Fig. 1-1Structure of the IQ SENSOR NET operating manual
The IQ SENSOR NET operating manual has a modular structure like the
IQ S
ENSOR NET itself. It consists of a system operating manual and the
operating manuals of all the components used.
Please file this component operating manual in the ring binder of the
system operating manual.
1 - 1
Page 6
OverviewVARiON
12345
1.2Structure of the combination sensor
VARi ON
®Plus
700 IQ
®Plus
700 IQ
ElectrodesFor a VARiON
Automatic interfering
ions compensation
Fig. 1-2Structure of the combination sensor VARiON
®Plus
700 IQ
1Protective hood
2Temperature probe
3Electrode support with electrodes (sample equipment)
4Sensor shaft
5Plug head connector
®Plus
700 IQ combination sensor ready to measure, a
jointly used reference electrode and at least one ion sensitive electrode
for the main measured parameters (ammonium, nitrate) are required.
The electrodes are screwed into the electrode support. The electrode
support has four receptacles for this.
®Plus
The VARiON
700 IQ enables the automatic interfering ions
compensation for one main measured parameter. Thus the influence of
certain interfering ions due to measuring technique can be
automatically compensated for.
Interfering ions in water / waste water applications are mostly chloride
for nitrate measurement and potassium for ammonium measurement.
To determine the interfering ions concentration, another electrode
(compensation electrode) is mounted into a free receptacle.
Note
Information on the fundamentals of measuring with ion sensitive
electrodes are given in the YSI primer, I
ONLINEANALYSIS.
Operating modes and
electrode equipment
1 - 2
Due to its modular structure, the VARiON
to various requirements (see table on the following page).
ONSELECTIVEMEASUREMENTIN
®Plus
700 IQ can be adapted
ba76000e0101/2012
Page 7
VARiON
Ref
VARiON
®Plus
NH4
VARiON
®Plus
K
Blind plug
VARiON
®
Ref
(recess)
Ref
VARiON® Ref
VARiON
®Plus
NO3
VARiON
®Plus
Cl
Blind plug
Ref
VARiON® Ref
VARiON
®Plus
NH4
VARiON
®Plus
K
VARiON
®Plus
NO3
Ref
VARiON® Ref
VARiON
®Plus
NO3
VARiON
®Plus
Cl
VARiON
®Plus
NH4
Ref
VARiON
®Plus
NH4
Blind plug
Blind plug
VARiON
®
Ref
Ref
VARiON® Ref
VARiON
®Plus
NO3
Blind plug
Blind plug
Ref
VARiON® Ref
VARiON
®Plus
NH4
VARiON
®Plus
NO3
Blind plug
®Plus
700 IQOverview
Notes:
The reference electrode has an extra receptacle marked by a recess.
The ion sensitive electrodes can be mounted in the remaining three
receptacles in any order. Empty receptacles have to be closed with the
VARiON
Nitrate measurement,
®
BP blind plug.
Operating modeElectrode equipment
Ammonium
measurement,
compensated
compensated
Ammonium
measurement,
compensated,
plus nitrate
measurement
Nitrate measurement,
compensated
plus ammonium
measurement
Ammonium
measurement
Nitrate measurement
ba76000e0101/2012
Ammonium
measurement,
nitrate measurement
1 - 3
Page 8
OverviewVARiON
®Plus
700 IQ
Calibration free
operation
Shielding of the
VARiON
®Plus
700 IQ
The VARiON
®Plus
700 IQ combination sensor is immediately ready to
measure after being equipped with electrodes. For precise
measurements, it is only necessary to adjust the electrodes to the
sample matrix ("matrix adjustment"). In the recommended application
(see section 1.3 R
ECOMMENDEDFIELDSOFAPPLICATION), the measuring
characteristics of the electrodes remain stable for their entire service
life. Thus, calibration is no longer required.
Possible changes of the sample matrix can be determined by
occasional comparison measurements (e.g. photometer) and
compensated for by a new matrix adjustment. The sensor does not
have to be taken out of the sample for this.
The VARiON
electrodes in conjunction with the
®Plus
700 IQ combination sensor and the corresponding
IQ SENSOR NET system form a
measuring system that is protected to a high degree against low and
high frequency interference as well as against the indirect effects of
lightning strikes.
1.3Recommended fields of application
The VARiON
®Plus
700 IQ combination sensor is a sensor for the online
determination of ammonium ions and/or nitrate ions in water / waste
water applications. It supplements D. O. measurement in the aeration
tank of waste water treatment plants and enables an efficient process
control of nitrogen removal.
Note
More detailed information on measuring with ion sensitive electrodes is
given in the YSI primer, I
ANALYSIS.
ONSELECTIVEMEASUREMENTINONLINE
1 - 4
ba76000e0101/2012
Page 9
VARiON
®Plus
700 IQSafety instructions
2Safety instructions
Special user
qualifications
General safety
instructions
This component operating manual contains special instructions that
®Plus
must be followed in the operation of the VARiON
700 IQ
combination sensor. Thus, it is essential to read this component
operating manual before carrying out any work using this sensor. In
addition to this manual, the S
AFETY chapter of the IQ SENSOR NET
system operating manual must be followed.
Always keep this component operating manual together with the
system operating manual and any other component operating manuals
in the vicinity of the IQ S
The VARiON
®Plus
ENSOR NET system.
700 IQ combination sensor was developed for
applications in online measurement - essentially in the field of
wastewater treatment. Thus, we assume that the operators are familiar
with the necessary precautions to take when dealing with chemicals as
a result of their professional training and experience.
Safety instructions in this operating manual are identified by the
warning symbol (triangle) in the left column. The signal word (e. g.
"Caution") indicates the level of danger:
Warning
indicates instructions that must be followed precisely in order to
prevent serious dangers to persons.
Other labels
Caution
indicates instructions that must be followed precisely in order to
avoid slight injuries or damage to the instrument or the
environment.
Note
indicates notes that draw your attention to special features.
Note
indicates cross-references to other documents, e.g. operating
manuals.
ba76000e0101/2012
2 - 1
Page 10
Safety instructionsVARiON
2.1Authorized use
®Plus
700 IQ
Function and
operational safety
The authorized use of the VARiON
in consists of its use as a sensor within the IQ S
®Plus
700 IQ with the electrodes built
ENSOR NET.
Please observe the technical specifications according to chapter 9
ECHNICALDATA. Only operation according to the instructions given in
T
this operating manual is considered to be authorized.
Any other use is considered to be unauthorized. Unauthorized use
invalidates any claims with regard to the guarantee.
Caution
Only connect and operate the sensor together with IQ SENSOR NET
accessories.
2.2General safety instructions
The sensor left the factory in a safe and secure technical condition.
The failure-free function and operational safety of the sensor is only
guaranteed if the generally applicable safety measures and the special
safety instructions in this operating manual are followed during its use.
The failure-free function and operational safety of the sensor is only
guaranteed under the environmental conditions that are specified in
chapter 9 T
The specified temperature (chapter 9 T
ECHNICALDATA.
ECHNICALDATA) must be
maintained during the operation and transport of the sensor. Protect
the sensor, particularly against frost or overheating.
Caution
The sensor may only be opened by specialists authorized by YSI.
2 - 2
ba76000e0101/2012
Page 11
VARiON
®Plus
700 IQSafety instructions
Safe operationIf safe operation is no longer possible, the sensor must be taken out of
operation and secured against inadvertent operation.
Safe operation is no longer possible if the sensor:
has been damaged in transport
has been stored under adverse conditions for a lengthy period of
time
is visibly damaged
no longer operates as described in this manual.
If you are in any doubt, contact the supplier of your sensor.
Obligations of the
operator
The operator of the sensor must ensure that the following rules and
regulations are followed when dealing with hazardous substances:
EEC directives for protective labor legislation
National protective labor legislation
Safety regulations
Safety data sheets of the chemical manufacturer.
ba76000e0101/2012
2 - 3
Page 12
Safety instructionsVARiON
®Plus
700 IQ
2 - 4
ba76000e0101/2012
Page 13
VARiON
®Plus
700 IQCommissioning
3Commissioning
3.1Scopes of delivery
YSI supplies the VARiON
®Plus
700 IQ in sets for different measuring
requirements. Each set contains the following components:
Unequipped sensor VARiON
®Plus
700 IQ. The electrode
receptacles are closed with blind plugs
Reference electrode, VARiON
®
Ref
Depending on the set, the suitable selection from the following
measurement and compensation electrodes:
– VARiON
– VARiON
– VARiON
– VARiON
®Plus
NH4 (ammonium electrode)
®Plus
K (potassium electrode for compensation)
®Plus
NO3 (nitrate electrode)
®Plus
Cl (chloride electrode for compensation)
Special socket wrench
Protective hood VARiON
®
700 IQ-SK
Potassium chloride solution for storing the reference electrode
Operating manual and YSI primer, I
ONLINEANALYSIS.
