YSI IQSENSORNET User Manual

Page 1
IQ SENSOR NET
VARiON
Operating manual
®Plus
700 IQ
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IQ SENSOR NET
Modular combination sensor
Page 2
VARiON
®Plus
700 IQ
Note
For the most recent version of the manual, please visit www.ysi.com
.
Contact YSI
1725 Brannum Lane Yellow Springs, OH 45387 USA Tel: +1 937-767-7241
800-765-4974 Email: environmental@ysi.com Internet: www.ysi.com
Copyright © 2012 Xylem Inc.
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VARiON
®Plus
700 IQ Contents
VARiON
®Plus
700 IQ - Contents
1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.1 How to use this component operating manual . . . . . . . . 1-1
1.2 Structure of the combination sensor VARiON
1.3 Recommended fields of application . . . . . . . . . . . . . . . . 1-4
®Plus
700 IQ . . . . . . . . . . . . . . . . . . . . . . 1-2
2 Safety instructions . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-2
2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 2-2
3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.1 Scopes of delivery . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1
3.2 IQ S
3.3 Notes on the handling of the electrodes . . . . . . . . . . . . . 3-3
3.4 Preparing the sensor for measurement . . . . . . . . . . . . . 3-5
3.5 Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-10
ENSOR NET system requirements . . . . . . . . . . . . . . 3-2
3.3.1 Reference electrode . . . . . . . . . . . . . . . . . . . . . 3-3
3.3.2 Measurement electrodes and compensation
electrodes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-4
3.4.1 Equipping the sensor with electrodes . . . . . . . . 3-5
3.4.2 Mounting the protective hood . . . . . . . . . . . . . . 3-7
3.4.3 Connecting the sensor to the IQ S
3.5.1 General information . . . . . . . . . . . . . . . . . . . . . 3-10
3.5.2 Setting table of the VARiON A (ammonium
sensor) . . . . . . . . . . . . . . . . . . . . . . . . . 3-11
3.5.3 Setting table of the VARiON N (nitrate sensor) 3-14
3.5.4 Setting table of the VARiON K (potassium
sensor) . . . . . . . . . . . . . . . . . . . . . . . . . 3-16
ENSOR NET .3-8
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4 Matrix adjustment, check and calibration . . . . . . . . . 4-1
4.1 General information . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1
4.2 Matrix adjustment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-3
4.2.1 General information on matrix adjustment . . . . 4-3
4.2.2 Carrying out the matrix adjustment . . . . . . . . . . 4-3
4.2.3 Result of the matrix adjustment . . . . . . . . . . . . . 4-5
4.2.4 Program extension . . . . . . . . . . . . . . . . . . . . . . 4-7
4.3 Check and calibration in standard solutions . . . . . . . . . . 4-8
4.3.1 General information on checking and
calibrating . . . . . . . . . . . . . . . . . . . . . . . . 4-8
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Contents VARiON
4.3.2 Result of the check . . . . . . . . . . . . . . . . . . . . .4-10
4.3.3 Result of the calibration . . . . . . . . . . . . . . . . . .4-11
5 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-1
5.1 Measuring operation . . . . . . . . . . . . . . . . . . . . . . . . . . . .5-1
5.2 Factors affecting the measured value . . . . . . . . . . . . . . .5-1
6 Maintenance and electrode exchange . . . . . . . . . . . . 6-1
6.1 General maintenance notes . . . . . . . . . . . . . . . . . . . . . .6-1
6.2 Exterior cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6-3
6.3 Exchanging the electrodes . . . . . . . . . . . . . . . . . . . . . . .6-5
6.4 Polishing the chloride electrode . . . . . . . . . . . . . . . . . . .6-6
7 Replacement parts and accessories . . . . . . . . . . . . . 7-1
7.1 Electrodes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7-1
7.2 General accessories . . . . . . . . . . . . . . . . . . . . . . . . . . . .7-1
®Plus
700 IQ
8 What to do if ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-1
8.1 Interpretation of the drift voltage . . . . . . . . . . . . . . . . . . .8-1
8.2 Error causes and remedies . . . . . . . . . . . . . . . . . . . . . . .8-2
9 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9-1
9.1 Measuring characteristics . . . . . . . . . . . . . . . . . . . . . . . .9-1
9.2 Application conditions . . . . . . . . . . . . . . . . . . . . . . . . . . .9-3
9.3 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9-4
9.4 Electrical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9-4
9.5 Data of the VARiON
®Plus
electrodes . . . . . . . . . . . . . . .9-5
9.5.1 Response times . . . . . . . . . . . . . . . . . . . . . . . . .9-5
9.5.2 Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9-5
9.5.3 Weights . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9-5
10 Contact Information . . . . . . . . . . . . . . . . . . . . . . . . . . 10-1
10.1 Ordering & Technical Support . . . . . . . . . . . . . . . . . . .10-1
10.2 Service Information . . . . . . . . . . . . . . . . . . . . . . . . . . . .10-1
11 Indexes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11-1
11.1 Explanation of the messages . . . . . . . . . . . . . . . . . . . .11-1
11.1.1 Error messages . . . . . . . . . . . . . . . . . . . . . . . .11-1
11.1.2 Info messages . . . . . . . . . . . . . . . . . . . . . . . . .11-2
11.2 Status info . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11-3
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VARiON
IQ Sensor Net Operating Manual
System
Operating
Manual
(Ring Binder)
IQ Sensor Operating
Manual
MIQ Module
Operating
Manual
MIQ Terminal
Operating
Manual
Component Operating Manuals
®Plus
700 IQ Overview
Structure of the
IQ SENSOR NEToperating
manual

1Overview

1.1 How to use this component operating manual

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Fig. 1-1 Structure of the IQ SENSOR NET operating manual
The IQ SENSOR NET operating manual has a modular structure like the
IQ S
ENSOR NET itself. It consists of a system operating manual and the
operating manuals of all the components used.
Please file this component operating manual in the ring binder of the system operating manual.
1 - 1
Page 6
Overview VARiON
123 4 5
1.2 Structure of the combination sensor VARi ON
®Plus
700 IQ
®Plus
700 IQ
Electrodes For a VARiON
Automatic interfering
ions compensation
Fig. 1-2 Structure of the combination sensor VARiON
®Plus
700 IQ
1 Protective hood
2 Temperature probe
3 Electrode support with electrodes (sample equipment)
4 Sensor shaft
5 Plug head connector
®Plus
700 IQ combination sensor ready to measure, a jointly used reference electrode and at least one ion sensitive electrode for the main measured parameters (ammonium, nitrate) are required. The electrodes are screwed into the electrode support. The electrode support has four receptacles for this.
®Plus
The VARiON
700 IQ enables the automatic interfering ions compensation for one main measured parameter. Thus the influence of certain interfering ions due to measuring technique can be automatically compensated for. Interfering ions in water / waste water applications are mostly chloride for nitrate measurement and potassium for ammonium measurement. To determine the interfering ions concentration, another electrode (compensation electrode) is mounted into a free receptacle.
Note
Information on the fundamentals of measuring with ion sensitive electrodes are given in the YSI primer, I
ONLINE ANALYSIS.
Operating modes and
electrode equipment
1 - 2
Due to its modular structure, the VARiON to various requirements (see table on the following page).
ON SELECTIVE MEASUREMENT IN
®Plus
700 IQ can be adapted
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VARiON
Ref
VARiON
®Plus
NH4
VARiON
®Plus
K
Blind plug
VARiON
®
Ref
(recess)
Ref
VARiON® Ref
VARiON
®Plus
NO3
VARiON
®Plus
Cl
Blind plug
Ref
VARiON® Ref
VARiON
®Plus
NH4
VARiON
®Plus
K
VARiON
®Plus
NO3
Ref
VARiON® Ref
VARiON
®Plus
NO3
VARiON
®Plus
Cl
VARiON
®Plus
NH4
Ref
VARiON
®Plus
NH4
Blind plug
Blind plug
VARiON
®
Ref
Ref
VARiON® Ref
VARiON
®Plus
NO3
Blind plug
Blind plug
Ref
VARiON® Ref
VARiON
®Plus
NH4
VARiON
®Plus
NO3
Blind plug
®Plus
700 IQ Overview
Notes: The reference electrode has an extra receptacle marked by a recess. The ion sensitive electrodes can be mounted in the remaining three receptacles in any order. Empty receptacles have to be closed with the VARiON
Nitrate measurement,
®
BP blind plug.
Operating mode Electrode equipment
Ammonium
measurement,
compensated
compensated
Ammonium measurement, compensated,
plus nitrate
measurement
Nitrate measurement,
compensated
plus ammonium
measurement
Ammonium
measurement
Nitrate measurement
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Ammonium measurement,
nitrate measurement
1 - 3
Page 8
Overview VARiON
®Plus
700 IQ
Calibration free
operation
Shielding of the
VARiON
®Plus
700 IQ
The VARiON
®Plus
700 IQ combination sensor is immediately ready to measure after being equipped with electrodes. For precise measurements, it is only necessary to adjust the electrodes to the sample matrix ("matrix adjustment"). In the recommended application (see section 1.3 R
ECOMMENDED FIELDS OF APPLICATION), the measuring
characteristics of the electrodes remain stable for their entire service life. Thus, calibration is no longer required.
Possible changes of the sample matrix can be determined by occasional comparison measurements (e.g. photometer) and compensated for by a new matrix adjustment. The sensor does not have to be taken out of the sample for this.
The VARiON electrodes in conjunction with the
®Plus
700 IQ combination sensor and the corresponding
IQ SENSOR NET system form a
measuring system that is protected to a high degree against low and high frequency interference as well as against the indirect effects of lightning strikes.

