3M MMM34764 User Manual

3M™ Heavy Duty Bowl Cleaner Ready-to-Use 03/21/14

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Safety Data Sheet

Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

23-9752-9

Version Number:

3.00

Issue Date:

03/21/14

Supercedes Date:

08/02/11

SECTION 1: Identification

1.1. Product identifier

3M™ Heavy Duty Bowl Cleaner Ready-to-Use

Product Identification Numbers

ID Number UPC ID Number UPC
70-0713-1487-9 00-48011-34764-1 70-0716-8331-5 00-48011-34764-1

1.2. Recommended use and restrictions on use

Recommended use

An HCL acid product formulated to help remove the most difficult rust stains and hard water mineral deposits from toilet
bowls and urinals., Hard Surface Cleaner

1.3. Supplier’s details
MANUFACTURER:

3M

DIVISION:

Commercial Solutions Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification

Corrosive to metal: Category 1.
Acute Toxicity (oral): Category 4.
Acute Toxicity (inhalation): Category 4.
Serious Eye Damage/Irritation: Category 1.
Skin Corrosion/Irritation: Category 1B.
Specific Target Organ Toxicity (respiratory irritation): Category 3.

2.2. Label elements

Signal word

Danger

Symbols

3M™ Heavy Duty Bowl Cleaner Ready-to-Use 03/21/14

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Corrosion | Exclamation mark |

Pictograms

Hazard Statements

May be corrosive to metals.

Harmful if swallowed.
Causes severe skin burns and eye damage.
Harmful if inhaled.
May cause respiratory irritation.

Precautionary Statements

Prevention:

Keep only in original container.
Do not breathe fume/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves, protective clothing, and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.

Response:

IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Immediately call a POISON CENTER or doctor/physician.
Wash contaminated clothing before reuse.
Absorb spillage to prevent material damage.

Storage:

Store in a corrosive resistant container with a resistant inner liner.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.

Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified

May cause chemical gastrointestinal burns. May cause chemical respiratory tract burns.

1% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

WATER 7732-18-5 60 - 90 Trade Secret *
HYDROCHLORIC ACID 7647-01-0 10 - 30 Trade Secret *

3M™ Heavy Duty Bowl Cleaner Ready-to-Use 03/21/14

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ETHOXYLATED C9-11 ALCOHOLS 68439-46-3 0.1 - 1 Trade Secret *
Benzene, ethenyl-, homopolymer 9003-53-6 0.1 - 0.5 Trade Secret *
BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM
CHLORIDES

68424-85-1 < 0.1 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. Get immediate medical attention.

Skin Contact:

Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate
medical attention. Wash clothing before reuse.

Eye Contact:

Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.

If Swallowed:

Rinse mouth. Do not induce vomiting. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

Material will not burn. Non-combustible. Use a fire fighting agent suitable for surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Chlorine During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters

No unusual fire or explosion hazards are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation