3M 83-0781 User Manual

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 1 of 17

Safety Data Sheet

Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

25-2254-8

Version Number:

3.00

Issue Date:

04/27/15

Supercedes Date:

07/12/13

SECTION 1: Identification

1.1. Product identifier

3M™ Safety-Walk™ Primer

Product Identification Numbers

62-2141-6550-8

1.2. Recommended use and restrictions on use

Recommended use

Industrial use

Restrictions on use

Primer

1.3. Supplier’s details
MANUFACTURER:

3M

DIVISION:

Industrial Adhesives and Tapes Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification

Flammable Liquid: Category 2.
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Skin Sensitizer: Category 1.
Reproductive Toxicity: Category 1B.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (central nervous system): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elements

Signal word

Danger

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 2 of 17

Symbols

Flame | Exclamation mark | Health Hazard |

Pictograms

Hazard Statements

Highly flammable liquid and vapor.

Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause drowsiness or dizziness.
May damage fertility or the unborn child.
Suspected of causing cancer.

Causes damage to organs through prolonged or repeated exposure:
nervous system |
sensory organs |

Precautionary Statements

Prevention:

Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:

IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.

Storage:

Keep cool.

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 3 of 17

Keep container tightly closed.
Store locked up in a well-ventilated place.

Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified

None.

11% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

Toluene 108-88-3 30 - 40 Trade Secret *
Magnesium Resinate 68037-42-3 10 - 25 Trade Secret *
Petroleum Distillates 64741-84-0 15 - 25 Trade Secret *
Polychloroprene 9010-98-4 10 - 20 Trade Secret *
Acetone 67-64-1 10 - 20 Trade Secret *
n-Hexane 110-54-3 3 - 8 Trade Secret *
Glycerol Esters of Rosin Acids 8050-31-5 1 - 5 Trade Secret *
Rosin 8050-09-7 0.1 - 1 Trade Secret *
Zinc Oxide 1314-13-2 0.1 - 1 Trade Secret *
Ethylbenzene 100-41-4 0.1 - 1 Trade Secret *
Xylene 1330-20-7 0.1 - 1 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:

Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 4 of 17

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products

Substance Condition

Aldehydes During Combustion
Hydrocarbons During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up

Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue
with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Keep
away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures
against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not
be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal
protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer.

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 5 of 17

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids.
Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments

Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal

carcin.
Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm)
Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm
Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human

carcin
n-Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm)
n-Hexane 110-54-3 ACGIH TWA:50 ppm Skin Notation
Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2

mg/m3;STEL(respirable
fraction):10 mg/m3

Zinc Oxide 1314-13-2 OSHA TWA(as fume):5

mg/m3;TWA(as total dust):15
mg/m3;TWA(respirable

fraction):5 mg/m3
Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm)
Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human

carcin
Xylene 1330-20-7 CMRG TWA:50 ppm;STEL:75 ppm
Acetone 67-64-1 ACGIH TWA:500 ppm;STEL:750 ppm A4: Not class. as human

carcin
Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm)
Rosin 8050-09-7 ACGIH Limit value not established: Cntrl all exposr-low as

possib,

Dermal/Respiratory

Sensitizer

ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.

8.2.2. Personal protective equipment (PPE)

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 6 of 17

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form:

Liquid

Odor, Color, Grade:

Tan, sweet petroleum odor.

Odor threshold

No Data Available

pH

Not Applicable

Melting point

Not Applicable

Boiling Point

>=56 ºC [Details: Acetone]

Flash Point

-4 ºF [Test Method: Closed Cup] [Details: Petroleum Distillate]

Evaporation rate

>=2.5 [Ref Std: ETHER=1]

Flammability (solid, gas)

Not Applicable

Flammable Limits(LEL)

1.0 % volume

Flammable Limits(UEL)

12.8 % volume

Vapor Pressure

<=185 mmHg [@ 68 ºF]

Vapor Density

2.0 [Ref Std: AIR=1]

Density

0.86 g/ml

Specific Gravity

0.86 [Ref Std: WATER=1]

