Metrohm TitrIC pro III User Manual

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TitrIC pro lysis of w

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ductivity, p

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alytical seq

A

1.

The sample anion and c

2.

The sample flow-throug Afterwards and m valu

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355

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Delivery

1.

- deliver

-Optional

Installati

2.

. 815 Rob

. Titrando

. Conduct

. 850 Prof

. Dosino h

3.

Cable co

Tubing c

4.

. External

. Installati

. Overvie

5.

Miscella

5.

. Membra

. Stirrer ....

. Length o

. Electrod

6.

Software

ts:

ackage ........

d with TitrIC

accessories:

n ..................

tic USB Sam

2.905.0010) .

meter (2.856

ssional IC A

lder (6.2057.

nections ......

nnections .....

ell$ ..............

n of the 50 m

of all the tub

eous .............

e Pumps of t

.....................

the aspiratio

s ...................

.....................

ro III packag

.....................

ple Processo

.....................

.0010) ...........

Cat – MCS (

210) .............

.....................

L Dosing Uni

ing connectio

.....................

e 815 ..........

.....................

n tips in the e

.....................

: ..................

.....................

XL (2T/2P) ..

.....................

.850.3030) ..

.....................

....................

s .................

.....................

ternal cell ....

.....................

.... 3

.... 4

.... 5

.... 6

.... 7

6.

. Installati

. Configur

.1. Devices .

.2. Solution .

.3. Swing H

.4. Lift positi

.5. Needle ri

Fig

.: TitrIC pro III

ystem setup

.6. Methods

. Configur

.1. Devices .

.2. Solution .

.3. Electrod

n of the soft

tion of MagI

.....................

ad configura

ns ................

nse position ..

.....................

tion of tiamo

.....................

s ...................

are ...............

Net .............

.....................

ion ................

.....................

..................

.....................

Page 1

.... 7

.... 8

.... 9

f 14

Application Bulletin 355

Installation Instructions for TitrIC pro III

6.3.4. Methods .................................................................... 9

6.4. Setup of RS232 communication between MagIC Net

and tiamo

TM

.............................................................. 9

7. Complete Analysis with TitrIC ................................. 10

9. TitrIC pro – Combo Kit Dilution ............................... 11

9.1 Delivery package .................................................... 11

9.2 Installation .............................................................. 11

9.3 Dosino .................................................................... 11

9.4 Transfer Tubing ...................................................... 11

9.5 External Dilution Vessel .......................................... 11

9.6 Analysis .................................................................. 11

9. TitrIC pro – Combo Kit Partial Loop ........................ 13

9.1 Delivery package .................................................... 13

9.2 Installation .............................................................. 13

9.3 Rinsing station ........................................................ 13

9.4 MiPT Dosino ........................................................... 13

9.5 Analysis .................................................................. 13

Page 2 of 14

Application Bulletin 355

Installation Instructions for TitrIC pro III

1. Delivery package

- delivered with TitrIC pro III package:

No. Article no. Article designation

IC

1 2.850.3030 850 Professional IC AnCat – MCS

2 2.850.9010 IC Conductivity Detector

Sample processor

1 2.815.0110 815 Robotic USB Sample Processor

XL (2T/2P)

2 2.786.0040 Swing Head

1 6.1462.040 Robotic Arm with transfer head for

786 Swing Head, right swinging

1 6.1462.080 Robotic Arm DIS-COVER

1 6.2833.020 Needle holder 1/8 in. With tubing

connection M6

1 6.1835.050 PEEK sample aspiration tube (1.58

mm ID)

1 6.2629.000 Screw nut to needle holder IC

Conductometry

1 2.856.0010 856 Conductivity Module

1 6.0915.100 Five-ring conductivity measuring

cell, c = 0.7 cm-1, with Pt 1000

1 6.2151.000 Cable USB A - mini-DIN 8P (R)

1 6.2763.000 Flow through cell for 60915100

p and m value titration (pH measurement)

