY

z Slope = SLO

Note

You can display the slope in the units, mV/pH or %. You can display the zero point in the units, mV or pH.

solutions (pH 7.0 ± 0.5 and any other buffer solution) or a single-point calibration using any buffer solution and is used as a high-speed method.

The calibration procedure automatically activates the stability control function. The current measurement with stability control can be terminated at any time (accepting the current value) by pressing

<ENTER>.

Operation pH 3110

Calibration record When finishing a calibration, the new calibration values are first

displayed as an informative message and stored.

Displaying the

You can display the data of the last calibration (see section 4.4).

calibration data

Calibration evaluation After calibrating, the meter automatically evaluates the calibration. The

zero point and slope are evaluated separately. The worse evaluation of both is taken into account. The evaluation appears on the display as the sensor symbol and in the calibration record.

Sensor symbol Zero point

[mV]

Slope [mV/pH]

-15 ... +15 -60.5 ... -58

-20 ... +20 -58 ... -57

-25 ... +25 -61 ... -60.5 or

-57 ... -56

Preparatory activities

-30 ... +30 -62 ... -61 or

-56 ... -50

Clean the combination electrode according to the electrode operating manual

CalError

< -30 or > 30

... -62 or ... -50

Eliminate the error according to chapter 6 W

HAT TO DO IF...

1 Switch on the meter with <On/Off>.

2 Connect the pH combination electrode to the meter.

3 Keep the buffer solutions ready.

4 Adjust the temperature of the solutions and measure the

current temperature if the measurement is made without temperature sensor.

ba75791e02 11/2008

pH 3110 Operation

Time

5 Set the buffer set to be used for calibration as necessary.

4.3.1 Calibration interval (Int.C)

The calibration interval reminds you to calibrate regularly. When the adjusted calibration interval (Int.C) has expired, the sensor symbol flashes. It is still possible to measure.

Note

To ensure the high measuring accuracy of the measuring system, calibrate after the calibration interval has expired.

Setting the calibration

interval

The calibration interval (Int.C) is set to 7 days (d7) in the factory. You can change the interval (1 ... 999 days):

1 Open the menu for measurement settings with <M_>.

2 Confirm all settings with <ENTER> until Int.C is displayed.

3 Set the calibration interval with <▲><▼>.

4 Confirm the setting with <ENTER>.

ba75791e02 11/2008

Operation pH 3110

AutoCal TEC

AutoCal DIN

AutoCal TEC

AutoCal DIN

4.3.2 Automatic calibration (AutoCal)

For the AutoCal TEC and AutoCal DIN procedures, use one to three buffer solutions of the relevant buffer set (Technical buffers or DIN buffers) in any order.

Note

The steps 2 and 6 are not necessary if you use a temperature sensor.

1 Press <CAL> repeatedly until the AutoCal TEC or AutoCal DIN

function display indicator appears.

2 If necessary, set the temperature of the buffer solution with

<▲><▼>.

3 Immerse the pH combination electrode in the first buffer

solution.

4 Start the measurement with <ENTER>.

The AR display indicator flashes. The electrode voltage (mV) or the nominal value of the buffer (setting: see section 4.5.2) is displayed. As soon as a stable value is recognized, Ct2 or Cd2 appears.

ba75791e02 11/2008

pH 3110 Operation

AutoCal TEC

AutoCal DIN

Note

Here you can cancel the calibration procedure with <M>. This corresponds to a single-point calibration. The value of the zero point (ASY) is displayed. Pressing <ENTER> displays the value of the slope (SLO).

Continuing with two-

point calibration

5 Thoroughly rinse the combination electrode with distilled water.

6 If necessary, set the temperature of the second buffer solution

with <▲><▼>.

7 Immerse the combination electrode in the second buffer

solution.

8 Press the <ENTER>

The AR display indicator flashes. The electrode voltage (mV) or the nominal value of the buffer (setting: see section 4.5.2) is displayed. As soon as a stable value is recognized, Ct3 or Cd3 appears.

key.

Continuing with three-

point calibration

ba75791e02 11/2008

Note

Here you can cancel the calibration procedure with <M>. This corresponds to a two-point calibration. The value of the zero point (ASY) is displayed. Pressing <ENTER> displays the value of the slope (SLO).

9 Thoroughly rinse the combination electrode with distilled water.

10 If necessary, set the temperature of the third buffer solution

with <▲><▼>.

