Metrohm TitrIC pro I User Manual
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A
plicatio
I
stallati
Th
TitrIC pro
lysis of w
titr
tion, and ion
determine
ductivity, p
allel, the con
trohm instru
tem at any
ameters.
alytical seq
A
The sample
anion analy
The sample
flow-throug
Afterwards
and m valu
whole pro
Th
tware: The u
ntification int
is
one by Mag
rting titration
tia
oTM is done
All
data is concl
gIC Net.
M
Bulleti
on ins
I system is
ter samples
chromatogra
in a ve
, acid capa
centrations o
ents can b
time and
ence
is transferre
is.
is transferre
cell to deter
he temperatu
s) are deter
cedure is c
er enters th
MagIC Net
C Net. MagI
analysis, res
via RS232.
ded in a joint
353
ruction
used for th
using dire
phy. The foll
y short ti
ity, water h
the individu
incorporate
sed to det
to the 881 C
into an exter
ine the cond
re, pH and a
ined in the e
ntrolled by
sample po
nly. All sam
Net Comm
pectively tran
report contai
s TitrI
fully autom
t measurem
wing parame
e: temperat
rdness and
l anions. Fur
in the exis
rmine additi
mpact IC for
al cell via th
uctivity.
id capacity (p
ternal cell.
the MagIC
ition and sa
le liquid hand
nication suc
sfer of result
ing all result
pro I
atic
ent,
ers
re,
, in
her
ting
nal
the
Net
ple
ling
as
to
by
Ta
ble of conte
1.
Scope of
- deliver
- Option
2.
Installati
5.
815 Rob
Titrando
Conduct
Bottle ho
5.
881 Com
Dosino h
3
Cable co
Tubing c
5.
External
Installati
Overvie
5
Miscella
5.
Membra
5.
Stirrer ....
Length o
ts
delivery: .......
d with TitrIC
l accessories
n ..................
tic USB Sam
2.905.0010) .
meter (2.856
der for Dosin
pact IC pro –
lder (6.2057.
nections ......
nnections .....
ell ................
n of the 50 m
of all the tub
eous .............
e Pumps of t
.....................
the aspiratio
.....................
ro I package
: ....................
.....................
ple Processo
.....................
.0010) ...........
s (6.2061.01
Anion – MCS
210) .............
.....................
.....................
.....................
L Dosing Uni
ing connectio
.....................
e 815 ..........
.....................
n tips in the e
.....................
....................
.....................
.....................
XL (1T/2P) ..
.....................
.....................
0) .................
(2.881.0030)
.....................
.....................
.....................
.....................
....................
s .................
.....................
.....................
.....................
ternal cell ....
.... 2
.... 2
.... 3
.... 4
.... 4
.... 4
.... 4
.... 4
... 4
.... 4
.... 4
.... 5
.... 5
.... 5
.... 6
.... 6
.... 6
.... 6
.... 7
Fig
.: TitrIC pro I S
stem
Electrod
6
Software
6.
Installati
6.
Configur
.1 Devices .
.2 Solution .
.3 Swing H
.4 Lift positi
.5 Needle ri
.6 Methods
Configur
Devices .
Solution .
Electrod
s ...................
.....................
n of the soft
tion of MagI
.....................
.....................
ad configura
ns ................
nse position ..
.....................
tion of tiamo
.....................
.....................
s ...................
.....................
.....................
are ...............
Net .............
.....................
.....................
ion ................
.....................
.....................
.....................
..................
.....................
.....................
.....................
.....................
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Page 1
.... 7
.... 7
.... 7
.... 7
.... 7
.... 7
.... 7
.... 8
.... 8
.... 8
.... 8
.... 8
.... 8
.... 9
f 14
Application Bulletin 353
Installation Instructions of TitrIC pro I
6.7 Methods .................................................................... 9
6.8 Setup of RS232 communication between MagIC Net
and tiamo
TM
.............................................................. 9
7 Complete Analysis with TitrIC ................................. 10
8 TitrIC pro – Combo Kit Dilution ............................... 11
8.1 Delivery package .................................................... 11
8.2 Installation .............................................................. 11
8.3 Dosino .................................................................... 11
8.4 Transfer Tubing ...................................................... 11
8.5 External Dilution Vessel .......................................... 11
8.6 Analysis .................................................................. 11
9 TitrIC pro – Combo Kit Partial Loop ........................ 13
9.1 Delivery package .................................................... 13
9.2 Installation .............................................................. 13
9.3 Rinsing station ........................................................ 13
9.4 MiPT Dosino ........................................................... 13
9.5 Analysis .................................................................. 13
1.
