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Teledyne Analytical Instruments, 16830 Chestnut Street, City of Industry, CA 91749-
1580.
Warranty
This equipment is sold subject to the mutual agreement that it is warranted by us
free from defects of material and of construction, and that our liability shall be limited to
replacing or repairing at our factory (without charge, except for transportation), or at
customer plant at our option, any material or construction in which defects become
apparent within one year from the date of shipment, except in cases where quotations or
acknowledgements provide for a shorter period. Components manufactured by others bear
the warranty of their manufacturer. This warranty does not cover defects caused by wear,
accident, misuse, neglect or repairs other than those performed by Teledyne or an authorized service center. We assume no liability for direct or indirect damages of any kind and
the purchaser by the acceptance of the equipment will assume all liability for any damage
which may result from its use or misuse.
We reserve the right to employ any suitable material in the manufacture of our
apparatus, and to make any alterations in the dimensions, shape or weight of any parts, in
so far as such alterations do not adversely affect our warranty.
Important Notice
This instrument provides measurement readings to its user, and serves as a tool by
which valuable data can be gathered. The information provided by the instrument may
assist the user in eliminating potential hazards caused by his process; however, it is
essential that all personnel involved in the use of the instrument or its interface, with the
process being measured, be properly trained in the process itself, as well as all instrumentation related to it.
The safety of personnel is ultimately the responsibility of those who control process
conditions. While this instrument may be able to provide early warning of imminent
danger, it has no control over process conditions, and it can be misused. In particular, any
alarm or control systems installed must be tested and understood, both as to how they
operate and as to how they can be defeated. Any safeguards required such as locks, labels,
or redundancy, must be provided by the user or specifically requested of Teledyne at the
time the order is placed.
Therefore, the purchaser must be aware of the hazardous process conditions. The
purchaser is responsible for the training of personnel, for providing hazard warning
methods and instrumentation per the appropriate standards, and for ensuring that hazard
warning devices and instrumentation are maintained and operated properly.
Teledyne Analytical Instruments, the manufacturer of this instrument, cannot
accept responsibility for conditions beyond its knowledge and control. No statement
expressed or implied by this document or any information disseminated by the manufacturer or its agents, is to be construed as a warranty of adequate safety control under the
user’s process conditions.
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Teledyne Analytical Instruments
Trace Oxygen Analyzer
The instrument for which this manual was supplied may incorporate
one or more options not supplied in the standard instrument. Commonly
available options are listed below, with check boxes. Any that are incorporated in the instrument for which this manual is supplied are indicated by a
check mark in the box.
Instrument Serial Number: _______________________
Options Included in the Instrument with the Above Serial Number:
Specific Model Information
q 3000TA-C:In addition to all standard features, this model also
has separate ports for zero and span gases, and builtin control valves. The internal valves are entirely
under the control of the 3000TA electronics, to
automatically switch between gases in
synchronization with the analyzer’s operations
q 19" Rack Mnt:The 19" Relay Rack Mount units are available with
either one or two 3000 series analyzers installed in a
standard 19" panel and ready to mount in a standard
rack.
A-5 Application Notes on Restrictors, Pressures and Flow .. A-5
A-6 Material Safety Data Sheet............................................ A-6
Teledyne Analytical Instruments
v
Model 3000TA
D ANGER
COMBUSTIBLE GAS USAGE WARNING
This is a general purpose instrument designed for usage in a
nonhazardous area. It is the customer's responsibility to ensure safety especially when combustible gases are being analyzed since the potential of gas leaks always exist.
The customer should ensure that the principles of operating of
this equipment is well understood by the user. Misuse of this
product in any manner, tampering with its components, or
unauthorized substitution of any component may adversely
affect the safety of this instrument.
Since the use of this instrument is beyond the control of
Teledyne, no responsibility by Teledyne, its affiliates, and
agents for damage or injury from misuse or neglect of this
equipment is implied or assumed.
vi
Teledyne Analytical Instruments
Trace Oxygen AnalyzerIntroduction 1
Introduction
1.1Overview
The Teledyne Analytical Instruments Model 3000TA Trace Oxygen
Analyzer is a versatile microprocessor-based instrument for detecting oxygen
at the parts-per-million (ppm) level in a variety of gases. This manual covers
the Model 3000TA General Purpose flush-panel and/or rack-mount units
only. These units are for indoor use in a nonhazardous environment.
