Model SC25V
Combined 12mm sensor;
pH, Ref, LE and Temperature
IM12B6J1-40E-E
2ndedition
2
Table 1
Production year according to
DIN. IEC 60062
Year Yearcode
2010 A
2011 B
2012 C
2013 D
2014 E
2015 F
2016 G
2017 H
2018 J
2019 K
2020 L
2021 M
2022 N
IM12B6J1-40E-E
Year Yearcode
2023 P
2024 Q
2025 R
2026 S
2027 T
2028 U
2029 V
2030 W
2031 X
2032 A
2033 B
2034 C
2035 D
Table 2
Production month according to
DIN. IEC 60062
Month Monthcode
January 1
February 2
March 3
April 4
May 5
June 6
July 7
August 8
September 9
October O
November N
December D
TABLE OF CONTENTS
1. Preface 4
1.1 Introduction 4
1.2 ATEX/IECEx compliance 4
1.3 Unpacking and checking 4
1.4 Warranty and service 4
2. General Specifications 5
2.1 Measuring elements 5
2.2 Construction materials 5
2.3 Functional specifications 5
2.4 Operating range 5
2.5 Dynamic specification 5
2.6 Sensor dimensions 6
2.7 Equipment and protective systems 6
3. Installation 7
3.1 Typical installation 7
3.2 Preparing the sensor for use 7
3.3 Mounting the sensor 7
4. Wiring to the pH analyzer 9
4.1 Cable marking and pin allocation 9
4.2 Instrument connection of sensor 9
4.3 Instrument connection setting for PH402G and PH202G(S) 9
4.4 Instrument connection setting for PH150, PH450 and FLXA21 9
4.5 Sensor VP connection 10
3
5. General calibration and maintenance procedure 10
5.1 Calibration for pH measurement 10
5.2 Maintenance 10
5.3 Chemical cleaning HCN 11
6. Model and suffix codes 12
6.1 SC25V sensor 12
6.2 Cable for Sensor with Variopin Connector 12
7. Spare parts 12
8. Appendix 13
Chemical Compatibility Chart 13
EC DECLARATION OF CONFORMITY 14
Application datasheet SC25V 15
IM12B6J1-40E-E
4
1. PREFACE
1.1 Introduction
This instruction manual provides information
for the installation and use of the SC25V,
combined 12mm glass sensor; pH, Ref, LE
and Temperature. The SC25V is the best
choice for the majority of typical processand waste water applications. The sensor is
designed with titanium liquid earth, increased
electrolyte reservoir and large surface area PTFE
diaphragm combined with a long pathway inner
junction resulting in a longtime stability and
prolonged lifetime.
1.2 ATEX/IECEx compliance
The model SC25V is intended for use in
potentially explosive atmospheres. A number of
restrictions apply on the use of this sensor.
All varieties of SC25V are ATEX certified:
II1G Ex ia IIC T3...T6 Ga (see chapter 2.7).
EC-type Examination Certificate Number:
DEKRA 11ATEX0014 X
IECEx-type Examination Certificate Number:
IECEx DEK 11.0064x
Special conditions for safe use:
For ambient temperature see chapter 2.7.
Electrostatic charges on the enclosure and
cable shall be avoided.
1.3 Unpacking & Checking
Upon delivery, unpack the sensor carefully and
inspect it to ensure it was not damaged during
shipment. If damage is found, retain the original
packing materials (including outer box) and
immediately notify the carrier and the relevant
Yokogawa sales office. Make sure the Model
Code on the sensor is the same as on the
packing list. The Model Code and Serial Number
are found on the VP-connector of the sensor.
Check that option(s) that were ordered are also
included.
1.4 Warranty & Service
Yokogawa products and parts are guaranteed
free from defects in workmanship and materials
under normal use and service for a period of
twelve months from the date of shipment from
the manufacturer. Individual sales organizations
can deviate from the typical warranty period,
and the conditions of sales relating to the
original purchase order should be consulted.
