Hanna Instruments HI 2212 User Manual

Instruction Manual
HI 2212 HI 2213
pH/mV/°C
Bench Meters
with Custom Buffers
www.hannainst.com
1
Dear Customer, Thank you for choosing a Hanna Instruments product. Please read this instruction manual carefully before using these instruments. This manual will provide you with the necessary information for correct
use of these instruments, as well as a precise idea of their versatility. If you need additional technical information, do not hesitate to e-mail us
at tech@hannainst.com or view our worldwide contact list at www.hannainst.com.
WARRANTYWARRANTY
WARRANTY
WARRANTYWARRANTY
HI 2212, HI 2213 are guaranteed for two years against defects in workmanship and materials when used for their intended purpose and maintained according to instructions. Electrodes and probes are guaranteed for six months. This warranty is limited to repair or replacement free of charge.
Damage due to accidents, misuse, tampering or lack of prescribed maintenance is not covered.
If service is required, contact the dealer from whom you purchased the instrument. If under warranty, report the model number, date of purchase, serial number and the nature of the problem. If the repair is not covered by the warranty, you will be notified of the charges incurred. If the instrument is to be returned to Hanna Instruments, first obtain a Returned Goods Authorization number from the Technical Service department and then send it with shipping costs prepaid. When shipping any instrument, make sure it is properly packed for complete protection.
TABLE OF CONTENTSTABLE OF CONTENTS
TABLE OF CONTENTS
TABLE OF CONTENTSTABLE OF CONTENTS
WARRANTY ............................................................................................. 2
PRELIMINARY EXAMINATION ...................................................................... 3
GENERAL DESCRIPTION ............................................................................ 3
FUNCTIONAL DESCRIPTION HI 2212 AND HI 2213 .................................... 4
HI 2212 AND HI 2213 SPECIFICATIONS ................................................... 5
OPERATIONAL GUIDE ................................................................................ 6
pH CALIBRATION ...................................................................................... 8
pH BUFFER TEMPERATURE DEPENDENCE ................................................. 13
GOOD LABORATORY PRACTICE (GLP) ........................................................ 14
SETUP .................................................................................................. 17
TEMPERATURE CALIBRATION (for technical personnel only) .......................... 20
mV CALIBRATION (for technical personnel only) .......................................... 22
RELATIVE mV CALIBRATION (HI 2213) .................................................... 23
ELECTRODE CONDITIONING & MAINTENANCE ............................................. 24
TROUBLESHOOTING GUIDE ..................................................................... 27
TEMPERATURE CORRELATION FOR pH SENSITIVE GLASS ............................. 28
ACCESSORIES ........................................................................................ 29
2
PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION
PRELIMINARY EXAMINATION
PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION
Remove the instrument from the packing material and examine it carefully to make sure that no damage has occurred during shipping. If there is any damage, notify your Dealer or the nearest Hanna Customer Service Center.
Each instrument is supplied with:
HI 1131B Glass-body Combination pH Electrode with 1 m (3.3') Cable
HI 7662 Temperature Probe
HI 76404N Electrode Holder
pH 4.01 & 7.01 Buffer Solutions (20 mL each)
HI 7071 Electrolyte Solution
HI 700661 Electrode Cleaning Solution
• 12VDC Power Adapter
• Instruction Manual
Note: Save all packing material until you are sure that the instrument
functions correctly. All defective items must be returned in the original packing with the supplied accessories.
GENERAL DESCRIPTIONGENERAL DESCRIPTION
GENERAL DESCRIPTION
GENERAL DESCRIPTIONGENERAL DESCRIPTION
The HANNA HI 2212 and HI 2213 are microprocessor based pH and temperature bench meters.
HI 2213 can also measure Oxidation Reduction Potential (ORP) in mV range. Relative mV feature is also provided.
pH measurements are compensated for temperature effect manually or automatically with the HI 7662 temperature probe.
Calibration can be performed at up to three-points using two custom buffers and five standard buffers.
The GLP feature provides data consistency. A calibration due alarm can be set to alert the user that too much time
elapsed since the last pH calibration.
3
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
HI 2212 AND HI 2213HI 2212 AND HI 2213
HI 2212 AND HI 2213
HI 2212 AND HI 2213HI 2212 AND HI 2213
Front Panel
Rear Panel
1) Liquid Crystal Display (LCD).
2) CAL key, to enter and exit calibration mode.
3) CFM/GLP key, to confirm different values or to display Good Laboratory Practice information.
4) ºC key, to manually increase temperature value or other parameters.
5) ºC key, to manually decrease temperature value or other parameters.
6) SETUP key, to enter/exit SETUP mode.
7) RANGE key, to select measurement range or to toggle between the buffer value and temperature during calibration or to change the focused data in setup (HI 2213 only).
u key, to toggle between the buffer value and temperature during calibration or to change the focused data in setup (HI 2212 only).
8) MEM key, to store a value into memory.
9) MR key, memory recall.
10) ON/OFF switch.
11) Power supply socket.
12) BNC electrode connector.