1. Scope of delivery:
- delivered with TitrIC pro I package:
No. Article no. Article designation
IC
1 2.881.0030 881 Compact IC pro - Anion
1 2.850.9010 IC Conductivity Detector
Sample processor
1 2.815.0020 815 Robotic USB Sample
Processor XL (1T/2P)
1 2.786.0040 Swing Head
1 6.1462.040 Robotic Arm with transfer head for
786 Swing Head, right swinging
1 6.2833.020 Needle holder 1/8 in. With tubing
connection M6
1 6.1835.050 PEEK sample aspiration tube (1.58
mm ID)
1 6.2629.000 Screw nut to needle holder IC
Conductometry
1 2.856.0010 856 Conductivity Module
1 6.0915.100 Five-ring conductivity measuring
cell, c = 0.7 cm-1, with Pt 1000
1 6.2151.000 Cable USB A - mini-DIN 8P (R)
1 6.2763.000 Flow through cell for 60915100
p and m value titration (pH measurment)
1 2.905.0010 905 Titrando
1 6.0277.300 iAquatrode plus with Pt 1000
1 6.2151.000 Cable USB A – mini-DIN 8P
1 6.2307.230 Buffer solutions pH 4, 7 and 9
1 6.2325.000 Phit kit
Ca and Mg titration
1 6.0510.100 Combined polymermembrane
electrode Ca
1 6.2104.020 Electrode cable / 1m / F
1 6.2327.000 Electrolyte solution c(NH4NO3) =1
mol/L
Liquid Handling
4 2.800.0010 800 Dosino
1 6.3032.210 807 Dosing Unit, glass 10 mL
2 6.3032.220 807 Dosing Unit, glass, 20 mL
1 6.3032.250 807 Dosing Unit, glass, 50 mL
1 6.2057.210 Holder Dosino for IC Instruments
1 6.2061.010 Bottle holder for Dosinos
3 6.1608.030 Glass bottle GL45 1L (round)
1 6.1808.280 Adapter Dosino Port 4 / M6
Page 2 of 14
Application Bulletin 353
Installation Instructions of TitrIC pro I
1 6.1618.020 Thread adapter S 40 to GL45
2 6.2744.080 Coupling M6-UNF 10/32 (Dosing
Unit – IC screw)
1 6.2744.070 Pressure screw made of PEEK,
short, 5x
1 6.1808.010 Coupling piece 2 x M6 outer threads
1 6.1808.060 T Connector M6
Connection tubings
3 6.1805.060 Connection tubing FEP, L = 60 cm,
2 x M6 thread
2 6.1805.110 Connection tubing FEP, L = 80 cm,
2 x M6 thread
1 6.1805.030 Connection tubing FEP, L = 150 cm,
2 x M6 thread
External cell
1 2.802.0020 802 Rod Stirrer
1 6.2001.070 Stand support for 804
1 6.1414.060 Titration vessel lid micro ECO
1 6.1415.250 Titration vessel / 50-150 mL
5 6.2730.030 Stopper with nipple and O-ring
1 6.2730.080 Screw nipple M16/NS14
1 6.2730.020 Septum stopper
3 6.2730.060 Screw nipple for electrodes
1 6.1543.170 Aspiration tip M8
1 6.2709.090 Stopper (12 mm)
1 6.1543.210 3-way stopper with antidiffusion
valve
Software
1 6.6056.231 Tiamo 2.3 light CD: 1 Licence
1 6.6059.232 MagIC Net 2.3 Professional CD: 1
Licence
RS232 Communcation MagIC - Tiamo
1 6.2134.040 Connecting cable RS-232 to IMP-
PC (DBp)
2 6.2148.050 USB/RS-232 Converter for 900
Touch Control / Ti-Touch
1 6.2301.060 Conductivity standard (12.88 mS)
1 6.2307.100
Buffer solutions 500 mL, pH 4 / 7 / 9
/110/120
1 6.2307.230 Buffer solutions 3 x 10 x 30mL of pH
4 / 7 / 9
1 6.2065.000 Stacking frame for 846 Dosing
Interface, 856 Conductivity
Module,867 pH Module
1 6.2041.800 Sample rack 100* 75 ml
1 6.2041.810 Sample rack 34* 150 ml
1 6.2041.820 Sample rack 28* 250 ml
1 6.2041.840 Sample rack 59* 120 ml
1 6.1432.210 Sample beaker 75 mL made of
glass (for 6.2041.800)
1 6.1432.320 Sample beaker 250 mL made of
glass (for 6.2041.820)
1 6.1453.250 Sample beaker 250 mL made of
polypropylene (for 6.2041.820)
1 6.1459.300 Sample beaker 120 mL made of
polypropylene (250 pieces) (for
6.2041.840)
- Optional accessories:
1 6.2041.xxx Sample rack made of PVC
1 6.1432.xxx Sample beaker
1 6.1030.xxx Anion column Metrosep A Supp 15
1 6.1030.xxx Guard column Metrosep A Supp 15
1 6.1050.xxx Cation column Metrosep C 4
1 6.1050.xxx Guard column Metrosep C 4
1 6.2324.000 Conductivity standard (100 µS/cm)
Page 3 of 14
Application Bulletin 353
Installation Instructions of TitrIC pro I
2. Installation
The following is a detailed description of the TitrIC pro I
installation.
