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Table of Contents
Table of Contents
1.About This Document................................................................................... 5
This document provides instructions for installing, using, and maintaining Vaisala PEROXCAPâ
Hydrogen Peroxide, Humidity and Temperature Probe HPP272.
Table 1 Document Versions
Document
Code
M211972EN-BDecember 2017This document. Added description and Modbus registers for
M211972EN-ASeptember 2017First version.
DateDescription
pressure compensation, removed restriction not to perform a
purge during H2O2 exposure, clarified operating system
requirements for Vaisala Insight software, clarified Indigo
200 transmitter compatibility with HPP272.
1.2 Related Manuals
Table 2 Related Manuals
Document Code Name
M211887ENHydrogen Peroxide, Humidity and Temperature Probe HPP270 Series Quick
M211877ENIndigo 201 Analog Output Transmitter User Guide
Guide
1.3 Documentation Conventions
WARNING!
follow instructions carefully at this point, there is a risk of injury or even death.
Warning alerts you to a serious hazard. If you do not read and
CAUTION!
follow instructions carefully at this point, the product could be damaged or
important data could be lost.
Caution warns you of a potential hazard. If you do not read and
5
HPP272 User GuideM211972EN-B
Note highlights important information on using the product.
Tip gives information for using the product more eciently.
Lists tools needed to perform the task.
Indicates that you need to take some notes during the task.
1.4 Trademarks
Vaisalaâ, HUMICAPâ, and PEROXCAPâ are registered trademarks of Vaisala Oyj.
Indigo™ is a trademark of Vaisala Oyj.
All other product or company names that may be mentioned in this publication are trade
names, trademarks, or registered trademarks of their respective owners.
1.5
Patent Notice
This product is protected by the following patents and patent applications and their
corresponding national rights:
Table 3 Applicable Patents or Applications
Issuing OcePublication Number
European Patent OceEP 3004868
State Intellectual Property Oce of the P.R.C.CN 105229463A
United States Patent and Trademark OceUS 20160084811
6
21543
6
Chapter 2 – Product Overview
2. Product Overview
2.1 Introduction to HPP272
Vaisala PEROXCAPâ Hydrogen Peroxide, Humidity and Temperature Probe HPP270 series is
designed for demanding hydrogen peroxide bio-decontamination processes. The probes are
suitable for a variety of applications such as isolator, material transfer hatch, and room biodecontamination.
Hydrogen Peroxide, Humidity and Temperature Probe HPP272 provides measurement for
vaporized H2O2 concentration, relative saturation, relative humidity, and temperature.
The H2O2 measurement is based on comparing the readings of two composite humidity
sensors to determine the vapor concentration of H2O2. The probes are easy to install with a
plug-in/plug-out M12/5 connection. The digital and analog output options include an RS-485
interface for Modbus communication and two current output channels.
The probe is not intended for safety level measurement.
The probe is not intended to be used in vacuum applications.
CAUTION!
always be powered on. When powered on, the PEROXCAP sensor is heated,
which permits using the probe in condensing H2O2 conditions, maintains
measurement performance, and lengthens the probe's lifetime. When the probe
is powered o, exposure to H2O2 condensation can break the PEROXCAP sensor
within a day, and the sensor will not recover.
When there is H2O2 in the probe's environment, the probe must
Figure 1 HPP272 Probe Parts
1Yellow transport cap. Remove this cap
before using the probe.
2Filter covering the sensor. The filter is
an essential part of the measurement
technology: do not remove the filter.
Filters are available as spare parts.
3PEROXCAP sensor under the filter.
4H2O2 and humidity probe.
5Temperature probe.
65-pin M12 connector.
7
HPP272 User GuideM211972EN-B
More Information
‣
Dimensions (page 43)
‣
Operating Principle of H2O2 Measurement (page 14)
‣
Installation (page 20)
‣
Wiring (page 22)
2.2 Basic Features and Options
• Vaisala PEROXCAPâ H2O2 measurement technology with excellent long-term stability.
• Vaporized H2O2 measurement range 0 ... 2000 ppm.