13) Temperature probe socket.
14) Electrode reference socket.
4
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HI 2212 AND HI 2213HI 2212 AND HI 2213
HI 2212 AND HI 2213
HI 2212 AND HI 2213HI 2212 AND HI 2213
SPECIFICATIONSSPECIFICATIONS
SPECIFICATIONS
SPECIFICATIONSSPECIFICATIONS
5
OPERATIONAL GUIDEOPERATIONAL GUIDE
OPERATIONAL GUIDE
OPERATIONAL GUIDEOPERATIONAL GUIDE
POWER CONNECTION
Plug the 12 VDC adapter into the power supply socket. Notes: • These instruments use non volatile memory to retain the pH,
mV, temperature calibrations and all other settings, even when unplugged.
• Make sure a fuse protects the main line.
ELECTRODE AND PROBE CONNECTIONS
For pH or ORP measurements connect an electrode with internal reference to the BNC connector on the back of the instrument.
For electrodes with a separate reference connect the electrode’s BNC to the BNC connector and the reference electrode plug to the reference socket.
For temperature measurements and automatic temperature compensation connect the temperature probe to the appropriate socket.
INSTRUMENT START-UP
• Turn the instrument on by pressing the ON/OFF switch located on the rear panel.
• All LCD tags are displayed and a beep is sounded while the instruments perform a self test.
pH MEASUREMENTS
Make sure the instrument has been calibrated before taking pH measurements.
• Submerse the electrode tip and the temperature probe approximately 3 cm (1¼”) into the sample to be tested and stir gently. Allow time for the
3 cm
(1¼")
electrode to stabilize.
• The pH is displayed on the primary LCD and the temperature on the secondary LCD.
• If the reading is out of range, the closest full-scale value will be displayed blinking on the primary LCD.
6
If measurements are taken successively in different samples, it is recommended to rinse the electrode thoroughly with deionized water or tap water and then with some of the next sample to prevent cross-contamination.
The pH reading is affected by temperature. In order to measure the pH accurately, the temperature effect must be compensated for. To use the Automatic Temperature Compensation feature, connect and submerse the HI 7662 temperature probe into the sample as close as possible to the electrode and wait for a few seconds.
If the temperature of the sample is known, manual temperature compensation can be used by disconnecting the temperature probe.
The display will show the last temperature reading with the “ºC” tag blinking.
The temperature can now be adjusted with the ARROW keys (from –20.0 ºC to 120.0 ºC).
mV/ORP MEASUREMENTS (HI 2213)
An optional ORP electrode must be used to perform ORP measurements (see Accessories).
Oxidation-Reduction Potential (REDOX) measurements provide the quantification of the oxidizing or reducing power of the tested sample.
The surface of the ORP electrode must be clean and smooth in order to obtain an accurate measurement.
• Press RANGE to enter mV range.
• Submerse the tip of the ORP electrode 3 cm (1¼”) into the sample to be tested and allow a few
3 cm
(1¼")
seconds for the reading to stabilize.
• The instrument displays the mV reading on the primary LCD and the temperature on the secondary LCD.
• If the reading is out of range, the closest full-scale value will be displayed blinking on the primary LCD.
7
RELATIVE mV MEASUREMENTS (HI 2213)
• Press RANGE until “rEL” message will be displayed on the secondary LCD line for one second and “mV” tag will blink. After one second the temperature will be displayed on the secondary LCD.
The reading displayed by the instrument is equal to the difference between the current mV input value and relative mV offset established in the relative mV calibration.
TEMPERATURE MEASUREMENTS
Connect the HI 7662 appropriate socket and turn the instrument on.
Submerse the temperature allow the reading on the secondary LCD to stabilize.
MEMORY FUNCTION
Press and hold down MEM key to store the last reading in the meters memory. The “MEM” tag will be displayed.
temperature probe to the
probe
into the sample and
Press MR (memory recall) key to display the memorized reading. The “MEM” tag will be displayed.
8
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H CALIBRATIONH CALIBRATION
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H CALIBRATION
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H CALIBRATIONH CALIBRATION
Calibrate the instrument frequently, especially if high accuracy is required.
The instrument should be recalibrated:
• Whenever the pH electrode is replaced.
• At least once a week.
• After testing aggressive chemicals.
• If “CAL” “INTV” tags are blinking during measurement.
Every time you calibrate the instrument use fresh buffers and perform an electrode Cleaning Procedure (see page 26).
PREPARATION
Pour small quantities of the buffer solutions into clean beakers. If possible, use plastic or glass beakers to minimize any EMC interferences.
For accurate calibration and to minimize cross-contamination, use two beakers for each buffer solution. One for rinsing the electrode and one for calibration.
If you are measuring in the acidic range, use pH 7.01 or 6.86 as first buffer and pH 4.01 as second buffer. If you are measuring in the alkaline range, use pH 7.01 or 6.86 as first buffer and pH 10.01, 9.18 as second buffer.
PROCEDURE
Calibration can be performed up to three-points. For accurate measurements, a three-point calibration is recommended.