1.2Typical Applications
A few typical applications of the Model 3000TA are:
•Monitoring inert gas blanketing
•Air separation and liquefaction
•Chemical reaction monitoring
•Semiconductor manufacturing
•Petrochemical process control
•Quality assurance
•Gas analysis certification.
1.3Main Features of the Analyzer
The Model 3000TA Trace Oxygen Analyzer is sophisticated yet simple
to use. The main features of the analyzer include:
•A 2-line alphanumeric display screen, driven by microprocessor
electronics, that continuously prompts and informs the operator.
•High resolution, accurate readings of oxygen content from low
ppm levels through 25%. Large, bright, meter readout.
•Stainless steel cell block.
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1-1
1 Introduction Model 3000TA
•Advanced Micro-Fuel Cell, redesigned for trace analysis, has a
one year warranty and an expected lifetime of two years.
•Versatile analysis over a wide range of applications.
•Microprocessor based electronics: 8-bit CMOS microprocessor
with 32 kB RAM and 128 kB ROM.
•Three user definable output ranges (from 0-10 ppm through 0250,000 ppm) allow best match to users process and equipment.
•Air-calibration range for convenient spanning at 20.9 %.
•Auto Ranging allows analyzer to automatically select the proper
preset range for a given measurement. Manual override allows
the user to lock onto a specific range of interest.
•Two adjustable concentration alarms and a system failure alarm.
•Extensive self-diagnostic testing, at startup and on demand, with
continuous power-supply monitoring.
•Two way RFI protection.
•RS-232 serial digital port for use with a computer or other digital
communication device.
•Four analog outputs: two for measurement (0–1 V dc and
Isolated 4–20 mA dc) and two for range identification.
•Convenient and versatile, steel, flush-panel or rack-mountable
case with slide-out electronics drawer.
1.4Model Designations
3000TA:Standard model.
3000TA-C:In addition to all standard features, this model also has
separate ports for zero and span gases, and built-in control
valves. The internal valves are entirely under the control of
the 3000TA electronics, to automatically switch between
gases in synchronization with the analyzer’s operations.
1-2
Teledyne Analytical Instruments
Trace Oxygen AnalyzerIntroduction 1
1.5Front Panel (Operator Interface)
The standard 3000TA is housed in a rugged metal case with all controls
and displays accessible from the front panel. See Figure 1-1. The front panel
has thirteen buttons for operating the analyzer, a digital meter, an alphanumeric display, and a window for viewing the sample flowmeter.
Function Keys: Six touch-sensitive membrane switches are used to
change the specific function performed by the analyzer:
Figure 1-1: Model 3000TA Front Panel
•AnalyzePerform analysis for oxygen content of a sample gas.
•SystemPerform system-related tasks (described in detail in
chapter 4, Operation.).
•SpanSpan calibrate the analyzer.
•ZeroZero calibrate the analyzer.
•AlarmsSet the alarm setpoints and attributes.
•RangeSet up the 3 user definable ranges for the instrument.
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1-3
1 Introduction Model 3000TA
Data Entry Keys: Six touch-sensitive membrane switches are used to
input data to the instrument via the alphanumeric VFD display:
•Left & Right ArrowsSelect between functions currently
displayed on the VFD screen.
•Up & Down ArrowsIncrement or decrement values of
functions currently displayed.
•EnterMoves VFD display on to the next screen in a series. If
none remains, returns to the Analyze screen.
•Escape Moves VFD display back to the previous screen in a
series. If none remains, returns to the Analyze screen.
Digital Meter Display: The meter display is a LED device that
produces large, bright, 7-segment numbers that are legible in any lighting. It
produces a continuous readout from 0-10,000 ppm and then switches to a
continuous percent readout from 1-25%. It is accurate across all analysis
ranges without the discontinuity inherent in analog range switching.
Alphanumeric Interface Screen: The VFD screen is an easy-to-use
interface from operator to analyzer. It displays values, options, and messages
that give the operator immediate feedback.
Flowmeter: Monitors the flow of gas past the sensor. Readout is 0.2 to
2.4 standard liters per minute (SLPM).
Standby Button: The Standby turns off the display and outputs,
but circuitry is still operating.
