Xylem Lab 860 User Manual
Operating manual
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pH
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Lab 860
Lab 860
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Laboratory pH meter
Lab 860
Accuracy when going to
press
Warranty We guarantee the instrument described for 3 years from the date of
The use of advanced technology and the high quality standard of our
instruments are the result of continuous development. This may result
in differences between this operating manual and your instrument.
Also, we cannot guarantee that there are absolutely no errors in this
manual. Therefore, we are sure you will understand that we cannot
accept any legal claims resulting from the data, figures or descriptions.
purchase.
The instrument warranty covers manufacturing faults that are
discovered within the warranty period.
The warranty does not cover components that are replaced during
maintenance work, e. g. batteries.
The warranty claim extends to restoring the instrument to readiness for
use but not, however, to any further claim for damages. Improper
handling or unauthorized opening of the instrument invalidates any
warranty claim.
To ascertain the warranty liability, return the instrument and proof of
purchase together with the date of purchase freight paid or prepaid.
Copyright
© 2010, SI Analytics GmbH
Reprinting - even in the form of excerpts - is only allowed with the
explicit written authorization of SI Analytics GmbH.
Printed in Germany.
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Lab 860
KONFORMITÄTSERKLÄRUNG
DECLARATION OF CONFORMITY
DÉCLARATION DE CONFORMITÉ
Wir erklären in alleiniger
Verantwortung, dass das
Produkt
pH-Meter
Lab 860
auf das sich diese Erklärung
bezieht, übereinstimmt mit
den Angaben im Kapitel
We declare under our sole
responsibility that the
product
pH meter
Lab 860
to which this declaration
relates is in conformity with
the specifications in the
chapter
Nous déclarons sous notre
seule responsabilité que le
produit
pH-mètre
Lab 860
auquel se réfère cette
déclaration est conforme aux
indications du chapitre
30. Oktober, October 30, 30 octobre 2009
AGQSF 0000-A101-01/091030
SI Analytics GmbH
Hattenbergstr. 10
D-55122 Mainz
Deutschland, Germany, Allemagne
Technische Daten
pH-Meter
Lab 860
30. Oktober 2009
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Lab 860
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Lab 860 Contents
Lab 860 - Contents
1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.3 Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 12
3 Commissioning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.1 Scope of delivery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.2 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
4 Operation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.1 Switching on the meter . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.2 General operating principles . . . . . . . . . . . . . . . . . . . . . . 18
4.2.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . 18
4.2.2 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.3 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
4.3.1 Measuring the pH value . . . . . . . . . . . . . . . . . . . 20
4.3.2 Measuring the ORP . . . . . . . . . . . . . . . . . . . . . . 21
4.4 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
4.4.1 Calibration interval (Int.C) . . . . . . . . . . . . . . . . . 27
4.4.2 Automatic calibration (AutoCal) . . . . . . . . . . . . . 28
4.5 Saving . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
4.5.1 Manual storage . . . . . . . . . . . . . . . . . . . . . . . . . 31
4.5.2 Automatic storage at intervals (AutoStore) . . . . 33
4.5.3 Downloading the data memory . . . . . . . . . . . . . 35
4.5.4 Erasing the data memory . . . . . . . . . . . . . . . . . . 36
4.5.5 Downloading calibration data . . . . . . . . . . . . . . . 36
4.6 Transmitting data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
4.6.1 Options for data transmission . . . . . . . . . . . . . . 39
4.6.2 Automatically downloading measurement
datasets at intervals . . . . . . . . . . . . . . . . . . . . . . 40
4.6.3 Downloading stored measurement datasets . . . 40
4.6.4 Downloading calibration data . . . . . . . . . . . . . . . 40
4.6.5 RS232 interface . . . . . . . . . . . . . . . . . . . . . . . . . 40
4.6.6 USB interface (device) . . . . . . . . . . . . . . . . . . . . 41
4.6.7 Operation with MultiLab pilot . . . . . . . . . . . . . . . 41
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Contents Lab 860
4.7 Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43
4.7.1 System settings . . . . . . . . . . . . . . . . . . . . . . . . . 44
4.7.2 Measurement settings . . . . . . . . . . . . . . . . . . . . 46
4.7.3 Interval for automatic data transmission . . . . . . . 50
4.8 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
4.8.1 Resetting calibration values . . . . . . . . . . . . . . . . 51
4.8.2 Resetting all meter settings . . . . . . . . . . . . . . . . 52
5 Maintenance, cleaning, disposal . . . . . . . . . . . . . . . . . 53
5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
5.1.1 Replacing the batteries. . . . . . . . . . . . . . . . . . . . 53
5.2 Cleaning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
5.3 Packing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
5.4 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
7 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
7.1 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
7.2 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . 61
8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
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Lab 860 Overview
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pH
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TP
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1Overview
The compact Lab 860 precision pH meter enables you to perform pH
measurements rapidly and reliably. The Lab 860 provides the
maximum degree of operating comfort, reliability and measuring
certainty for all applications.