1.3 Recommended fields of application

The VARiON
®Plus
700 IQ combination sensor is a sensor for the online determination of ammonium ions and/or nitrate ions in water / waste water applications. It supplements D. O. measurement in the aeration tank of waste water treatment plants and enables an efficient process control of nitrogen removal.
Note
More detailed information on measuring with ion sensitive electrodes is given in the YSI primer, I
ANALYSIS.
ON SELECTIVE MEASUREMENT IN ONLINE
1 - 4
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Page 9
VARiON
®Plus
700 IQ Safety instructions

2 Safety instructions

Special user
qualifications
General safety
instructions
This component operating manual contains special instructions that
®Plus
must be followed in the operation of the VARiON
700 IQ combination sensor. Thus, it is essential to read this component operating manual before carrying out any work using this sensor. In addition to this manual, the S
AFETY chapter of the IQ SENSOR NET
system operating manual must be followed.
Always keep this component operating manual together with the system operating manual and any other component operating manuals in the vicinity of the IQ S
The VARiON
®Plus
ENSOR NET system.
700 IQ combination sensor was developed for applications in online measurement - essentially in the field of wastewater treatment. Thus, we assume that the operators are familiar with the necessary precautions to take when dealing with chemicals as a result of their professional training and experience.
Safety instructions in this operating manual are identified by the warning symbol (triangle) in the left column. The signal word (e. g. "Caution") indicates the level of danger:
Warning
indicates instructions that must be followed precisely in order to prevent serious dangers to persons.
Other labels
Caution
indicates instructions that must be followed precisely in order to avoid slight injuries or damage to the instrument or the environment.
Note
indicates notes that draw your attention to special features.
Note
indicates cross-references to other documents, e.g. operating manuals.
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2 - 1
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Safety instructions VARiON

2.1 Authorized use

®Plus
700 IQ
Function and
operational safety
The authorized use of the VARiON in consists of its use as a sensor within the IQ S
®Plus
700 IQ with the electrodes built
ENSOR NET.
Please observe the technical specifications according to chapter 9
ECHNICAL DATA. Only operation according to the instructions given in
T this operating manual is considered to be authorized.
Any other use is considered to be unauthorized. Unauthorized use invalidates any claims with regard to the guarantee.
Caution
Only connect and operate the sensor together with IQ SENSOR NET
accessories.

2.2 General safety instructions

The sensor left the factory in a safe and secure technical condition.
The failure-free function and operational safety of the sensor is only guaranteed if the generally applicable safety measures and the special safety instructions in this operating manual are followed during its use.
The failure-free function and operational safety of the sensor is only guaranteed under the environmental conditions that are specified in chapter 9 T
The specified temperature (chapter 9 T
ECHNICAL DATA.
ECHNICAL DATA) must be
maintained during the operation and transport of the sensor. Protect the sensor, particularly against frost or overheating.
Caution
The sensor may only be opened by specialists authorized by YSI.
2 - 2
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VARiON
®Plus
700 IQ Safety instructions
Safe operation If safe operation is no longer possible, the sensor must be taken out of
operation and secured against inadvertent operation.
Safe operation is no longer possible if the sensor:
has been damaged in transport
has been stored under adverse conditions for a lengthy period of
time
is visibly damaged
no longer operates as described in this manual.
If you are in any doubt, contact the supplier of your sensor.
Obligations of the
operator
The operator of the sensor must ensure that the following rules and regulations are followed when dealing with hazardous substances:
EEC directives for protective labor legislation
National protective labor legislation
Safety regulations
Safety data sheets of the chemical manufacturer.
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Page 12
Safety instructions VARiON
®Plus
700 IQ
2 - 4
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Page 13
VARiON
®Plus
700 IQ Commissioning

3 Commissioning

3.1 Scopes of delivery

YSI supplies the VARiON
®Plus
700 IQ in sets for different measuring
requirements. Each set contains the following components:
Unequipped sensor VARiON
®Plus
700 IQ. The electrode
receptacles are closed with blind plugs
Reference electrode, VARiON
®
Ref
Depending on the set, the suitable selection from the following
measurement and compensation electrodes:
– VARiON
– VARiON
– VARiON
– VARiON
®Plus
NH4 (ammonium electrode)
®Plus
K (potassium electrode for compensation)
®Plus
NO3 (nitrate electrode)
®Plus
Cl (chloride electrode for compensation)
Special socket wrench
Protective hood VARiON
®
700 IQ-SK
Potassium chloride solution for storing the reference electrode
Operating manual and YSI primer, I
ONLINE ANALYSIS.
ON SELECTIVE MEASUREMENT IN
Note
Information on the available sets is given in the YSI catalog and on the Internet.
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3 - 1
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Commissioning VARiON

3.2 IQ SENSOR NET system requirements

®Plus
700 IQ
Software statuses of the
controller and terminal
components
Operation of the VARiON statuses in the IQ S
®Plus
700 IQ requires the following software
ENSOR NET, depending on the system:
DIQ/S 182 Software: Version 3.21
or higher
MIQ/MC Controller software: Version 2.83
or higher
IQ software pack Software: Version 5.00
or higher
3 - 2
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VARiON
Watering cap
Junction
Reference electrode
Nut
Sealing ring
®Plus
700 IQ Commissioning

3.3 Notes on the handling of the electrodes

Commissioning
The electrodes of the VARiON
®Plus
700 IQ combination sensor were developed for the rough use in waste water treatment plants. They are, however, precision parts that can be damaged by inappropriate use. Therefore, exactly follow the instructions in the two following chapters.

3.3.1 Reference electrode

Fig. 3-1 Reference electrode with storing aids
In the delivery condition, the electrode is equipped with a watering cap and a nut that protects the screw-in thread. The watering cap contains 3 mol/l potassium chloride solution. Before mounting, unscrew the watering cap. Then, using the special hexagon key, unscrew the electrode from the nut. Keep both storing aids in case you want to store the electrode.
Caution
The junction of the reference electrode must not
dry up (follow notes on storage)be damagedbe brought into contact with grease.
Notes on storage If you will not use the electrode for a longer period of time, screw the
electrode into the nut as far as it will go. Fill the watering cap to the brim with 3 mol/l potassium chloride solution and tightly screw the watering cap on the electrode by hand.
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Commissioning VARiON
Watering cap
Electrode
Nut
Sealing ring

3.3.2 Measurement electrodes and compensation electrodes

Commissioning
Fig. 3-2 Measurement electrode or compensation electrode with storing aids
In the delivery condition, each electrode is equipped with a watering cap and a nut that protects the screw-in thread. Prior to installation, first remove the watering cap and, using the special hexagon key, unscrew the electrode from the nut. Keep both storing aids in case you want to store the electrode.
®Plus
700 IQ
Caution
The membrane of the electrode must not
dry up (follow notes on storage)be damagedbe brought into contact with grease.
Notes on storage If you will not use the electrode for a longer period of time, screw the
electrode into the nut as far as it will go. Soak the foam insert in the
®
watering cap with VARiON
/ES-1 standard solution (lower
concentration) and plug the electrode into the watering cap.
Caution
Make sure to use the correct solution for the watering cap (VARiON solution of the reference electrode instead the function of the electrode can be seriously damaged.
®
/ES -1 standard solution). If you use the watering
3 - 4
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VARiON
Measurement and compensation electrodes
Reference electrode
Blind plug
Mark for reference electrode
Special socket wrench
®Plus
700 IQ Commissioning

3.4 Preparing the sensor for measurement

3.4.1 Equipping the sensor with electrodes

Caution
The sensor can be damaged by dirt and moisture. Before mounting the electrodes make sure the area behind the sealing ring of the electrodes and the receptacle are dry and clean. The VARiON or original blind plugs are mounted.
Note
More detailed information on the electrode equipment for the various operating modes is given in the table on page 1-3.
®Plus
700 IQ may only be submersed when the electrodes
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Fig. 3-3 Equipping the sensor with electrodes.
All receptacles are closed with blind plugs in the delivery condition. Screw the electrodes into the receptacles instead of the blind plugs.
When doing so observe the following points:
The receptacle for the reference electrode is marked by a recess. It
extends into the inside of the sensor clearly deeper than the other three receptacles (see Fig. 3-3).
3 - 5
Page 18
Commissioning VARiON
The measurement and compensation electrodes can be mounted in
the remaining three receptacles in any order.
During installation make sure the area behind the sealing ring of the
electrode and the receptacle are absolutely dry and clean.
Plug the electrode on the special socket wrench provided and insert
the electrode with the special socket wrench.
Screw until the electrode seats without any gap on the electrode
support. Thus the tightness and electrical contacting are granted.
Note
When mounted, the electrodes can be recognized by the features described in section 6.3.
®Plus
700 IQ
3 - 6
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Page 19
VARiON
1
®Plus
700 IQ Commissioning