1 2.905.0010 905 Titrando

1 6.0277.300 iAquatrode plus with Pt 1000

1 6.2151.000 Cable USB A – mini-DIN 8P

1 6.2307.230 Buffer solutions pH 4, 7 and 9

1 6.2325.000 Phit kit

Liquid Handling

2 2.800.0010 800 Dosino

1 6.3032.220 807 Dosing Unit, glass, 20 mL

1 6.3032.250 807 Dosing Unit, glass, 50 mL

1 6.2057.210 Holder Dosino for IC Instruments

1 6.1608.030 Glass bottle GL45 1L (round)

1 6.1808.280 Adapter Dosino Port 4 / M6

1 6.1618.020 Thread adapter S 40 to GL45

2 6.2744.080 Coupling M6-UNF 10/32 (Dosing

Unit – IC screw)

1 6.2744.070 Pressure screw made of PEEK,

short, 5x

1 6.1808.010 Coupling piece 2 x M6 outer threads

1 6.1808.060 T Connector M6

Connection tubings

1 6.1805.510 Connection tubing FEP, L = 60 cm,

2 x M8 thread

1 6.1805.110 Connection tubing FEP, L = 80 cm,

2 x M6 thread

1 6.1805.030 Connection tubing FEP, L = 150 cm,

2 x M6 thread

External cell

1 2.802.0020 802 Rod Stirrer

1 6.2001.070 Stand support for 804

1 6.1414.060 Titration vessel lid micro ECO

1 6.1415.250 Titration vessel / 50-150 mL

5 6.2730.030 Stopper with nipple and O-ring

1 6.2730.080 Screw nipple M16/NS14

1 6.2730.020 Septum stopper

3 6.2730.060 Screw nipple for electrodes

1 6.1543.170 Aspiration tip M8

1 6.2709.090 Stopper (12 mm)

1 6.1543.210 3-way stopper with antidiffusion

valve

Software

1 6.6056.231 Tiamo 2.3 light CD: 1 Licence

1 6.6059.232 MagIC Net 2.3 Professional CD: 1

Licence

RS232 Communcation MagIC - Tiamo

1 6.2134.040 Connecting cable RS-232 to IMP-PC

(DBp)

2 6.2148.050 USB/RS-232 Converter for 900

Touch Control / Ti-Touch

-Optional accessories:

1 6.2041.xxx Sample rack made of PVC

1 6.1432.xxx Sample beaker

1 6.2324.000 Conductivity standard (100 µS/cm)

1 6.2301.060 Conductivity standard (12.88 mS)

1 6.2307.230 Buffer solutions 3 x 10 x 30mL of pH

4 / 7 / 9

1 6.2065.000 Stacking frame for 846 Dosing

Interface, 856 Conductivity Module,867 pH Module

1 6.2041.800 Sample rack 100* 75 ml

1 6.2041.810 Sample rack 34* 150 ml

1 6.2041.820 Sample rack 28* 250 ml

1 6.2041.840 Sample rack 59* 120 ml

Page 3 of 14

Application Bulletin 355

Installation Instructions for TitrIC pro III

1 6.1432.210 Sample beaker 75 mL made of glass

(for 6.2041.800)

1 6.1432.320 Sample beaker 250 mL made of

glass (for 6.2041.820)

1 6.1453.250 Sample beaker 250 mL made of

polypropylene (for 6.2041.820)

1 6.1459.300 Sample beaker 120 mL made of

polypropylene (250 pieces) (for

6.2041.840)

1 6.1006.510

Metrosep A Supp 5 - 100/4.0

1 6.1006.520 Metrosep A Supp 5 - 150/4.0

1 6.1006.500 Metrosep A Supp 4/5 Guard/4.0

1

6.1030.410 Metrosep A Supp 15 – 100/4.0

6.1030.420 Metrosep A Supp 15 – 150/4.0

1 6.1030.500 Metrosep A Supp 15 Guard/4.0

1 6.1050.410 Metrosep C 4 – 100/4.0

1 6.1050.420 Metrosep C 4 – 150/4.0

1 6.1050.500 Metrosep C 4 Guard/4.0

1 2.849.1030 849 Level Control for Inline Eluent

Preparation

2. Installation

The following is a detailed description of the TitrIC pro III installation.

We strongly recommend that the individual steps are carried out in the order given below!

