The LFOx1400(-ID) is a modular sensor for conductivity, dissolved oxygen
(DO) and temperature. It consists of two basic components:
Conductivity basic module, according to the quadripole measuring princi-
ple, with integrated temperature sensor
Removable dissolved oxygen module, according to the galvanic measur-
ing principle
Structure of the
LFOx1400(-ID)
1Voltage electrode (inside, 2x)
2Current electrode (ring, 2x)
3Temperature sensor in a graphite enclosure
4Shaft
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5Connection head
6Membrane cap (filled with electrolyte solution)
7Gold working electrode (cathode)
8Insulator
9Lead counter electrode (anode)
10 Screw thread base with ventilation area
11 Cap nut
12 Plug connection
13 Closing cap for conductivity basic module
14 Closing cap for DO module
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LFOx1400(-ID)Overview
03360013
123
0342A007
1234
The conductivity basic module can be used as an independent conductivity
measuring cell. For this purpose, unscrew the DO module and close the open
plug connection with a closing cap.
The DO module is connected to the conductivity basic module via a watertight, three-pole plug connection. The conductivity basic module measures
the temperature, which is required for the determination of the DO content.
For this reason the DO module only works in conjunction with the conductivity
basic module.
Automatic sensor
recognition
Recommended
fields of
application
In the plug connector of the LFOx1400-ID sensor, data is stored for the automatic sensor recognition function. Among other, this data includes the sensor
type and series number. Besides, the calibration data is written in the sensor
with every calibration procedure. When the sensor is connected, the data is
called up by the meter and used for measurement and measured value documentation. The correct data is always used automatically if the sensor is operated with several meters because the data is stored in the sensor.
To be able to use the automatic sensor recognition function, a meter is
required that supports the function. More information on the automatic sensor
recognition function is given in the operating manual of the meter.
On site measurements in rivers, lakes and wastewater
Ground water measurements
Applications in water laboratories
1.2Instrument identification
A series number is printed on both LFOx1400(-ID) modules. Keep these
numbers ready if you have questions to ask the SI Analytics service
department. The series numbers contain the following information:
Conductivity basic
Dissolved oxygen
(DO) module
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The number is printed on the shaft.
module
1 Manufacturing year 20... (example: 2003)
2 Calendar week of manufacturing (CW 36)
3 Sequential batch number (0013)
The number is printed on the cap nut.
1 Manufacturing year 20... (example: 2003)
2 Calendar week of manufacturing (CW 42)
3 Sensor type (type A)
4 Sequential batch number (007)
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SafetyLFOx1400(-ID)
2Safety
This operating manual contains special instructions that must be followed
during the operation of the sensor.
Always keep this operating manual in the vicinity of the sensor.
Special user
qualifications
General safety
instructions
The membrane cap of the DO module is filled with a small amount of an
alkaline electrolyte solution. All maintenance work that requires dealing with
the electrolyte solution must only be carried out by persons who know how to
deal with chemicals safely.
The individual chapters of this operating manual use safety labels like the one
below to indicate danger:
Caution
indicates instructions that must be followed precisely in order to avoid
slight injuries or damage to the instrument or the environment.
3Commissioning
3.1Scopes of delivery
3.1.1Scope of delivery of the LFOx1400(-ID)
LFOx1400(-ID) combination conductivity and DO sensor,
DO module filled with electrolyte solution and ready to use
1 closing cap for conductivity basic module
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1 closing cap for DO module
3 exchange membrane caps, Ox923
Calibration and storage vessel, OxiCal
Polishing strip, SF300
Electrolyte solution, Ox920
Cleaning solution, Ox921
Operating manual for LFOx1400(-ID)
Note
The membrane cap that is mounted on the DO sensor for delivery serves
mainly as a transport protection. Depending on the duration of the transport
and storage period, it may have a shortened operational lifetime. If the measuring system cannot be calibrated (error message on the instrument),
please proceed according to section section 5.3 DO
ELECTROLYTESOLUTIONANDMEMBRANECAP.