3.4.2 Mounting the protective hood

CH cleaning head
(option)
Mounting the standard
protective hood
For permanent operation, we recommend to use the CH cleaning head for compressed air-driven cleaning. It is mounted instead of the standard protective hood. The compressed air cleaning is started time­controlled via the IQ S
ENSOR NET system. Information on the required
components is given in the YSI catalog and on the Internet.
If no CH cleaning head is used the standard protective hood should always be mounted for measuring. It protects the electrodes from rough mechanical impact.
Cleaning the protective
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hood
Fig. 3-4 Mounting the standard protective hood.
1 Loosen the coupling ring (1) of the protective hood.
2 Push the protective hood on the sensor as far as it will go.
3 Tighten the coupling ring of the protective hood.
The coupling ring of the protective hood can be taken apart for cleaning purposes (see section 6.2 E
XTERIOR CLEANING).
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Page 20
Commissioning VARiON
SACIQ
1
2

3.4.3 Connecting the sensor to the IQ SENSOR NET

Connection cable The SACIQ sensor connection cable is required to connect the sensor.
Information on this and other IQ S
ENSOR NET accessories is given in
the YSI catalog and on the Internet.
Note
Do not suspend the sensor on the sensor connection cable. Use an armature or electrode holder. Information on this and other IQ S N
ET accessories is given in the YSI catalog and on the Internet.
Note
How to connect the SACIQ sensor connection cable to the
ENSOR NET is described in chapter 3 INSTALLATION of the
IQ S IQ S
ENSOR NET system operating manual.
®Plus
700 IQ
ENSOR
Are the plug
connections dry?
Connecting the sensor
to the sensor
connection cable
Before connecting the sensor and sensor connection cable, make sure that the plug connections are dry. If moisture gets into the plug connections, first dry the plug connections (dab them dry or blow them dry using compressed air).
Fig. 3-5 Connect the sensor
1 Take the protective caps off the plug connections of the sensor
and the SACIQ sensor connection cable, and keep them safe.
3 - 8
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VARiON
®Plus
700 IQ Commissioning
2 Plug the socket of the SACIQ sensor connection cable onto the
plug head connector of the sensor. At the same time, rotate the socket so that the pin in the plug head connector (1) clicks into one of the two holes in the socket.
3 Then screw the coupling ring (2) of the sensor connection
cable onto the sensor up to the stop.
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Page 22
Commissioning VARiON

3.5 Settings

3.5.1 General information

®Plus
Automatic electrode
recognition
The VARiON in electrodes and checks the equipment for validity. Depending on the equipment, the following sensors are displayed in the list of sensors:
Sensor Designation
VARiON
VARiON
®Plus
®Plus
Note
Manually, you can also have the potassium electrode displayed as the extra sensor, VARiON K.
700 IQ software automatically recognizes the built-
700 IQ Ammonium sensor VARiON A
700 IQ Nitrate sensor VARiON N
®Plus
700 IQ
Sensor Designation
VARiON
®Plus
700 IQ potassium sensor VARiON K
Carrying out settings With <S>, switch to the main settings menu from the measured value
display. Then navigate to the setting menu (setting table) of the sensor. The exact procedure is described in the relevant IQ S
ENSOR NET
system operating manual.
The setting tables of the sensors are described in the following chapters.
Sensor overlapping
settings
Certain settings are sensor overlapping and can be made in any one of the setting tables. The setting is used by all sensors.
The sensor overlapping settings are:
Temperature mode (°C/°F)
Temp. adjustment
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Page 23
VARiON
®Plus
700 IQ Commissioning

3.5.2 Setting table of the VARiON A (ammonium sensor)

Menu item Selection/values Explanations
Measuring mode NH4-N
NH4
mV
Measuring range (Measuring mode: NH4-N)
AutoRange
0.1 ... 100.0 mg/l
1 ... 1000 mg/l
Measuring range (Measuring mode: NH4)
AutoRange
0.1 ... 130.0 mg/l
1 ... 1290 mg/l
Measuring range
-2000 ... 2000 mV Fixed range
(Measuring mode: mV)
VARiON K hide
show
Citation form of the mass concentration or voltage of the electrode.
2 measuring ranges can be selected. With AutoRange, the instrument automatically switches to the suitable measuring range.
2 measuring ranges can be selected. With AutoRange, the instrument automatically switches to the suitable measuring range.
hide (standard setting): The potassium electrode is not displayed as an extra sensor in the measured value display.
show: If the sensor is equipped with the potassium electrode, the electrode is displayed as the extra sensor VARiON K in the measured value display. The relevant settings can be done in an extra setting table (see section 3.5.4). Note:
If the maximum number of sensors for the system is exceeded by activating the sensor, the VARiON K cannot be activated.
Calib. history K (only with setting VARiON K: hide)
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Do not download
Transmit to log book
If you select Transmit to log book, a log book message with the calibration history of the potassium electrode is generated. When opening the setting table again the setting is reset to Do not download.
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Page 24
Commissioning VARiON
Menu item Selection/values Explanations
®Plus
700 IQ
Potassium compens.
(only with setting
VARiON K: hide)
automatic / manual 1 ... 1000 mg/l
automatic
(with a potassium electrode mounted): When the potassium electrode is mounted, the potassium compensation takes places automatically only. The value of the potassium concentration measured at the time the setting table was opened is displayed in the next line (Potassium
conc.).
manual
(without any potassium electrode mounted): After determining the potassium content of the test solution enter the determined potassium content manually in the next line (Potassium conc.). The measured value is accordingly corrected by the entered potassium content. Note:
Detailed information on the subject of potassium compensation is given in the YSI primer, I
IN ONLINE ANALYSIS.
ON SELECTIVE MEASUREMENT
Potassium conc.
(only with setting
VARiON K: hide)
1 ... 1000 mg/l With Potassium compens.: automatic:
Display of the potassium measured value. With Potassium compens.: manual: Entry of the K value
IQ-LabLink Not active (not used)
Temperature mode (only with Measuring mode:
°C
°F
Unit of the measured temperature value (Celsius, Fahrenheit).
NH4-N or NH4)
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VARiON
®Plus
700 IQ Commissioning
Menu item Selection/values Explanations
Temp. adjustment (only with Measuring mode: NH4-N or NH4)
-1.5 °C ... +1.5 °C The temperature compensation function
enables the temperature sensor to be balanced against a reference temperature measurement (displacement of the zero point by ±1.5 °C). Notes: Due to the thermal capacity of the
sensor, it is necessary to place it in a container with at least 2 liters of water.
Leave the sensor in this container for at
least 15 minutes while stirring occasionally, then carry out the adjustment. If the temperature difference of the water and sensor is > 10°C, leave the sensor in the container for at least one hour while stirring occasionally.
Conc. offset -1.0 mg/l ... +1.0 mg/l Constant value, which is added to the
measuered value.
Program level 0 ... 2 Program extension (0 = Off = standard set-
ting). Refer to section 4.2.4 for details about the
program extension.
Save and quit The system confirms the saving of the
settings and the display switches to the next higher level.
Quit The display switches to the next higher
level without saving the new settings.
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Commissioning VARiON

