Dear Customer,
Thank you for choosing a Hanna Product. Please read this
instruction manual carefully before using the instrument. It will
provide you with the necessary information for a correct use of the
instrument, as well as a precise idea of its versatility. If you require
further technical information, do not hesitate to e-mail us at
tech@hannainst.com.
CE DECLARATION OF CONFORMITY ......................................... 39
Manufacturers since 1978
These Instruments are in
Compliance with the CE Directives
2
PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION
PRELIMINARY EXAMINATION
PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION
Remove the instrument from the packing material and examine it
carefully to make sure that no damage has occurred during shipping.
If there is any noticeable damage, notify your Dealer immediately.
Note: Save all packing materials until you are sure that the instru-
ment functions correctly. Any damaged or defective item must
be returned in its original packing materials together with the
supplied accessories.
GENERAL DESCRIPTIONGENERAL DESCRIPTION
GENERAL DESCRIPTION
GENERAL DESCRIPTIONGENERAL DESCRIPTION
These waterproof Hanna instruments are heavy-duty pH meters
designed to provide laboratory results and accuracy under harsh
industrial conditions.
HI 9023C, pH/mV/°C meter utilizes an advanced customized microprocessor. The meter has three memorized buffer values (4.01, 7.01
and 10.01) and automatic buffer recognition to avoid errors during
calibration. There are no trimmers, making calibration an easy
process, even for non-technical personnel. Temperature effects are
automatically compensated for, or can be manually adjusted. With
HI 9023CHI 9023C
HI 9023C you can also measure ORP (Oxidation Reduction Poten-
HI 9023CHI 9023C
tial) or Ion Specific. Millivolt measurements automatically switch from
0.1 to 1 mV resolution when the reading reaches 400mV.
HI 9023C is supplied with HI 1230B combination double-junction gel
pH electrode, HI 7669/2W temperature probe, pH 4.01 and 7.01 (20
mL each) buffer solutions, sample vessel, 1.5V AA size batteries (4
each) and a rugged carrying case.
HI 9023CN, pH/mV/°C meter utilizes an advanced customized
microprocessor. The meter has three memorized buffer values (4.01,
7.01 and 10.01) and automatic buffer recognition to avoid errors
during calibration. Temperature effects are automatically compensated for.
HI 9023CN
electrode, pH 4.01 and 7.01 (20 mL each) buffer solutions, sample
vessel, 1.5V AA size batteries (4 each) and a rugged carrying case.
HI 9024C and HI 9025C are pH/°C meters with a built-in microprocessor. A large dual-level LCD displays the pH and temperature
simultaneously. The display has graphic symbols to make the calibration procedure easy to follow. The meters have 5 memorized buffer
is supplied with HI 1217D 4-in-1 amplified, gel pH/ C
values (4.01, 6.86, 7.01, 9.18 and 10.01), buffer recognition to
avoid errors during calibration and automatic temperature compensation. You can use HI 9025C with ORP (Oxidation Reduction Potential)
or Ion Specific Electrodes. Millivolt measurements automatically switch
from 0.1 to 1 mV resolution when the reading reaches 400 mV. To
insure trouble-free operation, the meter's circuitry comes with built-in
protection against electromagnetic interference.
HI 9024C and HI 9025C are supplied with HI 1230B combination
double-junction, gel pH electrode, HI 7669/2W temperature probe,
pH 4.01 and 7.01 (20 mL each) buffer solutions, sample vessel, 1.5V
AA size batteries (4 each) and a rugged carrying case.
HI 9110 pH meter has simple manual temperature compensation
and calibration which make this meter easy to use in laboratory and
field. The calibration trimmers are sealed behind a protective cover so
that they cannot be accidentally moved or readjusted by unauthorized
persons.
HI 9110 is supplied with FC 100B combination double-junction,
refillable pH electrode, calibration screwdriver, 1.5V AA size batteries
(4 each) and a soft carrying case.
HI 9210 pH meter has simple manual temperature compensation
and calibration with only two buttons, making it simple to use for
even non-technical personnel. The calibration trimmers are sealed
behind a protective cover so that they cannot be accidentally moved or
readjusted by unauthorized persons.
HI 9210 is supplied with HI 1230B combination double-junction, gel
pH electrode, calibration screwdriver and 1.5V AA size batteries (4
each).
HI 9210NpH/°C meter measures both pH and temperature. It has
only two buttons, making it simple to use for even non-technical
personnel. The calibration trimmers are sealed behind a protective
cover so that they cannot be accidentally moved or readjusted by
unauthorized persons.
HI 9210N is supplied with HI 1217D 4-in-1, gel, amplified pH/ C
electrode, calibration screwdriver and 1.5V AA size batteries (4 each).