ONSELECTIVEMEASUREMENTIN
Note
Information on the available sets is given in the YSI catalog and on the
Internet.
ba76000e0101/2012
3 - 1
Page 14
CommissioningVARiON
3.2IQ SENSOR NET system requirements
®Plus
700 IQ
Software statuses of the
controller and terminal
components
Operation of the VARiON
statuses in the IQ S
®Plus
700 IQ requires the following software
ENSOR NET, depending on the system:
DIQ/S 182Software:Version 3.21
or higher
MIQ/MCController software:Version 2.83
or higher
IQ software packSoftware:Version 5.00
or higher
3 - 2
ba76000e0101/2012
Page 15
VARiON
Watering cap
Junction
Reference electrode
Nut
Sealing ring
®Plus
700 IQCommissioning
3.3Notes on the handling of the electrodes
Commissioning
The electrodes of the VARiON
®Plus
700 IQ combination sensor were
developed for the rough use in waste water treatment plants. They are,
however, precision parts that can be damaged by inappropriate use.
Therefore, exactly follow the instructions in the two following chapters.
3.3.1Reference electrode
Fig. 3-1Reference electrode with storing aids
In the delivery condition, the electrode is equipped with a watering cap
and a nut that protects the screw-in thread. The watering cap contains
3 mol/l potassium chloride solution. Before mounting, unscrew the
watering cap. Then, using the special hexagon key, unscrew the
electrode from the nut. Keep both storing aids in case you want to store
the electrode.
Caution
The junction of the reference electrode must not
dry up (follow notes on storage)
be damaged
be brought into contact with grease.
Notes on storageIf you will not use the electrode for a longer period of time, screw the
electrode into the nut as far as it will go. Fill the watering cap to the brim
with 3 mol/l potassium chloride solution and tightly screw the watering
cap on the electrode by hand.
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3 - 3
Page 16
CommissioningVARiON
Watering cap
Electrode
Nut
Sealing ring
3.3.2Measurement electrodes and compensation electrodes
Commissioning
Fig. 3-2Measurement electrode or compensation electrode with storing aids
In the delivery condition, each electrode is equipped with a watering
cap and a nut that protects the screw-in thread. Prior to installation, first
remove the watering cap and, using the special hexagon key, unscrew
the electrode from the nut. Keep both storing aids in case you want to
store the electrode.
®Plus
700 IQ
Caution
The membrane of the electrode must not
dry up (follow notes on storage)
be damaged
be brought into contact with grease.
Notes on storageIf you will not use the electrode for a longer period of time, screw the
electrode into the nut as far as it will go. Soak the foam insert in the
®
watering cap with VARiON
/ES-1 standard solution (lower
concentration) and plug the electrode into the watering cap.
Caution
Make sure to use the correct solution for the watering cap
(VARiON
solution of the reference electrode instead the function of the
electrode can be seriously damaged.
®
/ES -1 standard solution). If you use the watering
3 - 4
ba76000e0101/2012
Page 17
VARiON
Measurement and
compensation electrodes
Reference
electrode
Blind plug
Mark for
reference electrode
Special socket wrench
®Plus
700 IQCommissioning
3.4Preparing the sensor for measurement
3.4.1Equipping the sensor with electrodes
Caution
The sensor can be damaged by dirt and moisture. Before
mounting the electrodes make sure the area behind the sealing
ring of the electrodes and the receptacle are dry and clean. The
VARiON
or original blind plugs are mounted.
Note
More detailed information on the electrode equipment for the various
operating modes is given in the table on page 1-3.
®Plus
700 IQ may only be submersed when the electrodes
ba76000e0101/2012
Fig. 3-3Equipping the sensor with electrodes.
All receptacles are closed with blind plugs in the delivery condition.
Screw the electrodes into the receptacles instead of the blind plugs.
When doing so observe the following points:
The receptacle for the reference electrode is marked by a recess. It
extends into the inside of the sensor clearly deeper than the other
three receptacles (see Fig. 3-3).
3 - 5
Page 18
CommissioningVARiON
The measurement and compensation electrodes can be mounted in
the remaining three receptacles in any order.
During installation make sure the area behind the sealing ring of the
electrode and the receptacle are absolutely dry and clean.
Plug the electrode on the special socket wrench provided and insert
the electrode with the special socket wrench.
Screw until the electrode seats without any gap on the electrode
support. Thus the tightness and electrical contacting are granted.
Note
When mounted, the electrodes can be recognized by the features
described in section 6.3.
®Plus
700 IQ
3 - 6
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Page 19
VARiON
1
®Plus
700 IQCommissioning
3.4.2Mounting the protective hood
CH cleaning head
(option)
Mounting the standard
protective hood
For permanent operation, we recommend to use the CH cleaning head
for compressed air-driven cleaning. It is mounted instead of the
standard protective hood. The compressed air cleaning is started timecontrolled via the IQ S
ENSOR NET system. Information on the required
components is given in the YSI catalog and on the Internet.
If no CH cleaning head is used the standard protective hood should
always be mounted for measuring. It protects the electrodes from rough
mechanical impact.
Cleaning theprotective
ba76000e0101/2012
hood
Fig. 3-4Mounting the standard protective hood.
1Loosen the coupling ring (1) of the protective hood.
2Push the protective hood on the sensor as far as it will go.
3Tighten the coupling ring of the protective hood.
The coupling ring of the protective hood can be taken apart for cleaning
purposes (see section 6.2 E
XTERIORCLEANING).
3 - 7
Page 20
CommissioningVARiON
SACIQ
1
2
3.4.3Connecting the sensor to the IQ SENSOR NET
Connection cableThe SACIQ sensor connection cable is required to connect the sensor.
Information on this and other IQ S
ENSOR NET accessories is given in
the YSI catalog and on the Internet.
Note
Do not suspend the sensor on the sensor connection cable. Use an
armature or electrode holder. Information on this and other IQ S
N
ET accessories is given in the YSI catalog and on the Internet.
Note
How to connect the SACIQ sensor connection cable to the
ENSOR NET is described in chapter 3 INSTALLATION of the
IQ S
IQ S
ENSOR NET system operating manual.
®Plus
700 IQ
ENSOR
Are the plug
connections dry?
Connecting the sensor
to the sensor
connection cable
Before connecting the sensor and sensor connection cable, make sure
that the plug connections are dry. If moisture gets into the plug
connections, first dry the plug connections (dab them dry or blow them
dry using compressed air).
Fig. 3-5Connect the sensor
1Take the protective caps off the plug connections of the sensor
and the SACIQ sensor connection cable, and keep them safe.
3 - 8
ba76000e0101/2012
Page 21
VARiON
®Plus
700 IQCommissioning
2Plug the socket of the SACIQ sensor connection cable onto the
plug head connector of the sensor. At the same time, rotate the
socket so that the pin in the plug head connector (1) clicks into
one of the two holes in the socket.
3Then screw the coupling ring (2) of the sensor connection
cable onto the sensor up to the stop.
ba76000e0101/2012
3 - 9
Page 22
CommissioningVARiON
3.5Settings
3.5.1General information
®Plus
Automatic electrode
recognition
The VARiON
in electrodes and checks the equipment for validity. Depending on the
equipment, the following sensors are displayed in the list of sensors:
SensorDesignation
VARiON
VARiON
®Plus
®Plus
Note
Manually, you can also have the potassium electrode displayed as the
extra sensor, VARiON K.
700 IQ software automatically recognizes the built-
700 IQ Ammonium sensorVARiON A
700 IQ Nitrate sensorVARiON N
®Plus
700 IQ
SensorDesignation
VARiON
®Plus
700 IQ potassium sensorVARiON K
Carrying out settingsWith <S>, switch to the main settings menu from the measured value
display. Then navigate to the setting menu (setting table) of the sensor.
The exact procedure is described in the relevant IQ S
ENSOR NET
system operating manual.