• Relative saturation (RS) measurement range 0 ... 100 %RS.
• Relative humidity (RH) measurement range 0 … 100 %RH.
• Temperature (T) measurement range +5 ... +70 °C.
• Robust design allowing the probe to be installed directly in the process environment.
When powered on, the probe withstands H2O2 and H2O condensation. The probe also
withstands nitrogen gas.
• Protective
• Sensor heating to avoid condensation on the sensors.
• Chemical purge for optimized performance and lifetime.
• Pressure compensation for H2O2 concentration (ppm), H2O concentration (ppm), and
relative saturation (%RS) measurement.
• Digital output: RS-485 interface for Modbus communication.
• Analog output: 2 x 4 ... 20 mA (default).
• Easy plug-in, plug-out.
• Can be used as a stand-alone probe or with Vaisala Indigo 200 series transmitters.
• Can be connected to Vaisala Insight software for
temporary online monitoring.
filter over the sensors designed to withstand high air flow rates and turbulence.
configuration, diagnostics, and
More Information
‣
Technical Data (page 41)
2.3
Safety
WARNING!
to minimize shock hazard.
WARNING!
has not been exposed to dangerous contamination, and is safe to handle
without special precautions.
8
Ground the product and verify installation grounding periodically
When returning a product for calibration or repair, make sure it
Chapter 2 – Product Overview
CAUTION!
Do not attempt to open the probe body. There are no user
serviceable parts inside the probe body.
2.4 ESD Protection
Electrostatic Discharge (ESD) can cause immediate or latent damage to electronic circuits.
Vaisala products are adequately protected against ESD for their intended use. However, it is
possible to damage the product by delivering an electrostatic discharge when touching,
removing or inserting any objects inside the equipment housing.
Avoid touching component contacts or connectors when working with the device.
2.5 Measured Parameters
Table 4 Available Parameters
ParameterUnit
Vaporized hydrogen peroxide concentration by
volume
Relative saturation (RS) (H2O + H2O2)%RS
Relative humidity (RH) (H2O)%RH
Temperature°C
Absolute hydrogen peroxide
Absolute humidity (H2O)
Water concentration by volumeppm
Water vapor pressurehPa
Water vapor saturation pressurehPa
ppm
mg/m
g/m
3
3
The probe provides both digital and analog outputs.
• In digital output mode, the probe outputs all the measurement parameters.
• In analog output mode, the probe outputs the readings of two measurement parameters
(one parameter in each analog output channel). These measurement parameters are
chosen at the time of ordering the probe, and you can change them using Insight
software and via Modbus. The probe is also compatible with Vaisala Indigo transmitters,
which provide the option of three analog output channels.
9
%RH%RS
00
100100
H2O
H2O
2
%RS%RH
00
100
100
H2O
12
HPP272 User GuideM211972EN-B
More Information
‣
Understanding Relative Humidity and Relative Saturation (page 10)
‣
Measurement Data Registers (page 47)
‣
Configuration Registers (page 48)
‣
Connectivity to Vaisala Insight Software (page 12)
‣
Setting Probe in Analog or Digital Mode (page 23)
2.5.1 Understanding Relative Humidity and Relative Saturation
Water and hydrogen peroxide have a very similar molecular structure, and they both aect the
humidity of the air in which they are present. HPP272 measurement makes a
between the humidity caused by both H2O2 vapor and water vapor, and the humidity caused
only by water vapor:
• Relative saturation is a parameter that indicates the humidity of the air caused by both
H2O2 vapor and water vapor. When relative saturation reaches 100 %RS, the vapor
mixture starts to condense.
• Relative humidity is a parameter that indicates the humidity of the air caused only by
water vapor.
dierence
Figure 2 Eect of H2O and H2O2 on relative saturation (RS) and relative humidity (RH)
Space without H2O2 vapor. When H2O2 vapor is not present, relative saturation equals
1
relative humidity.
2Same space with H2O2 vapor introduced. Relative saturation is higher than relative
humidity.