Solubility in Water

Slight (less than 10%)

Solubility- non-water

No Data Available

Partition coefficient: n-octanol/ water

No Data Available

Autoignition temperature

465 ºC

Decomposition temperature

No Data Available

Viscosity

900 - 1,500 centipoise [@ 73.4 ºF ]

Hazardous Air Pollutants

<=44.5 % weight [Test Method: Calculated]

VOC Less H2O & Exempt Solvents

<=569 g/l [Test Method: calculated SCAQMD rule 443.1]

Solids Content

20 - 45 %

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 7 of 17

SECTION 10: Stability and reactivity

10.1. Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Heat
Sparks and/or flames

10.5. Incompatible materials

Strong oxidizing agents

10.6. Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:

Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 8 of 17

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Prolonged or repeated exposure may cause target organ effects:

Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.

Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell.

Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or
numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.

Reproductive/Developmental Toxicity:

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation

Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Inhalation-

Vapor(4 hr)

No data available; calculated ATE > 50 mg/l

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Toluene Dermal Rat LD50 12,000 mg/kg
Toluene Inhalation-

Vapor (4
hours)

Rat LC50 30 mg/l

Toluene Ingestion Rat LD50 5,550 mg/kg
Acetone Dermal Rabbit LD50 > 15,688 mg/kg
Acetone Inhalation-

Vapor (4
hours)

Rat LC50 76 mg/l

Acetone Ingestion Rat LD50 5,800 mg/kg
Petroleum Distillates Dermal Rabbit LD50 > 2,000 mg/kg
Petroleum Distillates Inhalation-

Vapor (4
hours)

Rat LC50 259 mg/l

Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg
Polychloroprene Dermal LD50 estimated to be > 5,000 mg/kg

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 9 of 17

Polychloroprene Ingestion Rat LD50 > 20,000 mg/kg
n-Hexane Dermal Rabbit LD50 > 2,000 mg/kg
n-Hexane Inhalation-

Vapor (4
hours)

Rat LC50 170 mg/l

n-Hexane Ingestion Rat LD50 > 28,700 mg/kg
Magnesium Resinate Ingestion LD50 estimated to be 2,000 -5,000 mg/kg
Glycerol Esters of Rosin Acids Dermal Rabbit LD50 > 5,000 mg/kg
Glycerol Esters of Rosin Acids Ingestion Rat LD50 > 2,000 mg/kg
Xylene Dermal Rabbit LD50 > 4,200 mg/kg
Xylene Inhalation-

Vapor (4
hours)

Rat LC50 29 mg/l

Xylene Ingestion Rat LD50 3,523 mg/kg
Zinc Oxide Dermal LD50 estimated to be > 5,000 mg/kg
Zinc Oxide Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 5.7 mg/l

Zinc Oxide Ingestion Rat LD50 > 5,000 mg/kg
Rosin Dermal Rabbit LD50 > 2,500 mg/kg
Rosin Ingestion Rat LD50 7,600 mg/kg
Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg
Ethylbenzene Inhalation-

Vapor (4
hours)

Rat LC50 17.4 mg/l

Ethylbenzene Ingestion Rat LD50 4,769 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Toluene Rabbit Irritant
Acetone Mouse Minimal irritation
Petroleum Distillates Rabbit Irritant
Polychloroprene Human No significant irritation
n-Hexane Human

and
animal

Mild irritant

Glycerol Esters of Rosin Acids Rabbit Minimal irritation
Xylene Rabbit Mild irritant
Zinc Oxide Human

and
animal

No significant irritation

Rosin Rabbit No significant irritation
Ethylbenzene Rabbit Mild irritant

Serious Eye Damage/Irritation

Name Species Value

Toluene Rabbit Moderate irritant
Acetone Rabbit Severe irritant
Petroleum Distillates Rabbit Mild irritant
Polychloroprene Professio

nal
judgeme
nt

No significant irritation

n-Hexane Rabbit Mild irritant
Glycerol Esters of Rosin Acids Rabbit Mild irritant
Xylene Rabbit Mild irritant
Zinc Oxide Rabbit Mild irritant
Rosin Rabbit Mild irritant
Ethylbenzene Rabbit Moderate irritant