3.5.3 Setting table of the VARiON N (nitrate sensor)

Menu item Selection/values Explanations
®Plus
700 IQ
Measuring mode NO3-N
NO3
mV
Measuring range (Measuring mode NO3-N)
AutoRange
0.1 ... 100.0 mg/l
1 ... 1000 mg/l
Measuring range (Measuring mode: NO3)
AutoRange
0.5 ... 450.0 mg/l
5 ... 4500 mg/l
Measuring range
-2000 ... 2000 mV Fixed range
(Measuring mode: mV)
Chloride compens. automatic / manual
1 ... 1000 mg/l
Citation form of the mass concentration or voltage of the electrode.
2 measuring ranges can be selected. With AutoRange, the instrument automatically switches to the suitable measuring range.
2 measuring ranges can be selected. With AutoRange, the instrument automatically switches to the suitable measuring range.
automatic (with a chloride electrode mounted): When a chloride electrode is mounted, the chloride compensation takes places automatically only. The value of the chloride concentration measured at the time the setting table was opened is displayed in the next line.
manual (without any chloride electrode mounted): After determining the chloride content of the test solution enter the determined chloride content manually in the next line. The measured value is accordingly corrected by the entered chloride content. Note:
Detailed information on the subject of chloride compensation is given in the YSI primer, I
IN ONLINE ANALYSIS.
ON SELECTIVE MEASUREMENT
Chloride conc. 1 ... 1000 mg/l With Chloride compens.: automatic:
Display of the chloride measured value. With Chloride compens.: manual: Entry of the Cl value
Calib. history Cl (only with setting Chloride compens.: automatic)
Do not download
Transmit to log book
Send to log book generates a log book
message with the calibration history of the chloride electrode. When opening the
setting table again the setting is reset to Do not download.
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VARiON
®Plus
700 IQ Commissioning
Menu item Selection/values Explanations
IQ-LabLink Not active (not used)
°C
°F
Unit of the measured temperature value (Celsius, Fahrenheit).
Temperature mode (only with Measuring mode: NO3-N or NO3)
Temp. adjustment (only with Measuring mode: NO3-N or NO3)
-1.5 °C ... +1.5 °C The temperature adjustment function
enables the temperature sensor to be balanced against a reference temperature measurement (displacement of the zero point by ±1.5 °C). Notes: Due to the thermal capacity of the
sensor, it is necessary to place it in a container with at least 2 liters of water.
Leave the sensor in this container for at
least 15 minutes while stirring occasionally, then carry out the adjustment. If the temperature difference of the water and sensor is > 10°C, leave the sensor in the container for at least one hour while stirring occasionally.
Conc. offset -1.0 mg/l ... +1.0 mg/l Constant value, which is added to the
measuered value.
Program level 0 ... 2 Program extension (0 = Off = standard set-
ting). Refer to section 4.2.4 for details about the
program extension.
Save and quit The system confirms the saving of the
settings and the display switches to the next higher level.
Quit The display switches to the next higher
level without saving the new settings.
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Commissioning VARiON

3.5.4 Setting table of the VARiON K (potassium sensor)

Note
These sensor settings are only available if in the sensor settings for the VARiON A the VARiON K setting was set to Active (see section 3.5.2).
The basic settings are taken over from the VARiON A sensor but can be adjusted separately afterwards.
Menu item Selection/values Explanations
®Plus
700 IQ
Measuring mode K (mg/l)
mV
Measuring range
1 ... 1000 mg/l Fixed range
Citation form of the mass concentration or voltage of the electrode.
(Measuring mode: K (mg/l))
Measuring range
-2000 ... 2000 mV Fixed range
(Measuring mode: mV)
IQ-LabLink Not active (not used)
Temperature mode
(only with
°C
°F
Unit of the measured temperature value (Celsius, Fahrenheit).
Measuring mode: K (mg/l))
Temp. adjustment
(only with
Measuring mode: K (mg/l))
-1.5 °C ... +1.5 °C The temperature compensation function
enables the temperature sensor to be balanced against a reference temperature measurement (displacement of the zero point by ±1.5 °C). Notes: Due to the thermal capacity of the
sensor, it is necessary to place it in a container with at least 2 liters of water.
Leave the sensor in this container for at
least 15 minutes while stirring occasionally, then carry out the adjustment. If the temperature difference of the water and sensor is > 10°C, leave the sensor in the container for at least one hour while stirring occasionally.
Conc. offset -10 mg/l ... +10 mg/l Constant value, which is added to the
measuered value.
Program level 0 ... 2 Program extension (0 = Off = standard set-
ting). Refer to section 4.2.4 for details about the
program extension.
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VARiON
®Plus
700 IQ Commissioning
Menu item Selection/values Explanations
Save and quit The system confirms the saving of the
settings and the display switches to the next higher level.
Quit The display switches to the next higher
level without saving the new settings.
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Commissioning VARiON
®Plus
700 IQ
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Page 31
VARiON
Start: press
<C>
Electrode
zeroing
Yes/No
Selection of procedure
Matrix adjustment Check Calibration
Procedures for special cases
(see section 4.3)
Calibration free operation
Yes if a new or different electrode is
commissioned
®Plus
700 IQ Matrix adjustment, check and calibration

4 Matrix adjustment, check and calibration

4.1 General information

Calibration free
operation
Steps
The VARiON
®Plus
700 IQ combination sensor is immediately ready to measure after being equipped with electrodes. For precise measurements, it is only necessary to adjust the electrodes to the sample matrix ("matrix adjustment").With the recommended application (see section 1.3 R
ECOMMENDED FIELDS OF APPLICATION), the
measuring characteristics of the electrodes remain stable for their entire service life. Thus, calibration is no longer required.
Possible changes of the sample matrix can be determined by occasional comparison measurements (e.g. photometer) and compensated for by a new matrix adjustment as necessary. The sensor does not have to be taken out of the sample for this. At the same time, a matrix adjustment provides information on the state of the electrodes.
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Fig. 4-1 Schematic diagram
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Matrix adjustment, check and calibration VARiON
Drift potential Simultaneously with the matrix adjustment (or calibration), the drift
voltage DV(mV) of the combination electrode is determined. It serves to evaluate the long-term behavior of the combination electrode. The drift voltage changes due to the following factors:
Influences due to the sample composition (matrix)
Changes of the electrode characteristics.
Electrode zeroing The temporal change of the drift voltage is recorded in the calibration
history so the long-term behavior of a combination electrode can be evaluated. As a start value, the user has to set the drift voltage to zero at the beginning of this evaluation period in order to observe changes in the calibration history.
The electrode zeroing itself is carried out with the matrix adjustment (or calibration) procedure for the selected combination electrode(s). It becomes effective if the procedure was successfully carried out.
For each electrode, the user can carry out the electrode zeroing separately and at any time. We recommend, however, to start the evaluation period with the commissioning of a new or different electrode to be able to see the entire operating life of an electrode in the calibration history.
®Plus
700 IQ
Resetting the slope by
electrode zeroing
Maintenance and
calibration case,
®
VARi O N
Case
It is not possible to zero an electrode with the Check procedure, as this procedure stores no data in the sensor.
Electrode zeroing with the matrix adjustment procedure resets the slope to the default setting (+ or - 59.2 mV) at the same time. Electrode zeroing with the calibration procedure replaces the existing slope with the newly determined value.
For adjustment, calibration and maintenance activities on site, the VARiON
®
Case is available. The convenient case provides room for all
required accessories (details, see section 6.1).
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VARiON
®Plus
700 IQ Matrix adjustment, check and calibration

4.2 Matrix adjustment

4.2.1 General information on matrix adjustment

This procedure adjusts the value directly measured in the test sample to an independently determined reference value ("lab value"). To determine the reference values, a sample is taken from the measuring solution and the relevant concentrations are measured (e.g. photometrically).
First select for which of the installed combination electrodes the matrix adjustment should be carried out. Based on this selection and the electrode equipment, the sensor software determines the ion types for which a reference measurement must be carried out. The menu guided routine adapts itself correspondingly and informs you of all necessary actions.

4.2.2 Carrying out the matrix adjustment

Note
A chloride electrode should be checked for coatings and polished off as necessary before the matrix adjustment is carried out (see section 6.4).
Main steps
Step 1: Determination of all combination electrode voltages
("reference voltages"). The sensor is in the sample. The procedure is started from the measured value display with <C>. After completion the system returns to the measured value display.
Step 2: Sampling at the same place and time if possible and
determination of all relevant reference values
Step 3: Entry of the measured reference values. This step is
started by pressing <C> again.
Online help A comfortable, menu guided routine guides you through the matrix
adjustment. All steps are easily and understandably explained on the display. In addition, you can call up an Online help for each step. To do so, move the highlighting to the Online help menu item with the arrow keys <> or the toggle switch <> and press <OK>. A help text with detailed information on the relevant operating step appears on the display. It provides, for example, important instructions on how to keep the correct basic conditions. When <OK> is pressed once again, the display returns to the current operating step.
Matrix adjustment with
electrode zeroing
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After installing a new or different electrode you have to zero the electrode to facilitate a long-term evaluation. Details on electrode zeroing, see section 4.1.
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Matrix adjustment, check and calibration VARiON
®Plus
Practical instructions Ammonium and nitrate have to be determined immediately after
taking the sample as the their content changes very quickly due to the micro organisms that are present. It is best to take the sample using a syringe filter for transport to the laboratory or to stabilize it otherwise. When adding stabilizing solutions, the dilution factor has to be taken into account.
While determining the reference concentrations in the lab (step 2),
you can use the sensor for control purposes again by switching the maintenance condition off and thus releasing the linked outputs. The sensor continues to use the data of the previous matrix adjustment (or calibration). The reference voltages determined in step 1 will not be lost. They remain stored until step 3 of the matrix adjustment is completed. They do not have to be noted and entered again.
Use the Online help if you are unsure of anything during the matrix
adjustment.
700 IQ
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VARiON
Last electrode zeroing via matrix adjustment
Chronological list of the last matrix adjustments
®Plus
700 IQ Matrix adjustment, check and calibration

