Hanna Instruments HI 222 User Manual

Instruction Manual
HI 222
pH/mV/ºC
Bench Meter
with Calibration Check
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Manufacturer since 1978
www.hannainst.com
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Dear Customer, Thank you for choosing a Hanna Instruments product. Please read this instruction manual carefully before using the instrument. This manual will provide you with the necessary information for correct use of
the instrument, as well as a precise idea of its versatility. For additional technical information, do not hesitate to e-mail us at
tech@hannainst.com or refer to back cover for our worldwide contact list. This instrument is in compliance with the directives.
WARRANTY
HI 222 is guaranteed for two years against defects in workmanship and materials when used for their intended purpose and maintained according to instructions. Electrodes and probes are guaranteed for a period of six months. This warranty is limited to repair or replacement free of charge.
Damage due to accidents, misuse, tampering or lack of prescribed mainte­nance are not covered.
If service is required, contact the dealer from whom you purchased the instrument. If under warranty, report the model number, date of purchase, serial number and the nature of the problem. If the repair is not covered by the warranty, you will be notified of the charges incurred. If the instrument is to be returned to Hanna Instruments, first obtain a Returned Goods Authori­zation number from the Technical Service department and then send it with shipping costs prepaid. When shipping any instrument, make sure it is properly packaged for complete protection.
TABLE OF CONTENTS
PRELIMINARY EXAMINATION ........................................................................................... 3
GENERAL DESCRIPTION.................................................................................................... 3
FUNCTIONAL DESCRIPTION ............................................................................................. 4
HI 222 SPECIFICATIONS .................................................................................................. 5
OPERATIONAL GUIDE ....................................................................................................... 6
pH CALIBRATION ................................................................................................................ 8
ENHANCED CALIBRATION MESSAGES ....................................................................11
ELECTRODE CONDITION AND RESPONSE TIME ............................................................13
GOOD LABORATORY PRACTICE (GLP) .........................................................................14
LOGGING .........................................................................................................................17
SETUP ............................................................................................................................ 21
TEMPERATURE CALIBRATION (for technical personnel only) .............................. 25
mV CALIBRATION (for technical personnel only) .................................................. 27
PC INTERFACE ............................................................................................................... 28
pH VALUES AT DIFFERENT TEMPERATURES .................................................................... 30
ELECTRODE CONDITIONING & MAINTENANCE .............................................................. 31
TROUBLESHOOTING GUIDE .......................................................................................... 33
TEMPERATURE CORRELATION FOR pH SENSITIVE GLASS ............................................35
ACCESSORIES ................................................................................................................ 36
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PRELIMINARY EXAMINATION
Remove the instrument from the packing material and examine it carefully to make sure that no damage has occurred during shipping. If there is any damage, notify your Dealer or the nearest Hanna Customer Service Center.
Each instrument is supplied complete with:
HI 1048P Glass-body pH Electrode with 1 m (3.3 “) cable
HI 7669/2W Temperature Probe
HI 76404 Electrode Holder
HI 50003 & HI 70007 pH Calibration Solutions (20 mL each)
HI 700635 Cleaning Solution for wine deposits (2x20 mL)
HI 700636 Cleaning Solution for wine stains (2x20 mL)
HI 7082 Electrode Refilling Solution (30 mL) & 5 mL Syringe
• 12 VDC Power Adapter
• Instruction Manual
Note: Save all packing material until you are sure that the instrument
functions correctly. All defective items must be returned in the original packing with the supplied accessories.
GENERAL DESCRIPTION
HI 222 is a logging microprocessor-based pH/ORP/temperature bench meter with Calibration Check.
Calibration Check performs a set of diagnostic tests during calibration using the history of electrode slope and offset to detect problems that can cause loss of accuracy.
Calibration Check Features are listed below:
• Enhanced Calibration Messages
During calibration the user is warned if one or more parameters are not suitable to perform an accurate calibration.
• Electrode Condition on LCD Display
Determined from the electrode offset and slope.
• Electrode response time on LCD Display
Determined from electrode performance during calibration.
• Calibration Alarm Time Out
Can be programmed from 1 to 7 days or can be disabled.
Other features include 1 or 2-point pH calibration with seven memorized buffers (1.68, 3.00, 6.86, 7.01, 9.18, 10.01 and 12.45 pH), logging up to 100 samples, last calibration date and data (GLP), pH reading with manual or automatic temperature compensation and PC interface software.
The pH 3.00 memorized buffer makes the instrument useful for wine pH measurements.
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Front Panel
1
FUNCTIONAL DESCRIPTION
POOR GOOD
Electrode Response
SLOW
FAST
Primary LCD
pH
Secondary LCD
ATC
C
Electrode Condition
10
2
Functions pH Calibration
Select pH/ORP
3
5
7
CAL
4
6
LOG
RANGE
CFM
LOG
Store Log Information
GLP
RCL
Recall Log Information
Set Instrument Parameters
SET/CLR
Clear Log/Cal Information
CC
CFM/GLP
Show GLP Information
RCL
CAL
Start Calibration
st
/
Select 1 Buffer
st
CFM
Confirm 1 Buffer
nd
/
Select 2 Buffer
nd
CFM
Confirm 2 Buffer
HI 222 Calibration Check Microprocessor pH Meter
RANGE
SET CLR
8
9
Rear Panel
POWER
12VDC
11
1) Liquid Crystal Display (LCD)
2) CFM / GLP key, to confirm different values or to display Good Laboratory Practice information
3) CAL key, to enter and exit/escape the calibration mode
4) / ºC key, to manually decrease temperature, or other parameters
5) / ºC key, to manually increase temperature, or other parameters
6) RCL key, to enter or exit the recall mode
7) LOG key, to store measured data
8) RANGE key, to select the measurement range or switch the focused data
9) SET / CLR key, to enter the Setup mode or clear calibration history
10) ON / OFF switch
11) Power supply socket
12) BNC connector for electrode
13) Pin input socket
14) Temperature probe socket
15) RS232 serial communication port
Note: Pin input socket can not be used as reference input for separate
electrode reference.
