Safety Data Sheet
SECTION 1: IDENTIFICATION
Product Identifier: Black Matrix INK (T1) – P/N 259880-001
Product Code(s): 7660 with Surfactant
Product Use: Printronix P/N 081905,
107675-001/005/007/008, 141587-005/006, 141590-007/008,
175006-001, 175220-001, 175566-001, 176530-001, 179006-001, 179499-001, 254082-001, 254139-001, 255048401/402/402-WM/4GM, 255049-101/102/103/1GM,
255050-401/402, 255051-001/002/103/, 255162-001, 255165-001, 255661-101/102/103/104,
255670-401/402/403/404, 256109-104, 256110-104, 256111-404, 256976-403, 256977- /403, 257854-104, 2580644GC, 259885-104, 259885-104-R, 259886-104, 259886-104-R, 259887-104, 259888-104, 259889-104, 259890-104-R,
259890-404, 259891-104-R, 259891-404, 259892 -404, 259893-404, 259894-104, 41U1680, 41U1680-PTX, 41U1682PTX, 44A507014-G08B, 44A5091 60 - G03,
45U3891, 45U3891-PTX, 45U3895, 45U3895-PTX, 4A0040B02, 4A0040B05, 4A0040B13, P7EL30-004, P7UCX90V06,
Chemical Family: Mixture
Manufacturer’s name and address: Printronix L LC.
15345 Barranca Parkway
Irvine, CA 92618
Information Telephone #: 1 (714) 368-2300
24 Hr. Emergency Telephone #: CHEMTREC at 1-800-
SECTION 2:
HAZARDS IDENTIFICATION
080294, 080296, 082285, 083844, 09004294, 09005591, 09005660,
424-9300 or International at 1-703-527-3887.
Classification:
Skin irritation
Eye irritation
Reproductive toxicity
Acute aquatic toxicity
Chronic aquatic toxicity
Carcinogenicity
Category 2
Category 2B
Category 2
Category 2
Category 2
Category 2
Labeling: Symbols:
Signal Word: Danger
Hazard statements:
H315
H319
H351
H361
H401
H411
Precautionary statements:
P202
P264
P273
P281
Do not handle until all safety precautions have been read and understood
Wash skin thoroughly after handling
Avoid release to the environment
Use personal protective equipment as required
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305+351+338
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362
P501
185423-000 Rev F Page 1 of 8
IF IN EYES: Rinse continuously with water for several minutes.
Remove contact lenses if present and easy to do –
Take off contaminated clothing and wash before reuse.
Dispose of contents/container to an approved waste disposal plant
Causes skin irritation
Causes serious eye irritation
Suspected of causing cancer
Suspected of damaging fertility or the unborn child
Toxic to aquatic life
Toxic to aquatic life with long lasting effects
continue rinsing
P337 +
Safety Data Sheet
Hazard
Statements
Solvent Black 7 Dye
8005-02-5
10 - 20
Serious Eye Irritation (Cat 2)
H319
(4
Methyl Ricinoleate
141-24-2
5 - 10
Toxic to aquatic life
H401
SECTION 3: COMPOSITION / INFORMATION INGREDIENTS
Ingredients CAS # Wt. % GHS Classification
Oleic Acid
2,2-Methylenebis
-methyl-6-teriarybuty1 phenol)
Mineral Oil Base Black
Aniline
112-80-1
119-47-1
62-53-3 <0.20
40 - 60
<1
5 – 10
<0.2
Skin Irritation (Cat 2)
Reproductive Toxicity (Cat. 2)
Chronic aquatic toxicity (Cat. 4)
Toxic to aquatic life
Carcinogeni city (Cat 2)
H315
H361
H413
H401
H351
SECTION 4: FIRST AID MEASURES
Inhalation:
Immediately remove person to fresh air. If breathing has stopped, give artificial respiration. If breathing is
difficult, give oxygen by qualified medical personnel only. Seek immediate medical attention/advice.
Skin contact: Immediately flush with plenty of water, while removing contaminated clothing. When symptoms persist or
in all cases of doubt, seek medical advice.
Eye contact: Flush eyes with water for at least 15 minutes while holding eyelids open. When symptoms persist or in all
cases of doubt, seek medical advice.
