Hanna Instruments HI 9017 User Manual

Instruction Manual

HI9017 - HI9218
HI9219 - HI9318

Microprocessor

Bench-top

pH Meters with

RS232C

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DATE

CAL

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RANGE

http://www.hannainst.com

These Instruments are in

Compliance with the CE Directives

Dear Customer,
Thank you for choosing a Hanna Instruments Product.
Please read this instruction manual carefully before using the instru-

ment.
This manual will provide you with all the necessary information for the

correct use of the instrument, as well as a precise idea of its versatility
in a wide range of applications.

These instruments are in compliance with CSA, UL and directives
(EN 50081-1 and EN50082-1).

TABLE OF CONTENTSTABLE OF CONTENTS

TABLE OF CONTENTS

TABLE OF CONTENTSTABLE OF CONTENTS

GENERAL DESCRIPTION ........................................................................... 3

PRELIMINARY EXAMINATION ................................................................... 3

FRONT PANEL AND SPECIFICATIONS:

HI9017 ................................................................................... 5

HI9218 & HI9219 ................................................................................. 7

HI9318 ................................................................................... 9

REAR PANEL CONNECTIONS .................................................................. 11

OPERATIONAL GUIDE ............................................................................ 13

PH CALIBRATION ................................................................................. 18

PH VALUES AT VARIOUS TEMPERATURE ................................................. 26

TEMPERATURE CALIBRATION ................................................................. 26

HOW TO SET DATE & TIME (HI9218 & HI9219) .................................... 27

PROGRAMS OF HI9017 ......................................................................... 28

PROGRAMMING LOGGER FUNCTIONS HI9318 ........................................ 37

TROUBLESHOOTING GUIDE ................................................................... 45

INTERFACE WITH COMPUTER ................................................................. 46

ELECTRODE CONDITIONING AND MAINTENANCE ..................................... 50

TEMPERATURE-RESISTANCE CORRELATION FOR

HANNA PH SENSITIVE GLASS ................................................................ 53

ACCESSORIES ................................................................................. 54

ELECTRODE APPLICATION REFERENCE GUIDE .......................................... 61

WARRANTY ................................................................................. 62

CE CERTIFICATE OF CONFORMITY ........................................................... 63

ISO 9000 Certified
Company since 1992

2

PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION

PRELIMINARY EXAMINATION

PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION

Remove the instrument from the packing material and examine it to
make sure that no damage has occurred during shipping. If there is
any damage, notify your Dealer.

Note: Save all packing material until you are sure that the instrument

functions correctly. All defective items must be returned in the
original packing with the supplied accessories.

GENERAL DESCRIPTIONGENERAL DESCRIPTION

GENERAL DESCRIPTION

GENERAL DESCRIPTIONGENERAL DESCRIPTION

HI9017, HI9218, HI9219 and HI9318 are microprocessor-based bench­top meters designed to meet the most stringent demands of the laboratory.

They feature:

•user friendly rubber keyboard

•automatic calibration with memorized buffers values

•automatic or manual temperature compensation

•storage of calibration data even after the meters are shut off

•error codes to guide the user in calibration and troubleshooting
All these models incorporate a standard RS232C output for communi­cation with a computer.
The HI76405 electrode holder provided will hold your pH electrode
and temperature probe directly over the sample vessel which can be
placed on the enamel coated base of the holder. A magnetic stirrer
can also be placed on the enamel coated base if sample agitation is
required. The enamel coating is impervious to most chemicals and the
heavy steel base will not tip over easily.
These meters are perfect for use in Q.C. labs, R&D labs, environmen­tal testing, industrial processing, chemical treatment, waste water
treatment, drinking water analysis, titration, hydroponics, general ag­riculture, food processing and anywhere accurate pH measurements
are required.

• HI9017 pH/mV/°C meter automatically recognizes three stan-

dard calibration buffer values (pH 4.01, 7.01, 10.01). The pH
and temperature values are shown separately on the LCDs. A wide
mV range and high resolution allow for ORP or ion-selective
measurements (the range automatically switches from ISE to ORP
when readings exceed ±399.9 mV).

HI9017 comes supplied with HI1131B glass-body combination
pH electrode (with 1m/3.3' cable), HI7669/2W temperature probe

3

(with 1m/3.3' cable), 12VDC adapter (HI710005 or HI710006),
pH 4.01 & pH 7.01 buffer solutions (20 mL each), HI7071
electrolyte solution (30 mL), HI76405 electrode holder and a
dust cover.

• HI9218 and HI9219 are programmable pH/°C meter with built-

in printer. They print pH values together with temperature, time
and date. These meter provide you with pH and temperature
readings simultaneously and separately on the LCDs and feature a
unique stability indicator. When the pH electrode stabilizes in the
sample, the "NO" on the LCD changes to "YES". This indicates that
the reading is correct and can be recorded. They automatically
recognize three standard buffers (4.01, 7.01 and 10.01 pH) for
calibration purposes. These meters are extremely user-friendly,
giving step-by-step instructions on the printer at every stage to
help the user.

HI9218 has been specifically designed for the food industry.
HI9218 comes supplied with FC100B plastic-body combination

pH electrode (with 1m/3.3' cable) while HI9219 comes with
HI1131B glass-body combination pH electrode (with 1m/3.3'

cable). HI9218 and HI9219 are also supplied with: HI7669/2W
temperature probe (with 1m/3.3' cable), 12VDC adapter (HI710005
or HI710006), pH 4.01 & pH 7.01 buffer solutions (20 mL each),
HI7071 electrolyte solution (30 mL), 5 replacement rolls of printer
paper, HI76405 electrode holder and a dust cover.

• HI9318 is a pH/mV/°C meter designed for logging data in various

applications. This programmable printing meter prints pH or mV
values as well as sample number, temperature, time and date.
The pH/mV and temperature values are displayed on separate
LCDs for ease of reading. It recognizes and memorizes three
different standard buffers (pH 4.01, 7.01 and 10.01) for calibra­tion purposes. The printer can be programmed to print in one of 6
different languages (English, French, German, Italian, Spanish or
Swedish). Once your language is selected you can simply prompt
the meter to calibrate and it will print step-by-step instructions
through the entire process making this meter perfect for use by
even non-technical staff members.

HI9318 comes supplied with HI1131B glass-body combination
pH electrode (with 1m/3.3' cable), HI7669/2W temperature probe
(with 1m/3.3' cable), 12VDC adapter (HI710005 or HI710006),
pH 4.01 & pH 7.01 buffer solutions (20 mL each), HI7071
electrolyte solution (30 mL), 5 replacement rolls of printer paper,
HI76405 electrode holder and a dust cover.

4

FRONT PANEL ANDFRONT PANEL AND

FRONT PANEL AND

FRONT PANEL ANDFRONT PANEL AND

SPECIFICATIONS OF HSPECIFICATIONS OF H

SPECIFICATIONS OF H

SPECIFICATIONS OF HSPECIFICATIONS OF H

II

90179017

I

9017

II

90179017

1

to manually enter calibration buffervalue

PGM

1

to enter pH alarm

PGM

2

to enter mV alarm

PGM

3

to enter temperature alarm

PGM

4

to enter pH end point alarm

PGM

5

to enter RS 232 ESC code

PGM

6

to exit from any program

PGM

0

to clear entry or silence alarm

CLEAR

Standard pH buffer - 4.01, 7.01, 10.01

1. Program descriptions

Briefly describes the 6 programs

2. Temperature LCD
This LCD displays the temperature measured by the HI7669/2W

probe or the value that was manually set through the keyboard.
If the temperature has been set manually, the "°C" symbol will

flash.
When the temperature probe is connected the measured tempera-

ture is displayed and the "°C" symbol stops flashing.
When the temperature measured by the probe is out of range (-10

to 125°C) the "Err3" signal appears.

3. pH and mV LCD
This LCD displays the pH or mV reading (pH and mV is toggled

with the RANGE key). The corresponding pH or mV symbol will be
displayed along with the measured value.

An error signal ("Err1", "Err2", "Err4" or "Err5") will appear on this
display to indicate that the range is exceeded or that the buffer
used for calibration is not recognized by the meter's microproces­sor.

4. Keyboard

ENTER A key used in programming.
ENTER B key used in programming.
CLEAR key to clear entry or silence alarm.
PGM key to select a program.

PROGRAMS

ENTER ENTER

1st buffer 2nd buffer

ENTER ENTER

upper limit lower limit

ENTER ENTER

upper limit lower limit

ENTER ENTER

upper limit lower limit

ENTER ENTER

end point value alert value

ENTER

ESC code

A

BA

BA

BA

BA

BA

ENTERAENTERBCLEAR

7

4

1

0

pH°C

HI 9017 MICROPROCESSOR pH METER

ins rum n

ON

89

56

23

.

CAL

PGM

+/-

2

3

s

OFF

RANGE

CON

TEMP

4

5

ON key to switch the instrument on.
OFF key to switch the instrument off.
RANGE key to switch range from pH to mV or vice versa.
CAL key used in calibration with standard pH buffers (pH

4.01, 7.01, 10.01)

CON key confirmation of calibration data
+/- key entering negative values
TEMP key used for manual temperature adjustment
0 to 9 keys numeric and Decimal keys for numeric data input

SPECIFICATIONS HI 9017
Range pH 0.00 to 14.00

ISE ± 399.9 mV

ORP ±1999 mV

°C -10.0 to 125.0

Resolution pH 0.01

ISE 0.1 mV

ORP 1 mV

°C 0.1
Accuracy pH ±0.01
(@ 20°C/68°F) ISE ±0.2 mV

ORP ±1 mV

°C ±0.5
Typical EMC pH ±0.02
Deviation ISE ±0.2 mV

ORP ±1 mV

°C ±0.5
Calibration 2 point with automatic recognition of 3

buffers (pH 4.01, 7.01, 10.01)

Temperature -10° to +125°C (14 to 257 °F) completely

automatic with HI7669/2W temperature

probe; manual by means of keyboard
Comp. Interface RS232C
Electrode HI1131B Glass body combination

pH electrode (included)
Temperature Probe HI7669/2W Temperature probe (included)
Input Impedance 1012 Ohm
Power Power socket for 12VDC
Environment 0 to 50°C (32 to 122°F); RH 95%
Dimensions 230 x 170 x 70mm (9.1 x 6.7 x 2.7")
Weight 1.3 Kg (2.9 lb.); kit w/holder 3.2 Kg (7 lb.)

6

FRONT PANEL ANDFRONT PANEL AND

FRONT PANEL AND

FRONT PANEL ANDFRONT PANEL AND

SPECIFICATIONS OF HI9218 & HI9219SPECIFICATIONS OF HI9218 & HI9219

SPECIFICATIONS OF HI9218 & HI9219

SPECIFICATIONS OF HI9218 & HI9219SPECIFICATIONS OF HI9218 & HI9219

Foodcare

To change paper roll or ink ribbon

Slide cover to the left to open.

