Product Name: Electrochemical Oxygen Sensors P-21, P-31 and P-41
Manufacturer: IT Dr. Gambert GmbH,
Address: Hinter dem Chor 21; 23966 Wismar
Phone: +49 3841 220050
Technical Support: it@IT-wismar.de
Environment, Health
and Safety: wkaemtner@IT-Wismar.de
Date Prepared: 28. March 2008
Section II – Hazardous Ingredients/Composition
Material or Component C.A.S. # Quantity OSHA PEL ACGIH
Lead (Pb) 7439-92-1 7-13 gms 0.05 mg/m
Potassium hydroxide 1310-58-3 2 - 3 ml 2mg/m
(KOH)(8 - 34% KOH in
water)
Section III – Health Hazard Data
Routes of Entry: Inhalation: Highly unlikely.
Ingestion: May be fatal if swallowed.
Skin: The electrolyte (potassium hydroxide) is corrosive; skin
contact may cause irritation or severe chemical burns.
Eyes: The electrolyte (potassium hydroxide) is corrosive; eye
contact may cause irritation or severe chemicals burns.
Acute Effects: The electrolyte is harmful if swallowed, inhaled or absorbed through the
skin. It is extremely destructive to tissue of the mucous membranes,
stomach, mouth, upper respiratory tract, eyes and skin.
Chronic Effects: Prolonged exposure with the electrolyte has a destructive effect on
tissue.
Chronic exposure to lead may cause disease of the blood and blood
forming organs, kidneys and liver, damage to the reproductive systems
and decrease in fertility in men and women, and damage to the fetus of
a pregnant woman. Chronic exposure from the lead contained in this
product is extremely unlikely.
3
0.15 mg/m
3
(ceil) 2mg/m3 (ceil)
3
This data sheet is subject to change without prior notice !
MSDS P21_31_41 Rev 01-08 page
IT Dr. Gambert GmbH, Hinter dem Chor 21, 23966 Wismar, Germany
Signs and Symptoms of Contact of electrolyte with skin or eyes will cause a burning sensation
Exposure: and/or feel soapy or slippery to touch.
Other symptoms of exposure to lead include loss of sleep, loss of
appetite, metallic taste and fatigue. For additional exposure information
refer to 29 CFR 1910.1025, Appendix A – Substance Data Sheet for
Occupational Exposure to Lead.
Carcinogenicity: Lead is classified by the IARC as a class 2B carcinogen (possibly
carcinogenic to humans).
OSHA: Where airborne lead exposures exceed the OSHA action level, refer to
OSHA Lead Standard 1910.1025.
NTP: n.a.
Medical Conditions Lead exposure may aggravate disease of the blood and blood forming
Generally Aggravated by organs, hypertension, kidneys, nervous and possibly reproductive
Exposure: systems. Those with pre-existing skin disorders or eye problems may
be more susceptible to the effects of the electrolyte.
Section IV – Emergency First Aid Procedures
In case of contact with the skin or eyes, immediately flush with plenty of water for at least 15 minutes and
remove all contaminated clothing. Get medical attention immediately.
If ingested, give large amounts of water and DO NOT INDUCE VOMITING. Obtain medical attention
immediately.
If inhaled, remove to fresh air and obtain medical attention immediately.
Section V – Fire and Explosion Hazard Data
Flash Point: n.a.; Flammable Limits: n.a.; LEL: n.a.; UEL: n.a.;
Extinguishing Media: Use extinguishing media appropriate to surrounding fire conditions. No
specific agents recommended.
Special Fire Fighting
Equipment: Wear NIOSH/OSHA approved self-contained breathing apparatus and
protective clothing to prevent contact with skin and eyes.
Unusual Fire and Explosion
Hazards: n.a.
Section VI – Cleanup Procedures
Wipe down the area several times with a wet paper towel. Use a fresh towel each time. Contaminated
paper towels are considered hazardous waste.
This data sheet is subject to change without prior notice !
MSDS P21_31_41 Rev 01-08 page
IT Dr. Gambert GmbH, Hinter dem Chor 21, 23966 Wismar, Germany
Section VII – Precautions for Safe Handling and Use
Note: The oxygen sensors are sealed and under normal circumstances the contents of the
sensors do not present a health hazard. The following information is given as a guide in the
event that a cell leaks.
Protective Measures During Before opening the bag containing the sensor cell, check the sensor cell
Cell Replacement: for leakage. If the sensor cell leaks, do not open the bag. If there is
Section VIII – Exposure Controls/Personal Protection
Eye Protection: Chemical splash goggles
Hand Protection: Rubber gloves
Other Protective Clothing: Apron, face shield
Ventilation: n.a.
Section IX – Physical/Chemical Characteristics
Material or Boiling Specific Vapor Melting Density Evap. Solubility in Odor/Appearance
Component Point (°C) Gravity Pressure Point (°C) Rate Water P h ysical State
Lead 1744 11.34 n.a. 328 n.a. n.a. Insoluble Solid, silver
Potassium 1320 2.04 n.a. 360 n.a. n.a. Complete White or slightly
Hydroxide yellow. No odor
Ecotoxicity: The LC50 of lead for the daphnia magna is 3.6 mg/l, and 5.1 mg/l for
the daphnia pulex.
Environmental Fate: Lead is bioaccumulative in most aquatic life and mammals. It is highly
mobile as lead dust or fume, yet forms complexes with organic material which
limits its mobility.
Section XIII – Disposal Considerations
Waste must be disposed of in accordance with Federal, State and Local environmental control
regulations. If discarded in its purchased form, this product is hazardous by its characteristics of toxicity
and corrosivity under RCRA.
DOT: Regulated. Refer to Small Quantity Exceptions: 49 CFR 173.4
IATA: Regulated. Refer to IATA Dangerous Goods in Excepted Quantities, Sec. 2.7
Section XV – Regulatory Information
European Community: Potassium hydroxide (liquid)
R35 – Causes severe burns.
R42 – May cause sensitization by inhalation.
R36/37/38 – Irritating to eyes, respiratory system and skin.
US Federal Regulations: 1) OSHA – Hazardous by definition of Haz Com Std. 29 CFR 1910.1200
2) SARA TITLE III
Sec 302 (40 CFR Part 355)
Sec 311 & 312
Sec 313 (40 CFR Part 372):
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313, of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
This data sheet is subject to change without prior notice !
MSDS P21_31_41 Rev 01-08 page
IT Dr. Gambert GmbH, Hinter dem Chor 21, 23966 Wismar, Germany
3) TSCA (Toxic Substances Control Act)
Components of this product are listed on the TSCA inventory.
4) CERCLA Section 102(A) (40 CFR Part 302)
Hazardous Substances and Reportable Quantities
Canada: Canadian Environmental Protection Act (CEPA): Potassium hydroxide, liquid,
is on the Domestic Substances List (DSL) and is acceptable for use under the
provisions of CEPA.
WHMIS: Potassium hydroxide (liquid)
Class D-2A: Material causing other toxic effects
(VERY TOXIC)
Class E: Corrosive liquid.
Lead
Class D-2A
Section XVI – Other Information
All chemicals may pose unknown hazards and should be used with caution. While the information
contained in this Material Safety Data Sheet is believed to be correct and is offered for your information,
consideration and investigation, IT Dr. Gambert GmbH assumes no responsibility for the
completeness or accuracy of the information contained herein.
This data sheet is subject to change without prior notice !
MSDS P21_31_41 Rev 01-08 page
IT Dr. Gambert GmbH, Hinter dem Chor 21, 23966 Wismar, Germany