Damage caused by wear and tear, inadequate
maintenance, corrosion, or by the effects of
chemical processes are excluded from this
warranty coverage. In the event of warranty
claim, the defective goods should be sent
(freight paid) to the Service Department of
the relevant sales Organization for repair or
replacement (at Yokogawa’s discretion).
The following information must be included in
the letter accompanying the returned goods:
• Model Code and Serial Number.
• Original Purchase Order and Date.
• Length of time in service and description of
the process.
• Description of the fault and circumstances of
the failure.
• Process/environmental conditions that may be
related to the failure of the sensor.
• Statement as to whether warranty or
nonwarranty service is requested.
• Complete shipping and billing instructions for
return of material, plus the name and phone
number of a contact person that can be
reached for further information.
Returned goods that have been in contact with
process fluids must be decontaminated
and disinfected prior to shipment. Goods
should carry a certificate to this effect, for the
health and safety of our employees. Material
Safety Data sheets must be included for all
components of the process to which the
sensors/fittings have been exposed.
Junction resistance : 0.2 to 10 kΩ
Temp. element : Pt1000 to IEC 751
Asymmetry potential : 8 ±15 mV
Slope : > 96 %
(of theoretical value)
Sensor length : 120 mm and 225 mm
2.4 Operating range
pH : 0 to 14
Temperature
Type G-glass : -10 to 80°C
(14 to 176°F)
Type L-glass : +15 to 130°C
(59 to 266°F)
Pressure : 0 to 10 bar (0 to 145 psi)*
Conductivity : > 10 μS/cm
Storage temp. : -10 to 50°C (14 to 122°F)
* Damaging the screw thread might influence
the max process pressure.
Note: Specifications should not be considered
in isolation. For example the pH range
can be 2-12pH, where the measurement
is at elevated temperatures. For advice
about specific applications please contact
your local sales office.
2.5 Dynamic specifications
Response time pH step (7 to 4)
: < 5 sec for 90%
Response time temp step (25°C)
: < 90 sec for 90%
Stabilization time (0.02 pH unit/10 s)
: < 30 seconds
Note: The temperature sensor included in the
SC25V is intended to provide indication
and cell compensation. The construction
has not been tested to the pressure
vessel standards required for plant
temperature control.
IM12B6J1-40E-E
6
2.6 Sensor Dimensions
Dimension according to DIN 19263:2007-05
Criteria : 120 mm version
L (below plug head) : 120 ± 2 mm
Ø shaft : 11.9 ± 0.1 mm
Criteria : 225 mm version
L (below plug head) : 225 ± 2 mm
Ø shaft : 11.9 ± 0.1 mm
Concentricity : < 0,25 mm (centerline plug
head - 25 mm from tip)
Perpendicularity : < 0,5 mm (plug head
- 25 mm from tip)
Cilindricity : < 0,5 mm (centerline
sensor)
2.7 Equipment and protective systems
intended for use in potentially explosive
atmospheres
ATEX II1G Ex ia IIC T3...T6 Ga.
EC-type Examination Certificate Number:
DEKRA 11ATEX0014 X
IECEx-type Examination Certificate Number:
IECEx DEK 11.0064x
Description
pH sensor series SC25V for connection to a
certified associated pH/ORP transmitter are
used for measurement of pH, redox(ORP) and
temperature.
Criteria : All types
All measuring elements within 25mm from tip.
Wrench 19
PG13.5
YOKOGAWA
Made in the netherlands NL-3825 HD-2
173 / 278
II 1 G EX ia IIC T3/T4/T5/T6 Ga
DEKRA 11ATEX0014X
Ø12
0344
0344
S
-
A
C
5
2
V
X
6
1
-
1
0
0
120 / 225
< Ø11.8
25.0
Ambient temperature range:
-40°C to +40°C for temp. class T6,
-40°C to +55°C for temp. class T4 and T5,
-40°C to +105°C for temp. class T3,
Electrical data
Sensor input circuits (connector):
In type of protection intrinsic safety Ex ia IIC,
only for connection to a certified intrinsically safe
circuit, with the following maximum values:
Ui = 18V; Ii =170 mA; Pi = 0,4 W; Ci = 0 nF
(connector) or 3,6 nF (permanently connected
cable); Li = 0 mH;
Or for connection to the certified intrinsically
safe YOKOGAWA pH/ORP Transmitter Model
FLXA21 series or Model PH202S series.