3
4
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
HI 9023C & HI 9023CNHI 9023C & HI 9023CN
HI 9023C & HI 9023CN
HI 9023C & HI 9023CNHI 9023C & HI 9023CN
1) Electrode connector (BNC for HI 9023C and DIN for HI 9023CN)
Temperature Probe HI 7669/2W (incl.)not necessary
Input Impedance1012 Ohm
Battery Type & Life4x1.5V, AA size (alkaline batteries)
approx. 400 hours of continuous use
auto-shut off after 10 minutes of non-use
Environment0 to 50 C (32 to 122 F); 100% RH
Dimensions196x80x60 mm (7.7x3.1x2.4") (meter)
340x230x80 mm (13.8x9x3.1") (kit)
Weight425 g (15 oz.) (meter)
1.3 Kg (3.0 lb.) (kit)
5
6
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
HI 9024C & HI 9025CHI 9024C & HI 9025C
HI 9024C & HI 9025C
HI 9024C & HI 9025CHI 9024C & HI 9025C
1) BNC electrode connector
2) Temperature probe socket
3) Liquid Cristal Display
4) RANGE key to select pH or mV (HI 9025C only)
5) ON/OFF key to turn the meter on or off
6) CAL key to enter or exit calibration mode
7) CFM key to confirm calibration
8)ϰC andÐ
selecting pH buffer value
9) MEM key to store pH value in memory
10) MR key to recall the stored value from memory
11) User-friendly graphic symbols
12) Primary display
13) Secondary display
C C
C keys for manual temperature setting, or
C C
SPECIFICATIONS HI 9024C & HI 9025CSPECIFICATIONS HI 9024C & HI 9025C
SPECIFICATIONS HI 9024C & HI 9025C
SPECIFICATIONS HI 9024C & HI 9025CSPECIFICATIONS HI 9024C & HI 9025C
HI 9024CHI 9025C
Range0.00 to 14.00 pH; 0.0 to 100.0 C
—0.0/±399.9 mV (ISE)
—
Resolution0.01 pH; 0.1 C
—0.1 mV (ISE)
— 1 mV (ORP)
Accuracy±0.01 pH; ±0.5 C
(@20°C/68°F)—±0.2 mV (ISE)
Typical EMC±0.01 pH; ±0.1 C
Deviation—±0.3 mV (ISE)
CalibrationAutomatic with 5 memorized standard
buffers (4.01, 6.86, 7.01, 9.18, 10.01)
Offset Calibration±1 pH
Slope CalibrationFrom 70 to 108%
TemperatureAutomatic or manual from 0 to 100 C
Compensation (32 to 212 F)
ElectrodeHI 1230B pH electrode (included)
Temperature ProbeHI 7669/2W (included)
Input Impedance1012 Ohm
Battery Type & Life4x1.5V, AA size (alkaline batteries)
approx. 400 hours of continuous use
auto-shut off after 10 minutes of non-use
Environment0 to 50 C (32 to 122 F); 100% RH
Dimensionsmeter: 196x80x60 mm (7.7x3.1x2.4")
kit: 340x230x80 mm (13.8x9x3.1")
Weightmeter: 425 g (15 oz.)
kit: 1.3 Kg (3.0 lb.)
±
400/±1999 mV (ORP)
7
8
FUNCTIONAL DESCRIPTION HI 9110FUNCTIONAL DESCRIPTION HI 9110
FUNCTIONAL DESCRIPTION HI 9110
FUNCTIONAL DESCRIPTION HI 9110FUNCTIONAL DESCRIPTION HI 9110
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
HI 9210 & HI 9210NHI 9210 & HI 9210N
HI 9210 & HI 9210N
HI 9210 & HI 9210NHI 9210 & HI 9210N
1
2
3
4
1
5
2
3
4
5
7
6
pH
Foodcare
pH METER
6
pH
HI 9210N
ATC
pH METER
7
8
RANGE
0.00 TO 14.00 pH
ACCURACY
±0.02pH
HI 9110
OFF
SET
ON
pH
°C
9
RANGE
pH:
°C:
0.00 - 14.00
0.0 -70.0
ON/OFF
RANGE
8
9
1) Battery cover
2) BNC electrode connector
3) Offset calibration trimmer
4) Slope calibration trimmer
5) Temperature setting trimmer
6) Mode indicator
7) Liquid Crystal Display
8) ON/OFF key to turn the meter on or off
9) pH/°C SET key to select pH measurement or for manual
temperature setting
9
1) Battery cover
2) Electrode connector (BNC for HI 9210 and DIN for HI 9210N)
3) Offset calibration trimmer
4) Slope calibration trimmer
5) Temperature setting trimmer (HI 9210) or Temperature
Calibration (HI 9210N)
6) Mode indicator
7) Liquid Crystal Display
8) ON/OFF key to turn the meter on or off
9) RANGE key to visualize the temperature (HI 9210N) or for
manual temperature setting (HI 9210)
10
SPECIFICATIONS HI 9110, HI 9210SPECIFICATIONS HI 9110, HI 9210
SPECIFICATIONS HI 9110, HI 9210
SPECIFICATIONS HI 9110, HI 9210SPECIFICATIONS HI 9110, HI 9210
& HI 9210N& HI 9210N
& HI 9210N
& HI 9210N& HI 9210N
HI 9110HI 9210HI 9210N
RangepH0.00 to 14.00 pH
°C—0.0 to 70.0 C
ResolutionpH0.01 pH
°C—0.1 C
AccuracypH±0.02 pH
(@20°C/68°F) °C—±0.5 C
Typical EMCpH±0.05 pH±0.02 pH
Deviation°C—±0.5 C
CalibrationManual 2 points through trimmers
Offset Calibration±1 pH
Slope CalibrationFrom 85 to 105% of nominal value
TemperatureManual 0 to 100 CAuto 0 to 70 C
Compensation(32 to 212 F)(32 to 158 F)
ElectrodeFC 100BHI 1230BHI 1217D
pH (incl.) pH (incl.) pH/ C (incl.)
Input Impedance10
12
Ohm
Battery Type4x1.5 volt, AA size (alkaline batteries);
Life 2000 hours of continuous use
Environment0 to 50 C (32 to 122 F); 100% RH
Dimensions196 x 80 x 60 mm (7.7 x 3.1 x 2.4")
Weight320 g (11.3 oz.)
OPERATIONAL GUIDEOPERATIONAL GUIDE
OPERATIONAL GUIDE
OPERATIONAL GUIDEOPERATIONAL GUIDE
INITIAL PREPARATION
Each meter is supplied complete with batteries.
Remove the back cover, unwrap the batteries and
install them while paying attention to polarity.