However, a one or two point calibration can also be used. The calibration buffers can be selected from the calibration buffer list that
includes custom buffers and the memorized standard buffers:
pH 4.01, 6.86, 7.01, 9.18 and 10.01.
The custom buffers allow the user to calibrate in a buffer solution different from a standard one. Up to two custom buffers can be set in SETUP menu (see page 17). Each custom buffer value can be changed in a ±1.0 pH window around the set value (in according with temperature), during calibration, when it is selected; the “BUFFER pH” tag will blink.
The instruments will automatically skip the buffer used during calibration and the buffers which are in a ±0.2 pH window, around one of the calibrated buffers.
All new calibrations will override existing stored calibration data in a ±0.2 pH window. The slopes adjacent to the new points will be reevaluated.
9
THREE-POINT CALIBRATION
BUF
• Submerse the pH electrode and the temperature probe approximately 3 cm (1¼”) into a buffer solution and stir gently. The temperature probe should be close to the pH electrode.
• Press CAL. The “CAL” and “
” tags will
3 cm
(1¼")
appear and the “7.01” buffer will be displayed on the secondary LCD.
• If necessary, press the ARROW keys to select a different buffer value.
• The “ ” tag will blink on the LCD until the reading is stable.
• When the reading is stable and close to the selected buffer, the “READY” tag will be displayed and the “CFM” tag will blink.
• Press CFM to confirm calibration.
• The calibrated value will be displayed on the primary LCD and the second expected buffer value on the secondary LCD.
• After the first calibration point is confirmed, submerse the pH electrode and the temperature probe approximately 3 cm (1¼”) into the second buffer solution and stir gently. The temperature probe should be close to the pH electrode.
• If necessary, press the ARROW keys to select a different buffer value.
• The “ ” tag will blink on the LCD until the reading is stable.
• When the reading is stable and close to the selected buffer, the “READY” tag will be displayed and the “CFM” tag will blink.
• Press CFM to confirm calibration.
• The calibrated value is then displayed on the primary LCD and and the third expected buffer value on the secondary LCD.
• After the second calibration point is confirmed, submerse the pH electrode and the temperature probe approximately 3 cm (1¼”) into the next buffer solution and stir gently. The temperature probe should be close to the pH electrode.
• If necessary, press the ARROW keys to select a different buffer value.
10
• The “ ” tag will blink on the LCD until the reading is stable.
• When the reading is stable and close to the selected buffer, the “READY” tag will be displayed and the “CFM” tag will blink.
• Press CFM to confirm calibration.
• The instrument stores the calibration value and returns to measurement mode.
TWO-POINT CALIBRATION
• Proceed as described in “THREE-POINT CALIBRATION” section.
• Press CAL after the second calibration point was confirmed. The instrument will memorize the calibration data and return to measurement mode.
ONE-POINT CALIBRATION
Two SETUP selectable options are available: “Pnt” and “OFFS”. If the “Pnt” option is selected, the new calibration point overrides an
existing one. The adjacent slopes will be reevaluated. If the “OFFS” option is selected, an electrode offset correction is performed.
The existing slopes will remain unchanged.
• Proceed as described in “THREE-POINT CALIBRATION” section.
• Press CAL after the first calibration point was confirmed. The instrument will memorize the one-point calibration data and return to measurement mode.
Notes: • If the value measured by the instrument is not close to the
selected buffer, “WRONG” “ ” and “WRONG” “ ” tags will blink alternately. Check if the correct buffer has been used, or clean the electrode by following the Cleaning Procedure (see page 26). If necessary, change the buffer or the electrode.
• When a custom buffer is displayed, the “BUFFER pH” tag blinks. To change the custom buffer value in according with the buffer temperature proceed as described in “WORKING WITH CUSTOM BUFFERS” (see page 12).
• If the buffer temperature or the manual temperature exceeds the temperature limits of the buffer, “WRONG” tag and temperature reading will blink.
• If “WRONG”, “BUFFER pH” tags and “OLd” message are displayed blinking on the secondary LCD line, an inconsistency between new and previous (old) calibration is detected. Clear calibration parameters and proceed with calibration from the current calibration point. The instrument will keep all confirmed values during current calibration.
11
• To clear calibration parameters for all buffers starting with current buffer, press and hold down CFM, then press CAL. The calibration will continue from the current point. If this procedure is performed while calibrating in the first calibration point “CLr ALL” message is displayed for a few seconds then the instrument returns to measurement.
• Press RANGE (u for HI 2212) to toggle between pH buffer and temperature reading.
• Each time a buffer is confirmed, the new calibration data replaces the old calibration data of the corresponding buffer. If current confirmed buffer has no previous data stored and the calibration is not full (three buffers), the current buffer is added to the existing data. If the existing calibration is full, the instrument asks which buffer to replace. Press the ARROW keys to select another buffer to be replaced. Press CFM to confirm the buffer that will be replaced.
Press CAL to leave calibration without replacing. Note: If the replaced buffer is outside the ±0.2 pH window,
around each of the calibrated buffers, it is possible to select this buffer for next calibration during current calibration.