The setting tables of the sensors are described in the following
chapters.
Sensor overlapping
settings
Certain settings are sensor overlapping and can be made in any one of
the setting tables. The setting is used by all sensors.
The sensor overlapping settings are:
Temperature mode(°C/°F)
Temp. adjustment
3 - 10
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Page 23
VARiON
®Plus
700 IQCommissioning
3.5.2Setting table of the VARiON A (ammonium sensor)
Menu itemSelection/valuesExplanations
Measuring mode NH4-N
NH4
mV
Measuring range
(Measuring mode: NH4-N)
AutoRange
0.1 ... 100.0 mg/l
1 ... 1000 mg/l
Measuring range
(Measuring mode: NH4)
AutoRange
0.1 ... 130.0 mg/l
1 ... 1290 mg/l
Measuring range
-2000 ... 2000 mVFixed range
(Measuring mode: mV)
VARiON K hide
show
Citation form of the mass concentration or
voltage of the electrode.
2 measuring ranges can be selected.
With AutoRange, the instrument
automatically switches to the suitable
measuring range.
2 measuring ranges can be selected.
With AutoRange, the instrument
automatically switches to the suitable
measuring range.
hide (standard setting):
The potassium electrode is not displayed
as an extra sensor in the measured value
display.
show:
If the sensor is equipped with the
potassium electrode, the electrode is
displayed as the extra sensor VARiON K
in the measured value display.
The relevant settings can be done in an
extra setting table (see section 3.5.4).
Note:
If the maximum number of sensors
for the system is exceeded by activating
the sensor, the VARiON K cannot be
activated.
Calib. history K
(only with setting VARiON
K: hide)
ba76000e0101/2012
Do not download
Transmit to log book
If you select Transmit to log book, a log
book message with the calibration history
of the potassium electrode is generated.
When opening the setting table again the
setting is reset to Do not download.
3 - 11
Page 24
CommissioningVARiON
Menu itemSelection/valuesExplanations
®Plus
700 IQ
Potassium compens.
(only with setting
VARiON K: hide)
automatic / manual
1 ... 1000 mg/l
automatic
(with a potassium electrode mounted):
When the potassium electrode is
mounted, the potassium compensation
takes places automatically only. The value
of the potassium concentration measured
at the time the setting table was opened is
displayed in the next line (Potassium
conc.).
manual
(without any potassium electrode
mounted):
After determining the potassium content of
the test solution enter the determined
potassium content manually in the next
line (Potassium conc.).
The measured value is accordingly
corrected by the entered potassium
content.
Note:
Detailed information on the subject
of potassium compensation is given in the
YSI primer, I
Display of the potassium measured value.
With Potassium compens.: manual:
Entry of the K value
IQ-LabLink Not active(not used)
Temperature mode
(only with Measuring mode:
°C
°F
Unit of the measured temperature value
(Celsius, Fahrenheit).
NH4-N or NH4)
3 - 12
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Page 25
VARiON
®Plus
700 IQCommissioning
Menu itemSelection/valuesExplanations
Temp. adjustment
(only with Measuring mode:
NH4-N or NH4)
-1.5 °C ... +1.5 °CThe temperature compensation function
enables the temperature sensor to be
balanced against a reference temperature
measurement (displacement of the zero
point by ±1.5 °C).
Notes:
Due to the thermal capacity of the
sensor, it is necessary to place it in a
container with at least 2 liters of water.
Leave the sensor in this container for at
least 15 minutes while stirring
occasionally, then carry out the
adjustment.
If the temperature difference of the
water and sensor is > 10°C, leave the
sensor in the container for at least one
hour while stirring occasionally.
Conc. offset-1.0 mg/l ... +1.0 mg/lConstant value, which is added to the
measuered value.
Program level0 ... 2Program extension (0 = Off = standard set-
ting).
Refer to section 4.2.4 for details about the
program extension.
Save and quitThe system confirms the saving of the
settings and the display switches to the
next higher level.
QuitThe display switches to the next higher
level without saving the new settings.
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3 - 13
Page 26
CommissioningVARiON
3.5.3Setting table of the VARiON N (nitrate sensor)
Menu itemSelection/valuesExplanations
®Plus
700 IQ
Measuring mode NO3-N
NO3
mV
Measuring range
(Measuring modeNO3-N)
AutoRange
0.1 ... 100.0 mg/l
1 ... 1000 mg/l
Measuring range
(Measuring mode: NO3)
AutoRange
0.5 ... 450.0 mg/l
5 ... 4500 mg/l
Measuring range
-2000 ... 2000 mVFixed range
(Measuring mode: mV)
Chloride compens.automatic / manual
1 ... 1000 mg/l
Citation form of the mass concentration or
voltage of the electrode.
2 measuring ranges can be selected.
With AutoRange, the instrument
automatically switches to the suitable
measuring range.
2 measuring ranges can be selected.
With AutoRange, the instrument
automatically switches to the suitable
measuring range.
automatic
(with a chloride electrode mounted):
When a chloride electrode is mounted, the
chloride compensation takes places
automatically only. The value of the
chloride concentration measured at the
time the setting table was opened is
displayed in the next line.
manual
(without any chloride electrode mounted):
After determining the chloride content of
the test solution enter the determined
chloride content manually in the next line.
The measured value is accordingly
corrected by the entered chloride content.
Note:
Detailed information on the subject
of chloride compensation is given in the
YSI primer, I
Display of the chloride measured value.
With Chloride compens.: manual:
Entry of the Cl value
Calib. history Cl
(only with setting Chloride
compens.: automatic)
Do not download
Transmit to log book
Send to log book generates a log book
message with the calibration history of the
chloride electrode. When opening the
setting table again the setting is reset to
Do not download.
3 - 14
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Page 27
VARiON
®Plus
700 IQCommissioning
Menu itemSelection/valuesExplanations
IQ-LabLink Not active(not used)
°C
°F
Unit of the measured temperature value
(Celsius, Fahrenheit).
Temperature mode
(only with Measuring
mode: NO3-N or NO3)
Temp. adjustment
(only with Measuring
mode: NO3-N or NO3)
-1.5 °C ... +1.5 °CThe temperature adjustment function
enables the temperature sensor to be
balanced against a reference temperature
measurement (displacement of the zero
point by ±1.5 °C).
Notes:
Due to the thermal capacity of the
sensor, it is necessary to place it in a
container with at least 2 liters of water.
Leave the sensor in this container for at
least 15 minutes while stirring
occasionally, then carry out the
adjustment.
If the temperature difference of the
water and sensor is > 10°C, leave the
sensor in the container for at least one
hour while stirring occasionally.
Conc. offset-1.0 mg/l ... +1.0 mg/lConstant value, which is added to the
measuered value.
Program level0 ... 2Program extension (0 = Off = standard set-
ting).
Refer to section 4.2.4 for details about the
program extension.
Save and quitThe system confirms the saving of the
settings and the display switches to the
next higher level.
QuitThe display switches to the next higher
level without saving the new settings.
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3 - 15
Page 28
CommissioningVARiON
3.5.4Setting table of the VARiON K (potassium sensor)
Note
These sensor settings are only available if in the sensor settings for the
VARiON A the VARiON K setting was set to Active (see section 3.5.2).
The basic settings are taken over from the VARiON A sensor but can
be adjusted separately afterwards.
Menu itemSelection/valuesExplanations
®Plus
700 IQ
Measuring mode K (mg/l)
mV
Measuring range
1 ... 1000 mg/lFixed range
Citation form of the mass concentration or
voltage of the electrode.
(Measuring mode: K (mg/l))
Measuring range
-2000 ... 2000 mVFixed range
(Measuring mode: mV)
IQ-LabLink Not active(not used)
Temperature mode
(only with
°C
°F
Unit of the measured temperature value
(Celsius, Fahrenheit).
Measuring mode: K (mg/l))
Temp. adjustment
(only with
Measuring mode: K (mg/l))
-1.5 °C ... +1.5 °CThe temperature compensation function
enables the temperature sensor to be
balanced against a reference temperature
measurement (displacement of the zero
point by ±1.5 °C).
Notes:
Due to the thermal capacity of the
sensor, it is necessary to place it in a
container with at least 2 liters of water.
Leave the sensor in this container for at
least 15 minutes while stirring
occasionally, then carry out the
adjustment.
If the temperature difference of the
water and sensor is > 10°C, leave the
sensor in the container for at least one
hour while stirring occasionally.