Push ribbon cassette as marked - to release

Insert new paper roll. Pass leading end under guide plate and
press PAPER to feed paper through the printer.

Pass leading end through ribbon cassette, with ribbon at the
front and press cassette into position

1

ins

rum n

e

PAPER

STABILITY INDICATOR

READY

NO

YES

PRINT

HI 9218

PRITING pH METER
WITH STABILITY INDICATOR

s

°C

PRINT

Press to check
reading stability.

Wait

Reading is stable.
Press to obtain

a copy.

pH

ON

DATE

CAL

UP

1. Printer

Plain paper printer

2. Temperature LCD
This LCD displays the temperature measured by the HI7669/2W

probe or the value that was manually set through the keyboard. If
the temperature has been set manually, the "°C" symbol will
flash. When the temperature probe is connected the measured
temperature is displayed and the "°C" symbol stops flashing.
When the temperature measured by the probe is out of range (-

10.0 to 125.0°C) the "Err3" signal appears.

3. pH LCD
This LCD displays the pH reading. The corresponding pH symbol

will be displayed along with the measured value. An error
signal ("Err1", "Err4" or "Err5") will appear on this display to
indicate that the range is exceeded or that the buffer used for
calibration is not recognized.

4. Small LCD
This LCD normally displays the time. When the DATE button is

pressed, the date will be displayed. When the READY key is
pressed, the display shows "NO" while the electrode is stabilizing
and "YES" once the reading is stable.

5. Keyboard

ON/OFF key to switch the instrument "ON" or "OFF".
Note: Press OFF before unplugging instrument, otherwise, calibration

data and time setting could be lost.

2

3

4

OFF

5

TIME

CFM

DOWN

7

DATE/TIME key to display date and time.
CAL key to enter calibration mode.
CFM key to confirm memorized buffers 7.01 and 4.01/10.01.
UP/DOWN key to set manual temperature compensation and date/time.
PAPER key manual paper feed control.
PRINT key prints pH value together with temperature, date

and time.

READY key stability indicator to ensure correct pH reading or

to enable calibration.

SPECIFICATIONS HI9218 HI9219
Ranges pH 0.00 to 14.00

°C -10.0 to 125.0

Resolution pH 0.01

°C 0.1
Accuracy pH ±0.01
(@20°C/68°F) °C ±0.5
Typical EMC pH ±0.04
Deviation °C ±1.5
Calibration 2 point with automatic recognition of

3 buffers (pH 4.01, 7.01, 10.01)

Temperature -10° to 125°C (14 to 257°F) Completely
Compensation automatic with HI 7669/2W temperature

probe; manual by means of keyboard
Comp. Interface RS232C
Electrode HI9218: FC100B plastic body combination

pH electrode (included)

HI9219:HI1131B Glass body combination

pH electrode (included)
Temperature HI7669/2W Temperature probe (included)
Probe
Input Impedance 1012 Ohm
Display 2 large 4-digit LCD for pH and temperature

with symbols 1 small LCD for date/time and

stability indicator
Printer 1 x 16 line dot matrix printer,

paper width: 44 mm,

roll diameter: 35 mm

Power Supply Power socket for 12VDC
Environment 0 to 50°C (32 to 122°F); RH 95%
Dimensions 230x170x70mm (9.1x6.7x2.7")
Weight 1.3 Kg (2.9 lb.);

kit w/holder 3.2 Kg (7 lb.)

8

FRONT PANEL ANDFRONT PANEL AND

FRONT PANEL AND

FRONT PANEL ANDFRONT PANEL AND

PROGRAMS

0 PGM to exit from any program

1

1 PGM to set sampling number, time and date
2 PGM to manually enter calibration buffervalue
3 PGM to print calibration data
4 PGM to print sample data until specified time
5 PGM to print sample data until end point
6 PGM to set pH/mV alarm
7 PGM to select different working language
8 PGM to print ion concentration
9 PGM to enter RS232C ESC code
CLEAR to clear entry

2

SPECIFICATIONS OF HSPECIFICATIONS OF H

SPECIFICATIONS OF H

SPECIFICATIONS OF HSPECIFICATIONS OF H

°C

PAPER

PRINT CLEAR

ABC

789

456

423

+/- .

rum n

e

s

ins

II

I

II

PGM

93189318

9318

93189318

pH

SAMPLE DATE

ON

DATE RANGE

CAL

+/-

1. Program descriptions Briefly describes the 9 programs

2. Printer Plain paper printer

3. Temperature LCD This LCD displays the temperature. If

the temperature has been set manually, the "°C" symbol will
flash. When the temperature probe is connected the measured
temperature is displayed and the "°C" symbol stops flashing.
When the temperature measured by the probe is out of range (-10
to 125°C) the "Err3" signal appears.

4. pH and mV LCD This LCD displays the pH or mV reading

(pH and mV is toggled with the RANGE key). The corresponding
pH or mV symbol will be displayed along with the measured
value. An error signal ("Err1", "Err2", "Err4" or "Err5") will appear
on this display to indicate that the range is exceeded or that the
buffer used for calibration is not recognized.

5. Sample LCD Displays the sample number of the current lot.

6. Time and Date LCD Displays the Time as HH.MM. and the

date as MM.DD. This LCD also displays any numeric data entered
from the keyboard to show the user the entered values.

7. Keyboard
PAPER key manual paper feed control. Press and hold this button

and the printer will advance the paper roll

PRINT key prints the time, date, sample #, and pH/mV values
CLEAR key cancels wrong data entered during programming
ON key to switch the instrument on
OFF key to switch the instrument off.
DATE key allows to display the month and day or time in hours

and minutes

3

4

5
6

OFF

7

CON

TEMP.

9

RANGE key selects pH or mV readings to be displayed on the right LCD
CAL key to enter into the calibration mode
CON key for confirmation of buffer value during calibration
+ / - key select + or - value for manual temperature compensation
TEMP key allows to select temperature manually when the

temperature probe is not connected

PGM key selects any of the 9 available programs
0 to 9 keys numeric and Decimal keys for numeric data input

SPECIFICATIONS HI9318
Ranges pH 0.00 to 14.00

ISE 0 to ±399.9 mV

ORP 0 to ±1999 mV

°C -10.0 to 125.0

Resolution pH 0.01

ISE 0.1mV

ORP 1 mV

°C 0.1
Accuracy pH ±0.01
(@20°C/68°F) ISE ±0.2 mV

ORP ±1 mV

°C ±0.5
Typical EMC pH ±0.04
Deviation ISE ±2.5 mV

ORP ±3 mV

°C ±1.5
Calibration Automatic at pH 4, 7, 10 or at any two

buffer values with program 2

Offset ±1pH
Slope From 85 to 105%
Input Impedance 1012 Ohm
Temperature -10° to 125°C (14 to 257°F) completely

Compensation automatic with HI 7669/2W temp. probe;

manual by means of keyboard

Display 2 large 4 digit LCDs for pH/mV and

Temperature with symbols and one
LCD for date/time and sample #

Printer Dot matrix, 44mm wide paper
Power Supply Power socket for 12VDC

Languages English, German, French,

Spanish, Italian & Swedish

Electrode HI1131B Glass body combination

pH electrode (included)

Temperature Probe HI7669/2W Temperature probe (included)
Environment 0 to 50°C (32 to 122°F); RH 95%

Dimensions 230 x 170 x 70mm (9.1 x 6.7 x 2.7")
Weight 1.3kg (2.9 lb.); Kit: 3.4 Kg (7.4lb.)

10

REAR PANEL CONNECTIONSREAR PANEL CONNECTIONS

REAR PANEL CONNECTIONS

REAR PANEL CONNECTIONSREAR PANEL CONNECTIONS

DTR

TXD

GND

COMBINATION

pH

REFERENCE

ELECTRODE

ELECTRODE

TEMPERATURE

PROBE

RESET

123 4 5 6 7

RXD

51

ooooo

oooo

96

DSR

RS-232

ooooo

oooo

1) BNC male connector for single or combination electrode. Will
accept any pH or ORP electrode with a standard BNC connector.

2) Jack bush connector for reference electrode

3) Banana bush connector for reference electrode
When the electrode attached to the BNC does not have a refer-

ence, connect the reference to one of these sockets (2 choices for
different diameters).

4) Temperature probe socket for use with the HI7669/2W.

5) Reset button.

6) RS 232C socket for serial communication.

7) DC Power Socket (for HI710005 or HI710006).

Electrode and probe connections

For combination pH (or ORP for HI9017 and HI9318) electrodes
(with internal reference) plug the electrode's BNC to the socket pro­vided (#1).

For electrode with separate reference (see page 58), connect the
measuring electrode's BNC to the BNC socket (#1) and the reference
electrode's jack to the socket provided (#2 or #3).

For temperature measurements and automatic temperature compen­sation connect the temperature probe to the °C socket (#4).

RESET button

The RESET button (#5) is used when the instrument displays errone­ous messages due to strong electrical interference or when the
instrument's power supply was disconnected before the meter was
switched off. Press the RESET button and restart the entire operation.

11

-

Power connection

Plug the 12VDC adapter (HI710005 or HI710006) into the DC socket
(#7).

Plug the adapter into the mains.
Note: The instrument uses the following configuration.

+

It is recommendable to use the Hanna HI7710005 or HI710006
voltage adapters (supplied witht the meters) that use the proper
polarity configuration.

The meters can also be used with other adapters. In this case, remem­ber to check the correct polarity of your adapter before connecting it to
the meter.

Note: Make sure the main line is protected by a fuse.
Note: HI9017, HI9218, HI9219, HI9318 use a rechargeable battery

to retain the pH calibration data only. It lasts approximately one
month when fully charged. The battery is automatically charged
any time the meter is plugged-in (either turned on or off).

Notes:

1) If you need to unplug the instrument, press the OFF key before

disconnecting the meter from the mains. Only in this case will
the instrument retain the memorized data. Otherwise, the in­strument needs to be re-calibrated. In the case of a power
failure while the instrument is operational , re-calibration is
required.

2) When the instrument is initially switched on, the microprocessor

checks if any calibration data is in memory (i.e. if the offset is
within ±1 pH and the slope between 70 - 105%). If the
calibration data are not memorized, the offset and slope of the
instrument will be set to 0 mV and 100% respectively.

12

OPERATIONAL GUIDEOPERATIONAL GUIDE

OPERATIONAL GUIDE

OPERATIONAL GUIDEOPERATIONAL GUIDE

TAKING PH MEASUREMENTS

Make sure that the instrument has been calibrated for pH before
taking pH measurements (see page 18).

Connect the pH electrode (combination-type) or the electrode half cells
to the appropriate connectors on the rear panel (see page 11).

If automatic temperature compensation is required, connect the
HI7669/2W temperature probe to the proper socket on the rear panel
(see page 11).