CAUTION: The power cable must be unplugged to fully
disconnect power from the instrument. When chassis
is exposed or when access door is open and power
cable is connected, use extra care to avoid contact
with live electrical circuits .
Access Door: For access to the Micro-Fuel Cell, the front panel swings
open when the latch in the upper right corner of the panel is pressed all the
way in with a narrow gauge tool. Accessing the main circuit board requires
unfastening rear panel screws and sliding the unit out of the case.
1.6 Recognizing Difference Between LCD & VFD
LCD has GREEN background with BLACK characters. VFD has
DARK background with GREEN characters. In the case of VFD - NO
CONTRAST ADJUSTMENT IS NEEDED.
1-4
Teledyne Analytical Instruments
Trace Oxygen AnalyzerIntroduction 1
1.7Rear Panel (Equipment Interface)
The rear panel, shown in Figure 1-2, contains the gas and electrical
connectors for external inlets and outlets. Some of those depicted are optional and may not appear on your instrument. The connectors are described
briefly here and in detail in chapter 3 Installation.
Figure 1-2: Model 3000TA Rear Panel
•Power ConnectionUniversal AC power source.
•Gas Inlet and OutletOne inlet (must be externally valved)
and one exhaust out.
•Analog Outputs0–1 V dc concentration plus 0-1 V dc
range ID, and isolated 4–20 mA dc plus
4-20 mA dc range ID.
•Alarm Connections2 concentration alarms and 1 system
alarm.
•RS-232 PortSerial digital concentration signal output
and control input.
•Remote ProbeUsed in the 3000TA for controlling
external solenoid valves only.
•Remote Span/ZeroDigital inputs allow external control of
analyzer calibration.
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1-5
1 Introduction Model 3000TA
•Calibration ContactTo notify external equipment that
instrument is being calibrated and
readings are not monitoring sample.
•Range ID ContactsFour separate, dedicated, range relay
contacts. Low, Medium, High, Cal.
•Network I/OSerial digital communications for local
network access. For future expansion.
Not implemented at this printing.
Optional:
•Calibration Gas PortsSeparate fittings for zero, span and
sample gas input, and internal valves for
automatically switching the gases.
Note: If you require highly accurate Auto-Cal timing, use external
Auto-Cal control where possible. The internal clock in the
Model 3000TA is accurate to 2-3 %. Accordingly, internally
scheduled calibrations can vary 2-3 % per day.
1-6
Teledyne Analytical Instruments
Trace Oxygen Analyzer Operational Theory 2
Operational Theory
2.1Introduction
The analyzer is composed of three subsystems:
1. Micro-Fuel Cell Sensor
2. Sample System
3. Electronic Signal Processing, Display and Control
The sample system is designed to accept the sample gas and transport
it through the analyzer without contaminating or altering the sample prior
to analysis. The Micro-Fuel Cell is an electrochemical galvanic device that
translates the amount of oxygen present in the sample into an electrical
current. The electronic signal processing, display and control subsystem
simplifies operation of the analyzer and accurately processes the sampled
data. The microprocessor controls all signal processing, input/output and
display functions for the analyzer.
2.2Micro-Fuel Cell Sensor
2.2.1 Principles of Operation
The oxygen sensor used in the Model 3000T series is a Micro-Fuel
Cell designed and manufactured by Analytical Instruments. It is a sealed
plastic disposable electrochemical transducer.
The active components of the Micro-Fuel Cell are a cathode, an anode,
and the 15% aqueous KOH electrolyte in which they are immersed. The cell
converts the energy from a chemical reaction into an electrical current in
an external electrical circuit. Its action is similar to that of a battery.
There is, however, an important difference in the operation of a
battery as compared to the Micro-Fuel Cell: In the battery, all reactants are
stored within the cell, whereas in the Micro-Fuel Cell, one of the reactants
Teledyne Analytical Instruments
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2 Operational Theory Model 3000TA
(oxygen) comes from outside the device as a constituent of the sample gas
being analyzed. The Micro-Fuel Cell is therefore a hybrid between a
battery and a true fuel cell. (All of the reactants are stored externally in a
true fuel cell.)
2.2.2 Anatomy of a Micro-Fuel Cell
The Micro-Fuel Cell is a cylinder only 1¼ inches in diameter and 1¼
inches thick. It is made of an extremely inert plastic, which can be placed
confidently in practically any environment or sample stream. It is effectively sealed, although one end is permeable to oxygen in the sample gas.