Conc. offset-10 mg/l ... +10 mg/lConstant value, which is added to the
measuered value.
Program level0 ... 2Program extension (0 = Off = standard set-
ting).
Refer to section 4.2.4 for details about the
program extension.
3 - 16
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Page 29
VARiON
®Plus
700 IQCommissioning
Menu itemSelection/valuesExplanations
Save and quitThe system confirms the saving of the
settings and the display switches to the
next higher level.
QuitThe display switches to the next higher
level without saving the new settings.
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Page 30
CommissioningVARiON
®Plus
700 IQ
3 - 18
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Page 31
VARiON
Start: press
<C>
Electrode
zeroing
Yes/No
Selection of procedure
Matrix adjustmentCheckCalibration
Procedures for special cases
(see section 4.3)
Calibration free operation
Yes if a new or different electrode is
commissioned
®Plus
700 IQMatrix adjustment, check and calibration
4Matrix adjustment, check and calibration
4.1General information
Calibration free
operation
Steps
The VARiON
®Plus
700 IQ combination sensor is immediately ready to
measure after being equipped with electrodes. For precise
measurements, it is only necessary to adjust the electrodes to the
sample matrix ("matrix adjustment").With the recommended
application (see section 1.3 R
ECOMMENDEDFIELDSOFAPPLICATION), the
measuring characteristics of the electrodes remain stable for their
entire service life. Thus, calibration is no longer required.
Possible changes of the sample matrix can be determined by
occasional comparison measurements (e.g. photometer) and
compensated for by a new matrix adjustment as necessary. The sensor
does not have to be taken out of the sample for this. At the same time,
a matrix adjustment provides information on the state of the electrodes.
ba76000e0101/2012
Fig. 4-1Schematic diagram
4 - 1
Page 32
Matrix adjustment, check and calibrationVARiON
Drift potentialSimultaneously with the matrix adjustment (or calibration), the drift
voltage DV(mV) of the combination electrode is determined. It serves
to evaluate the long-term behavior of the combination electrode. The
drift voltage changes due to the following factors:
Influences due to the sample composition (matrix)
Changes of the electrode characteristics.
Electrode zeroingThe temporal change of the drift voltage is recorded in the calibration
history so the long-term behavior of a combination electrode can be
evaluated. As a start value, the user has to set the drift voltage to zero
at the beginning of this evaluation period in order to observe changes
in the calibration history.
The electrode zeroing itself is carried out with the matrix adjustment (or
calibration) procedure for the selected combination electrode(s). It
becomes effective if the procedure was successfully carried out.
For each electrode, the user can carry out the electrode zeroing
separately and at any time. We recommend, however, to start the
evaluation period with the commissioning of a new or different
electrode to be able to see the entire operating life of an electrode in
the calibration history.
®Plus
700 IQ
Resetting the slope by
electrode zeroing
Maintenance and
calibration case,
®
VARi O N
Case
It is not possible to zero an electrode with the Check procedure, as this
procedure stores no data in the sensor.
Electrode zeroing with the matrix adjustment procedure resets the
slope to the default setting (+ or - 59.2 mV) at the same time. Electrode
zeroing with the calibration procedure replaces the existing slope with
the newly determined value.
For adjustment, calibration and maintenance activities on site, the
VARiON
®
Case is available. The convenient case provides room for all
required accessories (details, see section 6.1).
4 - 2
ba76000e0101/2012
Page 33
VARiON
®Plus
700 IQMatrix adjustment, check and calibration
4.2Matrix adjustment
4.2.1General information on matrix adjustment
This procedure adjusts the value directly measured in the test sample
to an independently determined reference value ("lab value"). To
determine the reference values, a sample is taken from the measuring
solution and the relevant concentrations are measured (e.g.
photometrically).
First select for which of the installed combination electrodes the matrix
adjustment should be carried out. Based on this selection and the
electrode equipment, the sensor software determines the ion types for
which a reference measurement must be carried out. The menu guided
routine adapts itself correspondingly and informs you of all necessary
actions.
4.2.2Carrying out the matrix adjustment
Note
A chloride electrode should be checked for coatings and polished off as
necessary before the matrix adjustment is carried out (see section 6.4).
Main steps
Step 1:Determination of all combination electrode voltages
("reference voltages"). The sensor is in the sample.
The procedure is started from the measured value display
with <C>. After completion the system returns to the
measured value display.
Step 2:Sampling at the same place and time if possible and
determination of all relevant reference values
Step 3:Entry of the measured reference values. This step is
started by pressing <C> again.
Online helpA comfortable, menu guided routine guides you through the matrix
adjustment. All steps are easily and understandably explained on the
display. In addition, you can call up an Online help for each step. To do
so, move the highlighting to the Online help menu item with the arrow
keys <> or the toggle switch <> and press <OK>. A help
text with detailed information on the relevant operating step appears on
the display. It provides, for example, important instructions on how to
keep the correct basic conditions. When <OK> is pressed once again,
the display returns to the current operating step.
Matrix adjustment with
electrode zeroing
ba76000e0101/2012
After installing a new or different electrode you have to zero the
electrode to facilitate a long-term evaluation. Details on electrode
zeroing, see section 4.1.
4 - 3
Page 34
Matrix adjustment, check and calibrationVARiON
®Plus
Practical instructions Ammonium and nitrate have to be determined immediately after
taking the sample as the their content changes very quickly due to
the micro organisms that are present. It is best to take the sample
using a syringe filter for transport to the laboratory or to stabilize it
otherwise. When adding stabilizing solutions, the dilution factor has
to be taken into account.
While determining the reference concentrations in the lab (step 2),
you can use the sensor for control purposes again by switching the
maintenance condition off and thus releasing the linked outputs. The
sensor continues to use the data of the previous matrix adjustment
(or calibration). The reference voltages determined in step 1 will not
be lost. They remain stored until step 3 of the matrix adjustment is
completed. They do not have to be noted and entered again.
Use the Online help if you are unsure of anything during the matrix
adjustment.
700 IQ
4 - 4
ba76000e0101/2012
Page 35
VARiON
Last electrode
zeroing via
matrix adjustment
Chronological list of
the last matrix
adjustments
®Plus
700 IQMatrix adjustment, check and calibration
4.2.3Result of the matrix adjustment
EvaluationAfter the matrix adjustment, the system automatically evaluates the
current condition of the electrode(s) based on the drift voltage. For a
successful matrix adjustment, the drift voltage must be within the range
-45 mV ... +45 mV. The drift voltage is set to 0 mV if you have selected
to zero the electrode.
At the end of the matrix adjustment procedure the drift voltage of all
selected electrodes is shown on the display. The evaluation is
displayed with "+" (successful) or "-" (unsuccessful). Additionally, the
slopes are displayed that are used for the current measured value
calculation. The slopes are marked by a star (*) as they were not
changed by the matrix adjustment.
Taking over the
determined values
History of matrix
adjustments
(only available in the
IQ S
ENSOR NET
system 2020 XT)
For each successfully adjusted electrode you can individually decide
whether the values should be stored for measurement.
Note
If the matrix adjustment was erroneous due to an incorrect
determination or entry of the reference concentration, you can correct
the entry (if necessary several times). If, by doing so, it is not possible
to eliminate the error, the complete matrix adjustment has to be
repeated or discarded for this electrode. If it is discarded, measurement
is continued with the values of the last valid matrix adjustment (or
calibration). Values of successfully adjusted electrodes that were
already stored are retained.
Note
Actions for error elimination are given in the Online help and in chapter
8 W
HATTODOIF ....
The history of matrix adjustments can be viewed in the so-called
calibration history.
ba76000e0101/2012
Fig. 4-2Calibration history with matrix adjustments (example: VARiON A)
4 - 5
Page 36
Matrix adjustment, check and calibrationVARiON
The history of matrix adjustments contains the following information:
DateDate of the matrix adjustment
SSlope [mV] of the electrode.
The slopes are marked by a star (*) because they were not changed
by the matrix adjustment or reset to the default condition with the
electrode zeroing.
DVDrift voltage [mV]
0 is displayed after an electrode zeroing.
Ref1Reference concentration [mg/l]
Ref2This column is of no importance for the matrix adjustment
K+ or Cl-Measured or entered interfering ions concentration [mg/l]
PProcedure (1 = matrix adjustment)
®Plus
700 IQ
TTemperature [°C]
REvaluation of the matrix adjustment
+ : Matrix adjustment successful.