Press the ON key to turn the meter on. The meter will
automatically default to the pH measurement mode.

Immerse the electrode and the temperature probe
in the sample and shake briefly. Wait for 30
seconds before taking readings.

ON

ON

IN HI 9218 AND HI 9219

Press READY: "YES" confirms the read­ing is stable.

The LCD on the right shows the pH reading compensated for tempera­ture. The temperature reading is displayed on the LCD on the left.

Note: the electrode should be submerged approxi-

mately 4cm (1½") into the solution.

If the temperature probe is used, it should be
located as close to the pH electrode as possible.

If measurements are taken in different samples successively, it is
recommended that the electrode is rinsed thoroughly for better condi­tioning and to eliminate cross-contamination of the sample.

13

READY

pH°C

(1½
")

4 cm

For the rinsing process, it is recommended to use a liberal amount of
the next solution to be measured.

Using refillable electrodes

Unscrew the small refill cap to open the refill hole during measure­ments. After measurements replace the refill hole cap.

This will increase the pressure and give a faster response.

FOR HI 9218, HI 9219, HI 9318 ONLY

PRINT

Press the PRINT key to get a printout at any time.
All the printouts will be complete with date, time,

sample No. (for HI9318 only), temperature and pH
(or mV with HI9318 only) value.

DATE : 01-02-96
TIME : 12:21 Hr
°C : 17.9
pH : 7.18

DATE 1/02
TIME 12:21
SAMPLE 1
°C 17.9
pH 7.18

HI9218/HI9219 HI9318

Sample Printouts

MANUAL TEMPERATURE COMPENSATION

When the temperature probe is not connected, take the temperature of
the solution with a ChecktempC or a glass thermometer.

FOR HI 9017 ONLY

To manually set a temperature value (e.g. 37.2°C)
proceed as follows:

• press 3

• press 7

• press the key displaying decimal point "."

• press 2

• press TEMP

°C

32.7

TEMP

°C

14

With negative temperature values (e.g. -7.3°C) use the +/- key

• press 7

• press decimal point

• press 3

• press +/-

• press TEMP

7 +/-3.

TEMP

ºC

Notes:

1) For negative value inputs, always key in the value followed by
the +/- key.

2) If the +/- key is pressed twice it will toggle back to the

°C

positive value.

The value will be displayed on the left LCD and "°C" symbol will be
flashing.

FOR HI 9218 AND HI 9219 ONLY

Use the UP or DOWN keys to manually adjust the display reading to
the value of the ChecktempC or the glass thermometer (e.g. 20°C).
The value will be displayed on the left LCD and "°C" symbol will be
flashing.

UP

DOWN

ºC

FOR HI 9318 ONLY

Press the +/- key (for negative figures) followed by the noted
temperature on the numeric keypad (e.g. 20°C). The value will be
displayed on the small LCD. Then press the TEMP. key and the
manually set temperature will be displayed on the left LCD with the
"°C" symbol blinking.

20

SAMPLE

Note: with the temperature probe connected, the "°C" symbol is

displayed continuously and it is not possible to manually set
the temperature.

°C

DATE

TEMP.

ºC

°C

15

TAKING TEMPERATURE MEASUREMENTS

Taking a temperature measurement is very easy.
Turn the instrument ON.
Make sure the temperature probe is connected and

allow the reading to stabilize (1 or 2 minutes).
The temperature value will be displayed on the left LCD.

pH°C

TAKING ORP MEASUREMENTS
(FOR HI 9017 AND HI 9318 ONLY)

HI9017 and HI9318 have the capability to take ORP measurements,

using an ORP electrode. Hanna Instruments offers a variety of ORP
electrodes for this purpose (see page 59). Contact your Dealer for more
information.

Just as pH measurements allow the acidity or the alkalinity of a
substance to be expressed in numbers, oxidation­reduction potential (redox) measurements provide
the quantification of the oxidizing or reducing power
of any liquid.

Connect the ORP electrode to the meter and sub­merge the tip (4 cm / 1½") into the sample to be tested.

Note: ORP measurements are taken without temperature compensa-

tion.
Press the RANGE key once to enter the mV mode.
Allow a few minutes for the reading to stabilize.
The display will indicate the absolute mV value

(positive or negative).
When values are less than ±400 mV, tenths of

mV

mV are displayed; for values greater than ±400
mV, the decimal digit disappears.

Note that the change in scale (from 0.1 mV to 1 mV as resolution) is
automatic.

"Err2" appears if the value exceeds ±1999 mV
(out of range).

RANGE

(1½
")

4 cm

16

FOR HI 9318 ONLY

Press PRINT key to get a printout at any time.
All the printouts will be complete with date, time, sample No., tem-

perature and mV value.

DATE 1/02
TIME 12:40
SAMPLE 5
°C 20.5
mV -350.0

AFTER MEASUREMENTS

Press the OFF key to switch the instrument OFF.

See page 50 for storage, cleaning and maintenance
procedures for electrodes.

OFF

OFF

17

PH CALIBRATIONPH CALIBRATION

PH CALIBRATION

PH CALIBRATIONPH CALIBRATION

IMPORTANT

The instrument's pH range should be re-calibrated:

••

• When the meter is new.

••

••

• Whenever the pH electrode is replaced.

••

••

• At least once a month.

••

••

• After testing aggressive chemicals.

••

••

• After cleaning procedure and changing the reference electrolyte.

••

••

• For greatest accuracy.

••

INITIAL PREPARATION

Pour small quantities (about 4cm / 1½" as level) of pH7.01 (HI7007
or HI8007) and pH4.01 (HI7004 or HI8004) or pH 10.01 (HI7010
or HI8010) solution into clean beakers. If possible use plastic beakers
to minimize any EMC interferences.

4

0

0

I 7

H

HI 7004 HI 7007

If you are measuring in the acid range use pH4.01 as second buffer or
pH 10.01 if you are measuring in the alkaline range.

Note: with HI9017 and HI9318, different pH values can be selected

for calibration purposes. See page 29 and 39 respectively.
For accurate calibration, use two beakers for each buffer solution; the

first for rinsing the electrode, the second for calibration. In this way,
contamination of the buffer is minimized.

RINSE

HI 7007

CALIBRATION

HI 7007

PH CALIBRATION FOR HI 9017

Procedure

••

• Switch the instrument on after connecting the

••

pH electrode and the temperature probe.

18

ON

• Immerse the pH electrode and the ATC probe

into pH7.01 buffer solution. Shake briefly and
wait 1-2 minutes for thermal equilibrium.

HI 7007

(1½

4 cm

")

Note: the electrode should be submerged approximately 4 cm (1½")

into the solution. The temperature probe should be positioned

as close to the pH electrode as possible.

• Press the CAL key.

CAL

The temperature compensated value of the buffer
solution will appear on the left LCD and the pH
symbol will be blinking.

pHpH

E.g. if the buffer temperature is at 25°C, the display on the right will
show "pH7.01". If the buffer temperature is at 20°C, the display will
show "pH 7.03" (see page26).

pH

If a wrong buffer is used or the electrode is faulty, "Err4" will appear
on the left display.

pHpH

• Allow 1-2 minutes for the pH reading to stabilize.
Note: If you are not using the ATC probe, refer to page 25 to manually

correct for temperature.

• Press the CON key to accept the buffer value.

CON

"Err5" will appear on the left display and the
buffer value will be transferred to the right LCD.
The first point calibration is now complete.

pH

pH

Note: If a single point calibration is required, press the CAL key to

leave the calibration mode. However, it is always better to

proceed as follows for a 2-point calibration.

19

• Rinse the electrode and the temperature probe

before immersing them into pH 4.01 or pH10.01
calibration buffer, shake briefly and wait for
thermal equilibrium.

At this moment, "Err5" will disappear. The display will show the
temperature compensated value of the second buffer solution and
the pH symbol will be blinking.

pHpH

If a wrong buffer or a faulty electrode
has been used, "Err5" remains on the
left display.

pH

• Press the CON key to confirm the pH value.

The left display value is then transferred to
the right display. The left LCD will show the
temperature value to indicate that the meter
is now calibrated.

HI 7004

CON

(1½

4 cm

")

ºC

°C

pH

Note: The display on the left will indicate the temperature compen-

sated buffer value e.g. if the temperature is at 25°C, the

display will show "pH 4.01" or "pH 10.01", depending on the

solution used. If the temperature is at 20°C, the display will

show respectively "pH 4.00" or "pH 10.06" (see page 26).
Note: During calibration the pH symbol blinks on the left display, and

the right display always shows the measured value.

20

PH CALIBRATION FOR HI9218 & HI9219

Procedure

• Turn the instrument ON after connecting the pH

electrode and the temperature probe.

• Immerse the temperature probe together with

the electrode into pH 7.01 buffer solution or
manually set the temperature to the tempera­ture of the buffer (if you are not using the
temperature probe HI7669/2W see page 25).

Note: the electrode should be submerged approximately 4 cm (1½")

into the solution. The temperature probe should be positioned

as close to the pH electrode as possible.

ON

HI 7007

(1½
")

4 cm

• Shake briefly and then press the CAL button.

CAL

The printer will print this step by step procedure
instructions.

Dip electrode
in the pH 7
solution, wait
for 'YES' to
appear and then
press CFM

At the same time, the pH symbol will flash to indicate calibration is in
progress.

ºC

°C

pH

The temperature compensated pH value will be displayed. "Err4"
appears if the electrode is in the wrong buffer.

ºC

°C

pH

21

••

• After about 30 seconds, the small display will

••

show "YES": press the CFM key to confirm the
calibration.

The LCD will show "Err5" to indicate that the electrode is now
ready for slope calibration and another step of instruction proce­dures will be printed.

CFM

ºC

°C

pH

Now dip the
electrode in 2nd
solution, wait
for 'YES' to
appear and then
press CFM

HI 7004

(1½
")

••

• Rinse and immerse the pH electrode and tem-

••

perature probe in pH 4.01 or pH10.01 solution.
The LCD shows the corresponding buffer value at the working

temperature. If "Err5" does not disappear this means that the
buffer is not recognized as pH4 or pH10.

ºC

°C

••

• After about 30 seconds, the small LCD confirms the reading by

••

pH

displaying "YES".

• Press the CFM key and the printer will confirm

CFM

that the pH calibration is completed.

4 cm

Calibration is
now completed.

22

PH CALIBRATION FOR HI9318

Procedure

••

• Switch the instrument on after connecting the

••

electrode and temperature probe.

••

• Immerse the pH electrode and the ATC probe

••

into pH 7.01 buffer solution. Shake briefly and
wait 1-2 minutes for thermal equilibrium.

Note: the electrode should be submerged approxi-

mately 4 cm (1½") into the solution. The temperature probe

should be positioned as close to the pH electrode as possible.

ON

HI 7007

(1½

4 cm

")

••

• Press the CAL key.