During H2O2 bio-decontamination processes, it is often important to monitor the possibility of
condensation. For this purpose, it is not enough to know the level of relative humidity (RH),
because RH only indicates the humidity caused by water vapor. The possibility of
condensation is
aected by the combined humidity of H2O2 vapor and water vapor, which is
why you need to monitor relative saturation (RS).
10
Chapter 2 – Product Overview
2.6 Probe Filter
The white filter on the probe covers the PEROXCAP sensor. The filter is made of porous PTFE
that allows ambient air to reach the PEROXCAP sensor while protecting the sensor in strong or
turbulent air flow.
CAUTION!
broken, dirty, or removed altogether, measurement does not work as intended.
• Do not touch the
use clean gloves (rubber, cotton or similar material).
• Keep the
• Do not touch any parts under the filter. Touching parts under the filter may
damage the sensors.
More Information
‣
Problems and Their Possible Solutions (page 36)
2.7
Chemical Purge
Chemical purge is a 4-minute process where the sensors are heated to remove possible
contamination. The purge is essential for the long-term performance and accuracy of the
probe in demanding H2O2 environments. During the purge, only temperature measurement is
available.
The purge is automatically performed:
• At probe start-up.
• At intervals (default 24 hours,
software, Modbus, or Indigo 200 transmitters). Purge is postponed by 30 minutes if H2O
is present or RH is not steady.
Purge is recommended at least every 24 hours of powered-on time, even if the probe has not
been continuously exposed to H2O2.
Optional: if needed, you can also trigger a purge manually with Modbus (in digital mode) or
pin #5 on the M12 connector (in analog mode).
The filter is an essential part of the measurement. If the filter is
filter with bare hands. If you need to touch the filter, always
filter free of any grease or oil.
configurable between 1 hour ... 1 week using Vaisala Insight
2
More Information
‣
Triggering Purge in Analog Mode (page 27)
‣
Operation in Analog Mode (page 26)
11
HPP272 User GuideM211972EN-B
2.8 Environmental Compensation for Pressure
When necessary, you can apply pressure compensation to improve the measurement accuracy
of the probe (probe software v.1.1.0 and later). The probe does not have on-board pressure
measurement, but a pressure reading from an external source can be used as a setpoint value
for compensation.
You can configure the pressure compensation parameters using Vaisala Insight software,
Modbus configuration registers, or an Indigo 200 transmitter.
By default, the pressure compensation is turned o. When the compensation is o, the probe
uses the default compensation value (1013.25 hPa).
Pressure compensation
• H2O2 concentration (ppm)
• H2O concentration (ppm)
• Relative saturation (%RS)
More Information
‣
Vaisala Insight Software (page 28)
‣
Configuration Registers (page 48)
2.9
Measurement Filtering Factor
You can set a filtering factor that aects the speed at which the latest H2O2 and RS
measurements are integrated into the output of the probe. This allows averaging the output if
the measuring environment produces occasional exceptionally high or low readings.
filtering factor can be set either with Modbus configuration register 0308
The
Insight software, or an Indigo 200 transmitter.
By default, the
directly in the output, without any filtering. To apply filtering, enter a lower filtering factor to
include previous measurements in the calculation of measurement output. For example,
changing the
measurement (90%) and the previous measurement output (10%).
filtering factor to 0.9 results in an output that is a combination of the latest
aects the following parameters:
, Vaisala
hex
filtering factor is set to 1.0, which means the latest measurement is shown
More Information
‣
Configuration Registers (page 48)
2.10
Connectivity to Vaisala Insight Software
The probe can be connected to Vaisala Insight software using a Vaisala USB cable (no.
242659). With the Insight software, you can:
• See device information and status.
12
Chapter 2 – Product Overview
• See real-time measurement.
• Configure serial communication settings, purge settings, filtering factor, and analog
output parameters and scaling.
More Information
‣
Connecting to Insight Software (page 28)
2.11 Additional Features with Indigo Transmitters
The probes are compatible with Vaisala Indigo 200 transmitters starting from Indigo
transmitter serial number N4650357 (Indigo 200 transmitter software version 1.3.2 or higher).