The sensor measures with the new adjustment data.
? : Matrix adjustment unsuccessful.
Invalid adjustment data was discarded. Measurement is
continued with the last valid values.
Note
If you set the potassium electrode to be displayed as the extra sensor
VARiON K, the calibration history of the potassium electrode can be
viewed under VARiON K. The IQ S
log book for this sensor. Log book messages are displayed with the
main sensor, VARiON A.
For the chloride electrode, or if the potassium electrode is not displayed
as an extra sensor, you can generate a log book message with the
calibration history by means of the menu item, Calib. history Cl (or K)
in the setting table of the relevant sensor. How to do this is described
on page 3-11. The log book message is recorded in the log book of the
relevant main sensor (VARiON A -> message code IC5395 or VARiON
N -> message code IC6396).
ENSOR NET does not keep an extra
4 - 6
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Page 37
VARiON
®Plus
700 IQMatrix adjustment, check and calibration
4.2.4Program extension
The simple matrix adjustment, as described in the sections 4.2.2 to
4.2.3, will in most cases lead to precise measurement results. In some
cases, special effects in the matrix can cause the real characteristic
curve of the ISE measurement to deviate very much from the factory
characteristic curve. This can lead to measured values that are not
precise enough.
From sensor software version 3.20, the setting table provides the
Program Level setting, which can be used to enhance the functionality
of the matrix adjustment. Program Level 0 is the simple matrix
adjustment as described in the sections 4.2.2 to 4.2.3. The program levels 1 and 2 provide tools with which the real characteristic curve of
the ISE measurement can be better approximated.
For more detailed information please address your YSI contact person.
Note
To restore the factory characteristic curve, select Program Level 0 in
the setting table and then quit the menu with Save and quit.
ba76000e0101/2012
4 - 7
Page 38
Matrix adjustment, check and calibrationVARiON
4.3Check and calibration in standard solutions
4.3.1General information on checking and calibrating
In addition to the comparison measurement or matrix adjustment under
real measurement conditions, it is possible to check the function of the
entire sensor in standard solutions. If necessary, you can also take
over to the sensor the slope and potential level of the individual
combination electrodes via an exact calibration in standard solutions.
The slope will be retained with a future matrix adjustment if it is carried
out without zeroing the electrode.
®Plus
700 IQ
When does a check or
calibration make sense?
Caution
The long term stable VARiON
with the recommended application. A check in standard solutions
is only of significance if all basic conditions (cleanness,
conditioning etc.) are strictly kept. Calibration can cause major
measurement errors if the basic conditions are not sufficiently
kept. After calibrating, a matrix adjustment is normally required
additionally
(always with the recommended application). Standard solutions
do not represent any real test sample!
A check or calibration can be useful in the following special cases:
If the measured values do not appear to be correct even after a
careful matrix adjustment and if you suspect the electrode slopes to
have changed
If a new application is to be started, the sample composition of which
considerably deviates from that of the recommended application
(see section 1.3 R
ECOMMENDEDFIELDSOFAPPLICATION)
Routinely within the framework of the company quality assurance.
®Plus
electrodes are calibration-free
4 - 8
ba76000e0101/2012
Page 39
VARiON
®Plus
700 IQMatrix adjustment, check and calibration
Differences between
check and calibration
The check and calibration are carried out in two separate routines. The
schema is the same with both routines: Two standard solutions with
different concentrations are measured one after the other. The
differences between the check and calibration are as follows:
For the check, the basic conditions to be kept are less strict. It is
suitable as a quick method to check whether the slope and potential
level of the combination electrodes are within the allowed limits. The
results are just for information. No characteristics or sensor settings
are changed.
For calibration, the basic conditions must comply with very high
requirements (longer conditioning times, discarding of the
conditioning solution, temperature adjustment etc.).
Correspondingly, it requires more time. During calibration, the slope
and drift voltage are exactly determined and evaluated. If the
calibration was successful, the determined values can be taken over
for measurement. The procedure can, however, be used as a mere
check method. Calibration is documented in the calibration history
and in the log book.
Standard solutionsFor the check or calibration, the following two YSI standard solutions
are required in this order:
VARiON
VARiON
®
/ES-2 (high concentration)
®
/ES-1 (low concentration).
Online helpA comfortable, menu guided routine guides you through the procedure.
Calibration with
electrode zeroing
These standard solutions contain all ion types that come into question
(ammonium, nitrate, potassium and chloride) and are especially
adapted to the VARiON
®Plus
700 IQ.
All steps are easily and understandably explained on the display. In
addition, you can call up an Online help for each step. To do so, move
the highlighting to the Online help menu item with the arrow keys
<> or the toggle switch <> and press <OK>. A help text
with detailed information on the relevant operating step appears on the
display. It provides, for example, important instructions on how to keep
the correct basic conditions. When <OK> is pressed once again, the
display returns to the current operating step.
After installing a new or different electrode you have to zero the
electrode to facilitate a long-term evaluation. Details on electrode
zeroing, see section 4.1.
Note
A chloride electrode should be checked for coatings and polished off as
necessary before the check or calibration is carried out (see section
6.4).
ba76000e0101/2012
4 - 9
Page 40
Matrix adjustment, check and calibrationVARiON
®Plus
700 IQ
Preparations and
instructions on how to
keep the basic
conditions
Select a place where clean working conditions and a constant,
sufficiently high temperature are granted (a room, e.g. laboratory).
Temperatures under 10 °C extend the conditioning time
considerably.
Make sure the temperature of all components (sensor, standard
solutions, containers, accessories etc.) is similar and constant. We
recommend to store the standard solutions in the same place where
the check or calibration is carried out.
Use containers and accessories (beaker, stirring rod) that are
absolutely clean and without detergent residues. Detergent residues
can seriously affect the function of the electrodes.
Remove the protective hood and clean the sensor thoroughly.
Before the check, rinse the sensor with standard solution VARiON
ES-2.
Make sure the depth of immersion is sufficient (minimum 5 cm).
Make sure there are no air bubbles in front of the electrode
membrane.
Conditioning times: During the conditioning steps, all relevant
combination electrode voltages are indicated on the display. Thus
you can observe the conditioning process.
®
/
Regular stirring accelerates the conditioning process considerably.
Stirring with a stirring rod or the sensor itself is sufficient.
For calibration, the standard solution is discarded after conditioning.
This is pointed out by a corresponding note in the calibration routine.
It is essential for an exact calibration result.
Use the Online help if you are unsure of anything during calibration.
4.3.2Result of the check
EvaluationAt the end of the check, the result for the combination electrodes is
shown on the display with "+" (successful) or "-" (unsuccessful). The
exact check criteria are given in the Online help of the result display. At
the same time the result is entered in the log book as an info message.
There is no
entry in the calibration history.
4 - 10
ba76000e0101/2012
Page 41
VARiON
®Plus
700 IQMatrix adjustment, check and calibration
4.3.3Result of the calibration
EvaluationWith calibration, the system automatically evaluates the condition of a
combination electrode based on the data of its characteristic curve. The
drift potential and slope are evaluated separately. For a calibration
procedure to be valid, the potential level, slope and drift voltage must
be within certain ranges.
Valid ranges for slope and drift potential:
Value of the slope:50 ... 70 mV
Drift voltage:-45 ... +45 mV
The valid potential levels (MIN, MAX) can be taken from the online help.
Taking over the
determined values
For each successfully calibrated electrode you can individually decide
whether the values should be stored for measurement.
Note
Actions for error elimination are given in chapter 8 W
HATTODOIF ....
ba76000e0101/2012
4 - 11
Page 42
Matrix adjustment, check and calibrationVARiON
Last electrode
zeroing (here, via
calibration)
Chronological list
with the last matrix
adjustments and
calibrations
®Plus
700 IQ
Calibration history
(only available in the
IQ S
ENSOR NET
systems 2020 XT)
DateDate of the calibration or matrix adjustment
SSlope [mV] of the electrode.
In the calibration history, a calibration has the entries ES1 and ES2 in
the Ref1 and Ref2 columns which the matrix adjustment has not:
Fig. 4-3Calibration history (example: VARiON A)
The calibration history contains the following information:
After a matrix adjustment, the values for the slope are marked
Note:
by a star (*) because they were not changed by this procedure.
DVDrift voltage [mV]
After an electrode zeroing and subsequent calibration or matrix
adjustment, 0 is displayed.