INPUT TEMP
13
12
RS232
14
15
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HI222 SPECIFICATIONS
Range -2.00 to 16.00 pH
±699.9 mV / ±2000 mV
-20.0 to 120.0 °C
Resolution 0.01 pH
0.1 mV / 1 mV
0.1 °C
Accuracy ±0.01 pH (@20°C/68°F) ±0.2 mV / ±1 mV
±0.5 °C
pH Calibration 1 or 2-point, automatic,
with 7 memorized pH buffer values (1.68, 3.00, 6.86, 7.01, 9.18, 10.01, 12.45)
Temperature Compensation Automatic or manual, from -20 to 120°C pH Electrode HI 1048P glass-body, single junction,
(included) refillable, BNC + pin Temperature probe HI 7669/2W stainless steel probe
(included) Input impedance 10 Computer Interface RS232, optoisolated Logging 100 points Environment 0 to 50°C (32 to 122°F)
Power supply 12 VDC adapter (included) Dimensions 240x182x74 mm (9.4x7.1x2.9") Weight 1.1 kg (2.5 lb.);
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max. 95% RH non-condensing
kit with holder: 2.5 kg (5.5 lb.)
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OPERATIONAL GUIDE
POWER CONNECTION
Plug the 12 VDC adapter into the power supply socket. Note: These instruments use non volatile memory to retain the pH, mV,
temperature calibrations and all other settings, even when unplugged.
Note: Make sure a fuse protects the mains line.
ELECTRODE AND PROBE CONNECTIONS
For HANNA P Type pH or ORP electrodes (with internal reference) connect the electrode’s BNC to the socket on the back of the instrument and the pin to the appropriate socket.
Note: Electrode condition and response information is displayed on the bar
graph gauges. During the day the calibration is performed only if HANNA P type (PIN) electrodes are used.
If the electrode is not recognized as a HANNA P type electrode, the bar graph gauges will blink (25 seconds OFF, 4 seconds ON, full bar graph).
For temperature measurement and automatic temperature compensation connect the temperature probe to the appropriate socket.
INSTRUMENT START-UP
• Turn the instrument on by pressing the ON/OFF switch.
• All LCD tags are displayed and a beep is sounded
while the instrument performs a self test.
CFM
CAL
DUE
POOR GOOD
CHECK
WRONG
CONTAMINATED
ELECTRODE
CLEAN
SLOW
BUFFER BUFFER
Unscrew electrode refilling cap
FAST
CLEAR CAL if new electrode
mV
pH
SETUP
LOG
BUFFER 12
ATC
MTC
RCL
DEL
• The “Unscrew electrode refilling cap” message reminds the user to loosen
or remove the electrode refilling cap to improve the electrode’s response time.
• The instrument automatically defaults to pH measurement mode unless a
HANNA P type ORP electrode is detected.
pH MEASUREMENT
Make sure the instrument has been calibrated before taking pH measurements.
• Submerge the tip (4 cm/1½”) of a properly condi-
tioned electrode (see page 31) and the tempera­ture probe into the sample to be tested. Allow time for the electrode to stabilize.
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• The pH is displayed on the primary LCD and the temperature on the
secondary LCD.
ATC
POOR GOOD
SLOW
FAST
pH
• The pH reading is out of range, the closest full-scale value will be displayed
blinking on the primary LCD.
• It is also possible to view the mV reading by pressing the RANGE key.
POOR GOOD
SLOW
FAST
mV
If measurements are taken successively in different samples, it is recommended to rinse the electrode thoroughly with deionized water or tap water and then with some of the next sample to prevent cross-contamination.
The pH reading is affected by temperature. In order to measure the pH accurately, this temperature effect must be compensated for. To use the Automatic Temperature Compensation feature, connect and submerge the HI 7669/2W temperature probe into
ATC
C
the sample as close to the electrode as possible and wait for a few minutes.
If the temperature of the sample is known, manual compensation can be performed by disconnecting the temperature probe.
The display will then show the default temperature of 25 °C
MTC
C
or the last recorded temperature reading with the “°C” symbol blinking.
The temperature can now be adjusted with the ARROW keys (from -20.0 ºC to 120.0 ºC).
ORP MEASUREMENTS
An optional ORP electrode must be used to perform ORP measurements (see Accessories).
Oxidation-Reduction Potential (REDOX) measurements provide the quantifica­tion of the oxidizing or reducing power of the tested sample.
To correctly perform a REDOX measurement, the surface of the ORP electrode must be clean and smooth. Pretreatment solutions are available to condition the electrode and speed up the response time.
C
7
• The instrument automatically defaults to the ORP
measurement mode if HANNA P type ORP electrode is detected.
• Submerge the ORP electrode tip (4 cm/1½”) into the
sample. Allow a few minutes for the reading to sta­bilize.
• The instrument displays the mV reading on the primary LCD.
• If the reading is out of range, the closest full-scale value will be displayed
blinking on the primary LCD.
TAKING TEMPERATURE MEASUREMENTS
Connect the HI 7669/2W temperature probe and turn the instrument on. Dip the temperature probe into the sample and allow the reading on the secondary LCD to stabilize.
pH CALIBRATION
Calibrate the instrument frequently, especially if high accuracy is required. For best results and constant display of electrode condition and electrode response on the bar graph gauges we suggest at least a daily calibration.
The instrument should be re-calibrated:
• Whenever the pH electrode is replaced.
• At least once a day.
• After testing aggressive chemicals.
• If high accuracy is required.
• If CAL DUE message is displayed during measurement.
Every time you calibrate the instrument use fresh buffers and perform an electrode cleaning procedure (see page 31).
PREPARATION
Pour small quantities of the buffer solutions into clean beakers. If possible, use plastic or glass beakers to minimize any EMC interferences.
For accurate calibration and to minimize cross-contamination, use two beakers for each buffer solution. One for rinsing the electrode and one for calibration.
8
PROCEDURE
The user has a choice of 7 memorized buffers: pH 1.68, 3.00, 6.86, 7.01,
9.18, 10.01 and 12.45.
It is always recommended to perform a two-point calibration. The instrument however allows a one-point calibration, as described on page 10.
TWO-POINT CALIBRATION
For most applications it is recommended that pH 7.01 or 6.86 buffers to be used as the first calibration point and pH 3.00 (for acidic samples) or pH
9.18/10.01 (for alkaline samples) as the second calibration point.
Note: The pH 12.45 buffer is not for general measurement; use only if the
sample is very alkaline to avoid sodium error.
• Immerse the pH electrode and the temperature probe approximately 4 cm (1½”) into the buffer solution of your choice (pH 1.68, 3.00,
6.86, 7.01, 9.18, 10.01 or 12.45) and stir gently. The temperature probe should be close to the pH electrode.