We strongly recommend that the individual steps are carried
out in the order given below!
5.1 815 Robotic USB Sample Processor XL (1T/2P)
The sample processor is placed at the side at which it is
most easily accessible. Please note that the following
procedure refers exclusively to the version in which the
sample processor is located at the left-hand side of the IC
system.
On the left-hand side of the 815 Robotic USB Sample
Processor XL, attach the stand support (6.2001.070) for
the external titration vessel.
Mount the Swing Head (2.786.0040) onto the 815 (see
installation instructions).
Do not screw the robotic arm (6.1462.040) onto the
Swing Head!
The Sample Rack supplied is screwed onto the 815.
In the vicinity of the 815 the two canisters (standard
equipment of 815) are placed on the floor: One 10 L
canister is used as a waste container, the second one
as a reservoir for deionized (DI) water used for rinsing
the external cell.
From the smaller opening of the canisters containing DI
water, an M8 PTFE tubing connection of suitable length
is led to the connection box made of white plastic of
membrane pump 1 / tower 1 and connected. For further
information consult the Installation Instructions of the
815 Robotic USB Sample Processor XL.
From the front opening of the waste canister an M8
PTFE tubing connection of suitable length is led directly
to membrane pump 2 / tower 1 (black plastic) and
connected. For further information consult the
Installation Instructions of the 815 Robotic USB Sample
Processor XL.
A more detailed description is given in the instructions for
use of the 815 Robotic USB Sample Processor XL.
5.2 Titrando (2.905.0010)
Directly to the right of the 815 Robotic USB Sample
Processor, place the Titrando with a bottle of titration
solution (0.1 mol/L HCl, will be connected to the 20 mL
Dosing Unit and 800 Dosino).
5.3 Conductometer (2.856.0010)
The 856 Conductometer is placed directly at the left of the
Titrando. For detailed information about the usage check the
Instructions of Use of the 856.
Before measurement it is recommended to carry out the
calibration of the cell constant in the flow through cell of this
setup. For further information consult the Installation
Instructions of the 856 Conductometer.
5.4 Bottle holder for Dosinos (6.2061.010)
The bottle holder for Dosinos is placed onto the 856
Conductometer. This bottle holder is used for the two
solutions for the Calcium and Magnesium Titration. Solution
1 is 0.2 mol/L TRIS with 0.1 mol/L Acetylacetone. Solution 2
is 0.05 mol/L Na
EDTA
2
5.5 881 Compact IC pro – Anion – MCS (2.881.0030)
Place the 881 Compact IC pro – Anion – MCS (2.881.0030)
to the right of the Titrando. The IC instrument can already
be installed. Please consult the Instructions for Use for the
Compact IC pro instruments.
5.6 Dosino holder (6.2057.210)
The Dosino holder (6.2057.210) is placed on the left top
side of the 881 Compact IC pro – Anion – MCS; the 50 mL
(6.3032.250) Dosing Unit is screwed onto this holder at a
later stage.
3 Cable connections
First all the power cables are connected to the instruments.
Both the instruments and the PC remain switched off.
Controller cable USB (6.2151.000) from 856
Conductometer to USB 1 of the 815 Sample
Processor.
USB cable (6.2151.020) from the 881 Compact IC
pro to PC, do not connect!
Controller cable USB (6.2151.000) from PC to 815
Controller, do not connect!
Connect the MSB cable from Dosino 800, 50 mL
(transfer to external titration cell and to the IC
injection valves) to Anion 881 MSB 1.
Connect the MSB cable from Dosino 800, 20 mL
(0.1 mol/L HCl) to 905 MSB 1.
Controller cable USB (6.2151.000) from 905 to
USB 2 of the 815 Sample Processor.
Connect the MSB cable from Dosino 800, 10 mL
(0.05 mol/L Na2EDTA) to 905 MSB 2.
