Thank you for purchasing Chemical Cleaning pH Measuring System.
To have the system deliver its full capabilities, read this instruction manual thoroughly before you
use it. For safety reasons or to avoid possible damage to your equipment, strictly adhere to every
cautionary note that appears in this manual.
Chemical Cleaning pH Measuring System features automatic chemical cleaning of the pH sensor
without removing pH sensor, while maintaining its performance in pH measurement.
System Conguration of Chemical Cleaning pH Measuring System is as below;
Chemical Cleaning pH Measuring System
pH/ORP Converter2-wire Analyzer
Chemical Cleaning unitPH8SM3-EPH8SM3-G or PH8SM3-F
pH analyzerPH450GFLXA202 or FLXA21
Distributor―PH201G
pH sensor
HolderPH8HS3
(Note) You can select WTB10 Terminal Box, if necessary.
PH8EFP-□-TT2 (Note)
i
This document describes mainly PH8SM3 unit of the system and PH8HS3 Holder. For further
information on other products, please read corresponding manual attached to each product.
• No part of the user’s manuals may be transferred or reproduced without prior written
consent from YOKOGAWA.
• YOKOGAWA reserves the right to make improvements in the user’s manuals and product at
any time, without notice or obligation.
• If you have any questions, or you nd mistakes or omissions in the user’s manuals, please
contact our sales representative or your local distributor.
n Drawing Conventions
Some drawings may be partially emphasized, simplied, or omitted, for the convenience of
description.
Some screen images depicted in the user’s manual may have different display positions or
character types (e.g., the upper / lower case). Also note that some of the images contained in this
user’s manual are display examples.
n Inspection on delivery
Each component of Chemical Cleaning pH Measuring Systems comes in a separate package.
However, PH450G pH/ORP Converters (or FLXA202/FLXA21 2-Wire Analyzer ) are delivered
with factory-installed in PH8SM3 Chemical Cleaning pH Measuring Unit ,
After the delivery, open the package carefully and inspect for damages caused during transport.
Should there be any damage or breakage on the product, please contact YOKOGAWA
immediately and keep all the packing materials, containers and boxes that came with the
product.
ii
After the unpacking, make sure the delivered products include all of the component equipment
you ordered.
After completing the unpacking, make sure that the delivered component covers all of the
required specications. When conrming the specications, refer to the model and sufx codes
indicated on the nameplate on the instrument. The models are indicated on the name plates.
Check also those of accessories. For further information on PH8SM3 or PH8HS3, please read
subsection 1.2 of this document.
l Unpacking and handling
When unpacking, place the instrument on a level surface in the position in which the instrument
will actually be installed, (Do not allow the package to undergo any intense mechanical shock by
turning it over on its side.) Avoid applying any excess force to the pipes and cables. Otherwise, a
defective pipe and / or cable connection may result
PH8SM3 Chemical Cleaning pH Measuring Unit weighs approximately 50 kg. It is recommended
that the product be unpacked as near your installation location as possible.
IM 12B07W01-04EN1st Edition : Nov.11, 2016-00
u Safety Precautions
n Safety, Protection, and Modication of the Product
• In order to protect the system controlled by the product and the product itself and ensure
safe operation, observe the safety precautions described in this user’s manual. We assume
no liability for safety if users fail to observe these instructions when operating the product.
• If this instrument is used in a manner not specied in this user’s manual, the protection
provided by this instrument may be impaired.
• If any protection or safety circuit is required for the system controlled by the product or for
the product itself, prepare it separately.
• Be sure to use the spare parts approved by Yokogawa Electric Corporation (hereafter
simply referred to as YOKOGAWA) when replacing parts or consumables.
• Modication of the product is strictly prohibited.
• The following safety symbols are used on the product as well as in this manual.
WARNING
This symbol indicates that an operator must follow the instructions laid out in this manual in
order to avoid the risks for the human body and health including risk of injury, electric shock, or
fatalities. or the damages to instruments. The manual describes what special care the operator
must take to avoid such risks.
iii
CAUTION
This symbol indicates that the operator must refer to the instructions in this manual in order to
prevent the instrument (hardware) or software from being damaged, or a system failure from
occurring.
The following are signal words to be found only in our instruction manuals.
CAUTION
This symbol gives information essential for understanding the operations and functions.
NOTE
This symbol indicates information that complements the present topic.
n Warning and Disclaimer
The product is provided on an “as is” basis. YOKOGAWA shall have neither liability nor
responsibility to any person or entity with respect to any direct or indirect loss or damage arising
from using the product or any defect of the product that YOKOGAWA can not predict in advance.
n Trademark policy
FLEXA, FLXA, SENCOM are the registered trade marks and trade names of Yokogawa’s
products. All other company and product and product names mentioned in this document are
trade names, trademarks or registered trademarks of their representative companies. In this
document, trademarks or trade names are not indicated with TM or ® as trademark symbols.