Connecting the probe to an Indigo transmitter provides a range of additional options for
outputs, measurement viewing, status monitoring, and
Examples of additional features available with Indigo transmitters include:
• 3.5” TFT LCD color display or non-display model with LED indicator
• Digital output or 3 analog outputs (depending on the transmitter model)
• 2 configurable relays
• Wireless browser-based configuration interface for mobile devices and computers (IEEE
802.11 b/g/n WLAN)
The selection of available additional features (for example, output and connectivity options)
varies depending on the Indigo transmitter model. For more information on Indigo
transmitters, see www.vaisala.com/indigo.
More Information
‣
Indigo Overview (page 29)
configuration interface access.
13
HPP272 User GuideM211972EN-B
3. H2O2 Measurement
3.1 Operating Principle of H2O2 Measurement
CAUTION!
always be powered on. When powered on, the PEROXCAP sensor is heated,
which permits using the probe in condensing H2O2 conditions, maintains
measurement performance, and lengthens the probe's lifetime. When the probe
is powered o, exposure to H2O2 condensation can break the PEROXCAP sensor
within a day, and the sensor will not recover.
PEROXCAPâ sensor technology works using measurements from two Vaisala HUMICAPâ
sensors. HUMICAP sensors guarantee quality and reliability, with their reputation for
repeatability, accuracy, excellent long-term stability, and negligible hysteresis – even in the
most demanding high-concentration H2O2 applications in atmospheric pressure.
HUMICAP sensor is a
polymer film is deposited between two electrodes. The film absorbs or releases vapor
according to humidity changes in the environment. As the humidity changes, the dielectric
properties of the polymer
instrument’s electronics measure the capacitance of the sensor and convert it into a humidity
reading.
PEROXCAP measurement uses two composite HUMICAP sensors, one with a catalytic layer
and one without. The catalytic layer catalyzes H2O2 from the vapor mixture. Therefore, the
HUMICAP sensor with this layer only senses water vapor, providing a measurement of partial
water pressure, i.e. relative humidity (RH). The sensor without the catalytic layer senses both
hydrogen peroxide vapor and water vapor in the air mixture. The
readings from these two sensors indicates the vapor concentration of H2O2.
When there is H2O2 in the probe's environment, the probe must
thin-film polymer sensor consisting of a substrate on which a thin
film change, and so does the capacitance of the sensor. The
dierence between the
14
H20
2
H20
2H20
0
2
2H20
2
H20
2
1
3
2
3
AB
Chapter 3 – H2O2 Measurement
Figure 3 Operating principle of PEROXCAP measurement
HUMICAP sensor with a catalytic layer (under the probe filter). This sensor only senses
A
water vapor.
BHUMICAP sensor without a catalytic layer (under the probe filter). This sensor senses the
air mixture with both hydrogen peroxide vapor and water vapor.
1Catalytic layer over the thin film polymer. This layer catalyzes hydrogen peroxide into
water and oxygen and prevents it from entering the sensing polymer.
2Thin film polymer between two electrodes.
3Alumina substrate.
In addition to measuring vaporized H2O2 concentration, HPP272 provides measurement for
relative saturation, relative humidity, and temperature. Relative humidity (RH) is a parameter
that indicates the humidity value derived from water vapor only, whereas relative saturation
(RS) indicates the humidity percentage derived from water vapor and H2O2 vapor together.
When relative saturation reaches 100 %RS, the vapor mixture starts to condense.
15
HPP272 User GuideM211972EN-B
3.2 Typical Applications
The probe is not intended for safety level measurement.
The probe is not intended to be used in vacuum applications.
Vaporized hydrogen peroxide is used for bio-decontamination in several applications from
healthcare and pharmaceutics to food and beverage industry. Vaporized hydrogen peroxide is
an easy-to-use and eective bio-decontaminating agent that destroys the full spectrum of
biological contaminants including micro-organisms such as bacterial spores, mycobacteria,
and non-enveloped, non-lipid viruses. Bio-decontamination with vaporized hydrogen peroxide
is a low-temperature, environmentally friendly process that leaves no real residues, only water
vapor and oxygen. One of the
validated.