Ingestion:
Seek immediate medical attention/advice. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. If vomiting occurs spontaneously, keep victim’s head lowered (forward) to reduce the
risk of aspiration.
Notes for physician: Treat symptomatically.
SECTION 5: FIRE FIGHTING MEASURES
Suitable extinguishing media: Dry chemical, foam, carbon dioxide and water fog
Fire hazards/conditions of flammability: This material is not flammable.
Explosion data: Sensitivity to mechanical impact / static discharge: Not expected to be sensitive to mechanical impact or static
discharge.
Special fire-fighting procedures/equipment:
Firefighters should wear protective equipment and self-contained breathing apparatus with
full face piece operated in positive pressure mode. Move containers from fire area if safe
to do so. Water spray may be useful in cooling equipment exposed to heat and flame.
Hazardous combustion products: Oxides of carbon and nitrogen, irritating fumes and smoke.
NFPA Rating: Health: 2 Flammability: 1 Instability: 0 Special Hazards: 0
185423-000 Rev F Page 2 of 8
Pictograms
Safety Data Sheet
Control
Parameters
Methemoglobinemia
Danger of cutaneous absorption
5 ppm
2 ppm
8 mg/m3
USA OSHA Table Z-1
Limits for Air Contaminants – 1910.1000
2 ppm
8 mg/m3
USA OSHA Table Z-1
Limits for Air Contaminants – 1910.1000
Remarks
Skin notation
Potential Occupational Carcinogen
See Appendix A
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal precautions: All persons dealing with clean-up should wear the appropriate protective equipment. Do
not eat, drink or smoke while participating in clean up.
Environmental precautions: Ensure spilled product does not enter drains, sewers, waterways or confined spaces. For
large spills, dike the area to prevent spreading.
Spill response/cleanup: Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g.
sand), then place absorbent material into a container for later disposal (see Section 13).
Notify the appropriate authorities as required.
Prohibited materials: None specific
Special spill response procedures: In case of a transportation accident, in the United States contact CHEMTREC at 1-800-
424-9300 or International at 1-703-527-3887.
SECTION 7: HANDLING AND STORAGE
Precautions for safe handling: Wear suitable protective equipment during handling. Do not ingest. Avoid contact with
skin, eyes and clothing. Wash thoroughly after handling.
Conditions for safe storage: Store in a cool, dry, well-ventilated area. Store away from incompatibles, temperature
extremes and out of direct sunlight. Inspect periodically for damage or leaks.
Incompatible materials: Strong oxidizing agents; strong reducing agents; acids
Special packaging materials: Always keep in containers made of the same materials as the supply container.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Components with workplace control parameters:
Component CAS No. Value
Aniline 62-53-3 TWA 2 ppm USA ACGIH Threshold Limit Values (TLV)
Remarks
Confirmed animal carcinogen with unknown
Source
relevance to humans
TWA
TWA
TWA
185423-000 Rev F Page 3 of 8
19 mg/m3
Remarks Skin contact does contribute to exposure
Remarks Skin contact does contribute to exposure
Remarks
USA OSHA Table Z-1
Limits for Air Contaminants
Safety Data Sheet
Ventilation and engineering measures: Use general or local exhaust ventilation to maintain air concentrations
recommended exposure limits.
below
Respiratory protection: If the TLV is exceeded, a NIOSH/MSHA-approved respirator is advised. Confirmation of
which type of respirator is most suitable for the intended application should be obtained
from respiratory protection suppliers.
Skin protection: Impervious gloves must be worn when using this product. Advice should be sought
glove suppliers.
from
Eye / face protection: Good industrial hygiene practices should be used when handling this product including
preventing eye contact and minimizing skin contact and inhalation.
Other protective equipment: As needed to prevent eye contact and minimizing skin contact and inhalation.