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
u After-sales Warranty
n Do not modify the product.
n During the warranty period, for repair under warranty, carry or send the product
to the local sales representative or service ofce. Yokogawa will replace or
repair any damaged parts and return the product to you. Before returning a
product for repair under warranty, provide us with the model name and serial
number and a description of the problem. Any diagrams or data explaining the
problem would also be appreciated.
• If we replace the product with a new one, we won’t provide you with a repair report.
• Yokogawa warrants the product for the period stated in the pre-purchase quotation
Yokogawa shall conduct dened warranty service based on its standard. When the
customer site is located outside of the service area, a fee for dispatching the maintenance
engineer will be charged to the customer.
n In the following cases, customer will be charged repair fee regardless of
warranty period.
• Failure of components which are out of scope of warranty stated in instruction manual.
• Failure caused by usage of software, hardware or auxiliary equipment, which Yokogawa
Electric did not supply.
• Failure due to improper or insufcient maintenance by user.
• Failure due to modication, misuse or outside-of-specications operation which Yokogawa
does not authorize.
• Failure due to power supply (voltage, frequency) being outside specications or abnormal.
• Failure caused by any usage out of scope of recommended usage.
• Any damage from re, earthquake, storms and oods, lightning, disturbances, riots, warfare,
radiation and other natural changes.
iv
n Yokogawa does not warrant conformance with the specic application at the
user site. Yokogawa will not bear direct/indirect responsibility for damage due
to a specic application.
n Yokogawa Electric will not bear responsibility when the user congures the
product into systems or resells the product.
n Maintenance service and supplying repair parts will be covered for ve years
after the production ends. For repair for this product, please contact the
nearest sales ofce described in this instruction manual.
IM 12B07W01-04EN1st Edition : Nov.11, 2016-00
Chemical Cleaning
pH Measuring System
IM 12B07W01-04EN 1st Edition
CONTENTS
u Introduction ....................................................................................................i
u Safety Precautions ......................................................................................iii
1. General ...................................................................................................... 1-1
1.1 Standard Specications ................................................................................... 1-1
1.2 Model and Sufx Codes ................................................................................... 1-4
6.1 More Than 100 ml of Chemical Solution at a Time Is Being Fed to Holder 6-1
6.2 A Smaller Quantity of Chemical Solution Is Fed to Holder .......................... 6-2
6.3 CYLINDER FAIL Signal Appears .....................................................................6-2
6.4 When Liquid keeps leaking from bottom plate of Cleaning Chamber ........ 6-2
6.5 Chemical Solution Cannot Be Fed into Cleaning Chamber ......................... 6-3
Customer Maintenance Parts List (PH8SM3).................. CMPL 12B07W01-13E
Customer Maintenance Parts List (PH8HS3)....................CMPL 12B07W01-23E
Revision Record .......................................................................................................i
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
<1. General>
1. General
Chemical Cleaning pH Measuring System is designed to automatically clean pH electrodes
with a chemical solution while they remain in the system. The system is especially effective in
restoring the performance of a pH electrode which has been deteriorated through repeated
pH measurements of highly alkaline solutions. It is also effective in cleaning pH electrodes
contaminated with calcium sulfate (CaSO
1.1 Standard Specications
Chemical Cleaning pH Measuring System are congured as the table shown below.
pH/ORP Converter2-wire Analyzer
Chemical Cleaning unitPH8SM3-EPH8SM3-G or PH8SM3-F
pH analyzerPH450GFLXA202 or FLXA21
Distributor―PH201G
pH sensor
HolderPH8HS3
Note You can select WTB10 Terminal Box, if necessary.
The following are specication describing on PH8SM3 Chemical Cleaning Unit and PH8HS3
Holder. For more information on other products, please read corresponding instruction manuals
attached to each product.
) scale or calcium carbonate (CaCO3) scale.
4
Chemical Cleaning pH Measuring System
PH8EFP-□-TT2 (Note)
1-1
n PH8SM3 Chemical Cleaning Unit
Cleaning Method:
Automatic chemical cleaning by air bubbling
Interval Time:
0.1 to 36.0 hours (To be set in the pH converter)
Wash Time:
0.1 to 10 min (factory setting: 4 min)(To be set in the pH converter)
Relaxation Time:
0.1 to 10 min. (factory setting: 0.5 min.)(To be set in the pH converter)
Bubbling (SV1: On) Time:
0 to 10 min. (factory setting: Approx. 2 min.)