Special conditions for safe use:
For ambient temperature see above.
Electrostatic charges on the enclosure and
cable shall be avoided.
pH sensor series SC25V is suitable for use with
the PH202S, FLXA21-EA conform to ATEX.
Note: When the sensor has been connected
to none intrinsically safe equipment or
equipment which exceeds the restrictions
regarding the sensor input circuit, the
sensor is not suitable for intrinsically safe
use anymore.
Figure 1
IM12B6J1-40E-E
3. INSTALLATION
3.1 Typical installation
The SC25V sensor can be installed in-line, in a
bypass loop or in an immersion assembly. For
best results the SC25V should be mounted with
the process fluid flowing towards the sensor
and positioned at least 15° above the horizontal
plane to eliminate air bubbles in the glass bulb.
See fig. 6 section 3.3
7
SC25V
O-RING VITON 11x3
PR10
3.2 Preparing the sensor for use
Remove the sensor from its shipping box and
slide off the “wet pocket” (the flask including the
rubber ring). This wet pocket is filled with a weak
acid and saline solution to prevent the sensor
from drying out during storage and making sure
it is ready for immediate use.
Before mounting the sensor, it should be
validated with buffer solutions and calibrated
when necessary. The specific calibration
procedure is described in the Instruction Manual
of the pH transmitter, but a general procedure is
also provided in section 5 of this manual.
4.4 Instrument connection settings for PH150, PH450 and FLXA21
Function pH pH compensated
Setting (default)
sensor setup pH pH + ORP pH + ORP ORP ORP
measurement setup pH + ORP pH+rH
Impedance settings
input 1 High High High Low Low
input 2 Low Low Low Low High
jumper input 1 no no no yes yes
jumper input 2 yes yes yes yes no
pH&ORP pH&rH ORP
ORP
IM12B6J1-40E-E
10
4.5 Sensor VP connection
VP-Connector
(Temp 2) F
(Temp 1) E
(LE) D
(pH) A
(Ref.) B
Figure 8
5. GENERAL CALIBRATION AND MAINTENANCE PROCEDURE
5.1 Calibration for pH measurement
To calibrate a pH sensor, at least two buffer
solutions with known pH values are required. It
is recommended to use one buffer solution with
a value of pH=7. The second buffer solution
should be either acidic (pH<7) or alkaline
(pH>7), depending on the process value to be
measured. Example buffer solutions are the IEC
buffers with pH=4.01, pH=6.87 and pH=9.18.
The following is a general 2-point calibration
procedure:
1 Clean the sensor (deposits may be removed
Most instruments automatically correct the
measured pH value at process temperature to
a pH-value at a standard temperature of 25°C.
After the calibration is complete, replace or
re-install the sensor into the process.
5.2 Maintenance
Cleaning the electrodes
When the sensitivity of the electrode has
decreased or the response has slowed down,
the electrode should be cleaned. If cleaning
with hot water is not sufficient, more aggressive
water based agents should be used.
Examples:
• Deposits of lime, hydroxides or carbonates
can be removed by immersing the sensor in
or a dilute solution of hydrochloric acid (5% is
recommended). Afterwards rinse with water.
• Deposits of oils and fats can be removed with
hot water in conjunction with a detergent.
When the results are unsatisfactory, a mild
(carbonate based) abrasive can be used.