• Press the CAL key. “CAL” and “pH” tags will be on, and the “CLEAR CAL if new electrode” tag will blink.
CAL
CLEAR CAL if new electrode
pH
• Press the CLR key if you are using a new electrode or want to clear the calibration history. The instrument will display the “donE” message for a few seconds.
It is very important to clear the calibration history when a new electrode is used because all error and warning messages that appear during calibration depend on the calibration history.
• Press the CAL key or wait a few seconds to continue.
Note: The above behavior appears only if calibration history is not empty.
• The instrument will display the measured pH on the primary LCD, and the most common buffer (“7.01”) on the secondary LCD, along with “CAL”, “pH” and “BUFFER 1” tags.
• The “ ” tag will blink until the reading has stabilized.
CAL
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pH
ATC
BUFFER 1
• Press the ARROW keys to select a different buffer value, if necessary.
• When the reading is stable and close to the selected buffer, the “CFM” tag will blink and if enabled, an audible signal will sound.
CFM
CAL
pH
ATC
BUFFER 1
• Press the CFM key to confirm calibration. The instrument will ask for a second calibration buffer and will display the measured pH on the first LCD and the second calibration buffer on the second LCD.
CAL
pH
ATC
BUFFER 2
• If necessary, press the ARROW keys to select a different buffer value.
Note: The instrument will automatically skip the buffer used for the first point.
It also skips 6.86 if 7.01 was used, and vice versa. Likewise, it will skip
9.18 if 10.01 has been used, and vice versa.
• Rinse the electrode in one of the beakers of the second buffer solution, then immerse the pH electrode and the temperature probe approximately 4 cm (1½”) into the second buffer solution and stir gently. The temperature probe should be close to the pH electrode.
• The “ ” indication will blink on LCD until the reading has stabilized.
• When the reading is stable and close to the selected buffer, the “CFM” tag will blink.
• Press the CFM key to confirm the calibration.
The instrument will return to normal operational mode and will memorize the calibration data.
Note: Press the RANGE key any time during calibration to display the
temperature reading.
CAL
ATC
pH
ONE-POINT CALIBRATION
• Proceed as described in “two-point calibration” section.
• Press the CAL key after the first calibration point has been confirmed.
The instrument will return to normal operational mode and will memorize the one-point calibration data.
10
ENHANCED CALIBRATION MESSAGES
The stored calibration history to used issue error and warning messages during calibration to help ensure the highest accuracy.
As electrode aging is normally a slow process, substantial changes from previous calibrations are likely due to a temporary problem with the electrode or buffers. Calibrating under these conditions will give measurement errors.
ERROR MESSAGES
Error messages appear if one or all of the calibration parameters are out of accepted windows. When these messages are displayed calibration cannot be confirmed.
WRONG BUFFER
This message appears when the difference between the pH reading and the value of the selected buffer is too big. If this error message is displayed, check if you have selected the proper calibration buffer.
CAL
WRONG
BUFFER
CLEAN ELECTRODE
This error message indicates a bad electrode condition (offset out of accepted window, or slope under the accepted lower limit).
Clean the electrode according to the Cleaning Procedure on page 31 to improve its condition and repeat the calibration. This ensures the removal of film, dirt or deposits on the glass bulb and reference junction.
pH
ATC
BUFFER 1
CAL
ELECTRODECLEAN
pH
ATC
BUFFER 1
CHECK ELECTRODE alternating with CHECK BUFFER This error message appears when electrode slope exceeds the highest accepted
slope limit. You should check your electrode and use fresh buffer.
CHECK
CAL
ELECTRODE
BUFFER
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pH
ATC
BUFFER 1
ELECTRODE
This message appears if the cleaning procedure performed as a result of the above two messages is found by the instrument to be unsuccessful. Replace the electrode.
CAL
ELECTRODE
pH
ATC
BUFFER 1
WRONG BUFFER TEMPERATURE
This message appears if the temperature of the buffer is outside the defined buffer temperature range.
CAL
WRONG
BUFFER
ATC
pH
WARNING MESSAGES
During calibration, the Calibration Check feature analyzes the electrode calibration history and warns the user when problems have been detected. It is possible to over ride the warning messages and confirm the calibration but it is not recommended.
CLEAR CAL IF NEW ELECTRODE
This warning is displayed any time the new calibration parameters are better than the previous parameters. You can clear the calibration history by press­ing the CLR key, or continue by pressing the CAL key.
CAL
CLEAR CAL if new electrode
pH
ATC
BUFFER 1
CLEAN ELECTRODE
This warning appears during Calibration Check for the second calibration buffer when the instrument has detected a small variation of offset or both offset and slope parameters. This variation may result from dirt on the electrode. Refer to the electrode cleaning procedure. This ensures the removal of film, dirt or deposits on the glass bulb and reference junction.
CFM
CAL
ELECTRODECLEAN
pH
ATC
BUFFER 1
CLEAN ELECTRODE alternating with CHECK BUFFER This warning appears during Calibration Check in the first calibration buffer as
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a result of unacceptable offset variation or in the second calibration buffer as a result of unacceptable slope variation. This variation may result from dirt on the electrode or contaminated buffer. Refer to the electrode cleaning procedure or use fresh buffer.
CFM
CHECK
CAL
BUFFER
ELECTRODECLEAN
pH
ATC
BUFFER 1
CONTAMINATED BUFFER
This warning message appears in order to alert that the buffer could be contaminated. Refresh your buffer and continue the calibration procedure.
CFM
CAL
CONTAMINATED
BUFFER
pH
ATC
BUFFER 1
ELECTRODE CONDITION &
ELECTRODE RESPONSE TIME
When using HI 1048P electrode, HI 222 will assess electrode condition and response time during each calibration and will display the calibration status for the rest of the day.
POOR GOOD
SLOW
FAST
The digital gauge for electrode condition is a representation of the offset and slope performance of the electrode. The response gauge is a function of the stabilization time between the first and second calibration buffers. These gauges reflect electrode performance and should be expected to slowly de­crease over the life of the electrode. The condition and response gauges show the electrode’s condition at the time of calibration only and are displayed for the rest of the day the calibration is performed. For a continuous display of electrode condition at the time of calibration, daily calibration is necessary. The condition and response are also visible when viewing GLP data. If the instrument is not calibrated, it has been calibrated only at one point, the two-point calibration was not performed using pH 7.01 and pH 3.00 buffers, or if the calibration history was deleted, the electrode condition and response gauges will be empty.