The proven calibration procedures and special stability control function
(SC) support your work with the pH meter.
1 Keypad
2 Display
3 Socket field
Note
The meter is also available as part of individual Sets of equipment.
You will find information on this and other accessories in the SI
Analytics GmbH laboratory catalog or via the Internet.
Note
If you need further information or application notes, you can obtain the
following material from SI Analytics GmbH:
z Application reports
z pH primers
z Safety datasheets.
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Overview Lab 860
STO
RCL
MODE SC
CAL
MODE
CAL
SC
STO
STO
RCL
1.1 Keypad
In this operating manual, keys are indicated by brackets <..> .
The key symbol (e.g. <OK>) indicates a keystroke in this operating
manual.
<On/Off>:
<On/Off
<MODE>:
<MODE
<CAL>:
<CAL
<SC>:
<SC
<STO>:
<STO
<RCL>:
<RCL
<▲>: Increment values, scroll
_>:
_>:
_>:
_>:
_>:
_>:
Switch meter on / off
Reset calibration values
Select measured parameter
Open setting menu for calibration and
measurement
Call up calibration procedure
Display calibration data
Activate / deactivate stability control
Set interval for data transmission
Store measured value
Set interval for automatic storage in
memory
Display / transmit measured values and
calibration records
Erase stored measured values
8
<▼>: Decrement values, scroll
<OK>:
_>:
<OK
Confirm entries
Open setting menu for system settings
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Lab 860 Overview
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°
C
°F
U pH
%
LoBat
Auto
Store
SC
TP
CalError
Time
Day.Month
Year
Baud
No.
Ident
mV/pH
RCL
SET
BUFFER
AutoCal
Status display
indicator
CalClock (calibration
interval and sensor
evaluation)
Measured value
display
Temperature display
and further function
indicators
1.2 Display
Function display
indicators
[SET] During calibration: number of the buffer set
[BUFFER] During calibration: number of the buffer
[AutoCal] Calibration with automatic buffer recognition
[Auto][Store] Automatic storing is switched on
[CalError] An error occurred during calibration
[LoBat] With battery operation: batteries almost empty
[SC] Stability control is active
[RCL] Memory display / memory download
[TP] Temperature measurement active
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Overview Lab 860
1
2
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5
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1.3 Socket field
Connectors:
1 pH electrode
2 Reference electrode
3 Temperature sensor
4 USB interface
5 Power pack
6 RS 232 interface
CAUTION
Only connect sensors to the meter that cannot return any voltages
or currents that are not allowed (> SELV and > current circuit with
current limiting).
Almost all sensors - in particular SI Analytics GmbH sensors fulfill these conditions.
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Lab 860 Safety
2 Safety
This operating manual contains basic instructions that you must follow
during the commissioning, operation and maintenance of the meter.
Consequently, all responsible personnel must read this operating
manual before working with the meter.
The operating manual must always be available within the vicinity of the
instrument.
Target group The meter was developed for work in the laboratory.
Thus, we assume that, as a result of their professional training and
experience, the operators will know the necessary safety precautions
to take when handling chemicals.
Safety instructions Safety instructions in this operating manual are indicated by the
warning symbol (triangle) in the left column. The signal word (e.g.
"Caution") indicates the level of danger:
Further notes
WARNING
indicates instructions that must be followed precisely in order to
avoid possibly great dangers to personnel.
CAUTION
indicates instructions that must be followed precisely in order to
avoid the possibility of slight injuries or damage to the instrument
or the environment.
Note
indicates notes that draw your attention to special features.
Note
indicates cross-references to other documents, e.g. operating
manuals.
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Safety Lab 860
2.1 Authorized use
This meter is authorized exclusively for pH and ORP measurements in
the laboratory.
The technical specifications as given in chapter 7 T
ECHNICAL DATA
(page 59) must be observed. Only the operation and running of the
meter according to the instructions given in this operating manual is
authorized.
Any other use is considered unauthorized.
2.2 General safety instructions
This instrument is constructed and tested in compliance with the IEC
1010 safety regulations for electronic measuring instruments.
It left the factory in a safe and secure technical condition.
Function and
operational safety
The smooth functioning and operational safety of the meter can only be
guaranteed if the generally applicable safety measures and the specific
safety instructions in this operating manual are followed during
operation.