WORKING WITH CUSTOM BUFFERS
If a custom buffer was set in SETUP menu, it can be selected for calibration by pressing the ARROW keys. The “BUFFER pH” tag will blink.
Press SETUP if you want to adjust the buffer value. The buffer value will start blinking.
Use the ARROW keys to change the buffer value. After 5 seconds the buffer value is updated. Press SETUP if you want to
change it again. Note: Custom buffer value can be adjusted in a ±1.00 pH window,
around the set value.
12
PMET SREFFUBHp
10.4 68.6 10.7 81.9 10.01
0 23 10.4 89.6 31.7 64.9 23.01
5 14 00.4 59.6 01.7 93.9 42.01
01 05 00.4 29.6 70.7 33.9 81.01
51 95 00.4 09.6 40.7 72.9 21.01
02 86 00.4 88.6 30.7 22.9 60.01
52 77 10.4 68.6 10.7 81.9 10.01
03 68 20.4 58.6 00.7 41.9 69.9
53 59 30.4 48.6 99.6 01.9 29.9
04 401 40.4 48.6 89.6 70.9 88.9
54 311 50.4 38.6 89.6 40.9 58.9
05 221 60.4 38.6 89.6 10.9 28.9
55 131 70.4 48.6 89.6 99.8 97.9
06 041 90.4 48.6 89.6 79.8 77.9
56 941 11.4 58.6 99.6 59.8 67.9
07 851 21.4 58.6 99.6 39.8 57.9
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08 671 61.4 68.6 10.7 98.8 37.9
58 581 71.4 78.6 20.7 78.8 47.9
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59 302 02.4 98.6 40.7 38.8 67.9
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DEPENDENCEDEPENDENCE
DEPENDENCE
DEPENDENCEDEPENDENCE
The temperature has an effect on pH. The calibration buffer solutions are affected by temperature changes to a lesser degree than normal solutions. During calibration the instrument will automatically calibrate to the pH value corresponding to the measured or set temperature.
During calibration the instrument will display the pH buffer value at 25 ºC.
13
GOOD LABORATORY PRACTICE (GLP)GOOD LABORATORY PRACTICE (GLP)
GOOD LABORATORY PRACTICE (GLP)
GOOD LABORATORY PRACTICE (GLP)GOOD LABORATORY PRACTICE (GLP)
GLP is a set of functions that allows storage and retrieval of data regarding the maintenance and status of the electrode.
All data regarding the last calibration (one, two, or three point) is stored for the user to review when necessary. This data includes the following: calibration time stamp, offset (mV), average of slope (%), calibration buffers and the time until a new calibration is required.
EXPIRED CALIBRATION
These instruments allow the user to set the number of days before the next required calibration. This value can be set from 1 to 7 days. The default setting is OFF (disabled).
The instruments check if the time-out time has expired. If the time elapsed, the “CAL” “INTV” tags will blink as a reminder.
Note: If the instruments were not calibrated, the “CAL” “INTV” tags
will be displayed even if the feature is disabled in SETUP menu.
pH CALIBRATION DATA
Calibration data is stored automatically after a successful calibration. To view the pH calibration data, press GLP while in measurement mode. The instruments will display the time (hh:mm) of the last calibration.
Use the ARROW keys to scroll through the calibration data:
• The date (yyyy.mm.dd).
• The pH calibration offset.
• The pH calibration slope (the GLP slope is the average of the calibration slopes; the percentage is referred to the ideal value of 59.16 mV/pH).
14
• The pH calibration buffers in calibrating order. The first pH calibration buffer:
The second pH calibration buffer:
The third pH calibration buffer:
Notes:• The “OLd” message displayed beside the pH value means
that this buffer was not used during last calibration. Press and hold down SETUP if you want to see calibration date (or time, if old calibration was performed on the same day as the current calibration).
For each custom buffer used in calibration, the “BUFFER pH” tag will blink.
If “no bUF” message appears on the LCD, the instrument informs you that the calibration was performed with less than three buffers.
• Calibration Expiration status:
- if disabled
15
- or the number of days until the calibration alarm will be displayed
- or if expired (7 days ago)
Notes: • Press GLP to return to measurement mode.
• If calibration has not been performed, the instrument displays “no CAL”.
16
SETUPSETUP
SETUP
SETUPSETUP
Setup mode allows viewing and modifying the following parameters:
• Expired Calibration Alarm
• First Custom Buffer
• Second Custom Buffer
• One-point Calibration Behavior
• Current Time (hour & minute)
• Current Date (year, month & day)
• Beep Status
• Temperature Unit To enter SETUP mode press SETUP while the instrument is in
measurement mode. Select a parameter with the ARROW keys. Press CAL if you want to change a parameter value. The selected
parameter will start blinking. Press RANGE (u for HI 2212) to toggle between displayed parameters. Press the ARROW keys to increase or decrease the displayed value. Press CFM to save the modified value or CAL to escape.