Skin Sensitization

Name Species Value

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 10 of 17

Toluene Guinea

pig

Not sensitizing

Petroleum Distillates Guinea

pig

Not sensitizing

n-Hexane Human Not sensitizing
Glycerol Esters of Rosin Acids Guinea

pig

Not sensitizing

Zinc Oxide Guinea

pig

Some positive data exist, but the data are not
sufficient for classification

Rosin Guinea

pig

Sensitizing

Ethylbenzene Human Not sensitizing

Respiratory Sensitization

Name Species Value

Rosin Human Some positive data exist, but the data are not

sufficient for classification

Germ Cell Mutagenicity

Name Route Value

Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic
Acetone In vivo Not mutagenic
Acetone In Vitro Some positive data exist, but the data are not

sufficient for classification
Petroleum Distillates In Vitro Not mutagenic
n-Hexane In Vitro Not mutagenic
n-Hexane In vivo Not mutagenic
Glycerol Esters of Rosin Acids In Vitro Not mutagenic
Xylene In Vitro Not mutagenic
Xylene In vivo Not mutagenic
Zinc Oxide In Vitro Some positive data exist, but the data are not

sufficient for classification
Zinc Oxide In vivo Some positive data exist, but the data are not

sufficient for classification
Ethylbenzene In vivo Not mutagenic
Ethylbenzene In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

Toluene Dermal Mouse Some positive data exist, but the data are not

sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not

sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not

sufficient for classification
Acetone Not

Specified

Multiple
animal
species

Not carcinogenic

n-Hexane Dermal Mouse Not carcinogenic
n-Hexane Inhalation Mouse Some positive data exist, but the data are not

sufficient for classification
Xylene Dermal Rat Not carcinogenic
Xylene Ingestion Multiple

animal
species

Not carcinogenic

Xylene Inhalation Human Some positive data exist, but the data are not

sufficient for classification
Ethylbenzene Inhalation Multiple

animal
species

Carcinogenic

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 11 of 17

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

Toluene Inhalation Some positive female reproductive data

exist, but the data are not sufficient for
classification

Human NOAEL Not

available

occupational

exposure

Toluene Inhalation Some positive male reproductive data

exist, but the data are not sufficient for
classification

Rat NOAEL 2.3

mg/l

1 generation

Toluene Ingestion Toxic to development Rat LOAEL 520

mg/kg/day

during

gestation

Toluene Inhalation Toxic to development Human NOAEL Not

available

poisoning

and/or abuse

Acetone Ingestion Not toxic to female reproduction Mouse NOAEL

11,298
mg/kg/day

13 weeks

Acetone Ingestion Some positive male reproductive data

exist, but the data are not sufficient for
classification

Rat NOAEL

1,700
mg/kg/day

13 weeks

Acetone Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 5.2

mg/l

during
organogenesi
s

n-Hexane Ingestion Not toxic to development Mouse NOAEL

2,200
mg/kg/day

during
organogenesi
s

n-Hexane Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 0.7

mg/l

during
gestation

n-Hexane Ingestion Toxic to male reproduction Rat NOAEL

1,140
mg/kg/day

90 days

n-Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52

mg/l

28 days

Glycerol Esters of Rosin Acids Ingestion Not toxic to female reproduction Rat NOAEL

5,000
mg/kg/day

90 days

Glycerol Esters of Rosin Acids Ingestion Not toxic to male reproduction Rat NOAEL

5,000
mg/kg/day

90 days

Xylene Ingestion Not toxic to female reproduction Mouse NOAEL

1,000
mg/kg/day

103 weeks

Xylene Ingestion Not toxic to male reproduction Mouse NOAEL

1,000
mg/kg/day

103 weeks

Xylene Inhalation Some positive female reproductive data

exist, but the data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Xylene Ingestion Some positive developmental data exist,

but the data are not sufficient for
classification

Mouse NOAEL Not

available

during
organogenesi
s

Xylene Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Multiple
animal
species