HI 9023C, HI 9024C, HI 9025C:
To prepare the instrument for use connect the pH electrode and the
temperature probe to the BNC and temperature sockets on the top of
the instrument. The temperature probe can be used independently to
take temperature measurements, or it can be used in conjunction with
the pH electrode to utilize the meter's ATC capability. If the probe is
disconnected, temperature can also be set
manually with the UP and DOWN keys. To
switch the instrument on, press and hold the
or
ON/OFF key for a fraction of a second. The
meter has a built-in protection against electromagnetic interference and the delayed response
of the keys assures that the commands are not
mistaken for stray signals.
HI 9110 and HI 9210:
Connect the pH electrode to the BNC connector on the top of the
instrument and press the ON/OFF key.
HI 9210N and HI 9023CN:
°C
°C
ON/OFF
11
ON/OFF
Connect the pH/ C electrode to the DIN connector on the top of
the instrument and press the ON/OFF key.
ON/OFF
12
pH MEASUREMENTS
To take a pH measurement remove the electrode protective cap and simply submerge the
tip (4cm/1½") of the electrode and the temperature probe (wherever applicable) into the
sample to be tested.
Turn the instrument ON and if necessary, press RANGE until the
display changes to the pH mode.
ON/OFF
RANGE
Allow for the electrode to adjust to the solution and stabilize.
In order to take more accurate pH measurements, make sure that
the instrument is calibrated (see page 16).
It is recommended that the electrode is always kept wet and rinsed
thoroughly with the sample to be measured before use.
The pH reading is directly affected by temperature. In order for the
meter to measure the pH accurately, temperature must be taken in
consideration. If the sample temperature is quite different from the
temperature at which the pH electrode was kept, allow a few minutes
for a perfect thermal equilibrium between them.
HI 9023C, HI 9024C and HI 9025C:
To use the meter's Automatic Temperature Compensation feature,
submerge the temperature probe into the sample as close to the
electrode as possible and wait for a couple of minutes. If you know the
temperature of the sample to be tested you can manually compensate
for it.
If manual temperature compensation is desired the temperature
probe must be disconnected from the instrument.
The display will show the default temperature
of 25C or the last recorded temperature reading with the "C" indicator blinking.
The temperature can now be adjusted with the
UP and DOWN keys.
or
(1½
")
°C
°C
4 cm
°C
HI 9023C, HI 9023CN and HI 9210N
To use the meter's Automatic Temperature Compensation feature,
simply submerge the pH/C electrode into the sample and wait for a
couple of minutes. The pH electrode also houses the temperature
sensor which will measure and adjust for the temperature effect
automatically.
HI 9110, HI 9210:
To use the meter’s Manual Temperature Compensation feature:
Press the pH/C key of HI 9110 or the RANGE key of HI 9210 to
select the manual temperature mode.
pH
°C
SET
RANGE
°C
Remove the protective cap on top of the
meter to access the trimmers. Measure the
temperature of the buffer with a Checktemp
or an accurate thermometer.
Using the calibration screwdriver, turn the
temperature trimmer (#5 pages 9-10) to
display the measured temperature value.
Press the pH/C key of HI 9110 or the RANGE key of HI 9210 to
return to the pH measurement mode.
pH
°C
SET
RANGE
When finished, switch the instrument off and rinse the electrode
with clean water. Pour a few drops of HI 70300 storage solution,
or in its absence, pH 7 or pH 4 buffers in the protective cap and
replace it before storing away the electrode.
13
14
ORP MEASUREMENTS (HI 9023C AND HI 9025C)
To enter the "mV" mode (ORP or ISE), turn the instrument ON and
press the RANGE key until the display changes to mV.
ON/OFF
RANGE
To measure the mV of a solution simply
submerge the ORP or ISE electrode tip (4cm/
1½") into the sample to be tested. Allow a
few minutes for the readings to stabilize. See
also "Taking REDOX Measurements" section at
(1½
")
page 29.
TEMPERATURE MEASUREMENTS (HI 9023C,
HI 9023CN, HI 9024C, HI 9025C AND HI 9210N):
Taking a temperature measurement is very easy. Turn the instrument
ON and press the RANGE key to enter temperature mode.
ON/OFF
For HI 9023C, HI 9024C and HI 9025C, dip the liquid/general
purpose temperature probe HI 7669/2W into the sample. For
HI 9023CN and HI 9210N, simply dip the pH/C electrode which
contains the temperature sensor. Then allow a couple of minutes for
the reading to stabilize.
Note: You can also calibrate the offset point of the HI 9210N tem-
perature sensor, if needed. For this purpose, immerse the pH/
C electrode in a solution at a known temperature. Then turn
the #5 trimmer (see page 10) until the temperature displayed on the LCD is that of the solution.
RANGE
4 cm
pp
H CALIBRATIONH CALIBRATION
p
H CALIBRATION
pp
H CALIBRATIONH CALIBRATION
It is recommended to calibrate the instrument frequently, especially if
high accuracy is required.
The instrument should be recalibrated for pH:
a) Whenever the pH electrode or temperature probe is replaced.
b) At least once a month.
c) After testing aggressive chemicals.
d) Whenever the batteries have been replaced.
e) If greater accuracy is required.
PREPARATION
Pour small quantities of pH 7.01 and pH 4.01 solution into two clean
beakers.
HI 7004
HI 7004HI 7007
For accurate calibration use two beakers for each buffer solution, the
first one for rinsing the electrode and the second one for calibration.
This way contamination of buffer is minimized.
RINSE
HI 7007
CALIBRATION
HI 7007
To obtain accurate readings, use pH 7.01 and pH 4.01 buffers if you
are going to measure acidic samples, or pH 7.01 and pH 10.01 for
alkaline measurements.
PROCEDURE FOR HI 9023C AND HI 9023CN:
• Make sure that the meter is in the pH mode.
