Manufacturer's CAGE: SYNERGY
Part No. Indicator: A
Part Number/Trade Name: AHB Series- Lithium ion Polymer batteries.
===========================================================================
1. General Information
===========================================================================
Company's Name: SYNERGY SCIENTECH CORP.
Company's Street: 7F, No. 9, Park Ave. II, Hsinchu Science Park, Hsinchu, Taiwan 30075 R.O.C.
Company's City: HSIN-CHU, TAIWAN
Company's Emerge Ph #: 886-3-564-3700
Company's Info Ph #: 886-3-564-3700
Record No. For Safety Entry: 001
Tot Safety Entries This Sty #: 001
Status: SMJ
Date MSDS Prepared: January 1, 2016 (9th Edition)
Safety Data Review Date: January 1, 2016
MSDS Preparer's Name: Dr. Brian Shen
Preparer's Company: SAME
MSDS Serial Number: LIASN
===========================================================================
2. Ingredients/Identity Information
===========================================================================
Material Name.
(e.g. Sn alloy)
active material
Binder-PVDF Polyvinylidene difluoride 24937-79-9
Conductive material Carbon 1333-86-4
Conductive material Carbon 1333-86-4
Foil
active material Carbon 1333-86-4
Binder-PVDF Polyvinylidene difluoride 24937-79-9
conductive material Carbon 1333-86-4
additive Oxalic acid 144-62-7
foil Copper 7440-50-8
electrolyte-solvent Ethylene carbonate 96-49-1
electrolyte-solvent Diethyl carbonate 105-58-8
electrolyte-solvent Ethyl methyl carbonate 623-53-0
electrolyte-additive Lithium hexafluorophosphate 21324-40-3
separator Polyethylene 9002-88-4
tape-film Polyimide 75-55-8
tape-adhesive
tape-film Polyester 25038-59-9
Substance Name (e.g. Copper (Cu)) CAS No. Percentage (%)
LiCoO2
12190-79-3 32.62
1.04
0.78
0.26
7429-90-5
4.61
15.92
1.3
0.09
0.05
7.87
5.06
3.73
3.83
1.82
3.62
0.1
9011-14-7
0.03
0.14
tape-adhesive
Acrylic
Al bag
Al bag
Aluminum
Al
Aluminum
Nylon 32131-17-2
bag Polypropylene 9003-07-0
tab lead Nickel 7440-02-0
tab lead polypropylene 9003-07-0
tab lead
tab lead polypropylene 9003-07-0
tab Nickel 7440-02-0
3. Hazards Identification
===========================================================================
Route of Entry - Inhalation: YES
Route of Entry - Skin: YES
Route of Entry - Ingestion: YES
Health overexposure Acute and Chronic: UNDER NORM CNDTNS OF USE, THESE CHEMICALS
ARE CONTAINED IN SEALED CAN. RISK OF EXPOS OCCURS ONLY IF BATTERY IS
9011-14-7
7429-90-5
7429-90-5
0.03
3.85
9.75
2.57
0.38
0.05
0.24
0.05
0.22
MECHANICALLY ABUSED. ACUTE: INHAL: CONTENTS OF OPENED BATTERY CAN CAUSE
CONTENTS OF OPENED BATTERY CAN CAUSE IRRIT.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
===========================================================================
4. First Aid Measures
===========================================================================
Explanation Carcinogenicity: NOT RELEVANT.
Signs/Symptoms of Overexposure: SEE HEALTH HAZARDS.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
WASH WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION.
INGESTION: CALL MD IMMEDIATELY (FP N).
===========================================================================
5. Fire Fighting Measures
===========================================================================
Extinguishing Media: IN CASE OF FIRE, USE CARBON DIOXIDE OR DRY CHEMICAL
EXTINGUISHERS.
Special Fire Fighting Proc: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FPN).
Unusual Fire And Expel Hazards: NONE SPECIFIED BY MANUFACTURER.
===========================================================================
6. Accidental Release Measures
===========================================================================
Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected
personnel from entering.
===========================================================================
7. Handling and Storage
===========================================================================
Wear suitable chemical resistant gloves, safety glasses and filtered cartridge respirator. Goggles, full face
protection and other protective clothing is required if potential exists for direct exposure to liquid battery
electrolyte.