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SLOW
FAST
POOR GOOD
Also, when the instrument cannot evaluate the electrode response or pH 1.68 or pH 12.45 buffer were used as calibration buffer, the response gauge will be empty. If the electrode is in a very poor condition the first condition segment will blink. If electrode response is very slow the first response segment will blink.
GOOD LABORATORY PRACTICE (GLP)
GLP is a set of functions that allows the storage and retrieval of data regarding the maintenance and status of the electrode.
All data regarding the last calibration (one or two points) is stored for the user to review when necessary. This data includes the following: calibration time stamp, offset (in mV), slope (in mV/pH), electrode condition and response gauges, calibration buffers and the amount of time until a new calibration is required.
CALIBRATION ALARM TIME-OUT
HI 222 allows the user to set the number of days before the next required pH calibration. This value can be set from 1 to 7 days. The default value is OFF (disabled).
The instrument checks if the time-out time has expired. If the time has elapsed, the CAL DUE will blink as a reminder.
Note: If the instrument was not calibrated, or if the calibration history was
deleted, the CAL DUE message will be displayed even if this feature is disabled in the SETUP menu.
If the instrument was calibrated using an electrode with pin and the electrode is changed with an electrode without pin or vice-versa CAL DUE will blink. This feature helps ensure use of a calibrated instru­ment.
LAST CALIBRATION DATA
Last calibration data is stored automatically after a successful calibration. To view the pH calibration data, press the GLP key when the instrument is in
pH measuring mode. The instrument will display the time of the last calibration. Press the ARROW keys to view the following logged calibration parameters
(pressing the / ºC key):
The time (hh:mm).
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The date (mm.dd).
The year (yyyy).
The pH calibration offset.
The pH calibration slope in mV/pH normalized to 25 °C.
Note: If you calibrate using electrodes with pin the electrode condition and re-
sponse gauges appear while the offset and slope are displayed.
The first pH calibration buffer along with any warning messages issued while calibrating at this point.
The second pH calibration buffer along with any warning messages issued while calibrating at this point.
CAL
pH
BUFFER 2
RCL
Note: If the last calibration was a single point calibration, the message for
the second buffer will be: “no bUFF”.
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The calibration Alarm Time-Out status:
if disabled
or the number of days until the calibration alarm will be displayed
or if expired (7 days ago)
Press the GLP key at any time and the instrument will return to measuring mode. If calibration has not been performed, the instrument displays “no CAL” blinking.
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LOGGING
Up to 100 LOG samples can be stored in memory.
LOGGING THE CURRENT DATA
To store the current reading into memory press the LOG key while in measur­ing mode.
The instrument will display the current date (mm.dd) on the primary LCD, the record number on the secondary LCD and the “LOG” tag will blink for a few seconds (see example below: record No. 27 dated July 14):
If there are less than 6 memory locations remaining, the record number and the “Lo” message will blink to alert the user.
LOG
If the log space is full, the “FULL LOC” message will be displayed and no more data will be saved.
When the LOG key is pressed, a complete set of information is stored. The parameters of a record are date, time, pH, mV, temperature, and pH calibration data. If a HANNA P Type ORP electrode is used pH information is not stored.
VIEW LOGGED DATA
Press the RCL key to retrieve the information stored while in measuring mode. If no data were logged the instrument displays:
17
Otherwise the instrument will display log data on the primary LCD and the last stored record number on the secondary LCD, along with the “LOG” and the “RCL” tags.
Note: The “LOG” and “RCL” tags remain on LCD while instrument is in the
viewing logged data mode.
LOGpHRCL
Press the RCL key at any time to return to measuring mode. Press the ARROW keys to scroll between same parameter for different records,
while pH, mV, temperature, “Hour”, “Year”, “oFFS”, “SLoP” or “dEL record” is displayed:
pH
LOG
RCL
or to scroll between different dates while “dAtE” or “dEL date” is displayed.
LOG
RCL
Press the RANGE key and the instrument will display the next logged parameter, as follows:
•The mV value on the primary LCD and the record number on the secondary
LCD.
•The temperature value on the primary LCD and the record number on the
secondary LCD.
•The time on the primary LCD and the “Hour” message on the secondary
LCD.
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•The date on the primary LCD and the “dAtE” message on the secondary
LCD.
•The year on the primary LCD and the “YEAr” message on the secondary
LCD.
•The calibration offset on the primary LCD and the “oFFS” message on the
secondary LCD.
•The calibration slope on the primary LCD and the “SLoP” message on the
secondary LCD.
Note: Before displaying the “Hour”, “Year”, “oFFS” or “SLoP” messages,
the record number is displayed for about one second. The RANGE key has no effect if “nuLL” record message is displayed on
the first LCD line.
LOG
RCL
or if “nuLL” date message is displayed.
LOG
RCL
You can skip this message by selecting an undeleted record (date) using the ARROW keys.
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•The “dEL” message on the primary LCD and the selected record or date on
the secondary LCD. The “CFM” and the ”DEL” tags will blink:
Press SET key to select the current record, the records from the selected date or all records to be deleted.
the date.
or “ALL” records.
Press the ARROW keys to change the record or the date. Press the CFM key to confirm the deleting of the selected record, all the records
for the selected date, or all the records and the instrument will display on the secondary LCD the “nuLL” message.
LOG
RCL
Note:• Pressing RANGE key the instrument skips to the pH information on
the next undeleted record.
• The instrument optimizes the usage of the memory when it returns to measurement mode after a deleting operation is performed. This will change the record numbers of logged data.
• If all the records are deleted the instrument returns to the measuring mode.
• After the LOG key is pressed or “dEL” is confirmed the instrument will display the amount of free log space for about one second (example: 25 records free).
LOG
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SETUP
Setup mode allows viewing and modification of the following parameters:
• Calibration Alarm Time Out
• Instrument ID
• Current Time (hour & minute)
• Current Date (month & day)
• Current Year
• Beep Status
• Baud Rate (serial communication)
• Command Prefix (serial communication) To enter the Setup mode press the SET/CLR key while the instrument is in
measuring mode. Press SET/CLR key to exit SETUP mode. Select a parameter with the ARROW keys. Press the CAL key to change a parameter value. The selected parameter will
start to blink. Press the RANGE key to toggle between the displayed parameters. Press the ARROW keys to increase or decrease the displayed value. Press the CFM key to save the modified value or the CAL key to cancel. Press the ARROW keys to select the next/previous parameter.