• Remove the protective cap from the electrode, rinse it with some pH 7.01 solution,
then immerse the pH electrode and temperature probe (
electrode (
solution and stir gently and wait for the
reading to stabilize.
HI 9023CHI 9023C
HI 9023C) or the pH/C
HI 9023CHI 9023C
HI 9023CNHI 9023CN
HI 9023CN) into pH 7.01 buffer
HI 9023CNHI 9023CN
HI 7007
15
16
Note: The electrode should be submerged
approximately 4 cm (1½") into the
solution. With the temperature probe
located as close to it as possible (
9023C9023C
9023C).
9023C9023C
HIHI
HI
HIHI
(1½
")
• Press the CAL key. The temperature compensated pH value will
blink on the display. For example, if the temperature is 25C the
reading will be pH 7.01. If the temperature is 20C the reading
CAL
will be 7.03. The pH/temperature conversion chart is on page 24.
Note: If "E4" flashes, the buffer solution is
wrong or the probe is defective (see page 25 for troubleshooting).
• Wait for the "pH" symbol to stop flashing and press the CFM
4 cm
when it is turned off.
Note: The meter will lose the calibration if
the batteries are removed.
HI 9023C only:
To calibrate with manual temperature com-
pensation, follow this procedure:
• Disconnect the temperature probe and
switch the instrument ON.
• Press RANGE to select the temperature
mode.
• Place the pH electrode into the 7.01 buffer
stir gently and wait for the LCD to stabilize.
or
°C
°C
°C
ON/OFF
RANGE
°C
HI 7007
CFM
key. The symbol "E5" will flash to indicate that the electrode is
still in the pH 7.01 buffer.
• Rinse the pH electrode (and the temperature probe) with distilled water first
and with the pH 4.01 (or 10.01) buffer
after.
HI 7004
• Dip the electrode (and the temperature
probe) into the pH 4.01 (or 10.01) buffer solution. Stir gently
and wait for the reading to stabilize.
• The "E5" symbol should disappear and the temperature compensated value will blink on the display.
For example, if you are using pH 4.01 as
the buffer, the reading will be 4.01 at
25C.
• When the "pH" symbol stops flashing,
press CFM to confirm the calibration.
CFM
The instrument is now calibrated and will remain calibrated even
17
• Record the buffer temperature by using a Checktemp C or an
and then
RANGE
CAL
accurate thermometer (e.g. 18C).
• Press the UP and DOWN to adjust the temperature accordingly.
• Press RANGE to display pH and then press the CAL key. The
value of the buffer will be displayed.
CFM
• Wait for the "pH" symbol to stop flashing.
• Press CFM. The "E5" symbol will flash
HI 7004
to indicate that the electrode is still in
the 7.01 solution.
18
• Rinse the electrode with clean or distilled water first and then
1
with pH 4.01 (or 10.01) buffer. Dip the electrode into the pH
CFM
4.01 (or 10.01) solution and stir gently.
• Wait for the "pH" symbol to stop flashing. Press CFM to
confirm the calibration.
PROCEDURE FOR HI 9024C AND HI 9025C:
In order to calibrate HI 9024C and HI 9025C, there is a choice of
5 memorized buffers: 4.01, 6.86, 7.01, 9.18 and 10.01 pH.
• Make sure that the meter is in the pH mode.
• Remove the protective cap and rinse the electrode with some of
the buffer calibration solution that you are going to use first.
ONE-POINT CALIBRATION:
It is always recommended to perform a two-point calibration for
optimum accuracy. In case of necessity, it is possible to carry out only
a one-point calibration with the instruments. The offset buffers, that is
the Standard 7.01 or the NIST 6.86 are the
most appropriate for this purpose even though
both meters can be calibrated with any of
the 5 memorized calibration solutions.
• Immerse the pH electrode into a pH
buffer solution (e.g. pH 6.86) and stir
gently.
Note: The electrode should be submerged approximately 4 cm
(1½") into the solution. With the temperature probe located
CAL
CAL
BUF
as close to it as possible.
CAL
°C
BUF
HI 7006
(1½
")
1
pH
1
pH
4 cm
• Once the electrode is submerged in the
buffer solution, the LCD will notify the
NOT READY
user if the reading is not stable by an
intermittent "NOT READY". Only when the
reading is stable, will it change to a
READY
CON
blinking "READY" and "CON".
• Press the CFM key to confirm the calibration. If the reading is not close to the
selected buffer, "WRONG
BUF
" and "WRONG
CFM
" will blink alternatively. If the reading is
close to the selected buffer, the meter
stores the reading (and adjusts the offset
point). The buffer value is then displayed
on the primary LCD and the secondary
LCD will display another buffer value
(e.g."4.01").
WRONG
WRONG
1
BUF
CAL
1
BUF
• Press the CAL key and the calibration process is ended with only the offset of the
meter calibrated. For best accuracy however, do not press CAL and proceed with a
CAL
two-point calibration.
TWO-POINT CALIBRATION
After calibrating at 6.86 or 7.01 pH (see above), for the second
buffer use pH 4.01 if you are going to measure acidic samples,
and pH 9.18 or pH 10.01 if you are measuring alkaline solutions.
• Proceed as described in “One-point calibration above but do not end the
calibration by pressing CAL.
• After the first calibration point is confirmed, immerse the pH electrode into
HI 7004
the second buffer solution (pH 4.01,
9.18 or 10.01) and stir gently.
Note: The electrode should be submerged
approximately 4 cm (1½") into the
solution with the temperature probe
(1½
")
4 cm
located as close to it as possible.
• Select the second buffer value on the
secondary display by pressing the ϰC
C C
or Ð
C key.
C C
or
°C
°C
pH
pH
19
20
°C
Note: The electrode should be submerged
approximately 4 cm (1½") into the
solution with the temperature probe
READY
CON
located as close to it as possible.