4.2.3 Result of the matrix adjustment

Evaluation After the matrix adjustment, the system automatically evaluates the
current condition of the electrode(s) based on the drift voltage. For a successful matrix adjustment, the drift voltage must be within the range
-45 mV ... +45 mV. The drift voltage is set to 0 mV if you have selected to zero the electrode.
At the end of the matrix adjustment procedure the drift voltage of all selected electrodes is shown on the display. The evaluation is displayed with "+" (successful) or "-" (unsuccessful). Additionally, the slopes are displayed that are used for the current measured value calculation. The slopes are marked by a star (*) as they were not changed by the matrix adjustment.
Taking over the
determined values
History of matrix
adjustments
(only available in the
IQ S
ENSOR NET
system 2020 XT)
For each successfully adjusted electrode you can individually decide whether the values should be stored for measurement.
Note
If the matrix adjustment was erroneous due to an incorrect determination or entry of the reference concentration, you can correct the entry (if necessary several times). If, by doing so, it is not possible to eliminate the error, the complete matrix adjustment has to be repeated or discarded for this electrode. If it is discarded, measurement is continued with the values of the last valid matrix adjustment (or calibration). Values of successfully adjusted electrodes that were already stored are retained.
Note
Actions for error elimination are given in the Online help and in chapter 8 W
HAT TO DO IF ....
The history of matrix adjustments can be viewed in the so-called calibration history.
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Fig. 4-2 Calibration history with matrix adjustments (example: VARiON A)
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Matrix adjustment, check and calibration VARiON
The history of matrix adjustments contains the following information:
Date Date of the matrix adjustment
S Slope [mV] of the electrode.
The slopes are marked by a star (*) because they were not changed by the matrix adjustment or reset to the default condition with the electrode zeroing.
DV Drift voltage [mV]
0 is displayed after an electrode zeroing.
Ref1 Reference concentration [mg/l]
Ref2 This column is of no importance for the matrix adjustment
K+ or Cl- Measured or entered interfering ions concentration [mg/l]
P Procedure (1 = matrix adjustment)
®Plus
700 IQ
T Temperature [°C]
R Evaluation of the matrix adjustment
+ : Matrix adjustment successful.
The sensor measures with the new adjustment data.
? : Matrix adjustment unsuccessful.
Invalid adjustment data was discarded. Measurement is continued with the last valid values.
Note
If you set the potassium electrode to be displayed as the extra sensor VARiON K, the calibration history of the potassium electrode can be viewed under VARiON K. The IQ S log book for this sensor. Log book messages are displayed with the main sensor, VARiON A.
For the chloride electrode, or if the potassium electrode is not displayed as an extra sensor, you can generate a log book message with the calibration history by means of the menu item, Calib. history Cl (or K) in the setting table of the relevant sensor. How to do this is described on page 3-11. The log book message is recorded in the log book of the relevant main sensor (VARiON A -> message code IC5395 or VARiON N -> message code IC6396).
ENSOR NET does not keep an extra
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VARiON
®Plus
700 IQ Matrix adjustment, check and calibration

4.2.4 Program extension

The simple matrix adjustment, as described in the sections 4.2.2 to
4.2.3, will in most cases lead to precise measurement results. In some cases, special effects in the matrix can cause the real characteristic curve of the ISE measurement to deviate very much from the factory characteristic curve. This can lead to measured values that are not precise enough.
From sensor software version 3.20, the setting table provides the Program Level setting, which can be used to enhance the functionality of the matrix adjustment. Program Level 0 is the simple matrix adjustment as described in the sections 4.2.2 to 4.2.3. The program levels 1 and 2 provide tools with which the real characteristic curve of the ISE measurement can be better approximated.
For more detailed information please address your YSI contact person.
Note
To restore the factory characteristic curve, select Program Level 0 in the setting table and then quit the menu with Save and quit.
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Matrix adjustment, check and calibration VARiON

4.3 Check and calibration in standard solutions

4.3.1 General information on checking and calibrating

In addition to the comparison measurement or matrix adjustment under real measurement conditions, it is possible to check the function of the entire sensor in standard solutions. If necessary, you can also take over to the sensor the slope and potential level of the individual combination electrodes via an exact calibration in standard solutions. The slope will be retained with a future matrix adjustment if it is carried out without zeroing the electrode.
®Plus
700 IQ
When does a check or
calibration make sense?
Caution
The long term stable VARiON with the recommended application. A check in standard solutions is only of significance if all basic conditions (cleanness, conditioning etc.) are strictly kept. Calibration can cause major measurement errors if the basic conditions are not sufficiently kept. After calibrating, a matrix adjustment is normally required additionally (always with the recommended application). Standard solutions do not represent any real test sample!
A check or calibration can be useful in the following special cases:
If the measured values do not appear to be correct even after a
careful matrix adjustment and if you suspect the electrode slopes to have changed
If a new application is to be started, the sample composition of which
considerably deviates from that of the recommended application (see section 1.3 R
ECOMMENDED FIELDS OF APPLICATION)
Routinely within the framework of the company quality assurance.
®Plus
electrodes are calibration-free
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VARiON
®Plus
700 IQ Matrix adjustment, check and calibration
Differences between
check and calibration
The check and calibration are carried out in two separate routines. The schema is the same with both routines: Two standard solutions with different concentrations are measured one after the other. The differences between the check and calibration are as follows:
For the check, the basic conditions to be kept are less strict. It is
suitable as a quick method to check whether the slope and potential level of the combination electrodes are within the allowed limits. The results are just for information. No characteristics or sensor settings are changed.
For calibration, the basic conditions must comply with very high
requirements (longer conditioning times, discarding of the conditioning solution, temperature adjustment etc.). Correspondingly, it requires more time. During calibration, the slope and drift voltage are exactly determined and evaluated. If the calibration was successful, the determined values can be taken over for measurement. The procedure can, however, be used as a mere check method. Calibration is documented in the calibration history and in the log book.
Standard solutions For the check or calibration, the following two YSI standard solutions
are required in this order:
VARiON
VARiON
®
/ES-2 (high concentration)
®
/ES-1 (low concentration).
Online help A comfortable, menu guided routine guides you through the procedure.
Calibration with
electrode zeroing
These standard solutions contain all ion types that come into question (ammonium, nitrate, potassium and chloride) and are especially adapted to the VARiON
®Plus
700 IQ.
All steps are easily and understandably explained on the display. In addition, you can call up an Online help for each step. To do so, move the highlighting to the Online help menu item with the arrow keys <> or the toggle switch <> and press <OK>. A help text with detailed information on the relevant operating step appears on the display. It provides, for example, important instructions on how to keep the correct basic conditions. When <OK> is pressed once again, the display returns to the current operating step.
After installing a new or different electrode you have to zero the electrode to facilitate a long-term evaluation. Details on electrode zeroing, see section 4.1.
Note
A chloride electrode should be checked for coatings and polished off as necessary before the check or calibration is carried out (see section
6.4).
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Matrix adjustment, check and calibration VARiON
®Plus
700 IQ
Preparations and
instructions on how to
keep the basic
conditions
Select a place where clean working conditions and a constant,
sufficiently high temperature are granted (a room, e.g. laboratory). Temperatures under 10 °C extend the conditioning time considerably.
Make sure the temperature of all components (sensor, standard
solutions, containers, accessories etc.) is similar and constant. We recommend to store the standard solutions in the same place where the check or calibration is carried out.
Use containers and accessories (beaker, stirring rod) that are
absolutely clean and without detergent residues. Detergent residues can seriously affect the function of the electrodes.
Remove the protective hood and clean the sensor thoroughly.
Before the check, rinse the sensor with standard solution VARiON ES-2.
Make sure the depth of immersion is sufficient (minimum 5 cm).
Make sure there are no air bubbles in front of the electrode
membrane.
Conditioning times: During the conditioning steps, all relevant
combination electrode voltages are indicated on the display. Thus you can observe the conditioning process.
®
/
Regular stirring accelerates the conditioning process considerably.
Stirring with a stirring rod or the sensor itself is sufficient.
For calibration, the standard solution is discarded after conditioning.
This is pointed out by a corresponding note in the calibration routine. It is essential for an exact calibration result.
Use the Online help if you are unsure of anything during calibration.