CALIBRATION ALARM TIME OUT CHANGE
Press the CAL key when the calibration time out is displayed. Calibration time out (OFF=disabled or 1 to 7 days) will begin blinking.
Press the ARROW keys to change the calibration time out value. Press the CFM key to save the modified calibration time out value or press the CAL key to cancel without saving the calibration time out.
INSTRUMENT ID PARAMETER CHANGE
Press the CAL key when the instrument ID is displayed. The instrument ID (0000 to 9999) will begin blinking.
21
Press the ARROW keys to change the instrument ID value. Press the CFM key to save the modified instrument ID value or press the CAL
key to cancel without saving the instrument ID. Note: The instrument ID is downloaded to a PC as part of a logged data set
to identify it’s origin.
CURRENT TIME SET
Press the CAL key when the current time is displayed. The hour will begin blinking.
Press the ARROW keys to change the hour. Press the RANGE key. The minutes will begin blinking. Press the ARROW keys to change the displayed value.
Press the CFM key to save the modified value or press the CAL key to cancel without saving the time.
CURRENT DATE SET
Press the CAL key when the current date is displayed. The month will begin blinking.
Press the ARROW keys to change the month.
Press the RANGE key. The day will begin blinking. Press the ARROW keys to change the displayed value.
Press the CFM key to save the modified value or press the CAL key to cancel without saving the date.
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CURRENT YEAR SET
Press the CAL key when the current year is displayed. The year will begin blinking.
Press the ARROW keys to change the year. Press the CFM key to save the modified value or press the CAL key to cancel
without saving the year.
BEEP STATUS SET
Press the CAL key when the beep status is displayed. The beep status (On or OFF) will begin to blink.
Press the ARROW keys to change the beep status (On or OFF). Press the CFM key to save the modified beep status or press the CAL key to
cancel without saving the beep status. Note: If enabled, an audible signal will follow each key press. Inactive keys
have a longer beep. A longer beep is also sounded when the limits of the range of a parameter are reached.
An audible signal will also sound when the reading becomes stable during calibration.
23
SERIAL COMMUNICATION BAUD RATE SET
Press the CAL key when the baud rate is displayed. The baud rate (600, 1200, 2400, 4800 or 9600) will begin to blink.
Press the ARROW keys to change the baud rate. Press the CFM key to save the modified baud rate or press the CAL key to
cancel without saving the baud rate.
SERIAL COMMUNICATION COMMAND PREFIX SET
Press the CAL key when the command prefix is displayed. The command prefix (0 to 47) will begin to blink.
Press the ARROW keys to change the command prefix. Press the CFM key to save the modified command prefix value or press the CAL
key to cancel without saving the command prefix. Note: See the PC Interface section on page 28 for a complete explanation. The
command prefix must be 16 if the HI 92000 PC software is used.
24
TEMPERATURE CALIBRATION
(for technical personnel only)
The instruments are factory calibrated for temperature. Hanna’s temperature probes are interchangeable and temperature calibra-
tion is not necessary when replaced. If the temperature measurements are not accurate, temperature recalibration
should be performed. For an accurate recalibration, contact your dealer or the nearest Hanna
Customer Service Center, or follow the instructions below.
• Switch off the instrument.
• Prepare a vessel containing ice and water and another one containing hot water (around 50 °C). Place insulation material around the vessels to minimize temperature changes during calibration.
• Use a ChecktempC or a calibrated thermometer with a resolution of 0.1 °C as a reference thermometer.
• Immerse the temperature probe and the ChecktempC into the vessel containing ice and water. Wait a few minutes for the probe to stabilize.
• Press the CAL and LOG keys simultaneously and then switch the instru­ment on. After a few seconds, the instrument enters the temperature calibration mode. The “CAL” tag will come on. The primary LCD will display the measured temperature or the ”- - - -” message if the measured temperature is out of range. The secondary LCD will display 0.0 °C
(First calibration point). The “ ”tag will blink until the reading has stabilized.
• Use the ARROW keys to set the reading on the secondary LCD to that of ice and water measured by ChecktempC (for example, -0.1 °C).
CAL
C
-0.1°C
• When the reading is stable and close to the selected calibration point, the “CFM” tag will blink.
• Press the CFM key to confirm the calibration or the CAL key to leave the calibration mode.
• The secondary LCD will display 50.0 °C (Second calibration point).
• Immerse the temperature probe and the ChecktempC into the second vessel.
• Allow a few minutes for the probe to stabilize.
25
• The “ ” tag will blink until the reading has stabilized.
• Use the ARROW keys to set the reading on the secondary LCD to that of the hot water bath.
• When the reading is stable and close to the selected calibration point, the “CFM” tag will blink.
CFM
CAL
C
• Press the CFM key to confirm the calibration or the CAL key to leave the calibration mode.
Note: If the measured value is not close enough to the displayed value on
secondary LCD, the “WRONG “ tag will blink. In this case, check if the value set on secondary LCD and the temperature measured with ChecktempC are close. Change the temperature probe and restart calibration if necessary.
26
mV CALIBRATION
(for technical personnel only)
All instruments are factory calibrated for mV. Hanna’s pH and ORP electrodes are interchangeable and mV calibration is
not needed when replaced. If mV measurements are not accurate, mV recalibration should be carried out. For an accurate recalibration, contact your dealer or the nearest Hanna
Customer Service Center or follow the instructions below. A two or three point calibration can be performed at 0 mV, +600 mV and
+1800 mV.
• Switch off the instrument.
• Attach a mV simulator with an accuracy of at least ±0.1 mV to the BNC connector.
• Press the RCL and CFM/GLP keys simultaneously and switch the instru­ment on. After a few seconds, the instrument enters the mV calibration mode.
• The primary LCD will show the “CAL” and “mV” tags along with mea­sured mV and the secondary LCD will display 0.0 calibration point.
• Set 0.0 mV on the simulator.
• The “ ” tag will blink on LCD until the reading has stabilized.
• When the reading is stable, the “CFM” tag will blink.
• Press the CFM key to confirm the calibration.
• The instrument will prompt for a second calibration point and will display 600 on the secondary LCD line.
• Set the simulator to +600.0 mV.
• The “ ” tag will blink on the LCD until the reading has stabilized.
• When the reading is stable, the “CFM” tag will start to blink.
• Press the CFM key to confirm the calibration.