The other end of the cell is a contact plate consisting of two concentric foil
rings. The rings mate with spring-loaded contacts in the sensor block
assembly and provide the electrical connection to the rest of the analyzer.
Figure 2-1 illustrates the external features.
Figure 2-1: Micro-Fuel Cell
Refer to Figure 2-2, Cross Section of a Micro-Fuel Cell, which illustrates the following internal description.
2-2
Figure 2-2. Cross Section of a Micro-Fuel Cell (not to scale)
Teledyne Analytical Instruments
Trace Oxygen Analyzer Operational Theory 2
At the top end of the cell is a diffusion membrane of Teflon, whose
thickness is very accurately controlled. Beneath the diffusion membrane
lies the oxygen sensing element—the cathode—with a surface area almost
4 cm2. The cathode has many perforations to ensure sufficient wetting of
the upper surface with electrolyte, and it is plated with an inert metal.
The anode structure is below the cathode. It is made of lead and has a
proprietary design which is meant to maximize the amount of metal available for chemical reaction.
At the rear of the cell, just below the anode structure, is a flexible
membrane designed to accommodate the internal volume changes that
occur throughout the life of the cell. This flexibility assures that the sensing membrane remains in its proper position, keeping the electrical output
constant.
The entire space between the diffusion membrane, above the cathode,
and the flexible rear membrane, beneath the anode, is filled with electrolyte. Cathode and anode are submerged in this common pool. They each
have a conductor connecting them to one of the external contact rings on
the contact plate, which is on the bottom of the cell.
2.2.3 Electrochemical Reactions
The sample gas diffuses through the Teflon membrane. Any oxygen
in the sample gas is reduced on the surface of the cathode by the following
HALF REACTION:
O2 + 2H2O + 4e– → 4OH
–
(cathode)
(Four electrons combine with one oxygen molecule—in the presence
of water from the electrolyte—to produce four hydroxyl ions.)
When the oxygen is reduced at the cathode, lead is simultaneously
oxidized at the anode by the following HALF REACTION:
Pb + 2OH– → Pb+2 + H2O + 2e
–
(anode)
(Two electrons are transferred for each atom of lead that is oxidized.
Therefore it takes two of the above anode reactions to balance one cathode
reaction and transfer four electrons.)
The electrons released at the surface of the anode flow to the cathode
surface when an external electrical path is provided. The current is proportional to the amount of oxygen reaching the cathode. It is measured and
used to determine the oxygen concentration in the gas mixture.
Teledyne Analytical Instruments
2-3
2 Operational Theory Model 3000TA
The overall reaction for the fuel cell is the SUM of the half reactions
above, or:
2Pb + O2 → 2PbO
(These reactions will hold as long as no gaseous components capable
of oxidizing lead—such as iodine, bromine, chlorine and fluorine—are
present in the sample.)
The output of the fuel cell is limited by (1) the amount of oxygen in
the cell at the time and (2) the amount of stored anode material.
In the absence of oxygen, no current is generated.
2.2.4 The Effect of Pressure
In order to state the amount of oxygen present in the sample in partsper-million or a percentage of the gas mixture, it is necessary that the
sample diffuse into the cell under constant pressure.
If the total pressure increases, the rate that oxygen reaches the cathode
through the diffusing membrane will also increase. The electron transfer,
and therefore the external current, will increase, even though the oxygen
concentration of the sample has not changed. It is therefore important that
the sample pressure at the fuel cell (usually vent pressure) remain relatively
constant between calibrations.
2.2.5 Calibration Characteristics
Given that the total pressure of the sample gas on the surface of the
Micro-Fuel Cell input is constant, a convenient characteristic of the cell is
that the current produced in an external circuit is directly proportional to
the rate at which oxygen molecules reach the cathode, and this rate is
directly proportional to the concentration of oxygen in the gaseous mixture. In other words it has a linear characteristic curve, as shown in Figure
2-3. Measuring circuits do not have to compensate for nonlinearities.
In addition, since there is zero output in the absence oxygen, the
characteristic curve has close to an absolute zero (within ± 1 ppm oxygen).
In practical application, zeroing may still used to compensate for the
combined zero offsets of the cell and the electronics. (The electronics is
zeroed automatically when the instrument power is turned on.)