NOAEL Not
available

during
gestation

Zinc Oxide Ingestion Some positive

reproductive/developmental data exist,
but the data are not sufficient for
classification

Multiple
animal
species

NOAEL 125
mg/kg/day

premating &
during
gestation

Ethylbenzene Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 4.3

mg/l

premating &
during
gestation

Lactation

Name Route Species Value

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 12 of 17

Xylene Ingestion Mouse Does not cause effects on or via lactation

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Toluene Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Toluene Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

Toluene Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL

0.004 mg/l

3 hours

Toluene Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

poisoning
and/or abuse

Acetone Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Acetone Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

Acetone Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL 1.19

mg/l

6 hours

Acetone Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Guinea
pig

NOAEL Not
available

Acetone Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

poisoning
and/or abuse

Petroleum Distillates Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

n-Hexane Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

not available

n-Hexane Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Rabbit NOAEL Not

available

8 hours

n-Hexane Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 24.6

mg/l

8 hours

Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3

mg/l

8 hours

Xylene Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Xylene Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

Xylene Inhalation eyes Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 3.5

mg/l

not available

Xylene Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL Not
available

Xylene Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Multiple
animal
species

NOAEL Not
available

Xylene Ingestion eyes Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 250

mg/kg

not applicable

Ethylbenzene Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for

Human
and

NOAEL Not
available

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 13 of 17

classification animal

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Toluene Inhalation auditory system |

nervous system |
eyes | olfactory
system

Causes damage to organs
through prolonged or repeated
exposure

Human NOAEL Not

available

poisoning
and/or abuse

Toluene Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat LOAEL 2.3

mg/l

15 months

Toluene Inhalation heart | liver | kidney

and/or bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 11.3

mg/l

15 weeks

Toluene Inhalation endocrine system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 1.1

mg/l

4 weeks

Toluene Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL Not

available

20 days

Toluene Inhalation bone, teeth, nails,

and/or hair

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 1.1

mg/l

8 weeks

Toluene Inhalation hematopoietic

system | vascular
system

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Toluene Ingestion nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 625

mg/kg/day

13 weeks

Toluene Ingestion heart Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL

2,500
mg/kg/day

13 weeks

Toluene Ingestion liver | kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Multiple
animal
species

NOAEL
2,500
mg/kg/day

13 weeks

Toluene Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 600

mg/kg/day

14 days

Toluene Ingestion endocrine system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 105

mg/kg/day

28 days

Toluene Ingestion immune system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 105