••

The printer will then print
step by step instructions for
the calibration procedure.

Dip the electro­de in the pH 7
solution; wait
30 sec and then

CAL

press CON

ºC

°C

pH

At the same time, the pH symbol will flash to indicate that
calibration is in progress. The pH value at the measured (or
manually) adjusted temperature will be displayed (see page 26).

If "Err4" appears on the display it means the electrode is in the
wrong buffer. Check to make sure that the electrode is in the pH

7.01 beaker and wait for the "Err4" to disappear.

ºC

°C

••

• After approximately 30 seconds, press the CON key to confirm the

••

pH

calibration.
The printer will print further instructions for the calibration procedure.

CON

Now dip the e­lectrode in 2nd
solution, wait
30 sec and then
press CON

23

The LCD will show "Err5" to indicate that the electrode is now
ready for slope calibration.

ºC

°C

pH

• Immerse the pH electrode and the probe into

pH4.01 or 10.01 solution.

The LCD will show the corresponding buffer value
at the working temperature.

ºC

°C

••

• Wait approximately 30 seconds, and then press

••

pH

the CON key to confirm the calibration.
The printer will confirm the calibration process

is complete

Calibration com­pleted

HI 7004

CON

(1½

4 cm

")

The calibration is now complete.

24

CALIBRATION WITH MANUAL TEMPERATURE COMPEN­SATION

If for some reason the temperature probe is defective, or it is required
to calibrate with manual temperature compensation, follow the proce­dure below:

• Unplug the temperature probe from the meter.

• Note the temperature of the buffer with a

ChecktempC or a glass thermometer.

For HI9017 only

To manually set a temperature value (e.g. 20.0°C) proceed as follows:

• press 2 key

• press 0 key

• press TEMP key.

°C

20

TEMP

°C

ºC

The value will be displayed on the left LCD and "°C" symbol will be
flashing.

• For HI9218 and HI9219 only

Use the UP or DOWN keys to manually adjust the display reading
to the value of the reference thermometer (e.g. 20°C). The value
will be displayed on the left LCD and "°C" symbol will be flashing.

UP

DOWN

ºC

°C

• For HI9318 only

Press the +/- key (for eventual negative figures) followed by the
noted temperature on the numeric keypad. The value will be
displayed on the small LCD. Then press the TEMP key and the
manually set temperature will be displayed on the right LCD with
the "°C" symbol blinking.

SAMPLE

20

••

• Follow the calibration procedure as for pH calibration with tem-

••

DATE

TEMP.

ºC

°C

perature probe connected (see page 18 for HI9017 or page 21 for
HI9218/HI9219 or page 23 for HI9318).

25

PP

H VALUES AT VARIOUSH VALUES AT VARIOUS

P

H VALUES AT VARIOUS

PP

H VALUES AT VARIOUSH VALUES AT VARIOUS

TEMPERATURETEMPERATURE

TEMPERATURE

TEMPERATURETEMPERATURE

The calibration buffer solutions are effected by temperature changes to
a lesser degree than normal solutions.

When manually entering the calibration values (see program #1 for
HI9017 and program #2 for HI9318) please refer to the following chart.

pH Buffers

°C °F 4.01 6.86 7.01 9.18 10.01

0

5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95

32
41
50
59
68
77
86

95
104
113
122
131
140
149
158
167
176
185
194
203

4.01

4.00

4.00

4.00

4.00

4.01

4.02

4.03

4.04

4.05

4.06

4.07

4.09

4.11

4.12

4.14

4.16

4.17

4.19

4.20

6.98

6.95

6.92

6.90

6.88

6.86

6.85

6.84

6.84

6.83

6.83

6.84

6.84

6.85

6.85

6.86

6.86

6.87

6.88

6.89

7.13

7.10

7.07

7.04

7.03

7.01

7.00

6.99

6.98

6.98

6.98

6.98

6.98

6.99

6.99

6.99

7.01

7.02

7.03

7.04

9.46

9.39

9.33

9.27

9.22

9.18

9.14

9.10

9.07

9.04

9.01

8.99

8.97

8.95

8.93

8.91

8.89

8.87

8.85

8.83

10.32

10.24

10.18

10.12

10.06

10.01

9.96

9.92

9.88

9.85

9.82

9.79

9.77

9.76

9.75

9.74

9.73

9.74

9.75

9.76

When using automatic calibration, the appropriate value will be dis­played. For instance, if the buffer temperature is at 25°C, the display
will show "pH 4.01" or "7.01" or "10.01". If the buffer temperature is
at 20°C, the display will show "pH 4.00"/"7.03"/"10.06". If the
buffer temperature is at 50°C, the display will show pH "4.06"/
"6.98"/"9.82".

TEMPERATURE CALIBRATIONTEMPERATURE CALIBRATION

TEMPERATURE CALIBRATION

TEMPERATURE CALIBRATIONTEMPERATURE CALIBRATION

All Hanna bench-top meters have been accurately pre-calibrated in
temperature at the factory.

We recommend that you have your bench-top meters re-calibrated in
temperature once a year. Your nearest Hanna Service Center is avail­able to quickly service your meter. Contact your Dealer or the nearest
Hanna Service Center for more information.

26

HOW TO SET DATE AND TIMEHOW TO SET DATE AND TIME

HOW TO SET DATE AND TIME

HOW TO SET DATE AND TIMEHOW TO SET DATE AND TIME

(H(H

II

9218 & H9218 & H

(H

I

9218 & H

(H(H

II

9218 & H9218 & H

II

9219)9219)

I

9219)

II

9219)9219)

Press the PRINT key to get a printout of date and time. If you want to
change them, proceed as follows.

To set the date, press and hold
the DATE key.

DATE

The meter will give all instruc­tions to set this function.

Press UP or DOWN
key to set
year, or press
DATE key again
to continue

Press UP or DOWN
key to set
month, or press
DATE key again
to continue

Press UP or DOWN
key to set
day, or press
DATE to end

DATE: 21-01-96

DD-MM-YY

To set the time, press and hold
the TIME key.

TIME

The printer will help you giv­ing precise instructions.

Press UP or DOWN
key to set
hour, or press
TIME key again
to continue

Press UP or DOWN
key to set
minute, or press
TIME key again
to continue

TIME: 0842 Hr

27

PROGRAMS OF HI9017PROGRAMS OF HI9017

PROGRAMS OF HI9017

PROGRAMS OF HI9017PROGRAMS OF HI9017

ENTERAENTERBCLEAR

7

89

56

4

1

23

0

.

ins

ON

CAL

PGM

+/-

rum n

OFF

RANGE

CON

TEMP

s

There are all together 6 programs in the instrument. To select a
particular program, press the program number on the numeric key­board followed by the PGM key.

E.g. To select program 1

• press 1

• press PGM

1

PGM

pH

ENTER

A

At this stage, the left display shows "Px - y" (where
x refers to program number that you had pressed
and y refers to ENTER A or ENTER B). The right
display always shows the measured value of pH or
mV depending on the selected range.

Whenever a numeric value is entered, the entry
appears on the left display. There will be a long
beep after either ENTER A or ENTER B is pressed,
when the entered value is either wrong or not
acceptable by the particular program.

28

ENTER

B

The 6 programs stored in the instrument are:

Program 1: To manually enter calibration buffer values
Program 2: To set upper and lower pH alarm limits
Program 3: To set upper and lower mV alarm limits
Program 4: To set upper and lower temperature alarm limits
Program 5: To set end point and alert value pH alarms
Program 6: To set RS232C Esc code (Default value is 16 decimal)

To stop or exit any program:

• press 0

• press PGM

0

PGM

Note: the instrument must be in pH mode for program 1, 2 and 5.

Likewise the instrument must be in mV mode for program 3.
Otherwise a long beep will sound.

PROGRAM # 1 (HI 9017)

Setting of calibration buffer values other than those already memo­rized (pH 4, 7 and 10), e.g. pH 6.86 (HI7006 or HI8006) and
pH 9.18 (HI7009 or HI8009):

• set the instrument to the pH mode

• press 1

• press PGM

At this stage, the left display shows "P1-1", and the

1

PGM

right display shows the measured pH value.
Dip the electrode and the temperature probe into

HI7006 or HI8006 (pH6.86) buffer solution. Wait
for 30 seconds. Check the appropriate value for the
buffer at the measured buffer temperature from stan­dard charts (see page 26).

RANGE

pH

(1½

4 cm

")

HI 7006

29

e.g. 6.95 at 5°C:

• press 6

• press decimal point

• press 9

• press 5

• press ENTER A

ENTER

6 . 95

A

pH

pH

Value 6.95 appears on the left display with pH symbol blinking. If
there is a difference of 1 pH between the two displays, there will be a
long beep.

Otherwise,

CON

• press the CON key.

The left display value is transferred to the right display and the left
display shows "P1-2".

pH

Rinse the electrode and dip it with the temperature
probe into the second solution HI7009 or HI8009
(pH 9.18), the value of which for example is 9.39
at 5°C (read from the standard charts). Wait for 30

HI 7009

(1½

4 cm

")

seconds.

• press 9

• press decimal point

• press 3

• press 9

• press ENTER B

ENTER

9 . 39

B

pH

pH

The value "9.39" appears on the left display with a blinking pH
symbol. If there is a difference of 1 pH between the two displays, there
is a long beep.

Otherwise,

CON

• press the CON key.

30

The left display value is transferred to the right display and the left
display shows the temperature value.

ºC

°C

pH

The instrument is now completely calibrated and switches back to the
normal operating mode.

::

Notes

:

::

• If you wish to calibrate the instrument with the offset only, exit the
program by pressing 0 and PGM keys after the first CON key is
pressed.

• The instrument accepts any 2 buffers provided the difference
between the buffer values is at least 2 pH units. Any buffer can be
used first.

E.g. pH 4.01 (HI7004 or HI8004) and pH10.01 (HI7010

or HI8010)

or pH 4.01(HI7004 or HI8004) and pH6.86 (HI7006

or HI8006)

PROGRAM # 2 (HI 9017)

Setting the upper and lower pH alarm limits.
When either limit is reached, the alarm

will be activated and the value will flash
simultaneously.

When the CLEAR key is pressed, the alarm will be
deactivated while the value will remain flashing.

To stop:

• press 0

• press PGM.

pH

CLEAR

0

PGM

E.g. activation of alarm for values higher than 9.32 and lower than pH 6.03.

• set the instrument to the pH mode

• press 2

RANGE

• press PGM

31

At this stage, the left display shows "P2-1", and the right display
shows the measured pH value.

2

PGM

pH

• press 9

• press decimal point

• press 3

• press 2

• press ENTER A

The left display then shows "P2-2".

ENTER

9 . 32

A

pH

• press 6

• press decimal point

• press 0

• press 3

• press ENTER B.