• The instrument will prompt for a third calibration point and will display 1800 on the secondary LCD line.
• The two-point mV calibration is now complete.
• Set +1800.0 mV on the simulator.
• The “ ” tag will blink on the LCD until the reading has stabilized.
• When the reading is stable, the “CFM” tag will start to blink.
• Press the CFM key to confirm the calibration.
• The instrument will memorize the calibration and return to measuring mode.
27
Note: Press the CAL key to leave the calibration mode at any time.
If the measured value is not close to the calibration point, the “WRONG“ tag will start to blink. In this case, check if the value set on the simulator is the same as the calibration value on the instrument. Set the proper value on the simulator.
PC INTERFACE
Data transmission from the instrument to the PC can be done with HI 92000 Windows® compatible software (optional). The HI 92000 also offers graphing and on-line help.
Data can also be exported to the most popular spreadsheet programs for further analysis.
To connect your instrument to a PC, use the optional Hanna HI 920010 cable. Make sure that your instrument is switched off and plug one end into the instrument’s RS232 socket and the other end into the serial port of your PC.
Note: Cables other than HI 920010 may use a different configuration, in
which case communication between the instrument and the PC may not be possible.
If you are not using optional Hanna HI 92000 software, please see the following instructions.
The Command Prefix must be 16 when using HI 92000 software.
SENDING COMMANDS FROM PC
It is also possible to remotely control the instrument with any terminal pro­gram. Use the optional Hanna HI 920010 cable to connect the instrument to a PC, start the terminal program and set the communication options as follows: 8, N, 1, no flow control.
COMMAND TYPES
To send a command to the pH meter the scheme is:
<command prefix> <command> <CR>
where: <command prefix> is a selectable ASCII character
between 0 and 47 (default 16). <command> is the command code (3 characters).
Note: Either small or capital letters can be used.
28
SIMPLE COMMANDS
RNG Is equivalent to pressing the RANGE key CAL Is equivalent to pressing the CAL key CFM Is equivalent to pressing the CFM/GLP key UPC Is equivalent to pressing the UP arrow key DWC Is equivalent to pressing the DOWN arrow key SET Is equivalent to pressing the SET/CLR key
COMMANDS REQUIRING AN ANSWER
pH? Causes the instrument to send the pH reading (“Err 1” is sent if
out of range). If the range is set to mV, “Err 6” is received.
MV? Causes the instrument to send the mV reading (“Err 2” is sent if
out of range). If the range is set to pH, “Err 6” is received.
TM? Causes the instrument to send the temperature reading
(“Err 3” is sent if out of range). MDR Requests the instrument model name and firmware code. PAR Requests the setup parameters (instrument ID, calibration alarm
time-out, pH range, beep status). NSL Requests the number of logged samples. GLP Requests the calibration data record. LOD xxx Requests the xxxth record logged data. LOD ALL Requests all logged data.
Invalid commands will be ignored. The characters sent by the instrument are always capital letters. When the instrument receives an unknown or a cor­rupted command, it will send a character CAN (ASCII Code 24).
29
pH VALUES AT DIFFERENT
TEMPERATURES
Temperature has an effect on pH. The calibration buffer solutions are affected by temperature changes to a lesser degree than normal solutions. During calibration the instrument will automatically calibrate to the pH value corre­sponding to the measured or set temperature.
TEMP pH VALU
ºC ºF 1.68 4.01 6.86 7.01
0321.67 4.01 6.98 7.13
5411.67 4.00 6.95 7.10
10 50 1.67 4.00 6.92 7.07
15 59 1.67 4.00 6.90 7.04
20 68 1.68 4.00 6.88 7.03
25 77 1.68 4.01 6.86 7.01
30 86 1.68 4.02 6.85 7.00
35 95 1.69 4.03 6.84 6.99
40 104 1.69 4.04 6.84 6.98
45 113 1.70 4.05 6.83 6.98
50 122 1.71 4.06 6.83 6.98
55 131 1.72 4.07 6.84 6.98
60 140 1.72 4.09 6.84 6.98
65 149 1.73 4.11 6.85 6.99
70 158 1.74 4.12 6.85 6.99
During calibration the instrument will display the buffer value at 25 °C.
30
ELECTRODE CONDITIONING
& MAINTENANCE
PREPARATION
Remove the protective cap. DO NOT BE ALARMED IF SALT DEPOSITS ARE PRESENT. This is normal with
electrodes. They will disappear when rinsed with water. During transport, tiny bubbles of air may form inside the glass bulb affecting
proper functioning of the electrode. These bubbles can be removed by “shak­ing down” the electrode as you would do with a glass thermometer.
If the bulb and/or junction is dry condition the electrode by soaking it in HI 70300 or HI 80300 storage solution for at least one hour.
31
For Refillable Electrodes:
If the filling solution (electrolyte) is more than 2½ cm (1") below the fill hole, add HI 7082 or HI 8082 3.5M KCl Electrolyte Solution for double junction or HI 7071 or HI 8071 3.5M KCl+AgCl Electrolyte Solution for single junction electrodes using a plastic refilling pipette (HI 740157).
As recommended by the LCD message on instrument on start-up, remove or loosen the fill hole screw on the electrode for better performance.
STORAGE
To minimize clogging and assure a quick response time, the glass bulb and the junction should be kept moist and not allowed to dry out.
Replace the solution in the protective cap with a few drops of HI 70300 or HI 80300 Storage Solution or, in its absence, Filling Solution (HI 7071 or HI 8071 for single junction or HI 7082 or HI 8082 for double junction
electrodes). Follow the Preparation Procedure on page 31 before taking measurements.
Note: NEVER STORE THE ELECTRODE IN DISTILLED OR DEIONIZED WATER.
PERIODIC MAINTENANCE
Inspect the electrode and the cable. The cable used for connection to the instrument must be intact and there must be no points of broken insulation on the cable or cracks on the electrode stem or bulb. Connectors must be perfectly clean and dry. If any scratches or cracks are present, replace the electrode. Rinse off any salt deposits with water.
For Refillable Electrodes:
Refill the reference chamber with fresh electrolyte (HI 7071 or HI 8071 for single junction or HI 7082 or HI 8082 for double junction electrodes) using a plastic refilling pipette (HI 740157). Allow the electrode to stand upright for 1 hour.
Follow the Storage Procedure above.
CLEANING PROCEDURES
• General Soak in HI 7061 (or HI 8061) General Cleaning Solution
for approximately 30 minutes.