Ref1/Ref2Depending on the procedure.
Matrix adjustment: Reference concentration [mg/l]
Calibration: Used standard solution
REvaluation of the calibration or matrix adjustment
+ : Calibration or matrix adjustment.
The sensor measures with the new calibration or adjustment
data.
? : Calibration or matrix adjustment unsuccessful.
Invalid calibration or adjustment data were discarded.
Measurement is continued with the last valid values.
4 - 12
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Page 43
VARiON
®Plus
700 IQMatrix adjustment, check and calibration
Note
If you set the potassium electrode to be displayed as the extra sensor
VARiON K, the calibration history of the potassium electrode can be
viewed under VARiON K. The IQ S
ENSOR NET does not keep an extra
log book for this sensor. Log book messages are displayed with the
main sensor, VARiON A.
For the chloride electrode, or if the potassium electrode is not displayed
as an extra sensor, you can generate a log book message with the
calibration history by means of the menu item, Calib. history Cl (or K)
in the setting table of the relevant sensor. How to do this is described
on page 3-11. The log book message is recorded in the log book of the
relevant main sensor (VARiON A -> message code IC5395 or VARiON
N -> message code IC6396).
ba76000e0101/2012
4 - 13
Page 44
Matrix adjustment, check and calibrationVARiON
®Plus
700 IQ
4 - 14
ba76000e0101/2012
Page 45
VARiON
®Plus
700 IQMeasuring
5Measuring
5.1Measuring operation
Note the data given in section 9.2 APPLICATIONCONDITIONS, especially
the minimum immersion depth of the sensor (> 50 mm with mounted
protective hood).
Note
To keep the sensor clean, we recommend to use the CH cleaning head
(see chapter 7 R
5.2Factors affecting the measured value
Caution
Greases, oils, certain tensides and similar substances can
shorten the operational lifetime of the electrodes. Therefore, they
should not be present in the test sample.
EPLACEMENTPARTSANDACCESSORIES).
®Plus
For measurement with the VARiON
700 IQ the following
influencing variables can be important, depending on the measured
parameter:
Measured parameterInfluencing variable
Ammonium pH value
Potassium ions
Nitrate Chloride ions
Note
The effects of influencing variables on measurement and
compensating actions are described in detail in the YSI primer, I
SELECTIVEMEASUREMENTINONLINEANALYSIS.
ON
ba76000e0101/2012
5 - 1
Page 46
MeasuringVARiON
®Plus
700 IQ
5 - 2
ba76000e0101/2012
Page 47
VARiON
®Plus
700 IQMaintenance and electrode exchange
6Maintenance and electrode exchange
6.1General maintenance notes
Warning
Contact with the sample can be dangerous for the user!
Depending on the type of sample, suitable protective measures
must be taken (protective clothing, protective goggles, etc.).
Maintenance conditionWe recommend to switch on the maintenance condition each time the
sensor is taken out of the measuring position. This avoids unwanted
reactions of linked outputs. More information on the maintenance
VARi O N
condition is given in the relevant IQ S
manual.
®
/EpackThe VARiON®/Epack set with usual replacement parts is available for
maintenance (see chapter 7 R
EPLACEMENTPARTSANDACCESSORIES).
ENSOR NET system operating
Maintenance and
calibration case,
VARi ON
®
Case
For adjustment, calibration and maintenance activities on site, the
VARiON
®
Case is available. The convenient case provides room for all
required accessories (details, see next page).
ba76000e0101/2012
6 - 1
Page 48
Maintenance and electrode exchangeVARiON
9
6
7
10
8
11
2
3
4
5
1
ba76000e01 12/2011
VARiON
®
Plus
700 IQ
Operatingmanual
IQSENSOR NET
Modularcombination sensor
forammonium and nitrate
®Plus
700 IQ
Fig. 6-1Sample equipment of the VARiON® Case calibration and maintenance case
1Blind plug
2Special socket wrench
3Polishing strip
4Replacement electrodes with watering caps
5Compartments for various accessories (wiping cloths, sample
6Recess for sensor
7Storing solution for reference electrode
bottles, personal protective equipment etc.)
8Replacement reference electrode with storing aids
9Calibration standards
10Operating manual
11Protective hood
6 - 2
ba76000e0101/2012
Page 49
VARiON
®Plus
700 IQMaintenance and electrode exchange
6.2Exterior cleaning
Note
To keep the electrodes clean, we recommend to use the CH cleaning
head (see chapter 7 R
EPLACEMENTPARTSANDACCESSORIES).
With normal operation (e.g. municipal wastewater) we strongly
recommend to clean the outside of the sensor and calibrate:
when it is strongly contaminated (after visual check)
if erroneous measured values are suspected
each time before removing or exchanging an electrode
Caution
Do not use any detergents for cleaning. Detergent residues can
seriously affect the function of the electrodes.
Note
We recommend to clean the sensor shaft and electrodes while the
sensor is still connected to the sensor connection cable. Otherwise,
moisture and/or dirt can get into the plug connection where it can cause
contact problems.
If you would like to disconnect the sensor from the sensor connection
cable, please note the following points:
Before disconnecting the sensor from the SACIQ sensor connection
cable, remove any larger pieces of contamination from the sensor,
particularly in the area of the plug connection (brush it off in a bucket
of tap water, wash it off with a hose or wipe it off with a cloth).
Unscrew the sensor from the SACIQ sensor connection cable.
Always place a protective cap on the plug head of the sensor and on
the SACIQ sensor connection cable so that no moisture or dirt can
get into the contacting surfaces.
In corrosive environments, close the socket of the sensor
connection cable with the screwable SACIQ-Plug when it is dry in
order to protect the electrical contacts from corrosion. The protective
plug is available as an accessory (see section 7.2 G
ACCESSORIES).
ENERAL
Cleaning the sensorClean the sensor shaft with tap water and a soft sponge or brush.
Remove the protective hood. The electrodes are best cleaned under
running tap water using a soft toothbrush or brush.
ba76000e0101/2012
6 - 3
Page 50
Maintenance and electrode exchangeVARiON
1
2
3
®Plus
700 IQ
Cleaning the coupling
ring of the protective
hood
The coupling ring can be unscrewed and dismantled for cleaning as
follows:
Fig. 6-2Dismantling the coupling ring
1Remove the retaining ring (pos. 1 in Fig. 6-2).
2Remove the intermediate ring (pos. 2) and sealing ring (pos.
3).
After the parts have been cleaned, reassemble the coupling ring in
reverse order. When doing so make sure that the tapered side of the
intermediate ring (pos. 2) points towards the sealing ring (pos. 3).
6 - 4
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Page 51
VARiON
®Plus
700 IQMaintenance and electrode exchange
6.3Exchanging the electrodes
Caution
The sensor can be damaged by dirt and moisture. Each time
before dismantling an electrode carefully clean the area around
the electrodes (section 6.2). Before mounting an electrode make
sure the area behind the sealing ring of the electrode and the
receptacle are dry and clean. The VARiON
submersed when the electrodes or original blind plugs are
mounted.
Use the special socket wrench provided to dismantle an electrode.
Electrodes are installed as described in section 3.4.1 E
SENSORWITHELECTRODES.
®Plus
700 IQ may only be
QUIPPINGTHE
Recognizing the
electrode type from
outside
When mounted, the electrodes can be recognized by the following
features:
ElectrodeHexagonFront
Other features
surface
®
VARiON
Refblackblack– Thread at the
hexagon
®Plus
VARiON
NH4blackblack– Hexagon
without thread
®Plus
VARiON
VARiON
Kblackwhite
®Plus
NO3whitewhite– Labeled with the
electrode type
ba76000e0101/2012
®Plus
VARiON
Clblackblack– Larger
membrane
– Membrane flush
with the front
surface
Note
For the correct storage of the electrodes please follow the instructions
in section 3.3 N
OTESONTHEHANDLINGOFTHEELECTRODES.
6 - 5
Page 52
Maintenance and electrode exchangeVARiON
SF 300
6.4Polishing the chloride electrode
Caused by the test medium, a coating can develop on the surface of
the chloride electrode, which reduces the electrode slope. To maintain
a proper chloride compensation the surface must be renewed by
polishing at regular intervals.
Caution
Danger of damaging the electrode. Exclusively use the SF 300
polishing strip. Never use commercial sandpaper or similar.