6 . 03

ENTER

B

ºC

°C

pH

PROGRAM # 3 (HI 9017)

Setting of upper and lower mV alarm limits.
When either limit is reached, the alarm

will be activated and the value will flash
simultaneously.

When the CLEAR key is pressed, the alarm
will be deactivated.

For negative values:
e.g. -100.9 mV and -500mV, -100.9 mV should be treated as larger

than -500mV.
To stop:

• press 0

• press PGM.

mV

0

PGM

32

E.g. activation of alarm for values higher than 500 mV and lower than

-20.3 mV.

• set the instrument to the mV mode

RANGE

• press 3

• press PGM.

3

PGM

mV

At this stage, the left display shows "P3-1", and the right display mV
value.

• press 5

• press 0

• press 0

• press ENTER A

500

ENTER

A

mV

The left display then shows "P3-2".

• press 2

• press 0

• press decimal point

• press 3

• press +/-

• press ENTER B.

. 302+/-

ENTER

B

°C

ºC

mV

PROGRAM # 4 (HI 9017)

Setting of upper and lower temperature alarm limits.
When either limit is reached, the alarm

will be activated and the value will flash
simultaneously.

When the CLEAR key is pressed, the alarm will
be deactivated while the value will remain
flashing.

33

ºC

°C

CLEAR

To stop:

• press 0

• press PGM.

0

PGM

E.g. activation of alarm for values higher than 49.3°C and lower than

-6.3°C.

• press 4

• press PGM.

4

PGM

pH

At this stage, the left display shows "P4-1".

• press 4

• press 9

• press decimal point

• press 3

4

• press ENTER A

9

. 3

ENTER

A

pH

The left display then shows "P4-2".

• press 6

• press decimal point

• press 3

• press +/-

• press ENTER B

ENTER

6

. 3

+/-

B

ºC

°C

pH

34

PROGRAM # 5 (HI 9017)

Setting of endpoint and alert pH alarm values.
When the alert value is reached i.e. between the final value and the

alert value, there will be a single alert beep.
When the endpoint value is reached, the

alarm will be activated continuously and
the value will simultaneously flash.

To clear the alert or alarm, press the CLEAR
key.

To stop:

• press 0

• press PGM.

pH

CLEAR

0

PGM

E.g. activation of alarm for an endpoint value of pH 9.32 and alert
value of pH 9.03.

• set the instrument to the pH mode

• press 5

RANGE

• press PGM.

5

PGM

pH

At this stage, the left display shows "P5-1" and the right display
shows the measured pH value.

• press 9

• press decimal point

• press 3

• press 2

• press ENTER A.

ENTER

.

9

32

A

pH

35

The left display then shows "P5-2".

• press 9

• press decimal point

• press 0

• press 3

• press ENTER B.

9

. 30

PROGRAM #6 (HI9017)

Setting of RS232C ESC code.
E.g. ESC code is 20 (decimal).

• press 6

• press PGM.

ENTER

B

°C

ºC

pH

6

PGM

pH

At this stage, the left display shows "P6-1".

• press 2

• press 0

• press ENTER A.

ENTER

02

A

°C

ºC

pH

Note: the ESC code should be between 0 - 127 decimal, the default is

16.

36

PROGRAMMINGPROGRAMMING

PROGRAMMING

PROGRAMMINGPROGRAMMING

LOGGER FUNCTIONS OF HI9318LOGGER FUNCTIONS OF HI9318

LOGGER FUNCTIONS OF HI9318

LOGGER FUNCTIONS OF HI9318LOGGER FUNCTIONS OF HI9318

The following section explains how each of the HI 9318's logging
programs work.

Each program has up to 3 functions defined by the A, B and C key.
For program #4, #5 and #6 only, you can log pH or mV values

depending on the RANGE key selection.

PROGRAM #1 (HI9318)

This program allows the user to set sample number, time and date.
Values entered into program 1 are kept in memory even when pro­grams 2 to 9 are used.

To enter program 1:

1

1) Push the 1 key and then the PGM
key. The printer will then define
the three functions:

A

is the sample num-

ber,
B is time,

PROGRAM 1
A set sample no.
B set time
C set date

C is the date.

2) To set the sample number (A) choose any number from 1 to 999.
Push the desired number followed by the A key and the printer

prints the value.
Samples after 999 will be reset to zero and the sample number

will automatically advance from 0 to 999 in increments of 1, each
time the instrument logs and/or prints a reading.

E.g. sample number 200

PGM

PROGRAM 1
A set sample no.
B set time
C set date

Sample number

37

A20.0

200

3) The time value (B) can be set for a 24 hour clock. 2 P.M., for
example equals 14.00. Push "14.00" followed by "B".

14. 0

0

B

PROGRAM 1
A set sample no.
B set time
C set date

Sample number

200

Time

14.00

4) When setting the date (C), enter the month first. Separate month
and day with a decimal point. E.g. February 4th is entered as
"2.04" followed by "C".

2 . 04

PROGRAM 1
A set sample no.
B set time
C set date

C

Sample number

Time

Date

5) Push the 0 key and then the
PGM key to exit from pro­gram mode.

38

200

14.00

2.04

0

PGM

PROGRAM #2 (HI9318)

This program lets you calibrate with buffer values other than 4, 7 and
10 pH which are pre-programmed into memory.

To enter program 2, press the 2 key

2

PGM

and then the PGM key.

A is the first buffer value and
B is the second buffer value.

PROGRAM 2
A enter 1st buf­ fer
B enter 2nd buf­ fer

The buffers can be anywhere between 0 and 14 pH.

Example:

To calibrate with NBS buffers 6.86 pH and 9.18 pH at a temperature
of 10°C.

The corresponding pH values at this temperature are 6.92 and 9.33
respectively.

Immerse the pH electrode and the temperature probe
into the 1st buffer (e.g. pH 6.86).

Check the appropriate value for the buffer at the

HI 7006

(1½

4 cm

")

measured buffer temperature (see page 26).
After about 30 seconds enter the 1st buffer value at the working

temperature followed by "A". E.g. 6.92 (at 10°C).

6 . 92

A

PROGRAM 2
A enter 1st buf­ fer
B enter 2nd buf­ fer

1st buffer

6.92

Rinse the electrode and immerse it in the 2nd buffer
(e.g. pH 9.18).

39

HI 7009

(1½

4 cm

")

Check the appropriate value for the buffer at the measured buffer
temperature (see page 26).

After about 30 seconds enter the 2nd buffer value at the working
temperature and then press "B". E.g. 9.33 (at 10°C).

9 . 33

PROGRAM 2
A enter 1st buf­ fer
B enter 2nd buf­ fer

1st buffer

6.92

2nd buffer

9.33

B

Press the 0 key followed by the PGM key.
The calibration is now complete.

PROGRAM #3 (HI9318)

This program prints the date, time, the offset and slope characteristics
of the pH electrode.

Note: the offset and the slope characteristics of the electrode are

referred to the last performed pH calibration.
No programming is required.
Simply press the 3 key and the PGM

key.
Changes in an electrode's performance

can be determined from this information.
If the electrode's offset is within 0.50 pH and 1.00 pH or -0.50 pH

and -1.00 pH, it indicates contamination. If the value exceeds ±1
pH the electrode should be
replaced.

The slope characteristic is in
percentage of the theoreti­cal value of 58.16 mV per
pH unit at 20°C.

3

PROGRAM 3
DATE 2/04
TIME 14:04
OFFSET 0.16
SLOPE 95.3%

PGM

40

PROGRAM # 4 (HI9318)

This program logs and prints pH/mV and temperature values at a
preset interval between 1 minute and 24 hours.

To enter the program press the 4

4

PGM

key and the PGM key.

The printout defines functions
A, B and C:

PROGRAM 4

A is a start time,
B

is the time interval,

C

is the finish time.

Hours and minutes must be
separated by a decimal point.

A enter start
time
B enter time int­ erval
C enter end time

The minimum time interval is
1 minute.

E.g. Starting time 10:20, finishing time 11:30 with a printout interval
of 5 minutes.

1)

2)

3)

1

0

1

0

.

1

.

0

.

2

5

3

0

B

0

A

C

When the instrument is in this mode and it is desired to stop before
the end time, press the 0 key plus the PGM key.

PROGRAM #5 (HI9318)

This is the same as program 4 except that function "C" allows you to
select an interrupt value for pH/mV instead of end time.

When this interrupt value is exceeded, the program prints the hour and
minute of the endpoint.

To enter the program press the 5
key plus the PGM key.

41

5

PGM

The printout defines functions A, B and C:

A is a start time,
B

is the time interval,

C is the interrupt value of
pH/mV.

Hours and minutes must be
separated by a decimal
point. The minimum time in­terval is 1 minute.

PROGRAM 5

A enter start
time
B enter time in­ terval
C enter end
pH/mV value

E.g. Starting time 10:30, a printout interval of 1h and 30 minutes, pH
interruption value 3.50.

1)

2)

3)

1

1

3

0

.

.

.

3

5

3

0

0

0

B

C

If you need to interrupt the program before the endpoint is reached,
press the 0 key plus the PGM key or enter into any other program.

PROGRAM #6 (HI9318)

To enter the program press the 6

6

PGM

key plus the PGM key.

This program allows you to
set upper and lower limits
for pH/mV values.

PROGRAM 6

A set lower limit

A beeper will sound when­ever the measured value
exceeds the limit.

B set upper limit

C clear alarm

A

42

E.g. lower limit 6.5, upper limit 7.5.

6

7

.

.

5

5

A

B

To stop the beeper from sounding when the limit is exceeded, press
the C key.

To definitely exit the program press the 0 plus the PGM key.

PROGRAM #7 (HI9318)

This program allows the user to select a different working language.

Press the 7 key and then the PGM
key.

The printer will print out a
list of languages available.

The default working lan­guage is English.

To choose a language, key
in the corresponding num­ber then press the A key.

E.g. how to select French.

A3

PROGRAM 7

A select the lan­guage:

1. English

2. Deutch

3. Français

4. Español

5. Italiano

6. Svenska

7

PGM

Français

Press the PRINT key and the printout will be in French.

PRINT

DATE (M/J) 2/04
HEURE 10.20
ECHANTILLON 215
°C 20.0
pH 6.52

43

PROGRAM #8 (HI9318)

This program prints out the ion con­centration in M for the pH value
measured.

To activate the program, press the 8
key and then the PGM key.

PROGRAM 8

3.88 pH--

0.132 mM H+

Note: Make sure the meter is in pH mode, otherwise a long beep will

be heard.

8

PGM

PROGRAM #9 (HI9318)

For more details see "Interface with computer" section on page 46.
Press the 9 key and then the PGM

key.

Enter the ASCII Code of the desired
prefix character and then press the
A key.