Cylinder Failure Time:
0 to 1 min. (factory setting: Approx. 0.5 min.)
Structure:
Freestanding rack for indoor installation.(For the uv protection,when you install the unit
outdoors, specify tank cover and select Fluoropolymer (PTFE) tube, or specify hood if
necessary.
Main Components:
Chemical solution tank, control box, air-pressure regulator, and power supply unit (for pH/
ORP Converter only)
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
<1. General>
Chemicals for Cleaning:
Acid solution (e.g., hydrochloric acid or diluted sulfuric acid), or alkali solution. Organic
solvents are not allowed.
Note: Select appropriate solution for effective cleaning.
Material, Finish, and Color of Main Components:
Control Box (K9729AN)
Material: Aluminum alloy casting
Colors:
Deep sea moss green (Munsell 0.6GY3.1/2.0) and frosty white (Munsell 2.5Y8.4/1.2)
Finish: Baked polyurethane resin coating
Power Supply Unit (for pH/ORP converter only)
Material: Carbon steel (body)
Color: Deep sea moss green (Munsell 0.6GY3.1/2.0 or equivalent)
Finish: Baked polyurethane resin coating
Mounting Rack
Material: Carbon steel
Color: Deep sea moss green (Munsell 0.6GY3.1/2.0)
Finish: Baked polyurethane resin coating
Chemical Solution Tank (20 L, 2 to 10 % diluted hydrochloric acid or diluted sulfuric acid.
Effective capacity; approximately 17 L, approximately 100 ml is used for each cleaning)
Material: Polyethylene resin (for solution tank), and hard PVC resin (for internal tank)
Tubing for Solution, Air, or KCl
Material of tubes: Polyethylene or Fluoropolymer (PTFE)
Mateirial of tting (joint): polypropylene resin or Fluoropolymer (PTFE)
Ambient Temperature: 0 to 45°C (Note ; Freezing protection is required if necessary.)
1-2
Power Supply: 100 V AC ±10%, 50/60Hz ±5%
Power Consumption: Approx. 60 VA
2
Air Supply: 300 to 950 kPa {3 to 9.5 kg/cm
}
Max. Air Consumption: Approx. 10 Nl/min.
External Dimensions:
500 (W) x 600 (D) x 1630 mm (H)
Weight: Approx. 50 kg (when the chemical tank is empty)
Output Contact Signal: Cylinder failure
Contact State: Normally open (close on error )
Contact Capacity: 24 V DC, 1 A, 110 V AC 0.3 A (resistance load)
Output:
pH/ORP Converter : 4 to 20 mA DC 2 points (isolated transmission output; maximum load of
600 Ω)
2-Wire Analyzer : 1 to 5 V DC (minimum resistive load of 2 kΩ)
Cable Connection: G 1/2 gland packing is supplied.
Terminal Size: M4
Outside Cable Diameter: Φ9 to Φ12 mm
Piping Connection: Air for Instrumentation: Rc 1/4 female thread
Note 1: Install the KCl reserve tank in an appropriate place at the job site or attached to the stand for the
chemical cleaning unit.
IM 12B07W01-04EN1st Edition : Nov 11, 2016-00
<1. General>
1-3
Note 2: The wiring and piping between the chemical cleaning unit, sensor, KCl reserve tank, and holder are to
Note 3: The wiring between the switch in the holder and the chemical cleaning unit is to be done by the user.
be done by the user.
The terminal size is M4.
EMC Compliance: Korea Electromagnetic Conformity Standard Class A
A급 기기 (업무용 방송통신기자재)
이 기기는 업무용(A급) 전자파적합기기로서 판매자 또는
사용자는 이 점을 주의하시기 바라며, 가정외의 지역에서
사용하는 것을 목적으로 합니다.
n PH8SM3 Holder
Functions:
Moves the pH sensor up or down using a pneumatic cylinder (air cylinder), and provides
chemical cleaning.
Structure: Constructed for indoor use (
Max. External Dimensions:
190 (W) x 170 (D) x Approx. 830 to 2030 mm (H) (when the sensor is raised)
Mounting:
Mounted on a 2-inch (50A) vertical pipe (outside diameter: 60.5 mm). Two mounting
brackets are supplied.
pH Sensor Up/Down Movement (nominal):
한국 전자파적합성 기준
For outdoor installation, select Cylinder cover /SC as Option.)