EXPIRED CALIBRATION ALARM
Press CAL when the calibration time-out is displayed. Calibration time-out (“OFF” or “1” to “7” days) and “CFM” will start blinking.
Press the ARROW Press CFM to save the modified calibration time-out value. Press CAL to escape without saving.
FIRST CUSTOM BUFFER
Press CAL when “cb1” is displayed. The custom buffer (disabled – “no” or “0” to “16” pH) and “CFM” will start blinking.
Press the ARROW keys to change the custom buffer value. Press CFM to save the modified custom buffer value. Press CAL to escape without saving.
keys to change the calibration time-out value.
17
SECOND CUSTOM BUFFER
Press CAL when “cb2” is displayed. The custom buffer (disabled – “no” or “0” to “16” pH) and “CFM” will start blinking.
Press the ARROW keys to change the custom buffer value. Press CFM to save the modified custom buffer value. Press CAL to escape without saving.
ONE-POINT CALIBRATION BEHAVIOR
Press CAL when “1 Pnt” message is displayed on the secondary LCD. One of the two options (“Pnt” or “OFFS”) and “CFM” will start blinking (see pH CALIBRATION PROCEDURE for details, page 8).
Press the ARROW keys to toggle between “Pnt” and “OFFS” options. Press CFM to save the behavior for one-point calibration. Press CAL to escape without saving.
CURRENT TIME
Press CAL when the current time is displayed. The hour and “CFM” will start blinking.
Press the ARROW Press RANGE (HI 2213) or u (HI 2212). The minutes and “CFM” will
start blinking.
Press the ARROW keys to change the minutes. Press CFM to save the modified value. Press CAL to escape without saving.
keys to change the hour.
18
CURRENT DATE
Press CAL when the current date is displayed. The year and “CFM” will start blinking.
Press the ARROW Press RANGE (HI 2213) or u (HI 2212). The month and “CFM” will start blinking.
Press the ARROW Press RANGE (HI 2213) or u (HI 2212). The day and “CFM” will start
blinking.
Press the ARROW keys to change the day. Press CFM to save the modified value. Press CAL to escape without saving.
BEEP STATUS
Press CAL when the beep status is displayed. Beep status (“On” or “OFF”) and “CFM” will start blinking.
Press the ARROW Press CFM to save the modified beep status. Press CAL to escape without saving.
TEMPERATURE UNIT
Press CAL when “tnP is displayed. The temperature unit and “CFM” will start blinking.
keys to change the year.
keys to change the month.
keys to change the beep status (On or OFF).
Press the ARROW keys to change the option. Press CFM to save the modified temperature unit. Press CAL to escape without saving.
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TEMPERATURE CALIBRATIONTEMPERATURE CALIBRATION
TEMPERATURE CALIBRATION
TEMPERATURE CALIBRATIONTEMPERATURE CALIBRATION
((
for technical personnel onlyfor technical personnel only
(
for technical personnel only
((
for technical personnel onlyfor technical personnel only
All the instruments are factory calibrated for temperature. Hanna’s temperature probes are interchangeable and no temperature
calibration is needed when they are replaced. If the temperature measurements are inaccurate, temperature recalibration
should be performed. For an accurate recalibration, contact your dealer or the nearest Hanna Customer Service Center, or follow the instructions below.
• Prepare a vessel containing ice and water and another one containing hot water (around 50 ºC). Place insulation material around the vessels to minimize temperature changes.
• Use a calibrated thermometer with a resolution of 0.1 ºC as a reference thermometer.
• With the instrument off, press and hold down the CFM & SETUP keys, then power on the instrument. The “CAL” tag will appear and the secondary LCD will show “0.0 ºC”.
• Submerse the temperature probe in the vessel with ice and water as near as possible to the reference thermometer. Allow a few seconds for the probe to stabilize.
• Use the ARROW keys to set the reading on the secondary LCD to that of ice and water, measured by the reference thermometer. When the reading is stable and close to the selected calibration point, “READY” tag will appear and “CFM” tag will blink.
• Press CFM to confirm. The secondary LCD will show “50.0 ºC”.
))
)
))
• Submerse the temperature probe in the second vessel as near as possible to the reference thermometer. Allow a few seconds for the probe to stabilize.
20
• Use the ARROW keys to set the reading on the secondary LCD to that of the hot water.
When the reading is stable and close to the
selected calibration point, “READY” tag will appear and “CFM” tag will blink.
• Press CFM to confirm. The instrument returns to measurement mode.
Note: If the reading is not close to the selected calibration point,
WRONG” tag will blink. Change the temperature probe and restart calibration.
21
mm
V CALIBRATIONV CALIBRATION
m
V CALIBRATION
mm
V CALIBRATIONV CALIBRATION
((
for technical personnel onlyfor technical personnel only
(
for technical personnel only
((
for technical personnel onlyfor technical personnel only
All the instruments are factory calibrated for mV. Hanna’s ORP electrodes are interchangeable and no mV calibration is
needed when they are replaced. If the mV measurements are inaccurate, mV recalibration should be
performed. For an accurate recalibration, contact your dealer or the nearest
Hanna Customer Service Center, or follow the instructions below. A two-point calibration can be performed at 0.0 mV and 1800.0 mV.