• Select the second buffer value on the secondary display by
WRONG
WRONG
BUF
CFM
pressing the ϰC or Ð
CC
C key.
CC
2
• When the “READY” and “CON” symbols blink on the display,
the reading is stable and the calibration can be confirmed.
• Press the CFM key. If the reading is not close to the selected
BUF
buffer solution, “WRONG
2
” and “WRONG ” will blink
alternatively. If the reading is close to the selected buffer, the
slope and the offset are calibrated. The values will be stored in
memory and the meter will return to the operating mode.
Note: The meter will automatically skip the buffer that was used
for the first calibration to avoid erroneous calibration. At
least 1 full pH unit is required between the two buffers used
for the offset and slope calibration. As a result, once
calibrated at either pH 6.86 or 7.01, the microprocessor will
automatically ignore the other one for the second point
calibration. It will do likewise for pH 9.18 and 10.01
Note: During calibration, the secondary LCD displays the selected
buffer value. With HI 9025C, press the RANGE key to display
the buffer temperature during calibration.
PROCEDURE FOR HI 9110, HI 9210 & HI 9210N:
Manual Temperature Compensation
Note: The pH/C electrode of HI 9210N incorporates a tempera-
ture sensor which performs automatic temperature
pH
°C
SET
RANGE
°C
• Press pH/C SET key for HI 9110 or
the RANGE key for HI 9210 to select the
manual temperature setting. The "C"
symbol will be displayed to indicate the
temperature setting mode.
°C
• Remove the protective cap on the top of the meter to have
access to the calibration trimmers.
pH
°C
SET
RANGE
• Record the temperature of the buffer with a Checktemp C or
an accurate thermometer (e.g.20C).
• Using the screwdriver, turn the temperature trimmer (# 5
pages 9-10) to display the recorded temperature value.
• Press the pH/C SET key for HI 9110
°C
or the RANGE key for HI 9210 to read
pH.
pH Calibration
HI 7007
All three meters provide for manual pH cali-
bration. As a result, you can perform
one or two point calibration at a buffer
of your choice. The instructions below
explain a typical calibration procedure at
pH 7 and then 4 or 10.
• Remove the protective cap from the electrode, rinse it with some pH 7.01 solution, then dip in pH
7.01 buffer. Stir briefly and wait for one minute for the
reading to stabilize.
Note: The electrode should be submerged approximately 4 cm
compensation. Consequently, the following 5 paragraphs
are irrelevant to HI 9210N and you can just proceed with
pH calibration below.
21
pH
22
(1½") into the solution. For HI 9110 and
HI 9210, place the thermometer close
to the pH electrode.
• Adjust the OFFSET trimmer (#3 pages 9-
10) until the LCD shows the pH value at
the buffer temperature (see page 24 for pH values at various
temperatures). With HI 9210N, press RANGE to read the buffer
temperature.
pH
• Rinse first with clean or distilled water and then with a small
amount of the next buffer (2nd calibration point). Dip the
electrode into pH 4.01 (or 10.01) buffer, stir gently and wait
until the display has stabilized.
• Adjust the SLOPE trimmer (#4 pages 9-10) until the LCD
displays the pH value at the second buffer temperature (see
page 24).
• pH calibration is now complete. Once the calibration process is
complete, replace the trimmer cover and tighten it to ensure a
proper seal against water and humidity ingress.
HI 7004
pp
H VALUES AT VARIOUSH VALUES AT VARIOUS
p
H VALUES AT VARIOUS
pp
H VALUES AT VARIOUSH VALUES AT VARIOUS
TEMPERATURESTEMPERATURES
TEMPERATURES
TEMPERATURESTEMPERATURES
Temperature has an effect on pH. The calibration buffer solutions are
affected by temperature changes to a lesser degree than normal
solutions.
For manual temperature calibration (standard with HI 9110 and
HI 9210 or optional with HI 9023C, HI 9024C and HI 9025C)
please refer to the following chart.
TEMPpH VALUES
°C°F4.016.867.019.1810.01
0
32
4.01
6.98
7.13
9.46
10.32
5
41
4.00
6.95
7.10
9.39
10.24
10
50
4.00
6.92
7.07
9.33
10.18
15
59
4.00
6.90
7.04
9.27
10.12
20
68
4.00
6.88
7.03
9.22
10.06
25
77
4.01
6.86
7.01
9.18
10.01
30
86
4.02
6.85
7.00
9.14
9.96
35
95
4.03
6.84
6.99
9.10
9.92
40
104
4.04
6.84
6.98
9.07
9.88
45
113
4.05
6.83
6.98
9.04
9.85
50
122
4.06
6.83
6.98
9.01
9.82
55
131
4.07
6.84
6.98
8.99
9.79
60
140
4.09
6.84
6.98
8.97
9.77
65
149
4.11
6.85
6.99
8.95
9.76
70
158
4.12
6.85
6.99
8.93
9.75
23
For instance, if the buffer temperature is 25 C, the display should
show pH 4.01, 7.01 or 10.01 at pH 4, 7 or 10 buffers, respectively.
At 20 C, the display should show pH 4.00, 7.03 or 10.06. The
meter reading at 50 C will then be 4.06, 6.98 or 9.82.