• Protein Soak in HI 7073 (or HI 8073) Protein Cleaning Solution
for 15 minutes.
• Inorganic Soak in HI 7074 (or HI 8074) Inorganic Cleaning
Solution for 15 minutes.
• Oil/grease Rinse with HI 7077 (or HI 8077) Oil and Fat Cleaning
Solution for approx. 30 seconds.
32
IMPORTANT:
After performing any of the cleaning procedures, rinse the electrode thoroughly with distilled water, refill the reference chamber with fresh electrolyte (not necessary for gel-filled electrodes) and soak the electrode in HI 70300 or HI 80300 Storage Solution for at least 1 hour before taking measurements.
TROUBLESHOOTING GUIDE
Symptoms Problem Solution
Slow response / exces­sive drift.
The reading drifts. Low electrode condi­tion.
Readings fluctuate up and down (noise).
The display shows blinking dashes during pH measurements.
The display shows blinking dashes during mV measurements.
Out of range mV scale.
The meter does not work with temperature probe.
Dirty pH electrode.
Bad or dirty pH electrode.
Clogged or dirty junction. Low electrolyte level (for refillable electrodes only).
Out of range pH scale.
Out of range mV scale.
Dry membrane/junction.
Broken temperature probe.
Soak the electrode tip in HI7061 solution for about 30 minutes, then clean the elec­trode.
Soak the electrode tip in warm (approx. 50-60°C) HI7082 solution. Refill with fresh electrolyte solution (for refillable electrodes only). Replace the electrode.
Clean the electrode. Refill with fresh electrolyte so­lution (for refillable elec­trodes only).
a) Recalibrate. b) Make sure the pH sample
is in the specified range.
c) Check the electrolyte level
and the general state of the pH electrode.
Electrode not connected.
Soak in HI 70300 Storage so­lution for at least one hour.
Replace the temperature probe.
33
Symptoms Problem Solution
AmpHel electrodes do not respond to pH changes.
The meter fails to cali­brate or gives faulty readings.
At start-up the LCD dis­play all segments per­manently.
Explicit warnings are displayed during pH calibration.
The electrode condi­tion and response gauges are not dis­played after calibra­tion.
The electrode condi­tion and response gauges are empty.
The meter displays empty Electrode re­sponse scale.
“Err xx” message dis­played.
The battery is run down.
Broken pH electrode.
One of the keys is blocked.
Dirty pH electrode or con­taminated buffers.
a) The meter has not
been calibrated on the current day.
b) Only 1-point calibra-
tion has been pre­formed.
c) Calibration not per-
formed with pH 7.01 and pH 3.00 buffers.
Not enough data avail­able to evaluate re­sponse time.
Internal error.
Replace the electrode.
Replace the pH electrode.
Check the keyboard or con­tact your dealer.
Follow displayed instructions.
Use Hanna HI1048P elec­trode and check the pin con­nection.
Perform a 2-point calibration procedure. Calibrate using pH 7.01 and pH 3.00 buffers.
Repeat calibration more carefully.
Power the meter OFF and then ON again. If the error persists, contact your dealer.
34
TEMPERATURE CORRELATION
FOR pH SENSITIVE GLASS
The resistance of glass electrodes partially depends on the temperature. The lower the temperature, the higher the resistance. It takes more time for the reading to stabilize if the resistance is higher. In addition, the response time will suffer to a greater degree at temperatures below 25 °C.
Since the resistance of the pH electrode is in the range of 50-200 Mohm depending on the composition of the glass, the current across the membrane is in the pico-Ampere range. Large currents can disturb the calibration of the electrode for many hours. For these reasons high humidity environments, short circuits and static discharges are detrimental to a stable pH reading. The pH electrode’s life also depends on the temperature. If constantly used at high temperatures, the electrode life is drastically reduced.
Typical Electrode Life: Ambient Temperature 1- 3 years
90 °C Less than 4 months 120 °C Less than 1 month
Alkaline Error:
High concentrations of sodium ions interfere with readings in alkaline solu­tions. The pH at which the interference starts to be significant depends upon the composition of the glass. This interference is called alkaline error and causes the pH to be underestimated. Hanna’s glass formulations have the indicated characteristics.
Sodium Ion Correction for the Glass at 20-25 °C Concentration pH Error
0.1 Mol L-1 Na
1.0 Mol L-1 Na
+
+
13.00
13.50
14.00
12.50
13.00
13.50
14.00
0.10
0.14
0.20
0.10
0.18
0.29
0.40
35
ACCESSORIES
pH CALIBRATION SOLUTIONS
HI 50003P pH 3.00 Buffer Solution, 20 mL sachet, 25 pcs HI 70004P pH 4.01 Buffer Solution, 20 mL sachet, 25 pcs HI 70007P pH 7.01 Buffer Solution, 20 mL sachet, 25 pcs HI 70010P pH 10.01 Buffer Solution, 20 mL sachet, 25 pcs HI 7001M pH 1.68 Buffer Solution, 230 mL bottle HI 5003 pH 3.00 Buffer Solution, 500 mL bottle HI 7004L pH 4.01 Buffer Solution, 500 mL bottle HI 7006L pH 6.86 Buffer Solution, 500 mL bottle HI 7007L pH 7.01 Buffer Solution, 500 mL bottle HI 7009L pH 9.18 Buffer Solution, 500 mL bottle HI 7010L pH 10.01 Buffer Solution, 500 mL bottle HI 7001L pH 1.68 Buffer Solution in FDA approved bottle, 500 mL HI 8004L pH 4.01 Buffer Solution in FDA approved bottle, 500 mL HI 8006L pH 6.86 Buffer Solution in FDA approved bottle, 500 mL HI 8007L pH 7.01 Buffer Solution in FDA approved bottle, 500 mL HI 8009L pH 9.18 Buffer Solution in FDA approved bottle, 500 mL HI 8010L pH 10.01 Buffer Solution in FDA approved bottle, 500 mL
ELECTRODE STORAGE SOLUTION
HI 70300L Storage Solution, 460 mL bottle HI 80300L Storage Solution in FDA approved bottle, 460 mL
ELECTRODE CLEANING SOLUTIONS
HI 70000P Electrode Rinse Solution, 20 mL sachet, 25 pcs HI 700635P Cleaning Solution for wine deposits, 20 mL sachet, 25 pcs HI 700636P Cleaning Solution for wine stains, 20 mL sachet, 25 pcs HI 70635L Cleaning Solution for wine deposits, 460 mL bottle HI 70636L Cleaning Solution for wine stains, 460 mL bottle HI 7061L General Cleaning Solution, 460 mL bottle HI 7073L Protein Cleaning Solution, 460 mL bottle HI 7074L Inorganic Cleaning Solution, 460 mL bottle HI 7077L Oil & Fat Cleaning Solution, 460 mL bottle HI 8061L General Cleaning Solution in FDA approved bottle, 460 mL HI 8073L Protein Cleaning Solution in FDA approved bottle, 460 mL HI 8077L Oil & Fat Cleaning Solution in FDA approved bottle, 460 mL
36
REFILLING ELECTROLYTE SOLUTIONS
HI 7071 3.5M KCl + AgCl Electrolyte, 4x30 mL, for single junction electrodes HI 7072 1M KNO3 Electrolyte, 4x30 mL HI 7082 3.5M KCl Electrolyte, 4x30 mL, for double junction electrodes HI 8071 3.5M KCl + AgCl Electrolyte in FDA approved bottle, 4x30 mL,
for single junction electrodes HI 8072 1M KNO3 Electrolyte in FDA approved bottle, 4x30 mL HI 8082 3.5M KCl Electrolyte in FDA approved bottle, 4x30 mL, for
double junction electrodes
ORP PRETREATMENT SOLUTIONS
HI 7091L Reducing Pretreatment Solution, 460 mL bottle HI 7092L Oxidizing Pretreatment Solution, 460 mL bottle
pH ELECTRODES
All electrodes with code ending with P are supplied with BNC & pin connector and 1 m (3.3') cable, as shown below.