9

PROGRAM 9

PGM

E.g. 64

6

4

A

Escape character

44

A enter ASCII
code for escape
character

64

TROUBLESHOOTING GUIDETROUBLESHOOTING GUIDE

TROUBLESHOOTING GUIDE

TROUBLESHOOTING GUIDETROUBLESHOOTING GUIDE

Symptoms are:

The instrument does
not work with the ATC
probe.
The meter fails to
calibrate or gives er­roneous results.
The meter is slow in
responding or gives
erroneous readouts

The meter does not
accept the 2nd buffer
solution
The reading drifts
"Err1" on the display

"Err2" on the display
(for HI9017 and
HI9318 only)

"Err3" on the display

"Err4" on the display

"Err5" on the display

Note: when the temperature display is showing "Err3" the pH

display is always showing "Err1".

The problem is:

A defective ATC probe

A defective pH elec­trode

The electrode is not
working or the dia­phragm is clogged

A defective pH elec­trode

A defective pH electrode
Out of range on the
pH scale

Out of range in mV

Out of range in tem­perature
Erroneous buffer so­lution used for offset
calibration
Defective electrode

Erroneous buffer so­lution used for slope
calibration
Defective electrode

45

Possible Solutions:

Replace the probe.

Replace the electrode
and repeat the pH cali­bration
Leave the electrode in a
storage solution after
cleaning the junction. If
the problem is not solved,
replace the electrode and re­calibrate the pH scale.
Try the cleaning procedure.
If this does not work, re­place the electrode.
Replace the electrode.
a) Verify the pH electrode
is connected.
b) Make sure the
sample's pH is included
between 0 and 14
c) Check the level of the
electrode's filling electro­lyte and the state of the
electrode itself.
a) Verify the pH electrode
is connected.
b) Make sure the mV is
within ±1999 range.
Make sure the temperature
is within -10 and 125°C
Make sure that the buffer
solution used is pH 7 and
replace if necessary.
Replace the electrode
and re-calibrate pH
By sure the correct pH
solution is being used for
slope calibration.
Check the electrode and
replace if necessary.

INTERFACE WITH COMPUTERINTERFACE WITH COMPUTER

INTERFACE WITH COMPUTER

INTERFACE WITH COMPUTERINTERFACE WITH COMPUTER

Data transmission from the instrument to
the PC is now much easier with the new
HI92000 Windows® compatible applica-
tion software offered by Hanna Instruments.

User friendly, HI92000 offers a variety of
features and has an on line help feature to
support you throughout all situations.

HI92000 allows you to use the powerful means of the most diffused
spread sheet programs (e.g. Excel©, Lotus 1-2-3©). Simply run your
favorite spread sheet and open the file downloaded by HI92000. It is
then possible to make any elaboration available with your software
(e.g. graphics, statistical analysis).

To install HI92000 you need a 3.5" drive and few minutes to follow
the instructions conveniently printed on the disk’s label.

Contact your Hanna Dealer to request a copy.
To connect your Hanna Instruments bench meter to the PC use

HI920010, available through your Hanna Dealer. Make sure that your
meter is switched off and plug the connectors, one into the meter
RS232C connector, the other into the serial port of your PC.

Note: Cables different from the HI920010 may use a different con-

figuration. In such case any communication between the meter

and the PC is not possible.

SETTING THE BAUD RATE

The transmission speed (baud rate) of the meter and the external
device must be identical. The meter is factory set to 1200.

If you wish to change this value, please contact your nearest Hanna
Center.

SENDING COMMANDS FROM PC

With terminal programs such as, for example, Telix®, Windows Termi­nal®, it is possible to remotely control your Hanna Instruments bench
meter. Use HI920010 cable to connect the meter to the PC, start the
terminal program and set the communication options as follows: 8, N,
1, no flow control.

COMMAND TYPES

To send a command to the pH meter the scheme is:
<DLE> <command> <CR>

Excel© Copyright of "Microsoft Co."
Lotus 1-2-3© Copyright of "Lotus Co."
Windows® and Windows Terminal ® are registered Trademark of "Microsoft Co."
TELIX® is registered Trademark of "Deltacomm"

46

This line makes the computer send a Data Link Escape character (the
command expressed as a number or a 3-character sequence) and a CR
character.

Note: Windows Terminal® and all the other terminal programs that

support the ANSI escape sequence, represent the DLE character

by the string ‘^P’ and the CR character by the string ‘^M’.

E.g. the line ‘^PPHR^M’ sets the range to pH.

TYPE OF COMMANDS

Commands not requiring an answer from the pH meter.

PHR sets the range to pH
MVR sets the range to mV

Commands requiring an answer:

PH? Causes the pH meter to send the pH value through the serial

interface. If the reading is out of range ("Err1"), "Err1" is sent

instead of the pH value.

If the range is set to mV (no pH reading available), "Err6" is

sent (for HI9218 and HI9219 only).
MV? Causes the pH meter to send the mV value through the serial

interface. If the reading is out of range ("Err2"), "Err2" is sent;

if the range is set to pH, "Err6" is sent.
TM? Causes the pH meter to send the temperature value. If this is

out of range, an "Err3" signal is sent instead.
For HI9218,

HI9219 and

HM? This orders the pH meter to send the time value (in hours and

minutes), A 5-character string is sent in HH.MM format.
MD? This orders the pH meter to send the data value (in months and

days). A 5 character string is sent in MM.DD format.
These commands may be sent with either capital or small letters. The

characters sent by the meter are always capital letters.
For HI9318 only:
a) Numerical data: a command line containing figures , the minus

sign and the decimal point will be interpreted by the pH meter as
if that number was sent by means of the keyboard. The maximum
number of figures allowed is 4.

b) Commands which do not require a response by the pH meter:
CAL is equivalent to pressing the CAL key
CON is equivalent to pressing the CON key
AKY is equivalent to pressing the A key

HI9318 only:

Windows Terminal ® is registered Trademark of "Microsoft Co."

47

BKY is equivalent to the B key
CKY is equivalent to pressing the C key
PGM is equivalent to pressing the PGM key
TEM is equivalent to pressing the TEMP key
PRT is equivalent to pressing the PRINT key
CLR is equivalent to pressing the CLEAR key
PHR brings the instrument into pH measurement range
MVR brings the instrument into the mV measurement range
PAP causes the paper to advance by one tenth of a line. In order to

advance the paper by one entire line, send a RETURN charac-

ter.
TIM causes the time to be shown on the date/time display
DAT causes the date to be shown on the date/time display
CHP sets the printer in the character printout mode
PPR sets the printer in the graph printout mode
KBS after this command, the keys pressed on the pH keyboard are

no longer recognized by the pH meter itself, but instead pro-

voke the transmission of a string to the host computer. Only the

OFF and the PAPER keys retain their proper functions. In this

way, the keyboard may also function as an input device to the

host computer, as well as command the pH meter.

Naturally the pH meter continues to obey the commands which

are equivalent to the keys pressed and sent by means of serial

interface.
KBU cancels the KBS command

The 4 commands IDL, SEP, SEV and RV? are reserved for future use
and are not described here.

INTERFACE WITH PC

If you are not using Hanna Instruments HI92000 application soft­ware, please find here below some additional information to help your
connection to the PC.

HOW TO CHANGE THE COMMAND PREFIX CHARACTERS
(FOR HI9017 & HI9318 ONLY)

It is sometimes necessary to change the character used to indicate that
a command is to follow.

If the computer connection already makes use of DLE of other func­tions, its use as a prefix for "c"-type commands may cause problems to
the operating system.

In order to change the prefix character run program #6 for HI9017,
by pressing the 6 key and then the PGM key or run program #9 for

48

HI9318 by pressing the 9 key and then the PGM key.
Enter the ASCII Code of the desired prefix character and then press the

ENTER A key for HI9017 or the A key for HI9318.
It is advisable to use a control character as a prefix (not RETURN,

which already performs other functions) or a non-control character
which is not being used for other purposes, for example the "@" sign
(ASCII Code64).

MORE ABOUT KBS COMMAND (FOR HI9318 ONLY)

The KBS Command (KeyBoard Send) disconnects the keyboard from
the pH meter and connects it to the RS 232C interface.

Whenever a key is pressed on the keyboard, a string of characters
which represents the key itself is sent by means of interface, followed
by a RETURN character.

The strings corresponding to the various keys are the following:

- the figures from 0 to 9 for the numbered keys;

- the minus sign (-) for the +/- key;

- the full stop (.) for the decimal point.
The other keys (CAL, CON, A, B, C, DATE, RANGE, PGM, TEMP, PRINT

and CLEAR) are represented by their own abbreviations.
The OFF and PAPER keys maintain their own functions and are not

sent to the computer.

GRAPHIC PRINTOUT (FOR HI9318 ONLY)

The HI 9318 printer may also be programmed for graphic mode
printing for the reproduction of bit graphs and maps: every 16 bytes of
data received from the pH meter produce an elementary line of dots
rather than a line of text.

In order to print one or more lines of dots (96 dots per line), the
computer must first send the PPR command to set the printer in the
graphic mode, then:

- divide the 96-dot line into 16 segments of 6 dots long,

- interpret each segment as a binary number (the left most dot will

be the most significant bit),

- add hexadecimal 20 or decimal 32 to each binary number and

- send the 16 numbers as 16 characters.

49

ELECTRODE CONDITIONINGELECTRODE CONDITIONING

ELECTRODE CONDITIONING

ELECTRODE CONDITIONINGELECTRODE CONDITIONING

AND MAINTENANCEAND MAINTENANCE

AND MAINTENANCE

AND MAINTENANCEAND MAINTENANCE

Reference
Filling Hole

Reference
Filling Hole

Sensitive
Wire

Reference
Wire

Reference
Junction

Glass
Bulb

Reference
Wire

Reference
Junction

Platinum or
Gold tip

Plastic Body

pH Electrode

Reference

Plastic Body

ORP Electrode

Glass Body

pH Electrode

Wire

Glass Body

ORP Electrode

Reference

Wire

Sensitive

Wire

Reference

Junction

Glass

Bulb

Reference

Junction

Platinum or

Gold tip

PREPARATION

Remove the protective cap.
DO NOT BE ALARMED IF ANY SALT DEPOSITS ARE PRESENT.
This is normal with electrodes and they will disappear when rinsed

with water.
During transport tiny bubbles of air may have formed inside the glass

bulb. The electrode cannot function properly under these conditions.
These bubbles can be removed by "shaking down" the electrode as
you would do with a glass thermometer.

If the bulb and/or junction are dry, soak the electrode in HI70300 or
HI80300 Storage Solution for at least one hour.

50

For refillable electrodes:

If the filling solution (electrolyte) is more than 1 cm (½") below the
fill hole, add HI7082 or HI8082 3,5M KCl Electrolyte Solution for
double junction or HI7071 or HI8071 3,5M KCl+AgCl Electrolyte
Solution for single junction electrodes.

For a faster response, unscrew the fill hole screw during measure­ments.