24
TROUBLESHOOTING GUIDETROUBLESHOOTING GUIDE
TROUBLESHOOTING GUIDE
TROUBLESHOOTING GUIDETROUBLESHOOTING GUIDE
SymptomsProblemSolution
The meter is slow in responding or gives faulty
readings
The meter does not accept the 2nd buffer
solution for calibration
The reading drifts
Display shows: "E1" or
Display shows: "E2" or
Display shows: "E3" or
The electrode is not
working or the reference
junction is clogged
Out of order pH electrode
Out of order electrode
Out of range pH scale
Out of range temperature scale
Out of range mV scale
Leave the electrode in a storage solution after cleaning
the junction. If problem persists, replace the electrode
Follow the cleaning procedure. If this doesn't work
replace the electrode
Replace the pH electrode
a) Recalibrate
b) Make sure the pH
sample is in the 0 to 14
range
c) Check the electrolyte level
and the general state of
the pH electrode
Make sure the temperature
is in the 0 to 100 C (or 70
C) range and the probe is
plugged in
Electrode not connected
ELECTRODE CONDITIONINGELECTRODE CONDITIONING
ELECTRODE CONDITIONING
ELECTRODE CONDITIONINGELECTRODE CONDITIONING
& MAINTENANCE& MAINTENANCE
& MAINTENANCE
& MAINTENANCE& MAINTENANCE
Display shows: "E4" or
"WRONG
and/or
"WRONG "
Display shows: "E5" or
"WRONG
and/or
"WRONG "
The meter does not
work with the temperature probe
The meter fails to calibrate or gives faulty
readings
Display acts erratically
1
BUF
"
BUF
"
2
Erroneous buffer solution
used for offset calibration
Out of order electrode
Erroneous buffer solution
used for slope calibration
Out of order electrode
Out of order temperature
probe
Out of order pH electrode
The microprocessor has
been electronically disturbed
25
Make sure the buffer setting
is correct and the solution is
fresh. Replace the buffer if
necessary
Replace the pH electrode
Make sure the buffer setting
is correct and the solution is
fresh. Replace the buffer if
necessary
Replace the pH electrode
Replace the probe
Replace the electrode
Remove one of the batteries for one minute to reset
the microprocessor
* Not present in gel electrodes.
PREPARATION
Remove the protective cap.
DO NOT BE ALARMED IF ANY SALT DEPOSITS ARE PRESENT. This is
normal with electrodes and they will disappear when rinsed with water.
During transport tiny bubbles of air may form inside the glass bulb
affecting proper functioning of the electrode. These bubbles can be
removed by "shaking down" the electrode as you would do with a
glass thermometer.
If the bulb and/or junction is dry, soak the electrode in HI 70300 or
HI 80300
Storage Solution for at least one hour.
26
For refillable electrodes:
If the filling solution (electrolyte) is more than 2½ cm (1") below the
fill hole, add HI 7082 or HI 8082 3.5M KCl Electrolyte Solution for
double junction or HI 7071 or HI 8071 3.5M KCl+AgCl Electrolyte
Solution for single junction electrodes.
For a faster response, unscrew the fill hole screw during measurements.
For AmpHel® electrodes:
If the electrode does not respond to pH changes, the battery is run
down and the electrode should be replaced.
MEASUREMENT
Rinse the electrode tip with distilled water. Immerse the tip (bottom 4
cm /1½") in the sample and stir gently for a few seconds.
For a faster response and to avoid cross contamination of the samples,
rinse the electrode tip with a few drops of the solution to be tested,
before taking measurements.
STORAGE
To minimize clogging and assure a quick response time, the glass bulb
and the junction should be kept moist and not allowed to dry out.
Replace the solution in the protective cap with a few drops of HI 70300
or HI 80300 Storage Solution or, in its absence, Filling Solution
(HI 7071 or HI 8071 for single junction or HI 7082 or HI 8082 for
double junction electrodes). Follow the Preparation Procedure above
before taking measurements.
Note: NEVER STORE THE ELECTRODE IN DISTILLED OR DEIONIZED WA-
TER.
PERIODIC MAINTENANCE
Inspect the electrode and the cable. The cable used for connection to
the meter must be intact and there must be no points of broken
insulation on the cable or cracks on the electrode stem or bulb.
Connectors must be perfectly clean and dry. If any scratches or cracks
are present, replace the electrode. Rinse off any salt deposits with
water.
For refillable electrodes:
Refill the reference chamber with fresh electrolyte (HI 7071 or HI 8071
for single junction or HI 7082 or HI 8082 for double junction electrodes). Allow the electrode to stand upright for 1 hour.
Follow the Storage Procedure above.
AmpHel® is a registered Trademark of "Hanna Instruments"
27
CLEANING PROCEDURE
GeneralSoak in Hanna HI 7061 or HI 8061 General Clean-
ing Solution for approximately ½ hour.
Removal of films, dirt or deposits on the membrane/junction:
-
Protein
-
Inorganic
-
Oil/grease
IMPORTANT: After performing any of the cleaning procedures
rinse the electrode thoroughly with distilled water, refill the reference chamber with fresh electrolyte (not necessary for gel-filled
electrodes) and soak the electrode in HI 70300 or HI 80300
Storage Solution for at least 1 hour before taking measurements.
TROUBLESHOOTING
Evaluate your electrode performance based on the following.
• Noise (Readings fluctuate up and down) could be due to:
– Clogged/Dirty Junction: Refer to the Cleaning Procedure
– Loss of shielding due to low electrolyte level (in refillable
• Dry Membrane/Junction: Soak in HI 70300 or HI 80300
Storage Solution for at least 1 hour.
• Drifting: Soak the electrode tip in warm (approx. 50-60C)
Hanna HI 7082 or HI 8082 Solutions for one hour and rinse
the tip with distilled water. Refill with fresh HI 7071 orHI 8071 for single junction electrodes and HI 7082 or HI 8082
for double junction electrodes (refillable electrodes only).
• Low Slope: Refer to the cleaning procedure above.
• No Slope: Check the electrode for cracks in glass stem or bulb
and replace the electrode.
• Slow Response/Excessive Drift: Soak the tip in HI 7061 or
HI 8061 Solutions for 30 minutes, rinse thoroughly in distilled
water and then follow the Cleaning Procedure above.