IM12B6J1-40E-E
5.3 Chemical cleaning HCN
The chemical cleaning system is effective in
processes where deposits can be removed by
a suitable solvent. Good cleaning effects can
be obtained from periodically spraying of an
electrode. EXA PH450G has a built-in wash
timer with programmable wash time, interval
time and relaxation time for automatic cleaning
of the electrodes, preventing pollution of the
pH sensitive parts. After washing, it is possible
to check the response time of the electrodes.
A built-in (no return) nozzle in the spray unit
prevents penetration of the process liquid in the
cleaning system. The standardized dimensions
allow mounting in all flow-, insertion- and
immersion fittings of Yokogawa as well as
back-end mounting on the 4-in-one pH/Redox
electrodes.
Specifications
Materials
Nozzle : Hastelloy
O-rings : EPDM rubber
Mounting set : Stainless steel
Tubing : 1/4” (OD Ø) Nylon tubing
Process cond. : Max. 1 MPa (10 bar) at 100 ºC
Part no.
K1547PA : /HCN3, 3-hole flow-, insertion-,
immersion fitting
K1547PB : /HCN4, 4-hole flow-, insertion-,
immersion fitting
Chemical cleaning
Tubing
O-rings
(11x3)
11
Figure 9
K1547PP
(spare tubing, EPDM)
IM12B6J1-40E-E
12
6. MODEL AND SUFFIX CODES
6.1 SC25V sensor
Model Suffix Code Option code Description
SC25V Combined 12mm sensor: pH, Ref, LE, Temp.
Equiped with Variopin connector
Sensor type -AGP25 General purpose
-ALP25 High temp: Chemical resistant.
Sensor length -120 120 mm
K1500BV O-RINGS EPDM 11X3 (6 PCS.)
K1500BZ O-RINGS VITON 11X3 (6 PCS.)
K1500GR O-RINGS SILICON 11X3 (8PCS)
K1524AA O-ring 10.77X2.62 SILICON 70°sh
FP20-R12 Blind plug set for 1-hole
FP20-R12M Blind plug set for 1-hole (x12)
Adapters
Prod. No. Description
K1523JA Adapter for mounting Pg13,5-sensors in F*40
K1520JN Adapter M25x1.5 - PG13.5 PVC
K1520JP Adapter M25x1.5 - PG13.5 RVS
K1500DV Adapter M25x1.5 - PG13.5 PVDF
K1523JB Adapter PG13.5 to ¾"NPT
K1598AC Flow fitting (3.1), for SC4A (In combination with K1523JB)
K9148NA Adapter for mounting Pg13,5-sensors in HA405-120-S3
K9148NB Adapter for mounting Pg13,5-sensors in HA405-120-PP
K9148NC Adapter for mounting Pg13,5-sensors in HA405-120-PV
IM12B6J1-40E-E
8. APPENDIX
CHEMICAL
COMPATIBILITY
CHART
Material
Viton EPDM Ti PTFE PEEK Glass
(teflon)
13
Conc.%
Sulfiric acid 10 o o o o o o - - - o o o o o o o o o
50 o o o o x - - - - o o o o o o o o o
95 o o o x - - - - - o o o - - - o o o
fuming o o o - - - - - - o o o - - - o o o
Hydrochloric acid 10 o o o o o o - - - o o o o o x o o o
sat. o o o x x x - - - o o o o o x o o o
Nitric acid 25 o o x o x - o o o o o o o o o o o o
50 - - - - - - o o o o o o x x x o o o
95 - - - - - - o o o o o o - - - o o o
fuming - - - - - - o o o - - - o o o
Phosphoric acid 25 o o o o o o x x - o o o o o o o o o
50 o o o o o o x - - o o o o o o o o o
95 x x - o o o x - - o o o o o o o o o
Hydrofluoric acid 40 o o o - - - - - - o o o - - - x x x
75 o o x - - - - - - o o o - - - - - Acetic acid 10 - - - o o o o o o o o o o o o o o o
glacial - - - x x x o o o o o o o o x o o o
Formic acid 80 - - - o o x x x - o o o x x x o o o
Citric acid 50 o o o o o o x x x o o o o o o o o o