In case Material is released or spilled: Carefully recover spillages with appropriate ladle and transfer to a
suitably labeled, sealable container for safe disposal. Wash the spillage area neutralized with calcium hydroxide.
Wear suitable personal protection during removal of spillages.
Be stored in clearly labeled, tightly closed exclusive containers in a cool, dry area.
===========================================================================
8. Exposure Controls/Personal Protection
===========================================================================
Ventilation: Use local exhaust.
Protective Gloves: Wear rubber or plastic gloves.
Eye/Face Protection: Wear safety glasses, goggles or full face protections.
Respiratory Protection: Wear filtered cartridge respirator or a respirator of greater protection.
9. Physical and Chemical Properties
===========================================================================
Product Type: Solid
Appearance: Prismatic
Odor: Odorless
===========================================================================
10. Stability and Reactivity
===========================================================================
Stability: YES
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decamp Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT.
===========================================================================
11. Toxicological Information
===========================================================================
In case electrolyte is spilled and explored with air, the HF could be released.
May include hydrogen fluoride and carbon oxides gas.
May cause skin and eye irritation when contacted.
===========================================================================
12. Ecological Information
===========================================================================
If the battery scrapped, it should be selected and disposed by professional company.
===========================================================================
13. Disposal Consideration
===========================================================================
Disposal should be in accordance with local, state or national legislation.
===========================================================================
14. Transport Information
===========================================================================
UN No: UN3480 / UN3481
The battery models listed have aggregate equivalent lithium content below the 8g and the Watt hour is not more
than 100Wh. And shipment contains no item listed under IATA DGR Packing instruction PI-965 to PI-967
Section II and meets all requirements under UN Manual of Tests and Criteria Part III, subsection 38.3
UN 38.3 Lithium Battery Test results Remarks
NO Test item OK Test 1 to 5 must be conducted in
T1 Altitude simulation OK
T2 Thermal test OK
T3 Vibration OK
T4 Shock OK
T5 External short circuit OK
T6 Impact OK
T7 Overcharge OK Only battery do need this test item
T8 Forced discharge OK For cell only
The product is not classified as dangerous under the current edition of the 57th Edition IATA dangerous goods
regulations. The products are safe for air transportation and not regulated by IATA DGR. Also they comply
15. Regulatory Information
===========================================================================
sequence on the same cell or
battery
See ACGIH exposure limits information as noted in Section 3.
US: This MSDS meets/exceeds OSHA requirements
International: this MSDS conforms to European Union (UN), the International Standards Organization (ISO)
and the International Labor Organization (ILO) and as documental in ANSI (American National Standards
Institute) Standard Z400.1-1993.
Chemical substances information: Japan Advanced Information center of Safety and Health
International Chemical Safety Cards (ICSCs): International Occupational Safety and Health
Information Centre (CIS)
2002 TLVs and BELs: American Conference of Governmental Industrial Hygienists (ACGIH)
Dangerous Goods Regulations-57th Edition : International Air Transport
Association (IATA)
IMDG Code-2014 Edition: International Maritime Organization (IMO)
The European Agreement concerning the International Carriage of Dangerous Goods by Road-2015:
The United Nations Economic Commission for Europe (UNECE)
MSDS of raw materials prepared by the manufactures
SYNERGY SCIENTECH CORP. --
Aluminum
Acrylic
Advanced Hybrid Batteries
SAFETY DATA SHEET
Manufacturer's CAGE: SYNERGY
Part No. Indicator: A
Part Number/Trade Name: AHB Series- Lithium ion Polymer batteries.
===========================================================================
1. General Information
===========================================================================
Company's Name: SYNERGY SCIENTECH CORP.
Company's Street: 7F, No. 9, Park Ave. II, Hsinchu Science Park, Hsinchu, Taiwan 30075 R.O.C.