The polishing can be done while the electrode is mounted (remove the
protective hood as necessary). To polish the electrode, use the SF 300
polishing strip provided with the electrode. Moisten the rough side of
the polishing strip with water and polish off any coatings under slight
pressure.
®Plus
700 IQ
Fig. 6-3Polishing the chloride electrode
6 - 6
ba76000e0101/2012
Page 53
VARiON
®Plus
700 IQReplacement parts and accessories
7Replacement parts and accessories
7.1Electrodes
Exchange electrodes
Storing equipment
DescriptionModelOrder no.
®
Reference electrodeVARiON
Ammonium electrodeVARiON
Nitrate electrodeVARiON
Potassium electrodeVARiON
Chloride electrodeVARiON
Ref107 042Y
®Plus
NH4107 044Y
®Plus
NO3107 045Y
®Plus
K107 046Y
®Plus
Cl107 047Y
DescriptionModelOrder no.
250 ml potassium chloride
KCl-250109 705Y
solution for the storage of the
electrode
7.2General accessories
Standard solutions
for calibration
Maintenance equipment
Protective plugs
DescriptionModelOrder no.
®
1 liter combination standard 1
VARiON
/ES-1107 050Y
(low concentration)
®
1 liter combination standard 2
VARiON
/ES-2107 052Y
(high concentration)
DescriptionModelOrder no.
Polishing filmSF 300203 680Y
DescriptionModelOrder no.
Screwable plug for sensor
SACIQ-Plug480 065Y
connection cable
ba76000e0101/2012
7 - 1
Page 54
Replacement parts and accessoriesVARiON
®Plus
700 IQ
General replacement
parts
Calibration and
maintenance case
DescriptionModelOrder no.
®
Protective hoodVARiON
Replacement parts set,
VARiON
700 IQ-SK107 056Y
®
/Epack107 057Y
comprising
– 1 blind plug for receptacle
– 1 special socket wrench
– 3 replacement sealing rings
for electrodes/blind plugs
– Storing equipment for
electrodes:
1 nut (transparent),
1 watering cap with sponge
1 nut (black)
1 watering cap (without
sponge) for reference
electrode
DescriptionModelOrder no.
®
Empty case for the storage of
VARiON
Case107 058Y
calibration and maintenance
equipment for the
®Plus
VARiON
700 IQ
7 - 2
Components for
cleaning system
DescriptionModelOrder no.
Cleaning headCH900 107Y
Passive valve moduleDIQ/CHV472 007Y
Active valve module (does not
MIQ/CHV PLUS480 018Y
require a free relay output in the
ENSOR NET system)
IQ S
Air compressor supplying the
sensor cleaning system with
cleaning air
Cleaning Air Box
115 VAC
230 VAC
480 017Y
480 019Y
Note
Information on other IQ S
ENSOR NET accessories is given in the YSI
catalog and on the Internet.
ba76000e0101/2012
Page 55
VARiON
®Plus
700 IQWhat to do if ...
8What to do if ...
8.1Interpretation of the drift voltage
The drift voltage is influenced by the potential levels of the
measurement electrode and reference electrode. If the potential levels
shift, e.g. caused by aging, both parts can move into the same direction
or into opposite directions. The comparison of the drift voltages of two
or three electrodes enables to draw conclusions concerning the state
of individual electrodes if a matrix adjustment or calibration resulted in
an invalid or considerably deviating drift voltage.
Assessment aidsView the calibration history of the combination electrodes. In the
following cases, assessment is relatively easy:
If the drift voltages of all combination electrodes show the same
trend, i. e. the drift voltages have shifted in the same direction
(positive or negative) by approximately the same amount, this
indicates that the potential level of the reference electrode has
shifted. The reference electrode is possibly highly contaminated or
at the end of its service life.
If the drift voltages of all combination electrodes do not show a trend
but shift by different amounts into different directions, the potential
level of the reference electrode has not changed considerably. The
invalid drift voltage is probably caused by a defective measuring
electrode. The measuring electrode is possibly highly contaminated
or at the end of its service life.
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8 - 1
Page 56
What to do if ...VARiON
8.2Error causes and remedies
®Plus
700 IQ
No measured value
display
CauseRemedy
– Sensor not connected– Connect the sensor
– Incorrect electrode
– Correct electrode equipment
equipment
– Electrode(s) not at all or
incorrectly recognized by the
system
– Check the installation and
contacts of the electrode (gapfree mounting)
– Check electrode receptacle for
moisture
– If necessary, unscrew the
electrode/blind plug and
thoroughly dry the electrode/
blind plug and receptacle
– Unknown– Look for error messages in the
log book
– Liquid in the sensor shaft– Sensor defective, send it back
Measurement provides
implausible measured
values
CauseRemedy
– No matrix adjustment or
calibration carried out
– Adjustment or calibration
error (e.g. incorrect lab
values, contaminated
standard solutions)
– Manual interfering ions
compensation works with an
unsuitable value
– Electrode(s) not at all or
incorrectly recognized by the
system
– Adjust or calibrate the
electrode
– Check the adjustment or
calibration conditions
– Readjust or recalibrate the
electrode
– Determine and enter the
interfering ions compensation
once again, then recalibrate
– Check the installation and
contacts of the electrode (gapfree mounting)
– Check electrode receptacle for
moisture
– If necessary, unscrew the
electrode/blind plug and
thoroughly dry the electrode/
blind plug and receptacle
8 - 2
ba76000e0101/2012
Page 57
VARiON
®Plus
700 IQWhat to do if ...
CauseRemedy
– Electrode contaminated– Clean the electrode (see
section 6.2)
– Liquid in the sensor shaft– Sensor defective, send it back
Measurement provides
jumping, unstable or
drifting values
CauseRemedy
– Measurement /
compensation electrode:
Electrode membrane not
moistened by measuring
solution, e.g. due to air in
front of the membrane
– Moisten membrane with
deionized water using a wash
bottle. To do so, position the
opening of the wash bottle on
the membrane and splash
against the membrane
vigorously
– Measurement /
compensation electrode:
Air bubble behind the
membrane
– Measurement electrode /
compensation and reference
electrode:
Insufficient electrical contact
in the electrode receptacle
– Hold the electrode in a vertical
position with the membrane
down and knock it on the side
with the special socket wrench
– Check the installation and
contacts of the electrode (gapfree mounting)
– Check electrode receptacle for
moisture
– If necessary, unscrew the
electrode/blind plug and
thoroughly dry the electrode/
blind plug and receptacle
– Replace defective electrode
compensation electrode or
reference electrode leaky or
damaged
– Liquid in the sensor shaft– Sensor defective, send it back
8 - 3
Page 58
What to do if ...VARiON
®Plus
700 IQ
Faulty result of the
matrix adjustment
Faulty result of
calibration
CauseRemedy
– Error during procedure, e.g.
incorrect lab values
– Check the basic conditions
– Follow the practical notes on
page 4-4 or in the online help
– Recalibrate the electrode
– Reference electrode or
– Replace defective electrode
measurement electrode
defective due to aging (see
section 8.1)
CauseRemedy
– Error during procedure, e.g.
contaminated standard
solutions
– Check the basic conditions
– Follow the practical notes on
page 4-10 or in the online help
– Recalibrate the electrode
– Reference electrode or
– Replace defective electrode
measurement electrode
defective due to aging (see
section 8.1)
8 - 4
ba76000e0101/2012
Page 59
VARiON
®Plus
700 IQTechnical data
9Technical data
9.1Measuring characteristics
Measuring principlePotentiometric measurement by means of ion sensitive electrodes.
Modular structure with jointly used reference electrode and ion
sensitive electrodes. Integrated microprocessor electronics, screened
2-wire connection for power and data transmission.