mg/kg/day

4 weeks

Acetone Dermal eyes Some positive data exist, but the

data are not sufficient for
classification

Guinea
pig

NOAEL Not
available

3 weeks

Acetone Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL 3

mg/l

6 weeks

Acetone Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL 1.19

mg/l

6 days

Acetone Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Guinea
pig

NOAEL 119
mg/l

not available

Acetone Inhalation heart | liver All data are negative Rat NOAEL 45

mg/l

8 weeks

Acetone Ingestion kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 900

mg/kg/day

13 weeks

Acetone Ingestion heart Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL

2,500
mg/kg/day

13 weeks

Acetone Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 200

mg/kg/day

13 weeks

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 14 of 17

Acetone Ingestion liver Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL

3,896
mg/kg/day

14 days

Acetone Ingestion eyes All data are negative Rat NOAEL

3,400
mg/kg/day

13 weeks

Acetone Ingestion respiratory system All data are negative Rat NOAEL

2,500
mg/kg/day

13 weeks

Acetone Ingestion muscles All data are negative Rat NOAEL

2,500 mg/kg

13 weeks

Acetone Ingestion skin | bone, teeth,

nails, and/or hair

All data are negative Mouse NOAEL

11,298
mg/kg/day

13 weeks

n-Hexane Inhalation peripheral nervous

system

Causes damage to organs
through prolonged or repeated
exposure

Human NOAEL Not

available

occupational
exposure

n-Hexane Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Mouse LOAEL 1.76

mg/l

13 weeks

n-Hexane Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL Not

available

6 months

n-Hexane Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.76

mg/l

6 months

n-Hexane Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 35.2

mg/l

13 weeks

n-Hexane Inhalation auditory system |

immune system |
eyes

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

n-Hexane Inhalation heart | skin |

endocrine system

All data are negative Rat NOAEL 1.76

mg/l

6 months

n-Hexane Ingestion peripheral nervous

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL

1,140
mg/kg/day

90 days

n-Hexane Ingestion endocrine system |

hematopoietic
system | liver |
immune system |
kidney and/or
bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL Not

available

13 weeks

Glycerol Esters of Rosin
Acids

Ingestion liver Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL

5,000
mg/kg/day

90 days

Glycerol Esters of Rosin
Acids

Ingestion heart | skin |

endocrine system |
bone, teeth, nails,
and/or hair | blood |
bone marrow |
hematopoietic
system | immune
system | muscles |
nervous system |
eyes | kidney and/or
bladder | respiratory
system

All data are negative Rat NOAEL

5,000
mg/kg/day

90 days

Xylene Inhalation nervous system Causes damage to organs

through prolonged or repeated
exposure

Rat LOAEL 0.4

mg/l

4 weeks

Xylene Inhalation auditory system May cause damage to organs

though prolonged or repeated
exposure

Rat LOAEL 7.8

mg/l

5 days

Xylene Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL Not
available

Xylene Inhalation heart | endocrine All data are negative Multiple NOAEL 3.5 13 weeks

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 15 of 17

system |
hematopoietic
system | muscles |
kidney and/or
bladder | respiratory
system

animal
species

mg/l

Xylene Ingestion auditory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 900

mg/kg/day

2 weeks

Xylene Ingestion kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL

1,500
mg/kg/day

90 days

Xylene Ingestion liver Some positive data exist, but the

data are not sufficient for
classification

Multiple
animal
species

NOAEL Not
available

Xylene Ingestion heart | skin |

endocrine system |
bone, teeth, nails,
and/or hair |
hematopoietic
system | immune
system | nervous
system | respiratory
system

All data are negative Mouse NOAEL

1,000
mg/kg/day

103 weeks

Zinc Oxide Ingestion nervous system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 600

mg/kg/day

10 days

Zinc Oxide Ingestion endocrine system |

hematopoietic
system | kidney
and/or bladder

Some positive data exist, but the
data are not sufficient for
classification

Other NOAEL 500

mg/kg/day

6 months

Ethylbenzene Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 1.1

mg/l

2 years

Ethylbenzene Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 1.1

mg/l

103 weeks

Ethylbenzene Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 3.4

mg/l

28 days

Ethylbenzene Inhalation auditory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 2.4

mg/l

5 days

Ethylbenzene Inhalation endocrine system Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL 3.3

mg/l

103 weeks

Ethylbenzene Inhalation bone, teeth, nails,

and/or hair |
muscles

All data are negative Multiple

animal
species

NOAEL 4.2
mg/l

90 days

Ethylbenzene Inhalation heart | immune

system | respiratory
system

All data are negative Multiple

animal
species

NOAEL 3.3
mg/l

2 years

Ethylbenzene Ingestion liver | kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 680

mg/kg/day

6 months

Aspiration Hazard

Name Value

Toluene Aspiration hazard
Petroleum Distillates Aspiration hazard
n-Hexane Aspiration hazard
Xylene Aspiration hazard
Ethylbenzene Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 16 of 17

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal
facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt

n-Hexane 110-54-3 3 - 8
n-Hexane (Hexane) 110-54-3 3 - 8
Toluene 108-88-3 30 - 40
Ethylbenzene 100-41-4 0.1 - 1

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

3M™ Safety-Walk™ Primer 04/27/15

__________________________________________________________________________________________

Page 17 of 17

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 3 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group:

25-2254-8

Version Number:

3.00

Issue Date:

04/27/15

Supercedes Date:

07/12/13

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com