• Attach to the BNC connector a mV simulator with an accuracy of ±0.1 mV.
• With the instrument off, press and hold down the CAL & keys, then power on the instrument. The “CAL” tag will appear and the secondary LCD will show “0.0 mV”.
• Set 0.0 mV on the simulator. When the reading is stable and close to the selected calibration
point, “READY” tag will appear and “CFM” tag will blink.
• Press CFM to confirm. The secondary LCD will display “1800 mV”.
• Set 1800.0 mV on the simulator. When the reading is stable and close to the selected calibration
point, “READY” tag will appear and “CFM” tag will blink.
• Press CFM to confirm. The instrument returns to measurement mode.
Note: If the reading is not close to the selected calibration point,
WRONG” tag will blink. Verify calibration condition or contact your vendor if you can not calibrate.
))
)
))
22
RELATIVE RELATIVE
RELATIVE
RELATIVE RELATIVE
• Press CAL when the instrument is in RELATIVE mV measurement mode. The “mV” and “ ” tags will blink. Absolute mV is displayed on the primary LCD and “AbS” message is displayed on the secondary LCD.
• When the absolute reading is stable and in measurement range, the instrument asks for confirmation.
• If the reading is out of range, “WRONG” tag will be displayed.
• Press CFM to confirm the absolute value. The instrument will display “0.0 mV” on the primary LCD and “rEL” message on the secondary LCD. In this moment the relative mV offset is equal to absolute mV reading.
• Use the ARROW keys if you want to change the displayed relative mV value.
• Press CFM to confirm the relative mV value. The relative mV offset is displayed on the primary LCD and “OFF” message on the secondary LCD for a few seconds. The instrument returns to measurement mode.
Note: The relative mV value can be changed only inside the relative mV
offset window (± 2000 mV).
mm
V CALIBRATION (HI 2213)V CALIBRATION (HI 2213)
m
V CALIBRATION (HI 2213)
mm
V CALIBRATION (HI 2213)V CALIBRATION (HI 2213)
23
ELECTRODE CONDITIONINGELECTRODE CONDITIONING
ELECTRODE CONDITIONING
ELECTRODE CONDITIONINGELECTRODE CONDITIONING
& MAINTENANCE& MAINTENANCE
& MAINTENANCE
& MAINTENANCE& MAINTENANCE
PREPARATION PROCEDURE
Remove the protective cap of the pH electrode. DO NOT BE ALARMED IF SALT DEPOSITS ARE PRESENT. This is normal
with electrodes. They will disappear when rinsed with water. During transport, tiny bubbles of air may form inside the glass bulb
affecting proper functioning of the electrode. These bubbles can be removed by “shaking down” the electrode as you would do with a glass thermometer.
If the bulb and/or junction is dry, soak the electrode in HI 70300 or
HI 80300
Storage Solution for at least one hour.
24
For refillable electrodes:
If the filling solution (electrolyte) is more than 2½ cm (1”) below the fill hole, add HI 7082 or HI 8082 3.5M KCl Electrolyte Solution for double junction or HI 7071 or HI 8071 3.5M KCl+AgCl Electrolyte Solution for single junction electrodes.
For faster response, unscrew the fill hole screw during measurements.
For AMPHEL® electrodes:
If the electrode does not respond to pH changes, the battery is run down and the electrode should be replaced.
MEASUREMENT
Rinse the electrode tip with distilled water. Submerse the tip (3 cm /1¼”) in the sample and stir gently for a few seconds.
For a faster response and to avoid cross-contamination of the samples, rinse the electrode tip with a few drops of the solution to be tested, before taking measurements.
STORAGE PROCEDURE
To minimize clogging and assure a quick response time, the glass bulb and the junction should be kept moist and not allowed to dry out.
Replace the solution in the protective cap with a few drops of HI 70300 or HI 80300 Storage Solution or, in its absence, Filling Solution (HI 7071 or HI 8071 for single junction and HI 7082 or HI 8082 for double junction electrodes). Follow the Preparation Procedure on page 24 before taking measurements.
Note: NEVER STORE THE ELECTRODE IN DISTILLED OR DEIONIZED WATER.
PERIODIC MAINTENANCE
Inspect the electrode and the cable. The cable used for connection to the instrument must be intact and there must be no points of broken insulation on the cable or cracks on the electrode stem or bulb. Connectors must be perfectly clean and dry. If any scratches or cracks are present, replace the electrode. Rinse off any salt deposits with water.
For refillable electrodes:
Refill the reference chamber with fresh electrolyte (HI 7071 or HI 8071 for single junction and HI 7082 or HI 8082 for double junction electrodes). Allow the electrode to stand upright for 1 hour.
Follow the Storage Procedure above.
25
CLEANING PROCEDURE
• General Soak in Hanna HI 7061 or HI 8061 General
Cleaning Solution for approximately ½ hour.