11 Immerse the combination electrode in the third buffer solution.

Operation pH 3110

12 Press the <ENTER> key.

The AR display indicator flashes. The electrode voltage (mV) or the nominal value of the buffer (setting: see section 4.5.2) is displayed. The asymmetry is displayed as soon as a stable value is recognized.

13 Press the <ENTER> key.

The value of the slope (mV/pH) appears on the display.

14 To return to the measuring mode: Press the <ENTER> key.

Note

While the zero point (ASY) is being displayed, you can change the unit of the zero point with

While the slope (SLO) is being displayed, you can change the unit of the slope with The % display refers to the Nernst slope of 59.2 mV/pH at 25° C (100 x determined slope/Nernst slope).

<▲><▼>.

The unit of zero point and slope can also be changed permanently in the measurement settings (see section 4.5.2).

4.3.3 Conventional calibration (ConCal)

Single-point calibration Use any buffer solution for this rapid method.

The calibration will be the more exact the nearer the pH value of the buffer solution is to that of the test sample.

Two-point calibration Use two buffer solutions for this procedure:

z pH 7.0 ± 0.5

z any other buffer solution

Note

The steps 2 and 9 are not necessary if you use a pH combination electrode with a temperature sensor.

1 Press the <CAL> key repeatedly until the ASY display indicator

and the ConCal function indicator appear.

ba75791e02 11/2008

pH 3110 Operation

ConCal

2 If necessary, set the temperature of the first buffer solution with

<▲><▼>.

3 Immerse the pH combination electrode in the first buffer

solution (pH 7.0 ± 0.5 for two-point calibration).

4 Press the <ENTER> key.

The measured pH value appears on the display.

5 When the measured value is stable,

using <▲><▼>, set the measured value to the nominal pH value of the buffer solution (at the current temperature).

6 Press the <ENTER> key. SLO appears on the display.

Note

Here you can cancel the calibration procedure with <M>. This corresponds to a single-point calibration. The value of the zero point (ASY) is displayed. The sensor symbol shows the evaluation of the single-point calibration. Pressing <ENTER> displays the value of the slope (SLO).

ba75791e02 11/2008

Operation pH 3110

7 To continue the two-point calibration, thoroughly rinse the

combination electrode with deionized water.

8 If necessary, set the temperature of the second buffer solution

with <▲><▼>.

9 Immerse the combination electrode in the second buffer

solution.

10 Press the <ENTER> key. The second pH value appears on the

display.

11 When the measured value is stable,

using <▲><▼>, set the measured value to the nominal pH value of the buffer solution (at the current temperature).

12 Press the <ENTER> key.

The value of the zero point (ASY) is displayed.

13 Press the <ENTER> key.

The value of the slope (SLO) is displayed.

14 Press the <ENTER> key.

The measuring mode is active.

Note

While the zero point (ASY) is being displayed, you can change the unit of the zero point with

While the slope (SLO) is being displayed, you can change the unit of the slope with The % display refers to the Nernst slope of 59.2 mV/pH at 25° C (100 x determined slope/Nernst slope).

The units of the zero point and slope can also be changed permanently in the measurement settings (see section 4.5.2).

<▲><▼>.

ba75791e02 11/2008

pH 3110 Operation

ConCal

mV/pH

ConCal

4.4 Downloading calibration data

You can download calibration data to the display as follows:

1 Pressing <CAL_> displays the calibration data (asymmetry).

Note

While the calibration data is displayed you can press <▲><▼> to switch over the unit of the zero point (ASY).

2 With <ENTER> display the slope.

Note

While the calibration data is displayed you can press <▲><▼> switch over the unit of the slope (SLO).

ba75791e02 11/2008

Operation pH 3110

4.5 Settings

You can adapt the meter to your individual requirements. The settings are done in the following menus:

z System settings (<ENTER

– Switch-off interval (t.Off)

z Measurement settings (<M

– Display of the buffer during calibration

(pH nominal value or measured voltage value in mV)

– Unit of the value for the slope (mV/pH or %)

– Unit of the value for the zero point (mV, pH)

– Measured value resolution, pH (0.000 / 0.00 / 0.0)

– Measured value resolution, U (0.0 / 0)

– Temperature unit (°C / °F)

– Calibration interval (Int.C [0 ... 999])

Note

You can exit the setting menu at any time by pressing <M>. Settings already modified and confirmed with <ENTER> are stored.