®
-CX
MODULE: CHANGINGTHE
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LFOx1400(-ID)Commissioning
3.1.2Scope of delivery of the conductivity basic module
Conductivity basic module
1 closing cap, mounted on the conductivity basic module
Operating manual for LFOx1400(-ID)
3.1.3Scope of delivery of the DO module
DO module, filled with electrolyte solution and operable
1 closing cap, mounted on the DO module
1 exchange membrane cap, Ox923
Polishing strip, SF300
Electrolyte solution, Ox920
Cleaning solution, Ox921
Operating manual for LFOx1400(-ID)
Note
The membrane cap that is mounted on the DO sensor for delivery serves
mainly as a transport protection. Depending on the duration of the transport
and storage period, it may have a shortened operational lifetime. If the measuring system cannot be calibrated (error message on the instrument),
please proceed according to section section 5.3 DO
ELECTROLYTESOLUTIONANDMEMBRANECAP.
MODULE: CHANGINGTHE
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CommissioningLFOx1400(-ID)
12
213
3.2Getting the sensor ready for measuring
3.2.1Measurements with the conductivity basic module
Make sure that the plug connection is tightly closed by the closing cap. When
mounted, the closing cap (1) must be screwed on up to the stop.
Before screwing on the closing cap, check the following points:
The sealing (2) must be clean and evenly positioned in the groove.
The plug connection and the inside of the closing cap must be clean.
Screwing on the
DO module
3.2.2Measurements with the combination sensor
Make sure that the DO module and conductivity basic module are screwed
together tightly. When mounted, the cap nut of the DO module has to be
screwed on up to the stop.
Before screwing on the DO module, check the following points:
The sealing (3) must be clean and evenly positioned in the groove.
The plug connection must be dry on both sides.
Position the DO module (1) on the conductivity basic module and carefully
and with slight pressure turn it until the guiding nib on the DO module locks
in place in the corresponding groove on the conductivity basic module.
Subsequently tighten the cap nut (2) up to the stop. The thread only snatches
if the DO module was correctly positioned.
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LFOx1400(-ID)Measuring / Operation
Unscrewing the
DO module
Unscrew the cap nut and remove the DO module from the conductivity basic
module.
Caution
Inappropriate handling can lead to the release of electrolyte solution.
When unscrewing the DO module only turn the cap nut (not the
membrane cap!).
3.2.3Preparing the measuring operation
Connect the sensor to the measuring instrument. The sensor is immediately
ready to measure. It is not necessary to polarize the DO module.
4Measuring / Operation
4.1Calibration
To calibrate for DO measurements, use the OxiCal®-CX calibration and
storage vessel. If the A 325/K or A 325/S armoring is used, you have to
remove the protective hood and fixing nut of the armoring first.
Minimum
approach flow for
DO measurements
When determining the cell constant, observe the respective minimum
immersion depth with the closing cap or D. O. module screwed on (important:
the temperature sensor must be submersed). The minimum immersion
depths are given in chapter 7 T
ECHNICALDATA.
Note
Please read the course of the calibration in the operating manual of the measuring instrument.
4.2Measuring
Please always observe the required minimum immersion depth and the
minimum approach flow that is important for DO measurements (see
chapter 7 T
The minimum flow can be provided in different ways, e. g.:
The flow of the water to be measured is sufficient (aeration tank, water
pipe, stream)
Slowly pull the sensor through the water by hand (lake, container), or
Use a flow aid, e. g. a magnetic stirrer with stirring device or a battery stir-
rer (see chapter 8 W
ECHNICALDATA).
EARPARTSANDACCESSORIES)
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Note
When using the BR 325 battery stirrer, please make sure that the protective
pipe already has the groove in the area of the conductivity basic module (from
the year of manufacture, 2004).
33
Maintenance, cleaning, replacementLFOx1400(-ID)
12
4.3Storage
Always store the sensor with the DO module in the calibration vessel at a
temperature of 0 to +50 °C. Make sure that the sponge in the calibration vessel is always moist.
Storage in the
calibration vessel,
OxiCal
®
-CX
Moisten the sponge:
Remove the cap (1).
Take out the sponge (2), wet it, then slightly squeeze it out.
Reinsert the sponge and close the calibration vessel with the cap.
5Maintenance, cleaning, replacement
5.1General maintenance instructions
For your safetyNote the following safety instructions when handling electrolyte and cleaning
solutions:
Caution
The Ox920 electrolyte solution irritates eyes and skin. When dealing
with the Ox920 electrolyte solution, observe the following points:
During working activities, always wear suitable protective gloves
and protective goggles/face shield.
If it comes into contact with the skin, rinse thoroughly with water and
immediately change contaminated clothing.
If it comes into contact with the eyes, rinse thoroughly with water
and consult a doctor.
Follow the safety datasheet.
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LFOx1400(-ID)Maintenance, cleaning, replacement
Caution
The Ox921 cleaning solution irritates eyes and skin. When dealing with
the Ox921 cleaning solution, observe the following points:
During working activities, always wear suitable protective gloves
and protective goggles/face shield.
If it comes into contact with the skin, rinse thoroughly with water and
immediately change contaminated clothing.
If it comes into contact with the eyes, rinse thoroughly with water
and consult a doctor.
Follow the safety datasheet.
Caution
Before all maintenance activities, disconnect the sensor from the
instrument.
Note
Information on how to order wear parts and maintenance means can be
found in chapter 8 W
EARPARTSANDACCESSORIES.
Maintenance
activities on the
DO module
Cleaning agents
For better handling, leave the DO module screwed on the conductivity basic
module. Thus, you can better immerse the sensor head in the electrolyte or
cleaning solution and the plug connection remains protected against
damage.
5.2Outside cleaning
ContaminationCleaning procedure
Lime sedimentsImmerse in acetic acid for 1 minute (volume
share = 20 %)
Fat/oilClean with warm water that contains
washing-up liquid
After cleaning, thoroughly rinse with deionized water and recalibrate if
necessary.
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35
Maintenance, cleaning, replacementLFOx1400(-ID)
5.3DO module: Changing the electrolyte solution and
membrane cap
Caution
Before starting to work with the sensor, please note the GENERAL
MAINTENANCEINSTRUCTIONS on page 34.
General
information
SI Analytics delivers the DO module ready to use (see section 3). The electrolyte solution and the membrane cap must only be replaced if:
a calibration error occurs and the membrane is heavily contaminated
the membrane is damaged
the electrolyte solution is exhausted.
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LFOx1400(-ID)Maintenance, cleaning, replacement
Ox921
H O
2
Changing the electrolyte solution and membrane cap
Unscrew the membrane cap.
Caution:
Electrolyte solution!
For disposal of the membrane
cap and electrolyte solution,
see section 5.7.
Immerse the sensor head including the counter electrode
in Ox921 cleaning solution.
Allow to react for 1 to 3 minutes.
Rinse the sensor head with
deionized water.
Thoroughly rinse the sensor
head with deionized water.
Carefully rub and dry the
counter electrode with a lintfree paper towel.
Water the counter electrode in
deionized water for at least
10 minutes.
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37
Maintenance, cleaning, replacementLFOx1400(-ID)
Ox920
Ox920
Ventilation area
points upwards
4mm
Carefully shake off the drops
of water.
Thoroughly rinse the sensor
head with electrolyte solution.
Fill a new membrane cap with
Ox920 electrolyte solution.
Hold the sensor inclined and
screw on the membrane cap
fingertight using a paper towel. Excess electrolyte solution
is forced out of the ventilation
area.
Remove any air bubbles by
carefully tapping the membrane cap. Additionally, you
can prevent air bubbles by
throwing the first filling away
and refilling the membrane
cap.
Check the filling:
Inspect the face surface. No
air bubbles may be present
within the dashed circle. Air
bubbles outside this area do
not interfere.
Note
For measurements under high pressure the filling must be completely free of air bubbles.
Readiness to measureThe DO module is ready for operation after approx. 30 to 50 min-
utes. Subsequently calibrate the sensor for DO measurements.
Note
If you want to measure very low DO concentrations (< 0.5 % saturation), we recommend to let the sensor rest overnight and then
calibrate it.
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LFOx1400(-ID)Maintenance, cleaning, replacement
SF300
Ox921
5.4DO module: Cleaning the electrodes
Caution
Before starting to work with the sensor, please note the GENERAL
MAINTENANCEINSTRUCTIONS on page 34.
General
information
Cleaning is only required in cases of slopes too small or too large (sensor
cannot be calibrated) that cannot be resolved by changing the membrane cap
and electrolyte solution.
Cleaning the electrodes
Unscrew the membrane cap.
Caution:
Electrolyte solution!
For disposal of the membrane
cap and electrolyte solution,
see section 5.7.
Rinse the sensor head with
deionized water.
Using the rough side of the
wet SF300 polishing strip,
polish off any contamination
from the gold working electrode using light pressure.
Caution:
Do not use any conventional sandpaper or glassfiber brushes.
Rinse the sensor head with
deionized water.
