SAFETY DATA SHEET
1. Identification
Lithium-ion and Lithium-ion Polymer Batteries (Li-ion Batteries)Product identifier
Other means of identification
Recommended use
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Company Name
Address
None.
Lithium ion battery.
None known.
Motorola Solutions, Inc.
1303 E. Algonquin Road
Schaumburg, Illinois 60196 U.S.A.
General information
Emergency phone number
CHEMTREC
1-847-576-5000
1-800-424-9300
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Under normal conditions of processing and use, exposure to the chemical constituents in this product is unlikely. The battery
should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful.
Hazards shown here apply to exposure that may occur from damaged or leaking batteries or under extreme heat conditions
such as fire.
Label elements
Not classified.
Category 4Acute toxicity, oral
Category 1BSkin corrosion/irritation
Category 1Serious eye damage/eye irritation
Category 1Sensitization, skin
Category 1ACarcinogenicity
Not classified.
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Lithium-ion and Lithium-ion Polymer Batteries (Li -i on B atteries) SDS US
933626 Version #: 01 Revision date: - Issue date: 08-J une-2016
Danger
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin
reaction. May cause cancer.
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Avoid breathing fume/mist/vapors/spray. Wash thoroughly after handling. Do not
eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out
of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated
clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
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Supplemental information
None.
3. Composition/information on ingredients
Mixtures
following: Lithiated cobalt
oxides, Lithiated manganese
oxides, Proprietary lithiated
nickel-manganese-cobalt
oxides)
difluoride and/or
polytetrafluoroethylene)
one or more of lithium
hexafluorophosphate and
lithium tetrafluoroborate)
CAS number %Chemical name
12190-79-3, 12057-17-9,
NA
7782-42-5 10-20Negative electrode (Graphite)
24937-79-9, 9002-84-0 0-3Binders (Polyvinylidene
21324-40-3, 14283-07-9 1-5Electrolyte salt (Lithium salt:
20-40Positive electrode (One of the
96-49-1, 105-58-8,
solvents including one or more
of the following: Ethylene
carbonate, Diethyl carbonate,
Dimethyl carbonate, Ethyl
methyl carbonate, and
Propylene carbonate.)
(Polyethylene and/or
polypropylene)
All concentrations are in percent by weight unless otherwise indicated.
Ingredients shown are major constituents representative of various compositions for lithium ion cells.
Exposure to hazardous ingredients is not anticipated under normal conditions of use. For further information please refer to Section 8.
616-38-6, 623-53-0,
108-32-7
7440-50-8 5-10Other components (Copper)
7429-90-5 5-40Other components (Aluminum)
7440-02-0 0-5Other components (Nickel)
9002-88-4, 9003-07-0 1-3Other components
5-20Electrolyte solvent (Organic
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
Exposure to contents of an open or damaged battery: If breathing is difficult, remove to fresh air
and keep at rest in a position comfortable for breathing. Call a physician or poison control center
immediately.
Exposure to contents of an open or damaged battery: Remove contaminated clothes and rinse
skin thoroughly with water for at least 15 minutes. Call a physician or poison control center
immediately. Chemical burns must be treated by a physician.
Exposure to contents of an open or damaged battery: Immediately flush eyes with plenty of water
for at least 15 minutes. Provide eyewash station. Remove contact lenses, if present and easy to
do. Continue rinsing. Call a physician or poison control center immediately.
Exposure to contents of an open or damaged battery: Call a physician or poison control center
immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that
stomach content doesn't get into the lungs.
Exposure to contents of an open or damaged battery: Burning pain and severe corrosive skin
damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling,
and blurred vision. Permanent eye damage including blindness could result. May cause allergic
skin reaction. Difficulty in breathing. Coughing. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim warm. Keep victim
under observation. Symptoms may be delayed.
Lithium-ion and Lithium-ion Polymer Batteries (Li -i on B atteries) SDS US
933626 Version #: 01 Revision date: - Issue date: 08-J une-2016
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General information
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire fighting
equipment/instructions
Specific methods
General fire hazards
Use fire-extinguishing media appropriate for surrounding materials.
Leak from a damaged or opened battery: Do not use water unless flooding amounts are available.
In the event of fire and/or explosion do not breathe fumes. The evolved combustion products may
contain carbon oxides, metal oxides, hydrogen fluoride, and should be considered hazardous.
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.
Fight fire from protected location or safe distance. Keep upwind. Move containers from fire area if
you can do so without risk. Avoid discharge into drains, water courses or onto the ground.
Use standard firefighting procedures and consider the hazards of other involved materials.
Under normal use, the battery does not exhibit flammable properties. In the event that the battery
is abused and disassembly of the battery occurs resulting in exposure of internal components, the
exposed solution, may be flammable and/or corrosive. Exposure to excessive heat may lead to
venting or rupture of the sealed battery, exposing the internal components which may be corrosive
and/or flammable. Vented gas would be flammable when in sufficient concentration.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
None under normal use conditions. In the event of damage resulting in a leak or exposed
materials, avoid contact with contents of an open or damaged cell or battery. Wear protective
clothing as described in Section 8 of this safety data sheet.
Leak from a damaged or opened battery: Contain spillage with sand or earth. Collect with
absorbent, non-combustible material into suitable containers. For waste disposal, see Section 13
of the SDS.
Avoid allowing material from exposed battery to contaminate soil, sanitary sewers, or waterways.
7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Do not open, disassemble, crush or burn battery. Protect against physical damage. Do not expose
battery to extreme heat or fire. Do not allow conductive material to touch the battery terminals. A
dangerous short-circuit may occur and cause battery failure and fire.
Keep out of reach of children. Prevent short circuits. Store in original packaging. Store in a cool,
dry, ventilated area away from sources of heat, moisture and incompatibilities. Store away from
incompatible materials (See Section 10).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
OXIDE (CAS 182442-95-1)
(CAS 12057-17-9)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Type
PEL 5 mg/m3 Respirable dust.Aluminum (CAS 7429-90-5)
Ceiling 5 mg/m3COBALT LITHIUM NICKEL
PEL 1 mg/m3 Dust and mist.Copper (CAS 7440-50-8)
PEL 5 mg/m3 Respirable fraction.Graphite (CAS 7782-42-5)
Ceiling 5 mg/m3Lithium manganese oxide
PEL 1 mg/m3Nickel (CAS 7440-02-0)
Value
15 mg/m3 Total dust.
0.1 mg/m3 Fume.
15 mg/m3 Total dust.
Form
TypeComponents
TWA 15 mppcfGraphite (CAS 7782-42-5)
Lithium-ion and Lithium-ion Polymer Batteries (Li -i on B atteries) SDS US
933626 Version #: 01 Revision date: - Issue date: 08-J une-2016
Value
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