Connect the MSB cable from Dosino 800, 20 mL
(0.2 mol/L TRIS, 0.1mol/L acetylacetone) to 905
MSB 3.
Page 4 of 14
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Tubing co
5.1
External c
Th
numbers gi
drawing bel
In
he next step
ponents a
(6.
1414.060):
Th
small 6.27
screwed loo
in
osition when
eptum stop
6.2730.08
ning 9 and
nings 4, 8 a
titration ve
(6.
001.070) us
ght with the
nd support i
ew.
nections
ll
en here ( ,
w.
the external
e inserted
0.030 stopp
ely into ope
the buret tips
er (6.2730.0
screw nippl
the 6.2730
d 6.
ssel lid is a
ing opening
lamping ring
mounted on
…) and “ope
cell is prepar
in the titr
rs (with the
ings 1, 2, 3,
, etc. are ins
0) is put int
e M16/NS14
.060 screw
tached to t
10. It is fixe
nd the horiz
the 815 with
ing 1”,… ref
d. The follo
tion vessel
lack rubber r
and 7 and fi
rted.
the openin
is screwed
ipple M16
e stand sup
at the requ
ntal brace of
the socket h
r to
ing
lid
ing)
xed
6.
into
into
ort
ired
the
ead
pplication Bulle
stallation Instr
The rins
is insert
the distr
1 / towe
connecti
The 3-w
(6.1543.
20 mL
with the
cm, sup
Further
connect
(6.1805.
Port 1 o
Na2EDT
(6.1805.
The PT
inserted
distribut
tower 1
connecti
The co
(6.0510.
After th
screwed
(2.802.0
the tow
USB Sa
in 353
ctions of TitrIC
ng nozzle (6.
d into openin
butor (6.1808
1 of the 815
on (6.1805.0
y stopper wi
10) is put int
osing Unit (0.
FEP-tubing c
lied with the
he port 1 of t
d with an FE
110, 80 cm) t
the 10 mL D
) is connect
110, 80 cm) t
E aspiration
in opening 7,
r (6.1808.17
f the 815 wit
on (6.1805.51
bined polym
100) is enter
screw nipple
into opening
20) is pushe
r 1 stirrer con
ple Process
pro I
740.020, su
g 5, which is
.170) to the
with the FEP
0, supplied
h antidiffusio
o opening 6.
1 mol/L HCl)
nnection (6.
807) to the 3e 50 mL Dos
P-tubing con
the 3-way s
sing Unit (0.
d with an FE
the third po
ip (6.1543.17
which is con
) to the mem
the M8-PTF
0, 60 cm).
rmembrane
d here.
(6.2730.080)
9, the 802 R
d through it a
nection of th
or.
plied with 81
onnected vi
embrane pu
tubing
ith 815).
valve
ort 1 of the
s connected
805.100, 40
ay stopper.
ing Unit is
ection
opper. Also t
5 mol/L
-tubing
ition.
, M8) is
ected via the
brane pump
E-tubing
lectrode Ca
has been
d Stirrer
d connected
815 Robotic
)
p
e
/
to
Fig
.: Numbers an
414.060)
(6.
The rins
is insert
the distri
1 / towe
connecti
Port 1 o
0.1 mol/
tubing (
(6.1543.
tip is ins
The rins
is insert
the distri
1 / towe
connecti
This is
connections o
ng nozzle (6.
d into openin
butor (6.1808
1 of the 815
on (6.1805.0
the 20 mL D
Acetylaceto
.1805.110, 8
00, comes
rted into ope
ng nozzle (6.
d into openin
butor (6.1808
1 of the 815
on (6.1805.0
here the iAq
the titration v
740.020, su
g 1, which is
.170) to the
ith the FEP-
0, supplied
sing Unit (0.
e) is connec
cm) and a ti
ith the burett
ning 2.
740.020, su
g 3, which is
.170) to the
ith the FEP-
0, supplied
atrode is ins
ssel lid
plied with 81
onnected via
embrane pu
ubing
ith 815).
mol/L TRIS
ed with a FE
ration tip
). This titrati
plied with 81
onnected via
embrane pu
ubing
ith 815).
rted.
4.
Installatio
of the 50 m
Dosing Uni
)
6.562
.000
p
Luer: Po
6
.1805.030
t 4
P
rt 3
6.2744.
70
-
n
Port 1
M6: Port
6.27
4.080
6.1803.0
20
)
6.1805.
110
p
Fi
.: Connections
n the bottoms
of the 50 mL D
osing Unit
Page 5
f 14
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