Soak in Hanna HI 7073 or HI 8073 Protein Cleaning Solution for 15 minutes.
Soak in Hanna HI 7074 or HI 8074 Inorganic Cleaning Solution for 15 minutes.
Rinse with Hanna HI 7077 or HI 8077 Oil and Fat
Cleaning Solution.
above.
electrodes only): refill with fresh HI 7071 or HI 8071 for
single junction or HI 7082 or HI 8082 for double junction
electrodes.
28
TAKING REDOX MEASUREMENTS
(HI 9023C & HI 9025C only)
HI 9023C and HI 9025C have the capability to take ORP measurements. An optional ORP electrode must be used to perform these
measurements.
Oxidation-Reduction Potential (REDOX) measurements provide the
quantification of the oxidizing or reducing power of the sample
tested.
To correctly perform a redox measurement, the surface of the ORP
electrode must be clean and smooth.
In order to improve performance and obtain a faster response
time, precondition your ORP electrode with reducing or oxidizing
solutions.
Generally speaking, if the ORP mV reading corresponding to the pH
value of the solution is higher than the values in the table below,
an oxidizing pretreatment is necessary; otherwise a reducing
pretreatment is necessary:
pHmVpHmVpHmVpHmVpHmV
09901920286038004740
56806640758085209460
10400113401228013 22014160
Reducing pretreatment: immerse the electrode for a few minutes in
HI 7091.
Oxidizing pretreatment: immerse the electrode for a few minutes in
HI 7092.
When not in use, the tip of the electrode should be kept moist and
safe from any mechanical stress which might cause damage to the
glass/platinum junction.
- HI 9110, HI 9210 and HI 9210N will
display a "V" on the LCD. Note:
91109110
9110,
91109110
HI 9210HI 9210
HI 9210 and
HI 9210HI 9210
HI 9210NHI 9210N
HI 9210N are
HI 9210NHI 9210N
supplied with the advanced "BEPS", Bat-
LOW BAT
HIHI
HI
HIHI
V
tery Error Preventive System, that detects a low voltage condition
in the battery. The "V" symbol is to alert the user that the
display will be shut-off after about 5 hours of use. After that,
the meter shuts down the display, preventing the taking of
erroneous measurements due to low voltage.
Battery replacement must only take place in a
non hazardous area using the battery types
specified in this instruction manual. To replace rundown batteries, remove the two
screws on the rear cover of the instrument
and replace all four 1.5V AA batteries with
new ones, while paying attention to the
correct polarity. Replace the cover and tighten
the two screws. The meter is reset any time
the batteries are removed. In case of any
functional problems, reset the meter by removing and reinstalling
the batteries.
29
30
ACCESSORIESACCESSORIES
ACCESSORIES
ACCESSORIESACCESSORIES
pH CALIBRATION SOLUTIONS
HI 70004PpH 4.01 Buffer Sachets, 20mL, 25 pcs
HI 70007PpH 7.01 Buffer Sachets, 20mL, 25 pcs
HI 70010PpH 10.01 Buffer Sachets, 20mL, 25 pcs
HI 7004LpH 4.01 Buffer Solution, 460 mL
HI 7006LpH 6.86 Buffer Solution, 460 mL
HI 7007LpH 7.01 Buffer Solution, 460 mL
HI 7009LpH 9.18 Buffer Solution, 460 mL
HI 7010LpH 10.01 Buffer Sol., 460 mL
pH CALIBRATION SOLUTIONS IN FDA APPROVED
BOTTLE
HI 8004LpH 4.01 Buffer Solution, 460 mL
HI 8006LpH 6.86 Buffer Solution, 460 mL
HI 8007LpH 7.01 Buffer Solution, 460 mL
HI 8009LpH 9.18 Buffer Solution, 460 mL
HI 8010LpH 10.01 Buffer Solution, 460 mL
ELECTRODE STORAGE SOLUTION
HI 70300LStorage Solution, 460 mL
HI 80300LStorage Solution in a FDA approved bottle, 460 mL
ELECTRODE CLEANING SOLUTIONS
HI 70000PElectrode Rinse Sachets, 20 mL, 25 pcs
HI 7061LGeneral Cleaning Sol., 460 mL
HI 7073LProtein Cleaning Sol., 460mL
HI 7074LInorganic Cleaning Sol., 460mL
HI 7077LOil & Fat Cleaning Sol.,460 mL
ELECTRODE CLEANING SOLUTIONS IN FDA
APPROVED BOTTLES
HI 8061LGeneral Cleaning Solution, 460 mL
HI 8073LProtein Cleaning Solution, 230 mL
HI 8077LOil & Fat Cleaning Solution, 460mL
REFILL ELECTROLYTE SOLUTIONS
HI 70713.5M KCl + AgCl Electrolyte, 4x50mL, for single
junction electrodes
HI 70721M KNO3 Electrolyte, 4x50 mL
HI 70823.5M KCl Electrolyte, 4x50 mL, for double junction
electrodes
REFILL ELECTROLYTE SOLUTIONS IN FDA APPROVED
BOTTLES
HI 80713.5M KCl + AgCl Electrolyte, 4x50mL, for single
junction electrodes
HI 80721M KNO3 Electrolyte, 4x50 mL
HI 80823.5M KCl Electrolyte, 4x50 mL, for double junction
electrodes
ORP PRETREATMENT SOLUTIONS
HI 7091LReducing Pretreatment Solution, 460 mL
HI 7092LOxidizing Pretreatment Solution, 460 mL
pH & ORP ELECTRODES
All electrodes part numbers ending in B are supplied with a BNC
connector and 1 m (3.3') cable, as shown below:
Ultem® is registered Trademark of "General Electrics Co."
Kynar® is registered Trademark of "Pennwalt Corp."