_>)

ba75791e02 11/2008

pH 3110 Operation

Time

4.5.1 System settings

The default setting is printed in bold.

Switch-off interval (t.Off) 10, 20, 30, 40, 50 min,

1, 2, 3, 4, 5, 10, 15, 20, 24 h

1 Open the menu for system settings with <ENTER_>.

The first system setting is displayed.

Switch-off interval (t.Off)

2 Set the switch-off interval with <▲><▼>.

3 Confirm with <ENTER>.

The system settings are completed. The meter switches to the measuring mode.

ba75791e02 11/2008

Operation pH 3110

AutoCal DIN

AutoCal TEC

4.5.2 Measurement settings

These settings apply to calibration and measurement (the default setting is printed in bold).

Display during calibration (BUFFER) pH (buffer nominal value),

U (combination electrode voltage)

Unit of the value for the slope (SLO) mV/pH, %

Display during

calibration

(bUFF)

Unit of the value for the zero point (ASY)

Measured value resolution, pH 0.000 , 0.00 , 0.0

Measured value resolution, U 0.0 , 0

Temperature unit (UnIt) °C, °F

Calibration interval (Int.C) 0 ... 7 ... 999 d

1 With <M_> open the menu for measurement and calibration

settings. The first setting is displayed.

mV, pH

2 Using <▲><▼>, select the pH or U display during calibration.

3 Confirm with <ENTER>.

SLO, the unit of the value for the slope (mV/pH or %) is displayed.

ba75791e02 11/2008

pH 3110 Operation

mV/pH

Unit of the value for the

slope

(SLO)

4 Using <▲><▼>, select the unit for the slope.

5 Confirm with <ENTER>.

ASY, the unit of the value for the zero point (mV or pH) is displayed.

Unit of the value for the

zero point

(ASY)

6 Using <▲><▼>, select the unit for the zero point.

7 Confirm with <ENTER>.

res, the resolution of the pH display (0.0, 0.00 or 0.000) appears on the display.

ba75791e02 11/2008

Operation pH 3110

ooo

pH resolution

(res)

8 Select the resolution for the pH display with <▲><▼>.

9 Confirm with <ENTER>.

res, the resolution of the voltage display (0.0, 0.00 or 0.000) appears on the display.

U resolution

(res)

10 Using <▲><▼>, select the unit for the voltage display.

11 Confirm with <ENTER>.

Unit, the setting of the unit of the temperature value is displayed.

ba75791e02 11/2008

pH 3110 Operation

Time

AutoCal DIN

AutoCal TEC

Temperature unit (Unit)

12 Using <▲><▼>, toggle between °C and °F.

13 Confirm with <ENTER>.

Int.C, the setting of the calibration interval is displayed.

Calibration

interval

(Int.C)

14 Set the interval with <▲><▼>.

15 Confirm with <ENTER>.

The measurement settings are completed. The meter switches to the measuring mode.

ba75791e02 11/2008

Operation pH 3110

4.6 Reset

4.6.1 Resetting calibration values

This function resets the calibration values to the default condition. All other meter settings are retained.

Calibration values in the

default condition

Resetting calibration

values

Zero point 0 mV (pH 7.000)

Slope -59.16 mV/pH (100 %)

Note

The measuring system is not calibrated after a reset. Before measuring, recalibrate the meter.

1 Press <On/Off_> to open the menu for the reset of the

calibration data. Init.C is displayed.

2 Press <▲><▼> to display no or YES.

YES: Reset the calibration values. no: Retain the calibration values.

3 Confirm with <ENTER>.

The menu is finished. The meter switches to the measuring mode.

ba75791e02 11/2008

pH 3110 Operation

4.6.2 Resetting all meter settings

This function resets all meter settings to the default condition. The relevant values are given in the following sections:

System settings section 4.5.1

Measurement settings section 4.5.2

Resetting the meter

settings

1 Switch on the meter with <On/Off>.

The display test appears briefly on the display.

2 During the display test, press <M> to open the menu for the

reset of the meter settings. Init is displayed.

3 Press <▲><▼> to display no or YES.

YES: Reset the meter settings. no: Retain the meter settings.

ba75791e02 11/2008

4 Confirm with <ENTER>.

The menu is finished. The meter switches to the measuring mode.

Note

The measuring system is not calibrated after a reset. Before measuring, recalibrate the meter.