Calcium hydroxide sat. o o o o o o o o o o o o o o o o o o
Potassium hydroxide 50 o o o o x - o x - o o o o o o o o x
Sodium hydroxide 40 x x x o x - x x - o o o o o o o o x
Ammonia in water 30 x x x o o o x x - o o o o o o o o x
Ammonium chloride sat. o o o o o o o o o o o o o o o o o o
Zinc chloride 50 o o o o o o o o o o o o o o o o o o
Iron(III) chloride 50 o o o o o o o o o o o o o
Sodium sulfite sat. - - - o o o o o o o o o o o o o o o
Sodium carbonate sat. o o o o o o o o o o o o o o o o o o
Potassium chloride sat. o o o o o o o o x o o o o o o o o o
Sodium sulfate sat. o o o o o o o o o o o o o o o o o o
Calcium chloride sat. o o o o o o o o o o o o o o o o o o
Sodium chloride sat. o o o o o o o o o o o o o o o o o o
Sodium nitrate 50 o o o o o o o o o o o o o o o o o o
Aluminium chloride sat. o o o o o o o o x o o o o o o o o o
Hydrogen peroxide 30 o o o o o x o o o o o o o o o o o o
Sodium Hypochloride 50 o o x o o o x - - o o o o o o o o o
Potassium dichromate sat. o o o o o o o o o o o o o o o o o o
Chlorinated lime o o o x x x o o o
Ethanol 80 x - - o o o o o o o o o o o o o o o
Cyclohexane o o o - - - o o o o o o o o o o o o
Toluene - - - - - - o o o o o o o o o o o o
Trichloroethane x x x - - - o o o o o o o o o o o o
o = can be used / x = shortens useful life / - = cannot be used / Blank = no data currently available
Note: Information in this list is based on our general experience and literature data and given in good
faith. However Yokogawa is unable to accept responsebility for claims related to this information.
Temp. °C2060
1002060
1002060
1002060
1002060
1002060
IM12B6J1-40E-E
100
14
EC DECLARATION OF CONFORMITY
IM12B6J1-40E-E
APPLICATION DATA SHEET SC25V COMBINED PH SENSOR
Yokogawa has an extensive sales and distribution network. Please refer to the European website
Customer Please complete a separate form for each
Address process stream to be analyzed and return,
marked for the attention of:
Contact
Telephone
Fax
Serial no. Date received Date returned
1. Process data
Description
15
Application
Operation
Type of
solution
pH Value Nor Min Max
Temperature ( ºC, ºF) Nor Min Max
Pressure (psig, bar, kg/cm²) Nor Min Max
Flow Rate (m/s : ft/s) Nor Min Max
Conductivity (mS/cm) Nor Min Max
Concentration of salts Concentration of organics
Type(s) Type(s)
Problems with Present
measuring procedure
Description
Yokogawa
Confidential
Pulp & Paper Power
Pharmaceutical
Batch
Fouling
Other
Continuous Monitor
Poisoning
Chemical
Other
Control
Coating
YOKOGAWA
Euroweg 2
3825 HD Amersfoort
The Netherlands
www.yokogawa.com/eu
IM12B6J1-40E-E
A5 formaat
YOKOGAWA ELECTRIC CORPORATION
World Headquarters
9-32, Nakacho 2-chome, Musashino-shi
Tokyo 180-8750
Japan
www.yokogawa.com
YOKOGAWA CORPORATION OF AMERICA
2 Dart Road
Newnan GA 30265
USA
www.yokogawa.com/us
Euroweg 2
3825 HD Amersfoort
The Netherlands
www.yokogawa.com/eu
YOKOGAWA ELECTRIC ASIA Pte. LTD.
5 Bedok South Road
Singapore 469270
Singapore
www.yokogawa.com/sg
YOKOGAWA CHINA CO. LTD.
3F Tower D Cartelo Crocodile Building
No.568 West Tianshan Road Changing District
Shanghai, China
www.yokogawa.com/cn