3M 83-0781 User Manual
3M™ Safety-Walk™ Primer 04/27/15
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Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
25-2254-8
Version Number:
3.00
Issue Date:
04/27/15
Supercedes Date:
07/12/13
SECTION 1: Identification
1.1. Product identifier
3M™ Safety-Walk™ Primer
Product Identification Numbers
62-2141-6550-8
1.2. Recommended use and restrictions on use
Recommended use
Industrial use
Restrictions on use
Primer
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Industrial Adhesives and Tapes Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Flammable Liquid: Category 2.
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Skin Sensitizer: Category 1.
Reproductive Toxicity: Category 1B.
Carcinogenicity: Category 2.
Specific Target Organ Toxicity (central nervous system): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
Signal word
Danger
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Symbols
Flame | Exclamation mark | Health Hazard |
Pictograms
Hazard Statements
Highly flammable liquid and vapor.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause drowsiness or dizziness.
May damage fertility or the unborn child.
Suspected of causing cancer.
Causes damage to organs through prolonged or repeated exposure:
nervous system |
sensory organs |
Precautionary Statements
Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.
Storage:
Keep cool.
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Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
None.
11% of the mixture consists of ingredients of unknown acute inhalation toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Toluene 108-88-3 30 - 40 Trade Secret *
Magnesium Resinate 68037-42-3 10 - 25 Trade Secret *
Petroleum Distillates 64741-84-0 15 - 25 Trade Secret *
Polychloroprene 9010-98-4 10 - 20 Trade Secret *
Acetone 67-64-1 10 - 20 Trade Secret *
n-Hexane 110-54-3 3 - 8 Trade Secret *
Glycerol Esters of Rosin Acids 8050-31-5 1 - 5 Trade Secret *
Rosin 8050-09-7 0.1 - 1 Trade Secret *
Zinc Oxide 1314-13-2 0.1 - 1 Trade Secret *
Ethylbenzene 100-41-4 0.1 - 1 Trade Secret *
Xylene 1330-20-7 0.1 - 1 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
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5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Hydrocarbons During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue
with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Keep
away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures
against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do
not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not
be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid
contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal
protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer.
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7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids.
Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal
carcin.
Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm)
Ethylbenzene 100-41-4 CMRG TWA:25 ppm;STEL:75 ppm
Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human
carcin
n-Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm)
n-Hexane 110-54-3 ACGIH TWA:50 ppm Skin Notation
Zinc Oxide 1314-13-2 ACGIH TWA(respirable fraction):2
mg/m3;STEL(respirable
fraction):10 mg/m3
Zinc Oxide 1314-13-2 OSHA TWA(as fume):5
mg/m3;TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3
Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm)
Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human
carcin
Xylene 1330-20-7 CMRG TWA:50 ppm;STEL:75 ppm
Acetone 67-64-1 ACGIH TWA:500 ppm;STEL:750 ppm A4: Not class. as human
carcin
Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm)
Rosin 8050-09-7 ACGIH Limit value not established: Cntrl all exposr-low as
possib,
Dermal/Respiratory
Sensitizer
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
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Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Liquid
Odor, Color, Grade:
Tan, sweet petroleum odor.
Odor threshold
No Data Available
pH
Not Applicable
Melting point
Not Applicable
Boiling Point
>=56 ºC [Details: Acetone]
Flash Point
-4 ºF [Test Method: Closed Cup] [Details: Petroleum Distillate]
Evaporation rate
>=2.5 [Ref Std: ETHER=1]
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
1.0 % volume
Flammable Limits(UEL)
12.8 % volume
Vapor Pressure
<=185 mmHg [@ 68 ºF]
Vapor Density
2.0 [Ref Std: AIR=1]
Density
0.86 g/ml
Specific Gravity
0.86 [Ref Std: WATER=1]
Solubility in Water
Slight (less than 10%)
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
465 ºC
Decomposition temperature
No Data Available
Viscosity
900 - 1,500 centipoise [@ 73.4 ºF ]
Hazardous Air Pollutants
<=44.5 % weight [Test Method: Calculated]
VOC Less H2O & Exempt Solvents
<=569 g/l [Test Method: calculated SCAQMD rule 443.1]
Solids Content
20 - 45 %
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