Operation pH 3110

ba75791e02 11/2008

pH 3110 Maintenance, cleaning, disposal

5 Maintenance, cleaning, disposal

5.1 Maintenance

The only maintenance activity required is replacing the batteries.

Note

See the relevant operating manuals of the combination electrodes for instructions on maintenance.

5.1.1 Replacing the batteries

1 Unscrew the two screws (1) on the underside of the meter.

2 Open the battery compartment (2) on the underside of the

meter.

ba75791e02 11/2008

3 Remove the four batteries from the battery compartment.

4 Place four new batteries (type Mignon AA) in the battery

compartment.

Note

Alternatively, you can also use Ni-MH rechargeable batteries (type Mignon AA). In order to charge the batteries, an external charging device is required.

Caution

Make sure that the poles of the batteries are positioned correctly. The

± signs on the batteries must correspond to the ± signs in the

battery compartment.

Maintenance, cleaning, disposal pH 3110

5 Close the battery compartment (2) and tighten the screws (1).

5.2 Cleaning

Occasionally wipe the outside of the meter with a damp, lint-free cloth. Disinfect the housing with isopropanol as required.

Caution

The housing is made of synthetic material (ABS). Thus, avoid contact with acetone or similar detergents that contain solvents. Remove any splashes immediately.

5.3 Packing

This meter is sent out in a protective transport packing. We recommend: Keep the packing material. The original packing protects the meter against damage during transport.

5.4 Disposal

Note

This meter contains batteries. Batteries that have been removed must only be disposed of at a recycling facility set up for this purpose or via the retail outlet. It is illegal to dispose of them in household refuse.

ba75791e02 11/2008

pH 3110 What to do if...

6 What to do if...

Error message

OFL, UFL

Error message

CalError

Cause Remedy

pH combination electrode:

– Measured value outside the

measuring range

– Air bubble in front of the

diaphragm

– Air in the diaphragm – Extract air or moisten

– Cable broken – Replace combination

– Gel electrolyte dried out – Replace combination

Cause Remedy

pH combination electrode:

– The values determined for zero

point and slope of the combination electrode are outside the allowed limits.

– Use suitable combination

electrode

– Remove air bubble

diaphragm

electrode

– Recalibrate

ba75791e02 11/2008

– Diaphragm contaminated – Clean diaphragm

– Combination electrode broken – Replace combination

electrode

Buffer solutions

– Incorrect buffer solutions – Change calibration

procedure

– Buffer solutions too old – Use only once.

Note the shelf life

– Buffer solutions depleted – Change solutions

What to do if... pH 3110

No stable measured

Cause Remedy

value

pH combination electrode:

– Diaphragm contaminated – Clean diaphragm

– Membrane contaminated – Clean membrane

Test sample:

– pH value not stable – Measure with air excluded if

necessary

– Temperature not stable – Adjust temperature if

necessary

Sensor symbol flashes

Display,

LoBat

Combination electrode + test sample:

– Conductivity too low – Use suitable combination

electrode

– Temperature too high – Use suitable combination

electrode

– Organic liquids – Use suitable combination

electrode

Cause Remedy

– Calibration interval expired – Recalibrate the measuring

system

Cause Remedy

– Batteries almost empty – Replace the batteries (see

section 5.1 M

AINTENANCE)

ba75791e02 11/2008

pH 3110 What to do if...

Obviously incorrect

measured values

Meter does not react to

keystroke

You want to know which

software

version is in the meter

Cause Remedy

pH combination electrode:

– pH combination electrode

unsuitable

– Temperature difference

between buffer and test sample

– Use suitable combination

electrode

– Adjust temperature of buffer

or sample solutions

too high

– Measurement procedure not

– Follow special procedure

suitable

Cause Remedy

– Operating condition undefined

or EMC load unallowed

– Processor reset:

Press the <ENTER> and

simultaneously

Cause Remedy

– E. g., a question by the service

department

– Switch on the meter.