Measured parameters
Measuring ranges and
resolution,
Ammonium
measurement
Measuring ranges and
resolution,
Nitrate measurement
Main measured parametersAmmonium and/or nitrate
(depending on the electrode
equipment)
Secondary measured parameterTemperature
Compensation parametersPotassium or chloride
(depending on the electrode
equipment)
Measuring
Measuring rangeResolution
mode
NH4-N0.1 ... 100.0 mg/l
1 ... 1000 mg/l
NH40.1 ... 129.0 mg/l
1 ... 1290 mg/l
0.1 mg/l
1 mg/l
0.1 mg/l
1 mg/l
mV-2000 ... +2000 mV1 mV
Measuring
Measuring rangeResolution
mode
NO3-N0.1 ... 100.0 mg/l
1 ... 1000 mg/l
0.1 mg/l
1 mg/l
Measuring ranges and
resolution,
Potassium
measurement
ba76000e0101/2012
NO30.5 ... 450.0 mg/l
5 ... 4500 mg/l
0.5 mg/l
5 mg/l
mV-2000 ... +2000 mV1 mV
Measuring
Measuring rangeResolution
mode
K1 ... 1000 mg/l1 mg/l
mV-2000 ... +2000 mV1 mV
9 - 1
Page 60
Technical dataVARiON
®Plus
700 IQ
Measuring ranges and
resolution,
Chloride measurement
Interfering ions
compensation
Selectable procedures
for
interfering ions
compensation
Measuring
Measuring rangeResolution
mode
Cl1 ... 1000 mg/l1 mg/l
mV-2000 ... +2000 mV1 mV
Main measured parameterInterfering ions that can be
compensated for
+
AmmoniumPotassium (K
NitrateChloride (Cl
)
-
)
Compensation proceduresDescription
Automaticup to 1000 mg/l interfering ions
when equipped with the
corresponding compensation
electrode (chloride for nitrate
measurement or potassium for
ammonium measurement)
Temperature
measurement
Temperature
compensation
Manualwithout compensation electrode
by manual entry of the interfering
ions
concentration
(range 1 ... 1000 mg/l).
Sensing element typeintegrated NTC
Measuring range- 5 °C ... + 60 °C (23 ... 140 °F)
Accuracy± 0.5 K
Resolution0.1 K
Response time t
95
< 20 s
automatic in the range 0 °C ... 40 °C (32 ... 104 °F)
9 - 2
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VARiON
®Plus
700 IQTechnical data
9.2Application conditions
Allowed
Measuring medium0 °C ... 40 °C (32 ... 104 °F)
temperature range
Storage/transport0 °C ... 40 °C (32 ... 104 °F)
Allowed pH range of the
4 ... 12
measuring medium
Pressure resistanceSensor with the electrodes or blind plugs screwed in and the SACIQ
sensor connection cable connected:
Max. allowed overpressure2 x 104 Pa (0.2 bar)
Type of protectionSensor with the electrodes or blind plugs screwed in and the SACIQ
sensor connection cable connected:
IP 68, 0.2 bar (2 x 10
4
Pa)
Depth of immersionmin. 50 mm; max. 2 m depth
Operating positionElectrode support pointing downward (maximum angle to the plumb
line = 60 °)
Fields of application Control / monitoring in the aeration tank of a waste water treatment
plant
Water and waste water monitoring
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9 - 3
Page 62
Technical dataVARiON
48 5540
392
Socket SACIQ...
Minimum immersion
depth 50 mm
9.3General data
Dimensions
®Plus
700 IQ
Weight (without sensor
approx. 670 g with protective hood
connection cable)
Connection techniqueConnection via SACIQ sensor connection cable
Material
ShaftV4A stainless steel 1.4571
Protective hoodPOM
Electrode supportPOM
Temperature probeV4A stainless steel 1.4571
Plug head connector housingPOM
Plug, 3-poleETFE (blue) Tefzel
Electrodessee section 9.5
Instrument safety
Applicable norms– EN 61010-1
– UL 3111-1
– CAN/CSA C22.2 No. 1010.1
®
9 - 4
9.4Electrical data
Nominal voltagemax. 24 VDC
via the IQ S
chapter
IQ S
manual)
Power consumption0.2 W
Protective classIII
ENSOR NET system operating
ENSOR NET (details see
TECHNICALDATA of the
ba76000e0101/2012
Page 63
VARiON
®Plus
700 IQTechnical data
9.5Data of the VARiON
®Plus
electrodes
9.5.1Response times
Response time t
90
Measured at 20 °C (68 °F)
and a concentration change
(937) 767-7241
Monday through Friday, 8:00 AM to 5:00 PM ET
Fax
:(937) 767-1058
Email
:environmental@ysi.com
Mail:YSI Incorporated
1725 Brannum Lane
Yellow Springs, OH 45387
USA
Internet
:www.ysi.com
When placing an order please have the following information available:
YSI account number (if available)Name and Phone Number
Model number or brief descriptionBilling and shipping address
QuantityPurchase Order or Credit Card
10.2Service Information
YSI has authorized service centers throughout the United States and
Internationally. For the nearest service center information, please visit
www.ysi.com
directly at 800-897-4151.
When returning a product for service, include the Product Return form
with cleaning certification. The form must be completely filled out for an
YSI Service Center to accept the instrument for service. The Product
Return form may be downloaded at www.ysi.com
‘Support‘ tab.
and click ‘Support’ or contact YSI Technical Support
and clicking on the
ba76000e0101/2012
10 - 1
Page 66
Contact InformationVARiON
®Plus
700 IQ
10 - 2
ba76000e0101/2012
Page 67
VARiON
®Plus
700 IQIndexes
11Indexes
11.1Explanation of the messages
This chapter contains a list of all the message codes and related
message texts that can occur in the log book of the IQ S
®Plus
system for the VARiON
700 IQ sensor.
Note
Information on
the contents and structure of the log book and
the structure of the message code
ENSOR NET
is given in the L
OGBOOK chapter of the IQ SENSOR NET system
operating manual.
Note
The last three digits of the message code identify the source of the
message:
521 = VARiON+700 IQ (armature / component class, ADA adapters)
395 = VARiON A (ammonium / potassium sensor)
396 = VARiON N (nitrate sensor)
11.1.1 Error messages
Message codeMessage text
EA1395Meas. range exceeded or undercut
* Check process
* Select other meas. range
EA1396Meas. range exceeded or undercut
* Check process
* Select other meas. range
EA2521Sensor temperature too high!
* Check process and application
EA3521Sensor temperature too low!
* Check process and application
EAN395Potassium measurement: range exceeded or undercut
* Check process
EAO396Chloride measurement: range exceeded or undercut
* Check process
ba76000e0101/2012
11 - 1
Page 68
IndexesVARiON
Message codeMessage text
EIA521Incorrect equipment
* for correct electrode equipment see operating manual
ES1521Component hardware defective
* Contact service
11.1.2 Info messages
Message codeMessage text
IC3395K electrode has been successfully calibrated
* For calibration data, see calibration history
IC4396Cl electrode has been successfully calibrated
* For calibration data, see calibration history
®Plus
700 IQ
IC5395(this message contains calibration data of the potassium electrode)
IC6396(this message contains calibration data of the chloride electrode)
IC7395
IC7396
Sensor could not be calibrated,
Measuring with old calibration values
* Check calibration conditions and calibration standard
* View calibration history
* Service sensor immediately
(see operating manual)
IIA521(This message is generated when the electrode equipment is changed.
It informs you of the new assignment of the electrode receptacles)
IAI397see VARiON A
11 - 2
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Page 69
VARiON
®Plus
700 IQIndexes
11.2Status info
The status info is a piece of coded information about the current state
of a sensor. Each sensor sends this status info to the controller. The
status info of sensors consists of 32 bits, each of which can have the
value 0 or 1.
0 1 2 3 4 5 6 78 9 10 11 12 13 14 15
Status info,
general structure
VARiON
®Plus
700 IQ
1 0 0 0 0 0 0 00 0 0 0 0 0 0 0(general)
0 0 0 0 0 0 0 00 0 0 0 0 0 0 0(internal)
16 17 18 19 20 21 22 2324 25 26 27 28 29 30 31
The bits 0 - 15 are reserved for general information.
The bits 16 - 21 are reserved for internal service information.
You obtain the status info:
via a manual query in the menu, Einstellungen/Settings/Service/List
of all components (see system operating manual)
via an automated query
– of a superordinate process control (e. g. when connected to the
Profibus)
– of the IQ Data Server (see operating manual of the
IQ S
ENSOR NET software pack)
Note
The evaluation of the status info, e.g. in the case of an automated
query, has to be made individually for each bit.
Status bitExplanation
Status info
ba76000e0101/2012
Bit 0Component hardware defective
Bit 1-31-
11 - 3
Page 70
IndexesVARiON
®Plus
700 IQ
11 - 4
ba76000e0101/2012
Page 71
Page 72
1725 Brannum Lane
Yellow Springs, Ohio 45387 USA
+1 937-767-7241
800-765-4974 (US)
FAX (937) 767-1058
Email: environmental@ysi.com
Internet: www.ysi.com
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