2.1. 815 Robotic USB Sample Processor XL (2T/2P)

The sample processor is placed at the side at which it is most easily accessible. Please note that the following procedure refers exclusively to the version in which the sample processor is located at the left-hand side of the IC system.

 On the left-hand side of the 815 Robotic USB Sample

Processor XL, attach the stand support (6.2001.070) for the external titration vessel.

 Mount both Swing Heads (2.786.0040) onto the 815

(see installation instructions).

 Do not screw the robotic arm (6.1462.040) nor the

robotic arm DIS-COVER (6.1462.080) onto the Swing Head!

 The Sample Rack supplied is screwed onto the 815.

 In the vicinity of the 815 the two canisters (standard

equipment of 815) are placed on the floor: One 10 L canister is used as a waste container, the second one as a reservoir for deionized (DI) water used for rinsing the external cell.

 From the smaller opening of the canisters containing DI

water, an M8 PTFE tubing connection of suitable length is led to the connection box made of white plastic of membrane pump 1 / tower 1 and connected.

 From the front opening of the waste canister an M8

PTFE tubing connection of suitable length is led directly to membrane pump 1 / tower 2 (black plastic) and connected.

A more detailed description is given in the instructions for use of the 815 Robotic USB Sample Processor XL.

2.2. Titrando (2.905.0010)

Directly to the right of the 815 Robotic USB Sample Processor, place the Titrando with a bottle of titration solution (0.1 mol/L HCl will be connected to the 20 mL Dosing Unit and 800 Dosino).

2.3. Conductometer (2.856.0010)

The 856 Conductometer is placed directly at the left of the Titrando. For detailed information about the usage check the Instructions of Use of the 856.

Before measurement it is recommended to carry out the calibration of the cell constant in the flow-through cell of this

Page 4 of 14

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drawing bel

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he next step

ponents a

(6.

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osition when

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eptum stop

6.2730.08 ning 9 and nings 4, 8 a

o holder (6.2

der (6.2057.

50 Professi sing Unit is

ections

er cables are ents and the

r cable USB

ometer to US

r.

le (6.2151.0

not conne

r cable USB r, do not co

the MSB cab to external ti valves) to 85

the MSB cab

L HCl) to 90

r cable USB the 815 Sa

nections

al cell$

en here ( ,

w.

the external

e inserted

0.030 stopp ely into ope

the buret tips

er (6.2730.0 screw nippl

the 6.2730

d 6.

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10) is place nal IC An crewed ont

connected t

C remain s

6.2151.000) 1 of the 81

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6.2151.000) nect!

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MSB 1

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6.2151.000) ple Process

...) and “ope

cell is prepar

in the titr

rs (with the

ings 1, 2, 3,

, etc. are ins

0) is put int

e M16/NS14

.060 screw

on the left

at; the 50

this holder

the instrume itched off.

rom 856 Sample

rofessional I

rom PC to 81

800, 50 mL

to the IC

800, 20 mL

rom 905 to

r

ing 1”, ... ref

d. The follo

tion vessel

lack rubber r

and 7 and fi

rted.

the openin is screwed

ipple M16

top mL

t a

nts.

5

r to

ing

lid

ing) xed

6. into into

Fi

.: Numbers an

(6.

414.060)

The rins is insert the distr pump 1 connecti

This op

The rins is insert the distr pump 1 connecti

This is

The rins is insert the distr pump 1 connecti

815).

The 3-w (6.1543. 20 mL with the cm, sup Further connect (6.1805.

The PT inserted distribut

connections o

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here the pH

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d with an FE

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n the titration v

740.020, su

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740.020, su

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740.020, su

g 5, which is .170) to the e 815 with th

0, 60 cm, su

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plied with 81

onnected vi embrane FEP-tubing

ith 815).

plied with 81

onnected vi embrane FEP-tubing

ith 815).

erted.

plied with 81

onnected vi embrane FEP-tubing plied with

valve

ort 1 of the

s connected

805.100, 40 ay stopper.

ing Unit is

ection

opper.

, M8) is

ected via the

brane pump

)

/

Page 5

f 14

Metrohm TitrIC pro III User Manual

Specifications and Main Features

Frequently Asked Questions

User Manual