General hygiene considerations: Avoid breathing vapor or mist. Avoid contact with skin, eyes and clothing. Do not eat,
drink, smoke or use cosmetics while working with this product. Upon completion of
work, wash hands before eating, drinking, smoking or use of toilet facilities. Remove
wash contaminated clothing before re-use.
and
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Appearance:
Odor:
Black liquid
Mild
Odor Threshold: N/Av
Specific Gravity: 0.9
pH:
Boiling point: >300
Not applicable
o
F
Melting/Freezing point: Not available
Coefficient of water/oil distribution: Not available
Vapor pressure (mm Hg @ 20oC / 68oF): Not available
Vapor density (Air = 1): Heavier than air
Evaporation rate (n-Butyl acetate = 1): Slower than n-Butyl
acetate
Flash Point >200
Solubility in water: Slightly
o
F, TCC
Auto-ignition temperature Not
applicable
applicable
applicable
Lower flammable limit (% by vol) Not
Upper flammable limit (% by vol) Not
Flame Projection Length Not available
Flashback observed Not available
SECTION 10: STABILITY AND REACTIVITY
Chemical stability: Stable under the recommended storage and handling conditions prescribed.
Possibility of hazardous reactions: None are known.
Conditions to avoid: Avoid heat and open flame.
Materials to avoid and incompatibility: See Section 7 (Handling and Storage) for further details.
Hazardous decomposition products: None known; refer to hazardous combustion products in Section 5.
185423-000 Rev F Page 4 of 8
Safety Data Sheet
Routes of exposure:
Inhalation:
Vapors and spray mist may irritate throat and respiratory
system and cause coughing
Skin contact:
May be harmful in contact with skin. Defats the skin. May
cause redness and pain.
Eye contact:
Corrosive. Prolonged contact causes serious eye and tissue
damage.
Ingestion:
Not expected to be a route of exposure with proper use. May
be harmful if swallowed. Liquid irritates mucous membranes
and may cause abdominal pain.
Ingredient
LD
LD
Skin corrosion/irritation Serious eye damage/eye irritation
Aniline
IARC:
3 – Group 3: Not classifiable as to its carcinogenicity
to humans
NTP:
No component of this product present at levels greater
than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater
than or equal to 0.1% is identified as a known or
anticipated carcinogen by OSHA.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicological data: There is no available data for the mixture itself, only for the ingredients. See below
for individual ingredient acute toxicity data.
50
Oral, rat Rabbit, dermal Skin, rabbit Eyes, rabbit
50
Oleic acid
Sorbitan trioleate
Aniline
4-(phenylazo)benzene-1,3-
diamine
74,000 mg/kg No data available Human – Skin irritation – 3 d Mild eye irritation
No data available No data available Skin irritation – 24 h Mild eye irritation
250 mg/kg 820 mg/kg Skin irritation – 24 h Severe eye irritation
1,650 mg/kg No data available No data available Moderate eye irritation – 24 h
Carcinogenic status: This product contains a component that has been reported to be possibly carcinogenic
based on its IARC, ACGIH, NTP or EPA classification.
Reproductive effects: No information found
Teratogenicity:
No information found
Germ Cell Mutagenicity: 4-(phenylazo)benzene-1,3-diamine
Aniline
Rat – Liver - Unscheduled DNA synthesis
Laboratory experiments have shown mutagenic effects In vitro tests showed mutagenic
effects.
Epidemiology:
No information found
Specific target organ toxicity – single exposure: 4-(phenylazo)benzene-1,3-diamine
Inhalation – May cause respiratory irritation
Conditions aggravated by overexposure: No information found
185423-000 Rev F Page 5 of 8
Aniline
Toxicity to fish:
LC
50
Oncorhynchus mykiss
10.96 mg/l
96 h
Toxicity to aquatic invertebrates:
EC
Daphnia magna (water flea)
80 - 380 mg/l
48 h
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity:
4-(phenylazo)benzene1,3-diamine:
Safety Data Sheet
No data is available on the mixture itself.
Toxicity to fish: LC
Oryzias latipes 0.3 mg/l 48 h
50
Oleic acid: Toxicity to fish: LC
Toxicity to algae:
EC
Fathead Minnow 205 mg/l 96 h
50
50
50
Selenastrum
19 mg/l
Mobility:
Persistence:
Bioaccumulation potential: No data is available on the mixture itself.
Other adverse environmental effects: The ecological characteristics of this mixture have not been fully investigated.
