FT-31, Denatonium Benzoate Sensitivity Solution 04/22/14
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Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
07-6198-1
Version Number:
14.01
Issue Date:
04/22/14
Supercedes Date:
03/20/14
SECTION 1: Identification
1.1. Product identifier
FT-31, Denatonium Benzoate Sensitivity Solution
Product Identification Numbers
70-0707-0965-7
1.2. Recommended use and restrictions on use
Recommended use
Sensitivity Test Solution.
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Personal Safety Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
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SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 90 - 100 Trade Secret *
SODIUM CHLORIDE 7647-14-5 3 - 10 Trade Secret *
DENATONIUM BENZOATE 3734-33-6 0 - 1 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
No need for first aid is anticipated.
Eye Contact:
No need for first aid is anticipated.
If Swallowed:
No need for first aid is anticipated.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Material will not burn. Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
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Clean up residue with water.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.
8.2. Exposure controls
8.2.1. Engineering controls
No engineering controls required.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
None required.
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
None required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Liquid
Odor, Color, Grade:
Clear, odorless solution with a bitter taste. Freezing point = -4
degrees Centigrade
Odor threshold
No Data Available
pH
Approximately 6.52 Units not avail. or not appl.
Melting point
Not Applicable
Boiling Point
>=212 ºF
Flash Point
No flash point
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
18 mmHg [@ 20 ºC]
Vapor Density
Not Applicable
FT-31, Denatonium Benzoate Sensitivity Solution 04/22/14
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Density
1.034 g/ml
Specific Gravity
1.034 [Ref Std: WATER=1]
Solubility in Water
Complete
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
Not Applicable
Decomposition temperature
No Data Available
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known. Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
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Skin Contact:
Contact with the skin during product use is not expected to result in significant irritation.
Eye Contact:
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion:
No health effects are expected.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
SODIUM CHLORIDE Dermal Rabbit LD50 > 10,000 mg/kg
SODIUM CHLORIDE Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 10.5 mg/l
SODIUM CHLORIDE Ingestion Rat LD50 3,000 mg/kg
DENATONIUM BENZOATE Inhalation-
Dust/Mist
LC50 estimated to be 1 - 5 mg/l
DENATONIUM BENZOATE Dermal Rat LD50 > 2,000 mg/kg
DENATONIUM BENZOATE Ingestion Rat LD50 584 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
DENATONIUM BENZOATE Rabbit Mild irritant
Serious Eye Damage/Irritation
Name Species Value
DENATONIUM BENZOATE Rabbit Corrosive
Skin Sensitization
Name Species Value
Overall product Guinea
pig
Not sensitizing
DENATONIUM BENZOATE Human Some positive data exist, but the data are not
sufficient for classification
Respiratory Sensitization
Name Species Value
DENATONIUM BENZOATE Human Some positive data exist, but the data are not
sufficient for classification
Germ Cell Mutagenicity
Name Route Value
DENATONIUM BENZOATE In Vitro Not mutagenic
DENATONIUM BENZOATE In vivo Not mutagenic
Carcinogenicity
Name Route Species Value
DENATONIUM BENZOATE Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
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Duration
DENATONIUM BENZOATE Ingestion Not toxic to female reproduction Rat NOAEL 16
mg/kg/day
2 years
DENATONIUM BENZOATE Ingestion Not toxic to male reproduction Rat NOAEL 16
mg/kg/day
2 years
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
DENATONIUM
BENZOATE
Ingestion endocrine system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 16
mg/kg/day
2 years
DENATONIUM
BENZOATE
Ingestion heart | bone, teeth,
nails, and/or hair |
hematopoietic
system | liver |
immune system |
muscles | nervous
system | eyes |
kidney and/or
bladder | respiratory
system
All data are negative Rat NOAEL 16
mg/kg/day
2 years
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Product components have been assessed to be treatable in properly operating wastewater treatment systems (industrial,
municipal, commercial) with a minimum of biological (aerobic) secondary treatment. Waste product may be directly
discharged to wastewater treatment systems. Changes in the manner of which a product is used will require an evaluation to
determine proper disposal. Empty and clean product containers may be disposed as non-hazardous waste. Consult your
specific regulations and service providers to determine available options and requirements.
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EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification
and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information.
The components of this product are in compliance with the new substance notification requirements of CEPA.
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 0 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
07-6198-1
Version Number:
14.01
Issue Date:
04/22/14
Supercedes Date:
03/20/14
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
FT-31, Denatonium Benzoate Sensitivity Solution 04/22/14
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for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
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