The smooth functioning and operational safety of the meter can only be
guaranteed under the environmental conditions that are specified in
chapter 7 T
ECHNICAL DATA (page 59).
If the instrument was transported from a cold environment to a warm
environment, the formation of condensate can lead to the faulty
functioning of the instrument. In this event, wait until the temperature of
the instrument reaches room temperature before putting the instrument
back into operation.
CAUTION
The meter is only allowed to be opened by personnel authorized
by SI Analytics GmbH.
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Lab 860 Safety
Safe operation If safe operation is no longer possible, the instrument must be taken out
of service and secured against inadvertent operation!
Safe operation is no longer possible if the meter:
z has been damaged in transport
z has been stored under adverse conditions for a lengthy period of
time
z is visibly damaged
z no longer operates as described in this manual.
If you are in any doubt, please contact the supplier of the instrument.
Obligations of the
purchaser
The purchaser of this meter must ensure that the following laws and
guidelines are observed when using dangerous substances:
z EEC directives for protective labor legislation
z National protective labor legislation
z Safety regulations
z Safety datasheets of the chemical manufacturers.
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Safety Lab 860
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Lab 860 Commissioning
3 Commissioning
3.1 Scope of delivery
z Lab 860 laboratory meter
z Power pack
z 4 batteries 1.5 V Mignon type AA
z USB cable with A plug and B plug
z Transparent cover
z Operating manual
z CD-ROM with USB driver
3.2 Initial commissioning
Perform the following activities:
Insert batteries
z Insert batteries
z Switch on the meter
z Set the date and time
z Connect the power pack (for line power operation only).
1 Open the battery compartment (1) on the underside of the
meter.
2 Place four batteries (type Mignon AA) in the battery
compartment.
3 Close the battery compartment (1).
The date (day) flashes in the display.
4 Set the date and time according to page 44.
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Commissioning Lab 860
1
CAUTION
Make sure that the poles of the batteries are the right way round.
The
± signs on the batteries must correspond to the ± signs in the
battery compartment.
Only use leakproof alkaline manganese batteries.
Switching on the meter
Setting the date and
time
Connecting the power
pack
1 Switch on the meter with <On/Off>.
A display test is briefly displayed.
2 See page 44.
You can either operate the measuring instrument with batteries or with
the plug-in power supply. The plug-in power supply supplies the
measuring instrument with low voltage (12 VDC). This saves the
batteries.
CAUTION
The line voltage at the operating site must lie within the input
voltage range of the original power pack (see page 59).
CAUTION
Use original power packs only (see page 59).
3 Insert the plug into the socket of the pH meter.
4 Connect the original power pack to an easily accessible power
outlet.
Note
You can carry out measurements without the power pack.
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Lab 860 Operation
4 Operation
4.1 Switching on the meter
1 Place the meter on a flat surface and protect it from intense
light and heat.
2 Press the <On/Off>
A display test is briefly displayed.
Subsequently, the meter switches to the measuring mode
(measured value display).
Note
The meter has an energy saving feature to avoid unnecessary battery
depletion during battery operation.
The energy saving feature switches off the meter if no key was pressed
during the specified interval (setting the switch-off interval, see
page 44).
The energy saving feature is not active:
z if the meter is supplied via the power pack or the USB interface
z if a PC is connected (with communication cable to RS232 interface)
z if the printer cable is connected (for external printers).
key.
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Operation Lab 860
4.2 General operating principles
This section contains basic information on the operation of the Lab 860.
4.2.1 Operating modes
The instrument has the following operating modes:
z Measurement
The display indicates the measurement data in the measured value
display
z Calibration
The display guides you thru a calibration procedure with calibration
information
z Storage
The meter stores measuring data automatically or manually
z Transmitting data
The meter transmits measuring data and calibration records to a
serial interface automatically or manually.
z Configuration
The system menu or a sensor menu with submenus, settings and
functions is displayed
4.2.2 Operation
Keys The meter is operated via keys. The keys can have different functions
with long or short keystrokes.
Functions Generally, with a short keystroke a function is carried out. A long
keystroke opens a setting menu.
In a setting menu, settings are selected with the <▲><▼> keys.
A setting is confirmed with <OK>. With confirming, the setting is
finished and the next setting is displayed.
Representation In this operating manual, keys are indicated by brackets <..> .
The key symbol (e.g. <OK>) generally indicates a short keystroke
(under 2 sec) in this operating manual. A long keystroke (approx.
2 sec) is indicated by the underscore behind the key symbol (e.g.
<OK
_>).
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Lab 860 Operation
4.3 Measuring
Preparatory activities Perform the following preparatory activities when you want to measure:
1 Connect an electrode to the meter.
2 Adjust the temperature of the buffer solutions or test solutions,
or measure the current temperature, if you measure without a
temperature sensor.