SECTION 13: DISPOSAL CONSIDERATIONS
Disposal recommendations: Do not discharge into drains, water courses or onto the ground. Disposal
Hazardous Waste Code /RCRA: Not regulated.
SECTION 14: TRANSPORT INFORMATION
No data is available on the mixture itself.
No data is available on the mixture itself.
recommendations are based on material as supplied. Disposal must be in accordance with
current applicable laws and regulations, and material characteristics at time of disposal.
72 h
This material is not UN / IATA regulated.
This material is not classified as ICAO/IATA-DGR Dangerous Goods.
This material is not classified as hazardous per the IMDG Code.
This material is not classified as hazardous per ADR.
This material is not classified as hazardous per the U.S. Department of Transportation (DOT).
This material is not UN / IATA regulated.
Marine Pollutant: No
185423-000 Rev F Page 6 of 8
Safety Data Sheet
HMIS Rating:
Health: *2
Flammability: 1
Reactivity: 0
*Chronic hazard
0 - Minimal
1 - Slight
2 - Moderate
3 - Serious
4- Severe
Legend:
ACGIH
American Conference of Governmental Industrial Hygienists
CAS
Chemical Abstract Services
CERCLA
Comprehensive Environementa; Response, Compensation, and Liability Act of 1980
CFR
Code of Federal Regulations
DOT
Department of Transportation
EPA
Environme ntal Protect i on Agency
HMIS
Hazardous Material Identifications System
HSDB
Hazardous Substances Data Bank
IARC
International Agency for Research on Cancer
Inh
Inhalation
MSHA
Mine Safety and Health Administration
NFPA
National Fire Protection Associa tion
NIOSH
National Institute of Occupational Safety and Health
NTP
National Toxicology Program
OSHA
Occupational Safety and Health Administration
SECTION 15: REGULATORY INFORMATION
Inventory Status: All listed ingredients appear on the Toxic Substances Control Act (TSCA) Inventory, EINECS/ELINCS,
AICS, and DSL.
This material is classified as hazardous under OSHA regulations (29CFR 19410.1200). See Section 2.
SARA 302: Sec. 302, Extremely Hazardous Substances, 40 CFR 355: Aniline < 0.2% CAS No. 62-53-3
SARA 311/312 : Acute Health Hazard, Chronic Health Hazard
SARA 313: Subject to reporting levels established by SARA Title III, Section 313: Aniline < 0.2% CAS No. 62-53-3
RCRA CODE: None
Hazardous Air Pollutants (HAPS): Aniline < 0.2%
US State “Right to Know” Laws:
California Proposition 65:
Other US State “Right To Know” Lists:
The following chemicals are specifically listed by individual states: 4-(phenylazo)benzene-1,3-diamine (NJ, PA)
International Information:
Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL).
Aniline
CAS No. 62-53-3 <0.2%
Oleic acid (PA, NJ)
Sorbitan trioleate (NJ, PA)
Aniline (MA, PA, NJ)
SECTION 16: OTHER INFORMATION
185423-000 Rev F Page 7 of 8
Safety Data Sheet
PEL
Permissible exposure limit
RCRA
Resource Conservation and Recovery Act
RTECS
Registry and Toxic Effects of Chemical Substances
SARA
Superfund Amendments a nd Reauthoriz ation Act
STEL
Short Term Exposure Limit
TDG
Canadian Transportation of Dangerous Goods Act and Regulations
TLV
Threshold Limit Values
TPQ
Threshold Planning Quantity
TSCA
Toxic Substances Contro l Act
TWA
Time Weighted Average
WHMIS
Workplace Hazardous Materials Identification System
References:
1.
ACGIH, Threshold Limit Values and Biological Exposure Ind ic es
2.
International Agency for Research on Cancer Monographs
3.
Canadian Centre for Occupational Health and Safety, CCInfoWeb databases (Chempendium, HSDB and
RTECs) 4.
Material Safety Data Sheets for manufacturers
5.
US EPA Title III List of Lists
6.
California Proposition 65 List
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
in any process, unless specified in the text.
of its publication. The information given is designed only as guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials or
185423-000 Rev F Page 8 of 8
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