4.3.2 Result of the check

Evaluation At the end of the check, the result for the combination electrodes is
shown on the display with "+" (successful) or "-" (unsuccessful). The exact check criteria are given in the Online help of the result display. At the same time the result is entered in the log book as an info message. There is no
entry in the calibration history.
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VARiON
®Plus
700 IQ Matrix adjustment, check and calibration

4.3.3 Result of the calibration

Evaluation With calibration, the system automatically evaluates the condition of a
combination electrode based on the data of its characteristic curve. The drift potential and slope are evaluated separately. For a calibration procedure to be valid, the potential level, slope and drift voltage must be within certain ranges.
Valid ranges for slope and drift potential:
Value of the slope: 50 ... 70 mV
Drift voltage: -45 ... +45 mV
The valid potential levels (MIN, MAX) can be taken from the online help.
Taking over the
determined values
For each successfully calibrated electrode you can individually decide whether the values should be stored for measurement.
Note
Actions for error elimination are given in chapter 8 W
HAT TO DO IF ....
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Matrix adjustment, check and calibration VARiON
Last electrode zeroing (here, via calibration)
Chronological list with the last matrix adjustments and calibrations
®Plus
700 IQ
Calibration history
(only available in the
IQ S
ENSOR NET
systems 2020 XT)
Date Date of the calibration or matrix adjustment
S Slope [mV] of the electrode.
In the calibration history, a calibration has the entries ES1 and ES2 in the Ref1 and Ref2 columns which the matrix adjustment has not:
Fig. 4-3 Calibration history (example: VARiON A)
The calibration history contains the following information:
After a matrix adjustment, the values for the slope are marked
Note: by a star (*) because they were not changed by this procedure.
DV Drift voltage [mV]
After an electrode zeroing and subsequent calibration or matrix adjustment, 0 is displayed.
Ref1/Ref2 Depending on the procedure.
Matrix adjustment: Reference concentration [mg/l] Calibration: Used standard solution
K+ or Cl- Depending on the procedure.
Matrix adjustment: Interfering ions concentration [mg/l]
®
Calibration: Standard solution, VARiON
/ES-2
P Procedure (1 = matrix adjustment, 3 = calibration)
T Temperature [°C]
R Evaluation of the calibration or matrix adjustment
+ : Calibration or matrix adjustment.
The sensor measures with the new calibration or adjustment data.
? : Calibration or matrix adjustment unsuccessful.
Invalid calibration or adjustment data were discarded. Measurement is continued with the last valid values.
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VARiON
®Plus
700 IQ Matrix adjustment, check and calibration
Note
If you set the potassium electrode to be displayed as the extra sensor VARiON K, the calibration history of the potassium electrode can be viewed under VARiON K. The IQ S
ENSOR NET does not keep an extra
log book for this sensor. Log book messages are displayed with the main sensor, VARiON A.
For the chloride electrode, or if the potassium electrode is not displayed as an extra sensor, you can generate a log book message with the calibration history by means of the menu item, Calib. history Cl (or K) in the setting table of the relevant sensor. How to do this is described on page 3-11. The log book message is recorded in the log book of the relevant main sensor (VARiON A -> message code IC5395 or VARiON N -> message code IC6396).
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Matrix adjustment, check and calibration VARiON
®Plus
700 IQ
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Page 45
VARiON
®Plus
700 IQ Measuring

5 Measuring

5.1 Measuring operation

Note the data given in section 9.2 APPLICATION CONDITIONS, especially the minimum immersion depth of the sensor (> 50 mm with mounted protective hood).
Note
To keep the sensor clean, we recommend to use the CH cleaning head (see chapter 7 R

5.2 Factors affecting the measured value

Caution
Greases, oils, certain tensides and similar substances can shorten the operational lifetime of the electrodes. Therefore, they should not be present in the test sample.
EPLACEMENT PARTS AND ACCESSORIES).
®Plus
For measurement with the VARiON
700 IQ the following influencing variables can be important, depending on the measured parameter:
Measured parameter Influencing variable
Ammonium pH value
Potassium ions
Nitrate Chloride ions
Note
The effects of influencing variables on measurement and compensating actions are described in detail in the YSI primer, I
SELECTIVE MEASUREMENT IN ONLINE ANALYSIS.
ON
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Measuring VARiON
®Plus
700 IQ
5 - 2
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VARiON
®Plus
700 IQ Maintenance and electrode exchange

6 Maintenance and electrode exchange

6.1 General maintenance notes

Warning
Contact with the sample can be dangerous for the user! Depending on the type of sample, suitable protective measures must be taken (protective clothing, protective goggles, etc.).
Maintenance condition We recommend to switch on the maintenance condition each time the
sensor is taken out of the measuring position. This avoids unwanted reactions of linked outputs. More information on the maintenance
VARi O N
condition is given in the relevant IQ S manual.
®
/Epack The VARiON®/Epack set with usual replacement parts is available for
maintenance (see chapter 7 R
EPLACEMENT PARTS AND ACCESSORIES).
ENSOR NET system operating
Maintenance and
calibration case,
VARi ON
®
Case
For adjustment, calibration and maintenance activities on site, the VARiON
®
Case is available. The convenient case provides room for all
required accessories (details, see next page).
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6 - 1
Page 48
Maintenance and electrode exchange VARiON
9
6
7
10
8
11
2 3
4
5
1
ba76000e01 12/2011
VARiON
®
Plus
700 IQ
Operatingmanual
IQSENSOR NET
Modularcombination sensor
forammonium and nitrate
®Plus
700 IQ
Fig. 6-1 Sample equipment of the VARiON® Case calibration and maintenance case
1 Blind plug
2 Special socket wrench
3 Polishing strip
4 Replacement electrodes with watering caps
5 Compartments for various accessories (wiping cloths, sample
6 Recess for sensor
7 Storing solution for reference electrode
bottles, personal protective equipment etc.)
8 Replacement reference electrode with storing aids
9 Calibration standards
10 Operating manual
11 Protective hood
6 - 2
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Page 49
VARiON
®Plus
700 IQ Maintenance and electrode exchange

6.2 Exterior cleaning

Note
To keep the electrodes clean, we recommend to use the CH cleaning head (see chapter 7 R
EPLACEMENT PARTS AND ACCESSORIES).
With normal operation (e.g. municipal wastewater) we strongly recommend to clean the outside of the sensor and calibrate:
when it is strongly contaminated (after visual check)
if erroneous measured values are suspected
each time before removing or exchanging an electrode
Caution
Do not use any detergents for cleaning. Detergent residues can seriously affect the function of the electrodes.
Note
We recommend to clean the sensor shaft and electrodes while the sensor is still connected to the sensor connection cable. Otherwise, moisture and/or dirt can get into the plug connection where it can cause contact problems.
If you would like to disconnect the sensor from the sensor connection cable, please note the following points:
Before disconnecting the sensor from the SACIQ sensor connection
cable, remove any larger pieces of contamination from the sensor, particularly in the area of the plug connection (brush it off in a bucket of tap water, wash it off with a hose or wipe it off with a cloth).
Unscrew the sensor from the SACIQ sensor connection cable.
Always place a protective cap on the plug head of the sensor and on
the SACIQ sensor connection cable so that no moisture or dirt can get into the contacting surfaces.
In corrosive environments, close the socket of the sensor
connection cable with the screwable SACIQ-Plug when it is dry in order to protect the electrical contacts from corrosion. The protective plug is available as an accessory (see section 7.2 G
ACCESSORIES).
ENERAL
Cleaning the sensor Clean the sensor shaft with tap water and a soft sponge or brush.
Remove the protective hood. The electrodes are best cleaned under running tap water using a soft toothbrush or brush.
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Page 50
Maintenance and electrode exchange VARiON
1
2
3
®Plus
700 IQ
Cleaning the coupling
ring of the protective
hood
The coupling ring can be unscrewed and dismantled for cleaning as follows:
Fig. 6-2 Dismantling the coupling ring
1 Remove the retaining ring (pos. 1 in Fig. 6-2).
2 Remove the intermediate ring (pos. 2) and sealing ring (pos.
3).
After the parts have been cleaned, reassemble the coupling ring in reverse order. When doing so make sure that the tapered side of the intermediate ring (pos. 2) points towards the sealing ring (pos. 3).
6 - 4
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VARiON
®Plus
700 IQ Maintenance and electrode exchange

6.3 Exchanging the electrodes

Caution
The sensor can be damaged by dirt and moisture. Each time before dismantling an electrode carefully clean the area around the electrodes (section 6.2). Before mounting an electrode make sure the area behind the sealing ring of the electrode and the receptacle are dry and clean. The VARiON submersed when the electrodes or original blind plugs are mounted.
Use the special socket wrench provided to dismantle an electrode. Electrodes are installed as described in section 3.4.1 E
SENSOR WITH ELECTRODES.
®Plus
700 IQ may only be
QUIPPING THE
Recognizing the
electrode type from
outside
When mounted, the electrodes can be recognized by the following features:
Electrode Hexagon Front
Other features
surface
®
VARiON
Ref black black – Thread at the
hexagon
®Plus
VARiON
NH4 black black – Hexagon
without thread
®Plus
VARiON
VARiON
Kblackwhite
®Plus
NO3 white white – Labeled with the
electrode type
ba76000e01 01/2012
®Plus
VARiON
Cl black black – Larger
membrane
– Membrane flush
with the front surface
Note
For the correct storage of the electrodes please follow the instructions in section 3.3 N
OTES ON THE HANDLING OF THE ELECTRODES.
6 - 5
Page 52
Maintenance and electrode exchange VARiON
SF 300