Company's City: HSIN-CHU, TAIWAN
Company's Emerge Ph #: 886-3-564-3700
Company's Info Ph #: 886-3-564-3700
Record No. For Safety Entry: 001
Tot Safety Entries This Sty #: 001
Status: SMJ
Date MSDS Prepared: January 1, 2016 (9th Edition)
Safety Data Review Date: January 1, 2016
MSDS Preparer's Name: Dr. Brian Shen
Preparer's Company: SAME
MSDS Serial Number: LIASN
===========================================================================
2. Ingredients/Identity Information
===========================================================================
Material Name.
(e.g. Sn alloy)
active material
Binder-PVDF Polyvinylidene difluoride 24937-79-9
3. Hazards Identification
===========================================================================
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: UNDER NORMAL CONDITIONS OF USE, THESE CHEMICALS
ARE CONTAINED IN SEALED CAN. RISK OF EXPOS OCCURS ONLY IF BATTERY IS
9011-14-7
7429-90-5
7429-90-5
0.03
3.85
9.75
2.57
0.38
0.05
0.24
0.05
0.22
MECHANICALLY ABUSED. ACUTE: INHALER: CONTENTS OF OPENED BATTERY CAN CAUSE
CONTENTS OF OPENED BATTERY CAN CAUSE IRRIT.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
===========================================================================
4. First Aid Measures
===========================================================================
Explanation Carcinogenicity: NOT RELEVANT.
Signs/Symptoms of overleap: SEE HEALTH HAZARDS.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
WASH WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION.
INGESTION: CALL MD IMMEDIATELY (FP N).
===========================================================================
5. Fire Fighting Measures
===========================================================================
Extinguishing Media: IN CASE OF FIRE, USE CARBON DIOXIDE OR DRY CHEMICAL
EXTINGUISHERS.
Special Fire Fighting Proc: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FPN).
Unusual Fire And Expel Hazards: NONE SPECIFIED BY MANUFACTURER.
===========================================================================
6. Accidental Release Measures
===========================================================================
Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected
personnel from entering.
===========================================================================
7. Handling and Storage
===========================================================================
Wear suitable chemical resistant gloves, safety glasses and filtered cartridge respirator. Goggles, full face
protection and other protective clothing is required if potential exists for direct exposure to liquid battery
electrolyte.
In case Material is released or spilled: Carefully recover spillages with appropriate ladle and transfer to a
suitably labeled, sealable container for safe disposal. Wash the spillage area neutralized with calcium hydroxide.
Wear suitable personal protection during removal of spillages.
Be stored in clearly labeled, tightly closed exclusive containers in a cool, dry area.
===========================================================================
8. Exposure Controls/Personal Protection
===========================================================================
Ventilation: Use local exhaust.
Protective Gloves: Wear rubber or plastic gloves.
Eye/Face Protection: Wear safety glasses, goggles or full face protections.
Respiratory Protection: Wear filtered cartridge respirator or a respirator of greater protection.
9. Physical and Chemical Properties
===========================================================================
Product Type: Solid
Appearance: Prismatic
Odor: Odorless
===========================================================================
10. Stability and Reactivity
===========================================================================
Stability: YES
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decamp Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT.
===========================================================================
11. Toxicological Information
===========================================================================
In case electrolyte is spilled and explored with air, the HF could be released.
May include hydrogen fluoride and carbon oxides gas.
May cause skin and eye irritation when contacted.
===========================================================================
12. Ecological Information
===========================================================================
If the battery scrapped, it should be selected and disposed by professional company.
===========================================================================
13. Disposal Consideration
===========================================================================
Disposal should be in accordance with local, state or national legislation.
===========================================================================
14. Transport Information
===========================================================================
With regard to air transport, the Office of Hazardous Materials Safety within the US
Department of Transportation’s (DOT) Research and Special Programs
Administration are cited and considered.
Base on IATA dangerous goods regulations current edition (English) and IMDG Code
current Edition, Synergy AHB batteries can fulfil SP188,230,310,957 requirement.
The battery model listed has aggregated equivalent lithium content is not more than
100Wh, and has been tested, basing on Section 38.3 of UN Manual of Tests and
Criteria. And the battery is compliance with IMDG Special Provision 188 ,230 & 310
957.And the battery belongs to Non-dangerous goods.