• Protein Soak in Hanna HI 7073 or HI 8073 Protein
Cleaning Solution for 15 minutes.
• Inorganic Soak in Hanna HI 7074 Inorganic Cleaning
Solution for 15 minutes.
• Oil/grease Rinse with Hanna HI 7077 or HI 8077 Oil
and Fat Cleaning Solution.
IMPORTANT: After performing any of the cleaning procedures, rinse the electrode thoroughly with distilled water, refill the reference chamber with fresh electrolyte (not necessary for gel-filled electrodes) and soak the electrode in HI 70300 or HI 80300 Storage Solution for at least 1 hour before taking measurements.
26
SMOTPMYS MELBORP NOITULOS
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TROUBLESHOOTING GUIDETROUBLESHOOTING GUIDE
TROUBLESHOOTING GUIDE
TROUBLESHOOTING GUIDETROUBLESHOOTING GUIDE
27
TEMPERATURE CORRELATIONTEMPERATURE CORRELATION
TEMPERATURE CORRELATION
TEMPERATURE CORRELATIONTEMPERATURE CORRELATION
FOR FOR
pp
FOR
FOR FOR
The resistance of glass electrodes partially depends on the temperature. The lower the temperature, the higher the resistance. It takes more time for the reading to stabilize if the resistance is higher. In addition, the response time will suffer to a greater degree at temperatures below 25 ºC.
Since the resistance of the pH electrode is in the range of 50 – 200 Mohm, the current across the membrane is in the pico Ampere range. Large currents can disturb the calibration of the electrode for many hours. For these reasons high humidity environments, short circuits and static discharges are detrimental to a stable pH reading.
The pH electrode’s life also depends on the temperature. If constantly used at high temperatures, the electrode life is drastically reduced.
Typical Electrode Life
Ambient Temperature 1 – 3 years 90 ºC Less than 4 months 120 ºC Less than 1 month
Alkaline Error
High concentrations of sodium ions interfere with readings in alkaline solutions. The pH at which the interference starts to be significant depends upon the composition of the glass. This interference is called alkaline error and causes the pH to be underestimated. Hanna’s glass formulations have the indicated characteristics.
Sodium Ion Correction for the Glass at 20-25 ºC
H SENSITIVE GLASSH SENSITIVE GLASS
p
H SENSITIVE GLASS
pp
H SENSITIVE GLASSH SENSITIVE GLASS
0.1 Mol L-1 Na
1.0 Mol L-1 Na
+
+
28
13.00
13.50
14.00
12.50
13.00
13.50
14.00
0.10
0.14
0.20
0.10
0.18
0.29
ACCESSORIESACCESSORIES
ACCESSORIES
ACCESSORIESACCESSORIES
pH BUFFER SOLUTIONS
HI 70004P pH 4.01 Buffer Sachets, 20 mL, 25 pcs HI 70007P pH 7.01 Buffer Sachets, 20 mL, 25 pcs HI 70010P pH 10.01 Buffer Sachets, 20 mL, 25 pcs HI 7001L pH 1.68 Buffer Solution, 500 mL HI 7004L pH 4.01 Buffer Solution, 500 mL HI 7006L pH 6.86 Buffer Solution, 500 mL HI 7007L pH 7.01 Buffer Solution, 500 mL HI 7009L pH 9.18 Buffer Solution, 500 mL HI 7010L pH 10.01 Buffer Solution, 500 mL HI 8004L pH 4.01 Buffer Solution in FDA approved bottle, 500 mL HI 8006L pH 6.86 Buffer Solution in FDA approved bottle, 500 mL HI 8007L pH 7.01 Buffer Solution in FDA approved bottle, 500 mL HI 8009L pH 9.18 Buffer Solution in FDA approved bottle, 500 mL HI 8010L pH 10.01 Buffer Solution in FDA approved bottle, 500 mL
ELECTRODE STORAGE SOLUTIONS
HI 70300L Storage Solution, 500 mL HI 80300L Storage Solution in FDA approved bottle, 500 mL
ELECTRODE CLEANING SOLUTIONS
HI 70000P Electrode Rinse Sachets, 20 mL, 25 pcs HI 7061L General Cleaning Solution, 500 mL HI 7073L Protein Cleaning Solution, 500 mL HI 7074L Inorganic Cleaning Solution, 500 mL HI 7077L Oil & Fat Cleaning Solution, 500 mL HI 8061L General Cleaning Solution in FDA approved bottle, 500 mL HI 8073L Protein Cleaning Solution in FDA approved bottle, 500 mL HI 8077L Oil & Fat Cleaning Solution in FDA approved bottle, 500 mL
ELECTRODE REFILL ELECTROLYTE SOLUTIONS
HI 7071 3.5M KCl + AgCl Electrolyte, 4x30 mL, for single junction
electrodes
HI 7072 1M KNO3 Electrolyte, 4x30 mL HI 7082 3.5M KCl Electrolyte, 4x30 mL, for double junction electrodes HI 8071 3.5M KCl + AgCl Electrolyte in FDA approved bottle,
4x30 mL, for single junction electrodes
HI 8072 1M KNO3 Electrolyte in FDA approved bottle, 4x30 mL HI 8082 3.5M KCl Electrolyte in FDA approved bottle, 4x30 mL, for
double junction electrodes.