HI 1043P; Use: strong acid/alkali. Glass-body, double junction, refillable, combination pH electrode.
12 mm
0.5"
HI 1043
"S" VERSION
9.5mm DIA
120 mm
4.7"
0.37"
HI 1053P; Use: emulsions. Glass-body, triple ceramic, conic shape, refillable, combination pH electrode.
12 mm
0.5"
HI 1053
37
120 mm
4.7"
"S" VERSION
HI 1131P; Use: general purpose. Glass-body, single junction, refillable, combination pH electrode.
12 mm
0.5"
HI 1131
"S" VERSION
9.5mm DIA
120 mm
4.7"
0.37"
HI 1083P; Use: biotechnology, micro titration. Glass-body, micro, Viscolene, nonrefillable, combination pH electrode
HI 1083
12 mm
0.5"
5 mm
0.2"
120 mm
3 mm
0.12"
"
3.0 mm DIA
0.12"
HI 1048P; Use: wine measurements. Glass-body, refillable pH electrode with open junction, Teflon® collar
HI 1048
ORP ELECTRODES
HI 3131P; Use: titration. Glass-body, refillable, combination platinum ORP electrode
12 mm
0.5"
HI 3131
150 mm
"S" VERSION
5.9"
Consult the Hanna General Catalog for more electrodes with BNC and pin connectors.
OTHER ACCESSORIES
HI 710005 Voltage adapter from 115 VAC to 12 VDC (USA plug) HI 710006 Voltage adapter from 230 VAC to 12 VDC (European plug) HI 710012 Voltage adapter from 240 VAC to 12 VDC (UK plug) HI 710013 Voltage adapter from 230 VAC to 12 VDC (South African plug) HI 710014 Voltage adapter from 230 VAC to 12 VDC (Australian plug) ChecktempC Pocket-size thermometer (range -50.0 to 120.0 ºC)
Ultem® is registered Trademark of “General Electrics Co.” Kynar® is registered Trademark of “Pennwalt Corp.” Windows® is registered Trademark of “Microsoft Co.”
38
HI 76405Electrode holder
HI 8427 pH and ORP electrode simulator with 1 m (3.3') coaxial
cable ending in female BNC connectors
HI 931001 pH and ORP electrode simulator with LCD and 1 m (3.3')
coaxial cable ending in female BNC connectors HI 7669/2W Temperature probe with 1 m (3.3') cable HI 740157 Plastic electrode refilling pipet (20 pcs) HI 92000 Windows® compatible software HI 920010 9 to 9-pin RS232 connection cable
Recommendations for users
Before using this product, make sure that it is entirely suitable for the environment in which it is used. Operation of this instrument in residential areas could cause unacceptable inter­ferences to radio and TV equipment, requiring the operator to take all necessary steps to correct interferences.
The glass bulb at the end of the pH electrode is sensitive to electrostatic discharges. Avoid touching this glass bulb at all times.
During operation, ESD wrist straps should be worn to avoid possible damage to the electrode by electrostatic discharges.
Any variation introduced by the user to the supplied equipment may degrade the instrument's EMC performance.
To avoid electrical shock, do not use this instrument when voltages at the measurement surface exceed 24 VAC or 60 VDC.
To avoid damage or burns, do not perform any measurement in microwave ovens.
Hanna Instruments reserves the right to modify the design, construction and appearance of its products without advance notice.
39
HANNA SALES AND TECHNICAL SERVICE
Australia:
Tel. (03) 9769.0666 • Fax (03) 9769.0699
China:
Tel. (10) 88570068 • Fax (10) 88570060
Egypt:
Tel. & Fax (02) 2758.683
Germany:
Tel. (07851) 9129-0 • Fax (07851) 9129-99
Greece:
Tel. (210) 823.5192 • Fax (210) 884.0210
Indonesia:
Tel. (21) 4584.2941 • Fax (21) 4584.2942
Japan:
Tel. (03) 3258.9565 • Fax (03) 3258.9567
Korea:
Tel. (02) 2278.5147 • Fax (02) 2264.1729
Malaysia:
Tel. (603) 5638.9940 • Fax (603) 5638.9829
Singapore:
Tel. 6296.7118 • Fax 6291.6906
South Africa:
Tel. (011) 615.6076 • Fax (011) 615.8582
Taiwan:
Tel. 886.2.2739.3014 • Fax 886.2.2739.2983
Thailand:
Tel. (2) 619.0285 • Fax (2) 619.0284
United Kingdom:
Tel. (01525) 850.855 • Fax (01525) 853.668
USA:
Tel. (401) 765.7500 • Fax (401) 765.7575
For e-mail contacts and a complete list of Sales and Technical offices, please see www.hannainst.com.
40
05/04 R3
MAN222
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