IMDG special provision 188:
Lithium cells and batteries offered for transport are not subject to other provisions of
this Code if they meet the following
1. For a lithium ion cell, the equivalent lithium content is not more than 20Wh;
2. For a lithium ion battery, the aggregate equivalent lithium content is not more than
100Wh;
3. Each cell or battery is of the type proved to meet the requirements of each test in the
UN Manual of Tests and Criteria, Part III, sub-section 38.3;
4. Cells and batteries are separated so as to prevent short circuits and are packed in
strong packaging, except when installed in equipment; and
5. Except when installed in equipment, each package containing more than 24 lithium
cells or 12 lithium batteries shall in addition meet the following requirements;
a) Each package shall be marked indicating that it contains lithium batteries and
that special procedures shall be followed in the event that the package is
damaged;
b) Each shipment shall be accompanied with a document indicating that packages
contain lithium batteries and that special procedures shall be followed in the
event a package is damaged;
c) Each package is capable of withstanding a 1.2m drop test in any orientation
without damage to cells or batteries contained therein, without shifting of the
contents so as to allow battery to battery (or cell to cell ) contact and without
release of contents; and
d) Except for lithium batteries packed with equipment, packages may not exceed 10 kg gross mass.
As used above and elsewhere in this Code, “lithium content”means the mass of
lithium in the anode of a lithium metal or lithium alloy cell, except in the case of a
lithium-ion cell the “equivalent lithium content”in grams is calculated to be 0.3
times the rated capacity in ampere-hours.
IMDG special provision 230:
This entry applies to cells and batteries containing lithium in any form, including
lithium –polymer and lithium-ion cells and batteries .Lithium cells and batteries may
be transported under this entry if they meet the following conditions:
a) Each cell or battery is of the type proved to meet the requirements of each test
of the UN Manual of Tests and Criteria, Part III ,sub-section 38.3 ;
b) Each cell and battery incorporates a safety venting device or is designed to
preclude a violent rupture under normal conditions of transport;
c) Each cell and battery is equipped with an effective means of preventing
external short circuits;
d) Each battery containing cells or series of cells connected in parallel is equipped
with effective means as necessary to prevent reverse current flow (such as
diodes, fuses, etc.)
IMDG special provision 310
Special Provision 310 of the UN Recommendations for small lithium batteries and cells. Thus, we are
adopting the following small production run exception for small lithium batteries and cells transported
by motor vehicle, rail and vessel:
(1) The cells and batteries must be transported in an outer packaging that is a metal, plastic, or plywood drum;
or metal, plastic, or wooden box meeting the criteria for Packing Group I packaging’s; and
(2) Each cell and battery must be individually packed in an inner packaging inside the outer packaging
and surrounded by non-combustible, non-conductive cushioning material. Consistent with the international
standards, the exception will apply to production runs of up to 100 lithium batteries or cells of all types. This
exception addresses the need to increase safety standards for these lithium batteries, while not imposing undue
costs on the regulated community.
IMDG special provision 957:
Lithium cells and batteries manufactured before 1 January 2003 that have not
been tested in accordance with the requirements in chapter 38.3 of the UN Manual
of Tests and Criteria, as well as articles which contain such lithium cells or batteries,
may be transported until 31 December 2016 if all applicable provisions of this
Code are met.
===========================================================================
15. Regulatory Information
===========================================================================
See ACGIH exposure limits information as noted in Section 3.
US: This MSDS meets/exceeds OSHA requirements
International: this MSDS conforms to European Union (UN), the International Standards Organization (ISO)
and the International Labor Organization (ILO) and as documental in ANSI (American National Standards
Institute) Standard Z400.1-1993.
Chemical substances information: Japan Advanced Information center of Safety and Health
International Chemical Safety Cards (ICSCs): International Occupational Safety and Health
Information Centre (CIS)
2002 TLVs and BELs: American Conference of Governmental Industrial Hygienists (ACGIH)
Dangerous Goods Regulations-57th Edition : International Air Transport
Association (IATA)
IMDG Code-2014 Edition: International Maritime Organization (IMO)
The European Agreement concerning the International Carriage of Dangerous Goods by Road-2015:
The United Nations Economic Commission for Europe (UNECE)
MSDS of raw materials prepared by the manufactures
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