300 mm, 600 mm, 1000 mm, 1500 mm
Weight:
Approx. 8 kg (holder with 300 mm movement)
Approx. 10 kg (holder with 600 mm movement)
Approx. 12 kg (holder with 1000 mm movement)
Approx. 15 kg (holder with 1500 mm movement)
Materials
Frame: Baking nish over staineless steel
Color: Deep sea moss green (Munsell 0.6GY3.1/2.0 or equivalent)
Bottom Cover Pull-up Mechanism: Rod (PPS resin) and screws (PEEK)
Mounting bracket: staineless steel
Holder: Polypropylene and hard PVC (for part of a holder)
Solution Chamber: Hard PVC
O-ring: Fluororubber
Gasket: EPDM
Solution Temperature Range: -5 to 80°C
Ambient Temperature: 0 to 45°C
Flow Speed: 2 m/s or less
Provide an adequate ventilation when using chemicals.
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
<1. General>
1.2 Model and Sufx Codes
The name plate on product describes each specication of the product. The following are Model
and Sufx Code and their details on PH8SM3 and PH8HS3.
n PH8SM3 Chemical Cleaning Unit
●Model and Sufx Codes
ModelSufx code
PH8SM3- - - - - - - - - - - - - - - - - - Operating Unit for Chemical Cleaning System
*1: The pH/ORP converter or 2-wire analyzer is attached to the chemical cleaning operating unit when shipped.
*2: For PH8EFP sensor, select KCl reserve tank (sufx code “-TT2”) with a medium-pressure.
*3: Polyethylene is susceptible to degradation upon UV radiation. Specify the Fluoropolymer (PTFE) (-T10) as tube
material, when you install PH8SM3 outdoors. Specify the Fluoropolymer (PTFE) when using PH8HS3 holder
outdoors, even though you install PH8SM3 unit indoors.
*4: Specied at the outdoor installation. Hood is made of precoated SEHC.
*5: Specied at the outdoor installation. The cover is made of non-coated stainless steel.
*6: For FLXA21 or FLXA202 with the sufx code -F, or -G, specify the type -AG (for general purpose for KC
The system must undergo start-up service when the chemical cleaning pH measuring system is installed.
l Accessories
DescriptionQt'yRemarks
6 (OD) x 4 (ID) polyethylene
Fitting (polyethylene resin or Fluoropolymer (PTFE))63 for joint, 3 for spare parts *2
*1: 1 tube for the control box-the chemical tank assembly
3 tubes for the PH8SM3-Ph8HS3
1 tube for the pressure valve-KCI reserve tank, if the operating unit has the pressure reducing valve for KCI.
Cut the tube into an approriate length to use.
*2: If the operating unit has a pressure-reducing valve that lowers the pressure on the KCl reserve tank, one of
these spare ttings is to be used for the piping port of the valve.
resin or Fluoropolymer (PTFE) tube
40 m
For tubing *1
IM 12B07W01-04EN1st Edition : Nov 11, 2016-00
<1. General>
l Spare Parts
DescriptionP/NRemarks
Fuse for power supply
box
Polyethylene tubing
Fluoropolymer (PTFE)
tubing
Polypropylene tting
Fluoropolymer (PTFE)
tting
A1109EF Rating: 1A (for pH/ORP converter only)
L9901CA
L9901LG
L9831NA
L9831NE
L9831JE
L9831TS
L9831TT
Specied length by meters
Specied length by meters
Piping tting (polypropylene)3Parts for PH8SM3 holder (used for piping port)
Cable tie 5For KCl supply tube/sensor cable
Spare gaskets (P/N: K9729WJ)1Parts for cleaning chamber of PH8HS3 holder
4/pkg
Parts for mounting brackets (used to mount to the
8
holder)
Parts for mounting brackets
2
(used to mount to 2-inch pipe)
4/pkg
1
Parts for sensor holder (used to x sensor cable)
1
1
1
l Spare Parts
DescriptionP/N
GasketK9729WJ
O-ringsK9729YK
Qt'y
1
2
Remarks
Material : EPDM
1p/pkg. Replace both of the two rings at the same time.