For AmpHel electrodes:

If the electrode does not respond to pH changes, the battery is run
down and the electrode should be replaced.

MEASUREMENT

Rinse the electrode tip with distilled water.
Immerse the tip (4 cm /1½") in the sample and stir gently for at least

30 seconds.
For a faster response and to avoid cross contamination of the samples,

rinse the electrode tip with a few drops of the solution to be tested,
before taking measurements.

STORAGE

To minimize clogging and assuring a quick response time, the glass
bulb and the junction should be kept moist and not allowed to dry out.

Replace the solution in the protective cap with a few drops of HI70300
or HI80300 Storage Solution or, in its absence, Filling Solution
(HI7071 or HI8071 for single junction or HI7082 or HI8082 for
double junction electrodes).

Follow the Preparation Procedure above before taking measurements.

Note: NEVER STORE THE ELECTRODE IN DISTILLED WATER OR DRY.

PERIODIC MAINTENANCE

Inspect the electrode and the cable. The cable used for connection to
the meter must be intact and there must be no points of broken
insulation on the cable or cracks on the electrode stem or bulb.
Connectors must be perfectly clean and dry.

If any scratches or cracks are present, replace the electrode.
Rinse off any salt deposits with water.

For refillable electrodes:

Refill the reference chamber with fresh electrolyte (HI7071 or HI8071
for single junction or HI7082 or HI8082 for double junction elec­trodes). Allow the electrode to stand upright for 1 hour.

Follow the Storage Procedure above.

51

CLEANING PROCEDURE

General Soak in Hanna HI7061 or HI8061 General Cleaning
Solution for approximately 1 hour.

Removal of films, dirt or deposits on the membrane/junction:

- Protein Soak in Hanna HI7073 or HI8073 Protein Cleaning So-
lution for 15 minutes.

- Inorganic Soak in Hanna HI7074 or HI8074 Inorganic
Cleaning Solution for 15 minutes.

- Oil/grease Rinse with Hanna HI7077 or HI8077 Oil and

Fat Cleaning Solution.
IMPORTANT: After performing any of the cleaning procedures rinse

the electrode thoroughly with distilled water, drain and refill the
reference chamber with fresh electrolyte, (not necessary for GEL filled
electrodes) and soak the electrode in HI70300 or HI80300 Storage

Solution for at least 1 hour before taking measurements.

TROUBLESHOOTING

Evaluate your electrode performance based on the following.

• Noise (Readings fluctuate up and down) could be due to:

- Clogged/Dirty Junction: Refer to the Cleaning Procedure above.

- Loss of shielding due to low electrolyte level (in refillable elec-

trodes only): refill with fresh HI7071 or HI8071 for single junction
or HI7082 or HI8082 for double junction electrodes.

• Dry Membrane/Junction: Soak in Storage Solution HI70300

or HI80300 for at least 1 hour.

• Drifting: Soak the electrode tip in warm Hanna Solution HI7082

or HI8082 for one hour and rinse tip with distilled water. Refill
with fresh HI7071 or HI8071 for single junction electrodes and
HI7082 or HI8082 for double junction electrodes.

• Low Slope: Refer to the cleaning procedure above.

• No Slope: Check the electrode for cracks in glass stem or bulb

and replace the electrode.

• Slow Response/Excessive Drift: Soak the tip in Hanna Solution

HI7061 or HI8061 for 30 minutes, rinse thoroughly in distilled

water and then follow the Cleaning Procedure above.

52

TEMPERATURE-RESISTANCE CORRELATIONTEMPERATURE-RESISTANCE CORRELATION

20

0 +10+20 +30+40+50+60+70 +80+90

C

TEMPERATURE-RESISTANCE CORRELATION

TEMPERATURE-RESISTANCE CORRELATIONTEMPERATURE-RESISTANCE CORRELATION

FOR HANNA FOR HANNA

FOR HANNA

FOR HANNA FOR HANNA

pp

H SENSITIVE GLASSH SENSITIVE GLASS

p

H SENSITIVE GLASS

pp

H SENSITIVE GLASSH SENSITIVE GLASS

The resistance of glass electrodes partially depends on the temperature.
The lower the temperature, the higher the resistance. It takes longer time
for the reading to stabilize if the resistance is higher. In addition, the
response time will suffer to a greater degree at temperatures below 10°C.

Ω

Ω

9

2x10

-10

9

1x10

-10

8

-10

2x10

8

1x10

-10

7

2x10

-10

-10

7

1x10

-10

-20-

-20 -1 0 0 +10 +20+30+ 40+50+60 + 70 +80 +90 °C

°

Since the resistance of the pH electrode is in the range of 200 Mohm,
the current across the membrane is in the pico Ampere range. Large
currents can disturb the calibration of the electrode for many hours.

For these reasons high humidity environments, short circuits and
static discharges are detrimental for a stable pH reading.

The pH electrode's life also depends on the temperature. If constantly
used at high temperatures, the electrode life is drastically reduced.

Typical Electrode Life
Ambient Temperature 1- 3 years
90 °C Less than 4 months
120°C Less than 1 month

High concentrations of sodium ions interfere with readings in alkaline
solutions; the pH at which the interference starts to be significant
depends upon the composition of the glass. This interference is the
alkaline error and causes the pH to be underestimated. Hanna's glass
formulations have the indicated characteristics.

Alkaline Error

Sodium Ion Correction for the Glass at 20-25°C
Concentration pH Error

0.1 Mol L-1 Na

1.0 Mol L-1 Na

+

+

13.00

13.50

14.00

12.50

13.00

13.50

14.00

0.10

0.14

0.20

0.10

0.18

0.29

0.40

53

ACCESSORIESACCESSORIES

ACCESSORIES

ACCESSORIESACCESSORIES

pH CALIBRATION SOLUTIONS

HI 70004P pH 4.01 Buffer Sachets, 20mL, 25 pcs
HI 70007P pH 7.01 Buffer Sachets, 20mL, 25 pcs
HI 70010P pH 10.01 Buffer Sachets, 20mL, 25 pcs
HI 7004L pH 4.01 Buffer Solution, 460 mL
HI 7006L pH 6.86 Buffer Solution, 460 mL
HI 7007L pH 7.01 Buffer Solution, 460 mL
HI 7009L pH 9.18 Buffer Solution, 460 mL
HI 7010L pH 10.01 Buffer Sol., 460 mL

pH CALIBRATION SOLUTIONS IN FDA APPROVED
BOTTLES

HI 8004L pH 4.01 Buffer Solution, 460 mL
HI 8006L pH 6.86 Buffer Solution, 460 mL
HI 8007L pH 7.01 Buffer Solution, 460 mL
HI 8009L pH 9.18 Buffer Solution, 460 mL
HI 8010L pH 10.01 Buffer Solution, 460 mL

ELECTRODE STORAGE SOLUTION

HI 70300L Storage Solution, 460 mL

ELECTRODE STORAGE SOLUTION IN FDA APPROVED
BOTTLES

HI 80300L Storage Solution, 460 mL

ELECTRODE CLEANING SOLUTIONS

HI 70000P Electrode Cleaning Sachets, 20 mL, 25 pcs
HI 7061L General Cleaning Sol., 460 mL
HI 7073L Protein Cleaning Sol., 460mL
HI 7074L Inorganic Cleaning Sol., 460mL
HI 7077L Oil & Fat Cleaning Sol.,460 mL

ELECTRODE CLEANING SOLUTIONS IN FDA
APPROVED BOTTLES

HI 8061L General Cleaning Solution, 460 mL
HI 8073L Protein Cleaning Solution, 230 mL
HI 8077L Oil & Fat Cleaning Solution, 460mL

REFILL ELECTROLYTE SOLUTIONS

HI 7071 3.5M KCl + AgCl Electrolyte, 4x50mL, for single junc-

tion electrodes

HI 7072 1M KNO3 Electrolyte, 4x50 mL
HI 7082 3.5M KCl Electrolyte, 4x50 mL, for double junction electrodes

54

REFILL ELECTROLYTE SOLUTIONS IN FDA APPROVED BOTTLES

HI 8071 3.5M KCl + AgCl Electrolyte, 4x50mL, for single junc-

tion electrodes

HI 8072 1M KNO3 Electrolyte, 4x50 mL
HI 8082 3.5M KCl Electrolyte, 4x50 mL, for double junction electrodes

ORP PRETREATMENT SOLUTIONS

HI 7091L Reducing Pretreatment Solution, 460 mL
HI 7092L Oxidizing Pretreatment Solution, 460 mL

pH ELECTRODES

All electrodes part numbers ending in B are supplied with a BNC
connector and 1 m (3.3') cable.

B = BNC CONNECTION PLUG + 1 m (3.3’) CABLE

S = SCREW-TYPE CONNECTOR

HI 1043B / HI1040S

Glass-body, double junction, refillable, combination pH electrode. Use:
strong acid/alkali.

9.5mm DIA

0.37"

HI 1043

120 mm

"S" VERSION

4.7"

HI 1053B / HI1050S

Glass-body, triple ceramic, conic shape, refillable, combination pH
electrode. Use: emulsions.

12 mm

0.5"

12 mm

0.5"

HI 1053

"S" VERSION

120 mm

4.7"

HI 1083B

Glass-body, micro, Viscolene, non-refillable, combination pH elec-
trode. Use: biotechnology, micro titration.

HI 1083

12 mm

0.5"

5 mm

0.2"

120 mm

55

3 mm

0.12"

"

3.0 mm DIA

0.12"

HI 1131B / HI1111S

Glass-body, single junction, refillable, combination pH electrode.
Use: general purpose.

12 mm

0.5"

HI 1131

"S" VERSION

9.5mm DIA

120 mm

4.7"

0.37"

HI 1330B / HI1310S

Glass-body, semimicro, single junction, refillable, combination pH
electrode. Use: laboratory, vials.

HI 1330

"S" VERSION

120 mm

4.7"

5mm DIA

0.2"

5mm

0.2"

HI 1331B / HI1311S

Glass-body, semimicro, single junction, refillable, combination pH
electrode. Use: flasks.

HI 1331

"S" VERSION

8 mm

0.3"

7.5mm DIA

210 mm

8.25"

0.29"

HI 1230B / HI1210S

Plastic-body (Ultem®), double junction, gel-filled, combination pH
electrode. Use: general, field.

12 mm

0.5"

HI 1230

120 mm

"

"

4.7"

HI 2031B / HI2020S

Glass-body, semimicro, conic, refillable, combination pH electrode.
Use: semisolid products.

6 mm

0.25"

HI 2031

75 mm

"

"

Ultem® is registered Trademark of "General Electrics Co."

2.95"

56

HI 1332B / HI1312S

Plastic-body (Ultem®), double junction, refillable, combination pH
electrode. Use: general purpose.

12 mm

0.5"

HI 1332

"S" VERSION

120 mm

4.7"

FC 100B

Plastic-body (Kynar®), double junction, refillable, combination pH
electrode. Use: general purpose for food industry.