3 Calibrate or check the meter with the electrode.
4 Select the measured parameter with <MODE>.
Note
Incorrect calibration of pH electrodes leads to incorrect measured
values. Calibrate regularly before measuring.
CAUTION
When connecting an earthed PC/printer, measurements cannot be
performed in earthed media as incorrect values would result.
The RS232 and USB interfaces are not galvanically isolated.
Temperature sensor You can measure with or without a temperature sensor. If a
temperature sensor is connected, it is indicated on the display by TP.
Note
The pH meter automatically recognizes the type of the temperature
sensor used. Therefore, you can connect electrodes with an NTC30 or
Pt1000.
The temperature measurement is absolutely essential for a
reproducible pH measurement. If the measurement is made without a
temperature sensor, proceed as follows:
1 Measure the current temperature using a thermometer.
2 Set the temperature value with <▲><▼>.
Note
When calibrating without temperature sensor, also set the current
temperature of each buffer solution manually (see <▲><▼>).
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Operation Lab 860
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pH
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TP
4.3.1 Measuring the pH value
1 Perform the preparatory activities according to page 19.
2 Immerse the pH electrode in the test sample.
3 Using <MODE>, scroll as necessary until the measured
parameter pH is displayed.
Stability control SC
(drift control)
The stability control function (drift control) checks the stability of the
measurement signal. The stability has a considerable effect on the
reproducibility of the measured value.
For identical measurement conditions, the following criteria apply:
Drift within 15 sec < 0.02 pH units.
1 If necessary, call up the measured variable pH with <MODE>.
2With <SC>, activate the stability control function.
The SC function display indicator appears.
The current measured value is frozen (hold function).
3 Start measurement with stability control with <OK>.
SC flashes until a stable measured value is reached.
This measured value is downloaded to the interface.
4 If necessary, start the next measurement with stability control
with <OK>.
5 To terminate the stability control function: Press the <MODE>
or <SC>
key.
20
Note
The current measurement with stability control can be terminated at
any time (accepting the current value) by pressing <OK>.
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Lab 860 Operation
3
6
1
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U
°
C
TP
mV
4.3.2 Measuring the ORP
The meter can, in conjunction with an ORP electrode, measure the
ORP (mV) of a solution.
1 Perform the preparatory activities according to page 19.
2 Immerse the ORP electrode in the test sample.
3 If necessary, call up the measured parameter U with <MODE>.
4 Wait for a stable measured value.
Note
ORP electrodes are not calibrated. However, you can check ORP
electrodes using a test solution.
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Operation Lab 860
4.4 Calibration
Why calibrate? pH electrodes age. This changes the zero point (asymmetry) and slope
of the pH electrode. As a result, an inexact measured value is
displayed. Calibration determines the current values of the zero point
and slope of the electrode and stores them. Thus, you should calibrate
at regular intervals.
The calibration data is stored in the meter.
When do you have to
calibrate?
Buffer sets for
calibration
z After connecting another electrode
z If the CalClock has expired and flashes
You can use the buffer sets quoted in the table for an automatic
calibration. The pH values are valid for the specified temperature
values. The temperature dependence of the pH values is taken into
account during calibration.
No. Buffer set* pH values at
1 SI Analytics GmbH DIN buffers
according to DIN 19266/NBS
1.679
4.006
25 °C
6.865
9.180
12.454
2 SI Analytics GmbH Technical
buffers according to DIN 19267
2.000
4.010
25 °C
7.000
10.011
3 Merck1* 4.000
20°C
7.000
9.000
22
4 Merck2 * 1.000
6.000
8.000
13.000
5 Merck3 * 4.660
6.880
9.220
6 DIN 19267 * 1.090
4.650
6.790
9.230
7 Mettler Toledo USA * 1.679
4.003
7.002
10.013
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20°C
20°C
25 °C
25 °C
Lab 860 Operation
No. Buffer set* pH values at
8 Mettler Toledo TEC * 1.995
4.005
7.002
9.208
9 Fisher * 2.007
4.002
7.004
10.002
10 Fluka BS * 4.006
6.984
8.957
11 Radiometer * 1.678
4.005
7.000
9.180
12 Baker * 4.006
6.991
10.008
13 Metrohm * 3.996
7.003
8.999
25 °C
25 °C
25 °C
25 °C
25 °C
25 °C
14 Beckman * 4.005
25 °C
7.005
10.013
15 Hamilton Duracal * 4.005
25 °C
7.002
10.013
16 Precisa * 3.996
25 °C
7.003
8.999
* Brand names or trade names are trademarks of their respective
owners protected by law (see page 67).
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