6.4 Polishing the chloride electrode

Caused by the test medium, a coating can develop on the surface of the chloride electrode, which reduces the electrode slope. To maintain a proper chloride compensation the surface must be renewed by polishing at regular intervals.
Caution
Danger of damaging the electrode. Exclusively use the SF 300 polishing strip. Never use commercial sandpaper or similar.
The polishing can be done while the electrode is mounted (remove the protective hood as necessary). To polish the electrode, use the SF 300 polishing strip provided with the electrode. Moisten the rough side of the polishing strip with water and polish off any coatings under slight pressure.
®Plus
700 IQ
Fig. 6-3 Polishing the chloride electrode
6 - 6
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VARiON
®Plus
700 IQ Replacement parts and accessories

7 Replacement parts and accessories

7.1 Electrodes

Exchange electrodes
Storing equipment
Description Model Order no.
®
Reference electrode VARiON
Ammonium electrode VARiON
Nitrate electrode VARiON
Potassium electrode VARiON
Chloride electrode VARiON
Ref 107 042Y
®Plus
NH4 107 044Y
®Plus
NO3 107 045Y
®Plus
K 107 046Y
®Plus
Cl 107 047Y
Description Model Order no.
250 ml potassium chloride
KCl-250 109 705Y solution for the storage of the electrode

7.2 General accessories

Standard solutions
for calibration
Maintenance equipment
Protective plugs
Description Model Order no.
®
1 liter combination standard 1
VARiON
/ES-1 107 050Y
(low concentration)
®
1 liter combination standard 2
VARiON
/ES-2 107 052Y
(high concentration)
Description Model Order no.
Polishing film SF 300 203 680Y
Description Model Order no.
Screwable plug for sensor
SACIQ-Plug 480 065Y
connection cable
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7 - 1
Page 54
Replacement parts and accessories VARiON
®Plus
700 IQ
General replacement
parts
Calibration and
maintenance case
Description Model Order no.
®
Protective hood VARiON
Replacement parts set,
VARiON
700 IQ-SK 107 056Y
®
/Epack 107 057Y
comprising – 1 blind plug for receptacle
– 1 special socket wrench
– 3 replacement sealing rings
for electrodes/blind plugs
– Storing equipment for
electrodes: 1 nut (transparent), 1 watering cap with sponge 1 nut (black) 1 watering cap (without sponge) for reference electrode
Description Model Order no.
®
Empty case for the storage of
VARiON
Case 107 058Y calibration and maintenance equipment for the
®Plus
VARiON
700 IQ
7 - 2
Components for cleaning system
Description Model Order no.
Cleaning head CH 900 107Y
Passive valve module DIQ/CHV 472 007Y
Active valve module (does not
MIQ/CHV PLUS 480 018Y
require a free relay output in the
ENSOR NET system)
IQ S
Air compressor supplying the sensor cleaning system with cleaning air
Cleaning Air Box 115 VAC 230 VAC
480 017Y 480 019Y
Note
Information on other IQ S
ENSOR NET accessories is given in the YSI
catalog and on the Internet.
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VARiON
®Plus
700 IQ What to do if ...

8 What to do if ...

8.1 Interpretation of the drift voltage

The drift voltage is influenced by the potential levels of the measurement electrode and reference electrode. If the potential levels shift, e.g. caused by aging, both parts can move into the same direction or into opposite directions. The comparison of the drift voltages of two or three electrodes enables to draw conclusions concerning the state of individual electrodes if a matrix adjustment or calibration resulted in an invalid or considerably deviating drift voltage.
Assessment aids View the calibration history of the combination electrodes. In the
following cases, assessment is relatively easy:
If the drift voltages of all combination electrodes show the same
trend, i. e. the drift voltages have shifted in the same direction (positive or negative) by approximately the same amount, this indicates that the potential level of the reference electrode has shifted. The reference electrode is possibly highly contaminated or at the end of its service life.
If the drift voltages of all combination electrodes do not show a trend
but shift by different amounts into different directions, the potential level of the reference electrode has not changed considerably. The invalid drift voltage is probably caused by a defective measuring electrode. The measuring electrode is possibly highly contaminated or at the end of its service life.
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What to do if ... VARiON

8.2 Error causes and remedies

®Plus
700 IQ
No measured value
display
Cause Remedy
– Sensor not connected – Connect the sensor
– Incorrect electrode
– Correct electrode equipment
equipment
– Electrode(s) not at all or
incorrectly recognized by the system
– Check the installation and
contacts of the electrode (gap­free mounting)
– Check electrode receptacle for
moisture
– If necessary, unscrew the
electrode/blind plug and thoroughly dry the electrode/ blind plug and receptacle
– Unknown – Look for error messages in the
log book
– Liquid in the sensor shaft – Sensor defective, send it back
Measurement provides
implausible measured
values
Cause Remedy
– No matrix adjustment or
calibration carried out
– Adjustment or calibration
error (e.g. incorrect lab values, contaminated standard solutions)
– Manual interfering ions
compensation works with an unsuitable value
– Electrode(s) not at all or
incorrectly recognized by the system
– Adjust or calibrate the
electrode
– Check the adjustment or
calibration conditions
– Readjust or recalibrate the
electrode
– Determine and enter the
interfering ions compensation once again, then recalibrate
– Check the installation and
contacts of the electrode (gap­free mounting)
– Check electrode receptacle for
moisture
– If necessary, unscrew the
electrode/blind plug and thoroughly dry the electrode/ blind plug and receptacle
8 - 2
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VARiON
®Plus
700 IQ What to do if ...
Cause Remedy
– Electrode contaminated – Clean the electrode (see
section 6.2)
– Liquid in the sensor shaft – Sensor defective, send it back
Measurement provides
jumping, unstable or
drifting values
Cause Remedy
– Measurement /
compensation electrode: Electrode membrane not moistened by measuring solution, e.g. due to air in front of the membrane
– Moisten membrane with
deionized water using a wash bottle. To do so, position the opening of the wash bottle on the membrane and splash against the membrane vigorously
– Measurement /
compensation electrode: Air bubble behind the membrane
– Measurement electrode /
compensation and reference electrode: Insufficient electrical contact in the electrode receptacle
– Hold the electrode in a vertical
position with the membrane down and knock it on the side with the special socket wrench
– Check the installation and
contacts of the electrode (gap­free mounting)
– Check electrode receptacle for
moisture
– If necessary, unscrew the
electrode/blind plug and thoroughly dry the electrode/ blind plug and receptacle
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– Reference electrode dried up – Replace reference electrode
– Measurement /
– Replace defective electrode compensation electrode or reference electrode leaky or damaged
– Liquid in the sensor shaft – Sensor defective, send it back
8 - 3
Page 58
What to do if ... VARiON
®Plus
700 IQ
Faulty result of the
matrix adjustment
Faulty result of
calibration
Cause Remedy
– Error during procedure, e.g.
incorrect lab values
– Check the basic conditions
– Follow the practical notes on
page 4-4 or in the online help
– Recalibrate the electrode
– Reference electrode or
– Replace defective electrode measurement electrode defective due to aging (see section 8.1)
Cause Remedy
– Error during procedure, e.g.
contaminated standard solutions
– Check the basic conditions
– Follow the practical notes on
page 4-10 or in the online help
– Recalibrate the electrode
– Reference electrode or
– Replace defective electrode measurement electrode defective due to aging (see section 8.1)
8 - 4
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VARiON
®Plus
700 IQ Technical data

9 Technical data

9.1 Measuring characteristics

Measuring principle Potentiometric measurement by means of ion sensitive electrodes.
Modular structure with jointly used reference electrode and ion sensitive electrodes. Integrated microprocessor electronics, screened 2-wire connection for power and data transmission.
Measured parameters
Measuring ranges and
resolution,
Ammonium
measurement
Measuring ranges and
resolution,
Nitrate measurement
Main measured parameters Ammonium and/or nitrate
(depending on the electrode equipment)
Secondary measured parameter Temperature
Compensation parameters Potassium or chloride
(depending on the electrode equipment)
Measuring
Measuring range Resolution
mode
NH4-N 0.1 ... 100.0 mg/l
1 ... 1000 mg/l
NH4 0.1 ... 129.0 mg/l
1 ... 1290 mg/l
0.1 mg/l 1 mg/l
0.1 mg/l 1 mg/l
mV -2000 ... +2000 mV 1 mV
Measuring
Measuring range Resolution
mode
NO3-N 0.1 ... 100.0 mg/l
1 ... 1000 mg/l
0.1 mg/l 1 mg/l
Measuring ranges and
resolution,
Potassium
measurement
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NO3 0.5 ... 450.0 mg/l
5 ... 4500 mg/l
0.5 mg/l 5 mg/l
mV -2000 ... +2000 mV 1 mV
Measuring
Measuring range Resolution
mode
K 1 ... 1000 mg/l 1 mg/l
mV -2000 ... +2000 mV 1 mV
9 - 1
Page 60
Technical data VARiON
®Plus
700 IQ
Measuring ranges and
resolution,
Chloride measurement
Interfering ions
compensation
Selectable procedures
for
interfering ions
compensation
Measuring
Measuring range Resolution
mode
Cl 1 ... 1000 mg/l 1 mg/l
mV -2000 ... +2000 mV 1 mV
Main measured parameter Interfering ions that can be
compensated for
+
Ammonium Potassium (K
Nitrate Chloride (Cl
)
-
)
Compensation procedures Description
Automatic up to 1000 mg/l interfering ions
when equipped with the corresponding compensation electrode (chloride for nitrate measurement or potassium for ammonium measurement)
Temperature
measurement
Temperature
compensation
Manual without compensation electrode
by manual entry of the interfering ions concentration (range 1 ... 1000 mg/l).
Sensing element type integrated NTC
Measuring range - 5 °C ... + 60 °C (23 ... 140 °F)
Accuracy ± 0.5 K
Resolution 0.1 K
Response time t
95
< 20 s
automatic in the range 0 °C ... 40 °C (32 ... 104 °F)
9 - 2
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VARiON
®Plus
700 IQ Technical data