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Wipe the counter electrode
with a lint-free paper towel
and carefully remove any
loose white deposits.
Immerse the sensor head including the counter electrode
in Ox921 cleaning solution.
Allow to react for 1 to 3 minutes.
39
Maintenance, cleaning, replacementLFOx1400(-ID)
H O
2
Ox920
Ox920
Ventilation area
points upwards
4mm
Thoroughly rinse the sensor
head with deionized water.
Fill a new membrane cap with
Ox920 electrolyte solution.
Water the counter electrode in
deionized water for at least
10 minutes.
Remove any air bubbles by
carefully tapping the membrane cap. Additionally, you
can prevent air bubbles by
throwing the first filling away
and refilling the membrane
cap.
Carefully shake off the drops
of water.
Rinse the sensor head with
electrolyte solution.
Hold the sensor inclined and
screw on the membrane cap
fingertight using a paper towel. Excess electrolyte solution
is forced out of the ventilation
area.
40
Check the filling:
Inspect the face surface. No
air bubbles may be present
within the dashed circle. Air
bubbles outside this area do
not interfere.
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LFOx1400(-ID)Maintenance, cleaning, replacement
Note
For measurements under high pressure the filling must be completely free of
air bubbles.
Readiness to
measure
After approx. 30 to 50 minutes, the sensor is ready for operation. Subsequently calibrate the sensor.
Note
If you want to measure very low DO concentrations (< 0.5 % saturation), we
recommend to let the sensor rest overnight and then calibrate it.
5.5Checking the DO module for freedom from zero-current
The DO module is free from zero-current. Checking the module for freedom
from zero-current is only necessary in the case of malfunctions that cannot
be remedied by exchanging the electrolyte solution and membrane cap or by
cleaning the electrodes.
There are two possibilities to check the DO module for freedom from zerocurrent:
Measurement in a nitrogen atmosphere (recommended method)
Measurement in a sodium sulfite solution according to DIN EN 25814/
ISO 5814.
Caution
If you check the sensor according to DIN EN 25814/ISO 5814, do not
leave the sensor in the sodium sulfite solution for more than 2 minutes.
Danger of sensor poisoning!
Test criterionThe DO module is OK if the measuring instrument displays < 1 % DO
saturation after 2 minutes.
5.6Aging of the conductivity measuring cell
Normally, the conductivity measuring cell does not age. Special measuring
media (e.g. strong acids and lyes, organic solvents) or too high temperatures
shorten the operational lifetime considerably or damage the measuring cell.
The warranty does not cover cases where such conditions cause failure or
mechanical damage.
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41
Maintenance, cleaning, replacementLFOx1400(-ID)
5.7Disposal
Caution
The Ox920 electrolyte solution irritates eyes and skin. When dealing
with the Ox920 electrolyte solution, observe the following points:
During working activities, always wear suitable protective gloves
and protective goggles/face shield.
If it comes into contact with the skin, rinse thoroughly with water and
immediately change contaminated clothing.
If it comes into contact with the eyes, rinse thoroughly with water
and consult a doctor.
Follow the safety datasheet.
Conductivity basic
module, DO
module and
membrane cap
Electrolyte
solution
For disposal, unscrew the membrane cap from the DO module. Then rinse
the entire sensor and the membrane cap with water.
We recommend to dispose of the conductivity basic module and the DO
module without membrane cap as electronic waste. The membrane cap may
be disposed of with the household refuse.
Disposal according to the safety data sheet.
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LFOx1400(-ID)What to do if...
6What to do if...
6.1Error symptoms of DO measurement
Error symptomCauseRemedy
The sensor is in the air
and the display shows
0.0 mg/l or 0 % O
2
The sensor cannot be
calibrated
The sensor still cannot
be calibrated after
changing the electrolyte
and membrane cap
Incorrect temperature
display
Mechanical damage to
the sensor
– No connection between
measuring instrument and sensor
– Cable defective
– No electrolyte in the membrane
cap
– Contaminated membrane cap
– Electrolyte depleted
– Contaminated electrodes or
sensor toxification
– membrane cap not screwed on
tight enough
– The temperature sensor of the
conductivity basic module was not
immersed deep enough in the
measuring solution
– Temperature sensor defective
– Check connection between
measuring instrument and sensor
– Replace and refill the membrane
cap (see section 5.3)
– Replace and refill the membrane
cap (see section 5.3)
Subsequently, wait for 30 to
50 min and recalibrate.