29
ORP PRETREATMENT SOLUTIONS
HI 7091L Reducing Pretreatment Solution, 500 mL HI 7092L Oxidizing Pretreatment Solution, 500 mL
pH ELECTRODES
All electrodes part numbers ending in B are supplied with a BNC connector and 1 m (3.3') cable, as shown below :
HI 1043B
Glass-body, double junction, refillable, combination pH electrode. Use: strong acid/alkali.
HI 1053B
Glass-body, triple ceramic, conic shape, refillable, combination pH electrode. Use: emulsions.
HI 1083B
Glass-body, micro, Viscolene, non-refillable, combination pH electrode. Use: biotechnology, micro titration.
HI 1131B
Glass-body, single junction, refillable, combination pH electrode. Use: general purpose.
30
HI 1330B
Glass-body, semimicro, single junction, refillable, combination pH electrode. Use: laboratory, vials.
HI 1331B
Glass-body, semimicro, single junction, refillable, combination pH electrode. Use: flasks.
HI 1230B
Plastic-body (PES), double junction, gel-filled, combination pH electrode. Use: general, field.
HI 2031B
Glass-body, semimicro, conic, refillable, combination pH electrode. Use: semisolid products.
HI 1332B
Plastic-body (PES), double junction, refillable, combination pH electrode. Use: general purpose.
31
FC 100B
Plastic-body (PVDF), double junction, refillable, combination pH electrode. Use: general purpose for food industry.
FC 200B
Plastic-body (PVDF), open junction, conic, Viscolene, non-refillable, combination pH electrode. Use: meat & cheese.
FC 210B
Glass-body, double junction, conic, Viscolene, non-refillable, combination
pH electrode. Use: milk, yogurt.
FC 220B
Glass-body, triple-ceramic, single junction, refillable, combination pH electrode. Use: food processing.
FC 911B
Plastic-body (PVDF), double junction, refillable with built-in amplifier, combination pH electrode. Use: very high humidity.
32
HI 1413B
Glass-body, single junction, flat tip, Viscolene, non-refillable, combination pH electrode. Use: surface measurement.
ORP ELECTRODES
HI 3131B
Glass-body, refillable, combination platinum ORP electrode. Use: titration.
HI 3230B
Plastic-body (PES), gel-filled, combination platinum ORP electrode. Use: general purpose.
HI 4430B
Plastic-body (PES), gel-filled, combination gold ORP electrode. Use: general purpose.
Consult the Hanna General Catalog for more electrodes with screw-type or BNC connectors.
33
EXTENSION CABLE FOR SCREW-TYPE ELECTRODES (SCREW TO BNC ADAPTER)
HI 7855/1 Extension cable 1 m (3.3') long HI 7855/3 Extension cable 3 m (9.9') long
OTHER ACCESSORIES
HI 710005 Voltage adapter from 115 VAC to 12 VDC (USA plug) HI 710006 Voltage adapter from 230 VAC to 12 VDC (European
plug)
HI 710012 Voltage adapter from 240 VAC to 12 VDC (UK plug) HI 710013 Voltage adapter from 230 VAC to 12 VDC (South Africa plug) HI 710014 Voltage adapter from 230 VAC to 12 VDC (Australia plug)
HI 76404N Electrode holder
HI 8427 pH and ORP electrode simulator with 1 m (3.3') coaxial
cable ending in female BNC connectors
HI 931001 pH and ORP electrode simulator with LCD and 1 m (3.3')
coaxial cable ending in female BNC connectors
HI 7662 Temperature probe with 1 m (3.3') cable.
34
RECOMMENDATIONS FOR USERS
Before using these products, make sure they are entirely suitable for the environment in which they are used.
Operation of these instruments in residential areas could cause unacceptable interferences to radio and TV equipment, requiring the operator to follow all necessary steps to correct interferences.
The glass bulb at the end of the pH electrode is sensitive to electrostatic discharges. Avoid touching this glass bulb at all times.
During operation, ESD wrist straps should be worn to avoid possible damage to the electrode by electrostatic discharges.
Any variation introduced by the user to the supplied equipment may degrade the instruments’ EMC performance.
To avoid electrical shock, do not use these instruments when voltages at the measurement surface exceed 24 VAC or 60 VDC.
To avoid damage or burns, do not perform any measurement in microwave ovens.
Hanna Instruments reserves the right to modify the design,
construction and appearance of its products without advance notice.
35
Hanna Instruments Inc.
Highland Industrial Park 584 Park East Drive Woonsocket, RI 02895 USA
Technical Support for Customers
Tel. (800) 426 6287 Fax (401) 765 7575 E-mail tech@hannainst.com www.hannainst.com
Local Sales and Customer Service Office
Printed in EUROPE
(ROMANIA) MAN2213 09/10
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