During the display test, display the software version with <ENTER>.

key

ba75791e02 11/2008

What to do if... pH 3110

ba75791e02 11/2008

pH 3110 Technical data

7 Technical data

7.1 General data

Dimensions approx. 240 x 190 x 80 mm

Weight approx. 0.4 kg

Mechanical structure Type of protection IP 67

Electrical safety Protective class III

Test certificates CE

Ambient

conditions

Storage - 25 °C ... + 65 °C

Operation -10 °C ... + 55 °C

Climatic class 2

Power

Batteries 4 x 1.5 V alkali-manganese batteries,

supply

Rechargeable batteries

Operational life Approx. 2500 h operating hours (batteries)

Sensor input Input resistance > 5 * 10

Input current < 1 * 10

Guidelines

EMC EC directive 2004/108/EC

and norms used

Meter safety EC directive 2006/95/EC

Climatic class VDI/VDE 3540

type AA

4 x 1,2 V NiMH rechargeable batteries, type AA (no charging function)

ohm

-12

EN 61326-1 EN 61000-3-2 EN 61000-3-3 FCC Class A

EN 61010-1

ba75791e02 11/2008

IP protection EN 60529

Technical data pH 3110

7.2 Measuring ranges, resolution, accuracy

Measuring ranges,

resolution

Variable Measuring range Resolution

pH - 2.0 ... + 20.0 0.1

- 2.00 ... + 20.00 0.01

- 2.000 ... + 19.999 0.001

U [mV] - 1200.0 ... + 1200.0 0.1

- 2000 ... + 2000 1

T [°C] - 5.0 ... + 105.0 0.1

T [°F] 23.0 ... + 221.0 0.1

Manual

temperature input

Variable Range Increment

[°C] - 25 ... + 130 1

manual

[°F] -13 ... + 266 1

manual

Accuracy (± 1 digit) Variable Accuracy Temperature of the test

sample

pH / range *

- 2.0 ... + 20.0 ± 0.1 + 15 °C ... + 35 °C

- 2.00 ... + 20.00 ± 0.01 + 15 °C ... + 35 °C

- 2.000 ... + 19.999 ± 0.005 + 15 °C ... + 35 °C

U [mV] / range

- 2000 ... + 2000 ± 1 + 15 °C ... + 35 °C

-1200.0 ... +1200.0 ± 0.3 + 15 °C ... + 35 °C

T [°C] / temperature sensor

NTC 30 ± 0.1

PT 1000 ± 0.1

* when measuring in a range of ± 2 pH around a calibration point

Note

The accuracy values specified here apply exclusively to the meter. The accuracy of the combination electrodes and buffer solutions has to be taken into account additionally.

ba75791e02 11/2008

pH 3110 Lists

8Lists

This chapter provides additional information and orientation aids.

Specialist terms The glossary briefly explains the meaning of the specialist terms.

However, terms that should already be familiar to the target group are not described here.

Index The index helps you to find the topics that you are looking for.

Glossary

Adjusting To manipulate a measuring system so that the relevant value (e. g. the

displayed value) differs as little as possible from the correct value or a value that is regarded as correct, or that the difference remains within the tolerance.

Asymmetry see zero point

AutoRange Name of the automatic selection of the measuring range.

AutoRead Function to control the measured value stability.

Calibration Comparing the value from a measuring system (e. g. the displayed

value) to the correct value or a value that is regarded as correct. Often, this expression is also used when the measuring system is adjusted at the same time (see adjusting).

Electromotive force of

a combination

electrode

Junction The junction is a porous body in the housing wall of reference

Measured parameter The measured parameter is the physical dimension determined by

The electromotive force U of the combination electrode is the measurable electromotive force of an electrode in a solution. It equals the sum of all the galvanic voltages of the electrode. Its dependency on the pH results in the electrode function, which is characterized by the parameters, slope and zero point.

electrodes or electrolyte bridges. It arranges the electrical contact between two solutions and makes the electrolyte exchange more difficult. The expression, junction, is also used for ground or junctionless transitions.

measuring, e. g. pH, conductivity or D.O. concentration.

ba75791e02 11/2008

Lists pH 3110

Measured value The measured value is the special value of a measured parameter to

be determined. It is given as a combination of the numerical value and unit (e. g. 3 m; 0.5 s; 5.2 A; 373.15 K).

Molality Molality is the quantity (in Mol) of a dissolved substance in 1000 g

solvent.

ORP voltage The ORP is caused by oxidizing or reducing substances dissolved in

water, if these substances become effective at an electrode surface (e. g. a gold or platinum surface).

pH value The pH is a measure of the acidic or basic effect of an aqueous

solution. It corresponds to the negative decadic logarithm of the molal hydrogen ions activity divided by the unit of the molality. The practical pH value is the value of a pH measurement.

Potentiometry Name of a measuring technique. The signal (depending on the

measured parameter) of the electrode is the electrical potential. The electrical current remains constant.