35
Consult the Hanna General Catalog for an extensive selection of
electrodes.
OTHER ACCESSORIES
ChecktempC Pocket-size thermometer (range -50.0 to 150.0C)
HI 76405Electrode holder
HI 7669/2W Temperature probe with 1 m (3.3') screened cable
(not HI 9110, HI 9210, HI 9210N and HI 9023CN)
HI 8427pH and ORP electrode simulator with 1 m (3.3')
coaxial cable ending in female BNC connectors
HI 931001pH and ORP electrode simulator with LCD and 1 m
(3.3') coaxial cable ending in female BNC connectors
HI 721317Rugged carrying case
36
ELECTRODE APPLICATIONELECTRODE APPLICATION
ELECTRODE APPLICATION
ELECTRODE APPLICATIONELECTRODE APPLICATION
REFERENCE GUIDEREFERENCE GUIDE
REFERENCE GUIDE
REFERENCE GUIDEREFERENCE GUIDE
ApplicationElectrodes *
1. AquariumHI 1332B
2. Bath-waterHI1130B
3. BeerHI 1131B
4. BreadHI2031B, FC 200B
5. CheeseFC 200B
6. Dairy productsFC 100B
7. Dirty waterHI 1230B
8. EmulsionsHI1053B
9. EnvironmentHI 1230B
10. FlasksHI1331B
11. Food industry general useFC 911B, FC 100B
12. FruitFC 200B, FC 220B
13. Fruit juices, organicFC 210B
14. Galvanizing waste solutionHI 1130B
15. Heavy-duty applicationsHI 1135B
16. High purity waterHI 1053B
17. HorticultureHI 1053B, FC200B
18. Laboratory general useHI 1131B, HI1230B, HI 1332B, HI1330B
19. LeatherHI1413B
20. Lemon juiceFC100B
21. MeatFC200B, HI 2031B
22. Micro plate sampling of less thanHI1083B
100 mL
23. Milk and YogurtFC 210B
24. PaintsHI 1053B
25. PaperHI 1413B
26. Photographic chemicalsHI1230B
27. Quality controlHI1332B
28. SausagesFC200B, HI 2031B
29. Semisolid productsHI 2031B
30. SkinHI 1413B
31. Soil samplesHI 1230B
32. SolventsHI 1043B
33. Strong acidHI 1043B
34. Submersion applicationHI 1130B
35. Surface measurementsHI 1413B
36. Swimming poolH I1130B, HI 2114P/2
37. Titrations with constantHI 1131B
temperature range
38. Titrations with wide temperatureHI 1131B
range
39. Very high humidityFC 911B
40. Vials and test tubeHI 1330B
41. Wine processingFC 220B
WARRANTYWARRANTY
WARRANTY
WARRANTYWARRANTY
All Hanna Instruments meters are guaranteed for two years
against defects in workmanship and materials when used for their
intended purpose and maintained according to instructions. The
electrodes and the probes are guaranteed for a period of six
months. This warranty is limited to repair or replacement free of
charge.
Damage due to accident, misuse, tampering or lack of prescribed
maintenance are not covered.
If service is required, contact the dealer from whom you purchased
the instrument. If under warranty, report the model number, date
of purchase, serial number and the nature of the failure. If the
repair is not covered by the warranty, you will be notified of the
charges incurred. If the instrument is to be returned to Hanna
Instruments, first obtain a Returned Goods Authorization number
from the Customer Service department and then send it with
shipping costs prepaid. When shipping any instrument, make sure
it is properly packaged for complete protection.
To validate your warranty, fill out and return the enclosed warranty card within 14 days from the date of purchase.
All rights are reserved. Reproduction in whole or in part is
prohibited without the written consent of the copyright owner,
Hanna Instruments Inc., 584 Park East Drive, Woonsocket, Rhode
Island, 02895 , USA.
* All electrode listed are supplied with 1m (3") cable and BNC
connector.
37
Hanna Instruments reserves the right to modify the design,
construction and appearance of its products without advance
notice.
38
CE DECLARATION OF CONFORMITYCE DECLARATION OF CONFORMITY
CE DECLARATION OF CONFORMITY
CE DECLARATION OF CONFORMITYCE DECLARATION OF CONFORMITY
HANNA LITERATUREHANNA LITERATURE
HANNA LITERATURE
HANNA LITERATUREHANNA LITERATURE
Hanna publishes a wide range of catalogs and handbooks for an equally wide range of applications.
The reference literature currently covers areas such as:
• Water Treatment
• Process
• Swimming Pools
• Agriculture
• Food
• Laboratory
• Thermometry
and many others. New reference material is constantly
being added to the library.
For these and other catalogs, handbooks and leaflets,
contact your dealer or the Hanna Customer Service
Center nearest to you. To find the Hanna Office in
your vicinity, check our home page at
www.hannainst.com.
Recommendations for Users
Before using these products, make sure that they are entirely suitable for the environment in which they are
used.
Operation of these instruments in residential area could cause unacceptable interference to radio and TV
equipment, requiring the operator to take all necessary steps to correct interference.
The glass bulb at the end of the electrode is sensitive to electrostatic discharges. Avoid touching this glass
bulb at all times.
During calibration of instruments, ESD wrist straps should be worn to avoid possible damage to the electrode
by electrostatic discharge.
To maintain the EMC performance of equipment, the recommended cables noted in the user's manual must
be used.
In particular cases the instruments could turn off. In such cases, turn them on by pressing the ON/OFF
key.
Any variation introduced by the user to the supplied equipment may degrade the instruments' EMC
performance.
To avoid electrical shock, do not use these instruments when voltages at the measurement surface exceed 24VAC
or 60VDC.
To avoid damage or burns, do not perform any measurement in microwave ovens.
39
MANPHWPR3
02/00
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