Common vaporized H2O2 bio-decontamination applications include isolators, transfer hatches,
closed Restricted Access Barrier Systems, and room bio-decontamination (for example, in
hospital environments, cleanrooms, decontamination tents, aircrafts, ships, and shipping
containers).
The bio-decontamination process typically has the following phases:
1. Optional dehumidification, where relative humidity is decreased to a desired level, for
example, by warming the space.
2. Conditioning, where vaporized H2O2 mixture is introduced into the space to be biodecontaminated.
3. Decontamination, where H2O2 concentration is maintained at a desired level for a certain
time.
4. Aeration, where H2O2 is removed from the bio-decontaminated space.
benefits also is that the bio-decontamination process can be
16
100%
0%
More
Less
Cycle Phase
Aeration
Decontamination
Conditioning
Dehumidification
CONDENSATION POINT
RELATIVE
SATURATION (RS)
RELATIVE HUMIDITY (RH)
VAPORIZED HYDROGEN
PEROXIDE CONCENTRATION
Humidity
H2O
2
Concentration
Chapter 3 – H2O2 Measurement
Figure 4 Example behavior of H2O2 concentration, relative saturation (RS), and relative humidity
(RH) in a vaporized H2O2 bio-decontamination cycle (non-condensing conditions)
In the non-condensing bio-decontamination cycle example shown in Figure 4 (page 17):
• In the dehumidification phase, RH (and RS) decreases.
• When the conditioning phase starts, H2O2 concentration rises rapidly. There is also a rapid
increase in RS, which indicates the humidity caused by both H2O2 vapor and water vapor.
Because the generated H2O2 vapor is typically mixed with water vapor, RH also starts to
rise.
• In the decontamination phase, H2O2 concentration is steady. However, RS level rises slowly
close to 100 %RS, i.e. condensation point, due to rising RH level.
• In the aeration phase, H2O2 concentration, RS, and RH all decrease. When H2O
2
concentration is zero, RS equals RH.
The way your bio-decontamination process is designed
measure in dierent phases.
Depending on your bio-decontamination process, you may also want to either create or avoid
condensation during the conditioning and decontamination phases. In these phases, the air in
the bio-decontaminated space always contains both water and H2O2 vapor, which both
the possibility of condensation. To monitor and control whether and when condensation
forms, it is useful to know the combined humidity level of water vapor and H2O2 vapor: relative
aects which parameters you want to
saturation (RS). When relative saturation reaches 100 %RS, the vapor mixture starts to
condense.
aect
17
Temperature
Relative saturation
2121.52222.5
100
95
85
90
H2O2 = 500 ppm
H2O = 8850 ppm
HPP272 User GuideM211972EN-B
For condensation monitoring, choosing the right measurement location is very important. If
the bio-decontaminated space has surfaces with a lower temperature than where RS is
measured, condensation may start to form on those surfaces even before RS reaches 100 %RS
in the exact measurement location. To monitor the possibility of condensation, consider
installing the probe close to a surface where you suspect condensation may form.
More Information
‣
Understanding Relative Humidity and Relative Saturation (page 10)
‣
Installation (page 20)
3.3 Condensation Monitoring
H2O+H2O2 vapor mixture starts to condense when relative saturation (RS) reaches 100 %RS.
RS level is strongly aected by temperature: decreasing the temperature increases RS. If there
are temperature
that space even if the H2O+H2O2 vapor is evenly distributed.
dierences in the bio-decontaminated space, RS varies in dierent parts of
Figure 5 Example: RS behavior in dierent temperatures when H2O2 concentration (500 ppm) and
H2O concentration (8850 ppm) are constant
For condensation monitoring, this means that even if you measure < 100 %RS in one point, RS
may be 100 %RS in another, cooler point. The following
can vary in a decontaminated space according to temperature dierences.
18
figure shows an example of how RS
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