Reset Restoring the original condition of all settings of a measuring system.

Resolution Smallest difference between two measured values that can be

displayed by a measuring instrument.

Slope The slope of a linear calibration function.

Standard solution The standard solution is a solution where the measured value is

known by definition. It is used to calibrate a measuring system.

Test sample Designation of the test sample ready to be measured. Normally, a test

sample is made by processing the original sample. The test sample and original sample are identical if the test sample was not processed.

Zero point The zero point of a pH electrode is the pH value at which the

electromotive force of the pH electrode at a specified temperature is zero. Normally, this is at 25 °C.

ba75791e02 11/2008

pH 3110 Lists

Index

Authorized use . . . . . . . . . . . . . . . . . . . . . . 10

AutoCal . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

AutoRead . . . . . . . . . . . . . . . . . . . . . . . . . . 16

Battery compartment . . . . . . . . . . . . . . 13, 37

Baud rate setting . . . . . . . . . . . . . . . . . . . . 29

Calibration . . . . . . . . . . . . . . . . . . . . . . . . . 19

Calibration evaluation

pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

Calibration interval . . . . . . . . . . . . . . . . . . . 21

Calibration points

pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

ConCal . . . . . . . . . . . . . . . . . . . . . . . . . 19, 24

Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Energy saving feature . . . . . . . . . . . . . . . . 14

Initial commissioning . . . . . . . . . . . . . . . . . 14

Interval

Calibration . . . . . . . . . . . . . . . . . . . . . . 21

Precautions . . . . . . . . . . . . . . . . . . . . . . . . . 9

Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

All meter settings . . . . . . . . . . . . . . . . . 35

Calibration values . . . . . . . . . . . . . . . . 34

Resolution setting . . . . . . . . . . . . . 30, 31, 32

Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Scope of delivery . . . . . . . . . . . . . . . . . . . . 13

Single-point calibration . . . . . . . . . 19, 23, 25

Slope

pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

Socket field . . . . . . . . . . . . . . . . . . . . . . . . . 8

Stability control . . . . . . . . . . . . . . . . . . . . . 16

Two-point calibration . . . . . . . . . . . . . . . . . 19

ConCal . . . . . . . . . . . . . . . . . . . . . . . . . 24

Zero point of pH combination electrode . . . 19

Keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

LoBat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40

Measurement accuracy . . . . . . . . . . . . . . . 21

Operation location . . . . . . . . . . . . . . . . . . . 14

Operational safety . . . . . . . . . . . . . . . . . . . 10

ORP electrode . . . . . . . . . . . . . . . . . . . . . . 18

ORP voltage . . . . . . . . . . . . . . . . . . . . . . . . 18

ba75791e02 11/2008

Lists pH 3110

ba75791e02 11/2008

Wissenschaftlich-Technische Werkstätten GmbH

Dr.-Karl-Slevogt-Straße 1 D-82362 Weilheim

Germany

Tel: +49 (0) 881 183-0

+49 (0) 881 183-100 Fax: +49 (0) 881 183-420 E-Mail: Info@WTW.com Internet: http://www.WTW.com

Xylem PH3110 User Manual

Specifications and Main Features

Frequently Asked Questions

User Manual

1Overview

1.1 Keypad

1.2 Display

1.3 Socket field

2 Safety

2.1 Authorized use

2.2 General safety instructions

3 Commissioning

3.1 Scope of delivery

3.2 Initial commissioning

3.2.1 Inserting the batteries

3.2.2 Switching on the meter

4 Operation

4.1 General operating principles

4.1.1 Operating modes

4.1.2 Operation

4.2 Measuring

4.2.1 Measuring the pH value

4.2.2 Measuring the ORP

4.3 Calibration

4.3.1 Calibration interval (Int.C)

4.3.2 Automatic calibration (AutoCal)

4.3.3 Conventional calibration (ConCal)

4.4 Downloading calibration data

4.5 Settings

4.5.1 System settings

4.5.2 Measurement settings

4.6 Reset

4.6.1 Resetting calibration values

4.6.2 Resetting all meter settings

5 Maintenance, cleaning, disposal

5.1 Maintenance

5.1.1 Replacing the batteries

5.2 Cleaning

5.3 Packing

5.4 Disposal

6 What to do if...

7 Technical data

7.1 General data

7.2 Measuring ranges, resolution, accuracy

8Lists