12 mm

0.5"

FC 100

120 mm

4.7"

FC 200B / FC200S

Plastic-body (Kynar®), open junction, conic, Viscolene, non-refillable,
combination pH electrode. Use: meat & cheese.

6 mm

0.25"

FC 200

75 mm

2.95"

FC 210B

Glass-body, double junction, conic, Viscolene, non-refillable, combina­tion pH electrode. Use: milk, yogurt.

12 mm

0.5"

FC 210

120 mm

4.7"

FC 220B

Glass-body, triple-ceramic, single junction, refillable, combination pH
electrode. Use: food processing.

12 mm

0.5"

FC 220

Kynar® is registered Trademark of "Pennwalt Corp."
Ultem® is registered Trademark of "General Electrics Co."

57

9.5mm DIA

120 mm

4.7"

0.37"

FC 911B

Plastic-body (Kynar®), double junction, refillable with built-in ampli­fier, combination pH electrode. Use: very high humidity.

12 mm

0.5"

FC 911

110 mm

4.3"

HI 1413B / HI1410S

Glass-body, single junction, flat tip, Viscolene, non-refillable, combi­nation pH electrode. Use: surface measurement.

12 mm

0.5"

HI 1413

110 mm

4.3"

HALF-CELL ELECTRODES:
HI2110B

Glass-body, single half-cell pH electrode. Use: general purpose.

12 mm

0.5"

HI 2110

9.5mm DIA

120 mm

"

0.37"

HI5311

Glass-body, Ag/AgCl reference half-cell electrode, double junction,
refillable with 4mm plug with 1m (3.3') cable. Use: general purpose
with wide temperature range.

12 mm

0.5"

HI 5311

120 mm

4.7"

Kynar® is registered Trademark of "Pennwalt Corp."

58

HI5412

Glass-body, single Calomel reference half-cell electrode, refillable
with 4mm plug with 1m (3.3') cable. Use: general purpose with
constant temperature range.

12 mm

0.5"

HI 5412

120 mm

4.7"

ORP ELECTRODES:

HI3131B / HI3111S

Glass-body, refillable, combination platinum ORP electrode. Use: ti­tration.

12 mm

0.5"

HI 3131

150 mm

"S" VERSION

5.9"

HI3230B / HI3210S

Plastic-body (Ultem®), gel-filled, combination platinum ORP elec-
trode. Use: general purpose.

12 mm

0.5"

HI 3230

120 mm

"S" VERSION

4.7"

HI4430B / HI4410S

Plastic-body (Ultem®), gel-filled, combination gold ORP electrode.
Use: general purpose.

12 mm

0.5"

HI 4430

120 mm

"S" VERSION

Ultem® is registered Trademark of "General Electrics Co."

4.7"

59

EXTENSION CABLES FOR SCREW-TYPE ELECTRODES
ONLY (SCREW TO BNC CONNECTOR):

HI7855/1 Extension cable 1m (3.3') long
HI7855/3 Extension cable 3m (9.9') long
HI7855/5 Extension cable 5m (16.5') long
HI7855/10 Extension cable 10m (33') long
HI7855/15 Extension cable 15m (49.5') long

HI 7855 SERIES CABLE CONNECTORS

CONNECTOR AND 3.0 mm (0.12") CABLE WITH BNC

CONNECT TO
SCREW TYPE

ELECTRODES

CONNECT TO THE

BNC SOCKET

OF THE METER

POWER UNITS:

HI710005 Voltage adapter from 115 VAC to 12 VDC
HI710006 Voltage adapter from 230 VAC to 12 VDC

OTHER ACCESSORIES

ChecktempC Pocket-size thermometer with penetration probe and

0.1°C resolution (range -50.0 to 150.0°C)

HI 76405 Electrode holder
HI 7669/2W Temperature probe with 1 m (3.3') screened cable
HI 8427 pH and ORP electrode simulator with 1 m (3.3') coaxial

cable ending in female BNC connectors

HI 710032 Paper roll (10 pcs) (not for HI9017)
HI 710033 Ink catridge (1pc) (not for HI9017)
HI 92000/16 Windows® 3.11 compatible software for data transfer

to PC (for HI98240 and HI98240D only)

HI 92000/32 Windows® 95 compatible software for data transfer to

PC (for HI98240 and HI98240D only)

HI 920010 RS232 connection cable (25-pin)
HI 920010/9 RS232 connection cable (9-pin)
HI 931001 pH and ORP electrode simulator with LCD display 1 m

(3.3') coaxial for HI9824 and HI98240 only)

MANPHBN2R3 Instruction manual

Windows® is registered Trademark of "Microsoft Co."

60

ELECTRODE APPLICATIONELECTRODE APPLICATION

ELECTRODE APPLICATION

ELECTRODE APPLICATIONELECTRODE APPLICATION

REFERENCE GUIDEREFERENCE GUIDE

REFERENCE GUIDE

REFERENCE GUIDEREFERENCE GUIDE

Application Electrodes

1. Aquarium HI 1332B, HI 1911B, HI1312S

2. Bath-water HI 1910B, HI 1130B, HI1110S

3. Beer HI 1131B, HI 1111S

4. Bread HI 2031B, FC 200B, HI 2020S, FC200S

5. Cheese FC 200B, FC 200S

6. Dairy products FC 911B, FC100B

7. Dirty water HI 1910B, HI 1912B

8. Emulsions HI 1053B, HI1050S

9. Environment HI 1230B, HI1210S

10. Flasks HI 1331B, HI 1310S

11. Food industry general use FC 911B, FC 100B

12. Fruit FC 200B, FC 220B, FC 200S

13. Fruit juices, organic FC 210B

14. Galvanizing waste solution HI 1130B, HI 1912B, HI 1110S

15. Heavy-duty applications HI 1135B, HI 1115S

16. High purity water HI 1053B, HI1050S

17. Horticulture HI1053B, FC 200B, HI 1050S, FC 200S

18. In-line applications HI 1134B, HI 1135B, HI 2114B, HI 2910B,

19. Laboratory general use HI 1131B, HI 1230B, HI1332B, HI 1330B

20. Leather HI 1413B, HI1410S

21. Lemon juice FC 100B

22. Meat FC200B, HI 2031B, FC 200S, HI 2020S

23. Micro plate sampling of less than HI 1083B, HI 1080S
100 mL

24. Milk and Yogurt FC 210B

25. Paints HI 1053B, HI 1050S

26. Paper HI 1413B, HI 1410S

27. Photographic chemicals HI 1230B, HI 1210S

28. Quality control HI 1332B, HI 1312S

29. Sausages FC 200B, HI 2031B, FC 200S, HI2020S

30. Semi-solid products HI 2031B, HI2020S

31. Skin HI 1413B, HI 1410S

32. Soil samples HI 1230B, HI 1210S

33. Solvents HI 1043B, HI 1040S

34. Strong acid HI 1043B, HI 1040S

35. Submersion application HI 1130B, HI 1110S

36. Surface measurements HI 1413B, HI 1410S

37. Swimming pool H I1130B, HI 2114B, H I 2910B

38. Titrations with constant HI 1131B, HI 1111S
temperature range

39. Titrations with wide temperature HI 1131B, HI 1111S
range

40. Very high humidity FC 911B, HI 1912B, HI 1911B

41. Vials and test tube HI 1330B, HI 1310S

42. Wine processing FC 220B

HI 1114S, HI1115S

HI 1111S, HI 1210S, HI1312S, HI 1310S

B = BNC-type connector
S = Screw-type connector

61

WARRANTYWARRANTY

WARRANTY

WARRANTYWARRANTY

All Hanna Instruments meters are warranted for two years against
defects in workmanship and materials when used for their intended
purpose and maintained according to instructions. The electrodes
and the probes are warranted for a period of six months. This
warranty is limited to repair or replacement free of charge.

Damages due to accident, misuse, tampering or lack of prescribed
maintenance are not covered.

If service is required, contact the dealer from whom you purchased the
instrument. If under warranty, report the model number, date of
purchase, serial number and the nature of the failure. If the repair is
not covered by the warranty, you will be notified of the charges
incurred. If the instrument is to be returned to Hanna Instruments, first
obtain a Returned Goods Authorization number from the Customer
Service department and then send it with shipping costs prepaid.
When shipping any instrument, make sure it is properly packaged for
complete protection.

To validate your warranty, fill out and return the enclosed warranty
card within 14 days from the date of purchase.

All rights are reserved. Reproduction in whole or in part is prohibited
without the written consent of the copyright owner,
Hanna Instruments Inc., 584 Park East Drive, Woonsocket, Rhode
Island, 02895 , USA.

Hanna Instruments reserves the right to modify the design, construc­tion and appearance of its products without advance notice.

62

CE DECLARATION OF CONFORMITYCE DECLARATION OF CONFORMITY

CE DECLARATION OF CONFORMITY

CE DECLARATION OF CONFORMITYCE DECLARATION OF CONFORMITY

DECLARATION OF CONFORMITY

We

Hanna Instruments Srl
V.le delle industrie 12
35010 Ronchi di Villafranca (PD)
ITALY

herewith certify that the bench pH meters

have been tested and found to be in compliance with the following regulations:

HI 9017 HI 9218 HI 9219 HI 9318

IEC 801-2 Electrostatic Discharge
IEC 801-3 RF Radiated
IEC 801-4 Fast Transient
EN 55022 Radiated, Class B

Date of Issue: 02-02-1996

D.Volpato - Engineering Manager

On behalf of

Hanna Instruments S.r.l.

Recommendations for Users

Before using these products, make sure that they are entirely suitable for the environ­ment in which they are used.

Operation of these instruments in residential area could cause unacceptable interfer­ences to radio and TV equipments, requiring the operator to take all necessary steps to
correct interferences.

The glass bulb at the end of the electrode is sensitive to electrostatic discharges. Avoid
touching this glass bulb at all times.

During operation, ESD wrist straps should be worn to avoid possible damage to the
electrode by electrostatic discharges.

Any variation introduced by the user to the supplied equipment may degrade the
instrument's EMC performance.

To avoid electrical shock, do not use these instruments when voltages at the measure­ment surface exceed 24VAC or 60VDC.

To avoid damages or burns, do not perform any measurement in microwave ovens.
In particular cases HI9017 could turn off. In such cases, turn it on by pressing the ON

key.

63

HANNA LITERATUREHANNA LITERATURE

HANNA LITERATURE

HANNA LITERATUREHANNA LITERATURE

LAB RECORDING WATER ANALYSIS HANDBOOK

ENVIROCARE GENERAL CATALOG

PRINTED IN ITALY

These and many others catalogs, handbooks and leaflets are available
from Hanna. To receive your free copy, contact your dealer or the
nearest Hanna Customer Service Center.

http://www.hannainst.com

MANPHBN2R3

07/98