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
<1. General>
1.3 External Dimensions
n PH8SM3 Chemical Cleaning Unit
l pH/ORP Converter (PH8SM3-E)
)
Option
(
Hood
)
KCl reserve tank *1
an be installed
c
(
)
PH450G
Separated Order
(
1-6
unit:mm
Control Box
*2 Pressure Regulator
for KCI reserve tank
Tank Cover
Option
(
(AS3)
)
Power
Supply Unit
Air Inlet *3
(Rc1/4 or
1/4NPT)
Tank cover
fixing screws
option
(
)
PVC plate
30440
500600
4-Φ15fixing holes
l 2-Wire Analyzer (PH8SM3-G, -F)
KCI reserve tank *1
(Can be installed)
(Separated Order
FLXA21
Control Box
*2 Pressure Regulator AS3
for KCI reserve tank
(
Tank Cover
(Option)
fixing screws
)
)
Tank cover
(Option)
(1540)
(1200)
40
(30)
30540
FLXA202
(Separated order)
Air Inlet *3
Rc1/4
(
or 1/4NPT
)
(1200)
Stand
SEHC
(
Chemical Solution
tank (20 L)
Hood(Option)
(1540)
SEHC
(
Chemical Solution
Tank (20 L)
)
Stand
1630
1600
Power Cable Inlet
Cable O.D.
(Φ9 ~ 11)
(30)
unit:mm
1630
1600
)
PVC plate
40
30440
(30)
30540
(30)
500600
4-Φ15Fixing holes
*1: Mount the KCl solution reserve tank when necessary after installation. If the hood is specied, (Option code /H
is specied) mount the tank on the hood.
*2: This is a pressure valve to regulate the air that increases the pressure in the reserve tank for the KCl solution.
This valve is added only when specied.
*3: If no pressure valve is specied, there is no tube tting. Air inlet connects directly to piping port of the control
box.
IM 12B07W01-04EN1st Edition : Nov 11, 2016-00
<1. General>
n PH8HS3 Holder
1-7
36
Cylinder Cover
(Option)
(130)
(126)
35 pitch
60
80
Grommet for
external wiring
55485 max.
48
(
70
Approx.150
Mounting bracket
with U-bolts
50A Pipe
provided by customer
2-Φ9 holes
Sensor cable
and KCI tube
Approx.110
)
Cylinder
Movement
247
(65)
C
B
L6
L5
L4
300
230
Unit: mm
L2
136
L1
(95)
A
80
L3
nominal movement
(170)
During
measurement
30mm or longer
Solution being measured
During
Cleaning
30379
During
measurement
pH electrode
20
Tubing Connections
A : Chemical solution inlet (Ø6/Ø4 tube joint)
B : Lower air inlet of cylinder (Ø6/Ø4 tube joint)
C : Upper air inlet of cylinder (Ø6/Ø4 tube joint)
Specify the nominal movement when ordering. L4, L5, and L6 designate the movable position for the pipe mounting bracket.
Note: ● Mounting bracket for holder will be shipped separately.
● Joint nipple will be attached with PH8SM3 Chemical Cleaning unit.
● For the outdoor installation, select /SC option of cylinder cover
Actual
movement
L1L2L3L4L5L6
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
Blank Page
<2. Installation>
2. Installation
The chemical cleaning pH measuring system can be installed indoor/outdoors. Choose an
appropriate location (free from dust, sunlight, rain) for easy maintenance. Note that since the
system uses water for washing and a chemical solution, care must be taken to ensure that these
liquids are protected from freezing in winter.
Note: Install the PH201G distributor, which is required when using the 2-Wire Analyzer, in an
indoor location such as an instrument room.
This chapter explains the procedure for installing the component equipment, highlighting the
PH8SM3 Chemical Cleaning Unit for the chemical cleaning system and the PH8HS3 holder.
2.1 Installing the PH8SM3 Chemical Cleaning
Unit for a Chemical Cleaning System
2.1.1 Where to install the unit
Install the PH8SM3 operating unit for a chemical cleaning system in a location which meets the
following requirements.
(1) Close to the pH measurement point (location where the PH8HS3 holder is installed)
2-1
The operating unit for the chemical cleaning system and the holder are connected via
electrical wiring as well as the piping through which the chemical solution is supplied. Keep
the length of the tubing for supplying the chemical solution to a minimum (less than 10 m) in
order to reduce piping resistance.
(2) The maximum tube length between the cleaning unit and the sensor holder is 10 m.
It is preferable to install the stand at the same level as the sensor holder. If this is impossible,
the stand can be installed a maximum of 2 m below the holder level. Installation above the
holder level causes no problem.
(3) Easy access for maintenance work
The location must allow users to have an easy view of the display on the PH450G pH/ORP
Converter or 2-wire Analyzer FLXA202/FLXA21, and to operate the control box with ease
to set the pressure. Also, consider the ease of work required when relling the holding tank
with the chemical solution. Furthermore, secure the clearance for maintenance access
shown in Figure 2.1.
Unit: mm
PH8SM3
Approx. 1150
Front view
Approx. 500
More than 900
Figure 2.1 Clearance for Maintenance Access
F2.1.ai
IM 12B07W01-04EN1st Edition : Nov. 11, 2016-00
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