9.2 Application conditions

Allowed
Measuring medium 0 °C ... 40 °C (32 ... 104 °F)
temperature range
Storage/transport 0 °C ... 40 °C (32 ... 104 °F)
Allowed pH range of the
4 ... 12
measuring medium
Pressure resistance Sensor with the electrodes or blind plugs screwed in and the SACIQ
sensor connection cable connected:
Max. allowed overpressure 2 x 104 Pa (0.2 bar)
Type of protection Sensor with the electrodes or blind plugs screwed in and the SACIQ
sensor connection cable connected:
IP 68, 0.2 bar (2 x 10
4
Pa)
Depth of immersion min. 50 mm; max. 2 m depth
Operating position Electrode support pointing downward (maximum angle to the plumb
line = 60 °)
Fields of application  Control / monitoring in the aeration tank of a waste water treatment
plant
Water and waste water monitoring
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9 - 3
Page 62
Technical data VARiON
48 55 40
392
Socket SACIQ...
Minimum immersion depth 50 mm

9.3 General data

Dimensions
®Plus
700 IQ
Weight (without sensor
approx. 670 g with protective hood
connection cable)
Connection technique Connection via SACIQ sensor connection cable
Material
Shaft V4A stainless steel 1.4571
Protective hood POM
Electrode support POM
Temperature probe V4A stainless steel 1.4571
Plug head connector housing POM
Plug, 3-pole ETFE (blue) Tefzel
Electrodes see section 9.5
Instrument safety
Applicable norms – EN 61010-1
– UL 3111-1
– CAN/CSA C22.2 No. 1010.1
®
9 - 4

9.4 Electrical data

Nominal voltage max. 24 VDC
via the IQ S chapter IQ S manual)
Power consumption 0.2 W
Protective class III
ENSOR NET system operating
ENSOR NET (details see
TECHNICAL DATA of the
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VARiON
®Plus
700 IQ Technical data
9.5 Data of the VARiON
®Plus
electrodes

9.5.1 Response times

Response time t
90
Measured at 20 °C (68 °F) and a concentration change
VARiON
®Plus
NH4 VARiON
< 3min < 3min < 3min < 3min
10 to 100 mg/l NH4-N
5 to 50 mg/l NO3-N
®Plus
NO3 VARiON
®Plus
5 to 50 mg/l K
K VARiON
10 to 100 mg/l Cl
of ...

9.5.2 Materials

VARiON
®Plus
NH4
VARiON
®Plus
NO3
VARiON
®Plus
K VARiON
®Plus
Cl VARiON® Ref
Electrodes
Housing POM POM POM PVC PVC
Clamping ring POM POM POM - -
®Plus
Cl
Membrane soft PVC with
stainless steel protective grating
soft PVC with stainless steel protective grating
soft PVC with stainless steel protective
ISE element (solid body) in epoxy
-
grating
Junction - - - - Porous
PVDF
Sealing ring FPM (Viton
Connection
gold-plated gold-plated gold-plated gold-plated gold-plated
®
)FPM (Viton®)FPM (Viton
®
)FPM (Viton®)FPM (Viton®)
contacts
Storing equipment
Watering cap POM POM POM POM POM
Nut PMMA PMMA PMMA PMMA POM

9.5.3 Weights

VARiON
®Plus
NH4
VARiON
®Plus
NO3
VARiON
®Plus
K VARiON
®Plus
Cl VARiON® Ref
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5g 5g 5g 5g 13 g
9 - 5
Page 64
Technical data VARiON
®Plus
700 IQ
9 - 6
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Page 65
VARiON
®Plus
700 IQ Contact Information

10 Contact Information

10.1 Ordering & Technical Support

Telephone
: (800) 897-4151
(937) 767-7241 Monday through Friday, 8:00 AM to 5:00 PM ET
Fax
: (937) 767-1058
Email
: environmental@ysi.com
Mail: YSI Incorporated
1725 Brannum Lane Yellow Springs, OH 45387 USA
Internet
: www.ysi.com
When placing an order please have the following information available:
YSI account number (if available) Name and Phone Number Model number or brief description Billing and shipping address Quantity Purchase Order or Credit Card

10.2 Service Information

YSI has authorized service centers throughout the United States and Internationally. For the nearest service center information, please visit
www.ysi.com
directly at 800-897-4151.
When returning a product for service, include the Product Return form with cleaning certification. The form must be completely filled out for an YSI Service Center to accept the instrument for service. The Product Return form may be downloaded at www.ysi.com ‘Support‘ tab.
and click ‘Support’ or contact YSI Technical Support
and clicking on the
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10 - 1
Page 66
Contact Information VARiON
®Plus
700 IQ
10 - 2
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VARiON
®Plus
700 IQ Indexes

11 Indexes

11.1 Explanation of the messages

This chapter contains a list of all the message codes and related message texts that can occur in the log book of the IQ S
®Plus
system for the VARiON
700 IQ sensor.
Note
Information on
the contents and structure of the log book and
the structure of the message code
ENSOR NET
is given in the L
OG BOOK chapter of the IQ SENSOR NET system
operating manual.
Note
The last three digits of the message code identify the source of the message:
521 = VARiON+700 IQ (armature / component class, ADA adapters)
395 = VARiON A (ammonium / potassium sensor)
396 = VARiON N (nitrate sensor)

11.1.1 Error messages

Message code Message text
EA1395 Meas. range exceeded or undercut
* Check process * Select other meas. range
EA1396 Meas. range exceeded or undercut
* Check process * Select other meas. range
EA2521 Sensor temperature too high!
* Check process and application
EA3521 Sensor temperature too low!
* Check process and application
EAN395 Potassium measurement: range exceeded or undercut
* Check process
EAO396 Chloride measurement: range exceeded or undercut
* Check process
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Indexes VARiON
Message code Message text
EIA521 Incorrect equipment
* for correct electrode equipment see operating manual
ES1521 Component hardware defective
* Contact service

11.1.2 Info messages

Message code Message text
IC3395 K electrode has been successfully calibrated
* For calibration data, see calibration history
IC4396 Cl electrode has been successfully calibrated
* For calibration data, see calibration history
®Plus
700 IQ
IC5395 (this message contains calibration data of the potassium electrode)
IC6396 (this message contains calibration data of the chloride electrode)
IC7395 IC7396
Sensor could not be calibrated, Measuring with old calibration values * Check calibration conditions and calibration standard * View calibration history * Service sensor immediately (see operating manual)
ICA395
Electrode: check successful
ICA396
ICB395 K electrode: check successful
ICC396 Cl electrode: check successful
ICD395 ICD396
Electrode: check unsuccessful Please follow online help.
ICE395 K electrode: check unsuccessful
Please follow online help.
ICF396 Cl electrode: check unsuccessful
Please follow online help.
IIA521 (This message is generated when the electrode equipment is changed.
It informs you of the new assignment of the electrode receptacles)
IAI397 see VARiON A
11 - 2
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VARiON
®Plus
700 IQ Indexes

11.2 Status info

The status info is a piece of coded information about the current state of a sensor. Each sensor sends this status info to the controller. The status info of sensors consists of 32 bits, each of which can have the value 0 or 1.
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Status info,
general structure
VARiON
®Plus
700 IQ
1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 (general)
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 (internal)
16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31
The bits 0 - 15 are reserved for general information. The bits 16 - 21 are reserved for internal service information.
You obtain the status info:
via a manual query in the menu, Einstellungen/Settings/Service/List
of all components (see system operating manual)
via an automated query
– of a superordinate process control (e. g. when connected to the
Profibus)
– of the IQ Data Server (see operating manual of the
IQ S
ENSOR NET software pack)
Note
The evaluation of the status info, e.g. in the case of an automated query, has to be made individually for each bit.
Status bit Explanation
Status info
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Bit 0 Component hardware defective
Bit 1-31 -
11 - 3
Page 70
Indexes VARiON
®Plus
700 IQ
11 - 4
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Page 71
Page 72
1725 Brannum Lane Yellow Springs, Ohio 45387 USA +1 937-767-7241 800-765-4974 (US) FAX (937) 767-1058 Email: environmental@ysi.com Internet: www.ysi.com
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