2-4
Teledyne Analytical Instruments
Trace Oxygen Analyzer Operational Theory 2
Figure 2-3. Characteristic Input/Output Curve for a Micro-Fuel Cell
2.3Sample System
The sample system delivers gases to the Micro-Fuel Cell sensor from
the analyzer rear panel inlet. Depending on the mode of operation either
sample or calibration gas is delivered.
The Model 3000TA sample system is designed and fabricated to
ensure that the oxygen concentration of the gas is not altered as it travels
through the sample system. The sample encounters almost no dead space.
This minimizes residual gas pockets that can interfere with trace analysis.
The sample system for the standard instrument incorporates ¼ inch
tube fittings for sample inlet and outlet connections at the rear panel. For
metric system installations, 6 mm adapters are supplied with each instrument to be used if needed. The sample or calibration gas flows through the
system is monitored by a flowmeter downstream from the cell. Figure 2-4
shows the piping layout and flow diagram for the standard model.
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2-5
2 Operational Theory Model 3000TA
Figure 2-4: Piping Layout and Flow Diagram for Standard Model
Figure 2-5 is the flow diagram for the sampling system. In the standard instrument, calibration gases (zero and span) can be connected directly to the Sample In port by teeing to the port with appropriate valves.
The shaded portion of the diagram shows the components added when the
–C option is ordered. The valving is installed inside the 3000TA-C enclosure and is regulated by the instruments internal electronics.
2-6
Teledyne Analytical Instruments
Trace Oxygen Analyzer Operational Theory 2
Figure 2-5: Flow Diagram
2.4Electronics and Signal Processing
The Model 3000TA Trace Oxygen Analyzer uses an 8031 microcontroller with 32 kB of RAM and 128 kB of ROM to control all signal processing, input/output, and display functions for the analyzer. System power
is supplied from a universal power supply module designed to be compatible with any international power source. Figure 2-6 shows the location of
the power supply and the main electronic PC boards.
Figure 2-6: Electronic Component Location Inside the Model 3000TA
Teledyne Analytical Instruments
2-7
2 Operational Theory Model 3000TA
The signal processing electronics including the microprocessor,
analog to digital, and digital to analog converters are located on the
motherboard at the bottom of the case. The preamplifier board is mounted
on top of the motherboard as shown in the figure. These boards are accessible after removing the back panel. Figure 2-7 is a block diagram of the
Analyzer electronics.
2-8
Figure 2-7: Block Diagram of the Model 3000TA Electronics
Teledyne Analytical Instruments
Trace Oxygen Analyzer Operational Theory 2
In the presence of oxygen the cell generates a current. A current to
voltage amplifier converts this current to a voltage, which is amplified in
the second stage amplifier.
The second stage amplifier also supplies temperature compensation
for the oxygen sensor output. This amplifier circuit incorporates a thermistor, which is physically located in the cell block. The thermistor is a
temperature dependent resistance that changes the gain of the amplifier in
proportion to the temperature changes in the block. This change is inversely proportional to the change in the cell output due to the same temperature changes. The result is a signal that is temperature independent.
The output from the second stage amplifier is sent to an 18 bit analog to
digital converter controlled by the microprocessor.
The digital concentration signal along with input from the control
panel is processed by the microprocessor, and appropriate control signals
are directed to the display, alarms and communications port. The same
digital information is also sent to a 12 bit digital to analog converter that
produces the 4-20 mA dc and the 0-1 V dc analog concentration signal
outputs, and the analog range ID outputs.
Signals from the power supply are also monitored, and through the
microprocessor, the system failure alarm is activated if a malfunction is
detected.
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2 Operational Theory Model 3000TA
2-10
Teledyne Analytical Instruments
Trace Oxygen AnalyzerInstallation 3
Installation
Installation of the Model 3000TA Analyzer includes:
1. Unpacking
2. Mounting
3. Gas connections
4. Electrical connections
5. Installing the Micro-Fuel Cell
6. Testing the system.
3.1Unpacking the Analyzer
The analyzer is shipped with all the materials you need to install and
prepare the system for operation. Carefully unpack the analyzer and inspect
it for damage. Immediately report any damage to the shipping agent.
3.2Mounting the Analyzer
The Model 3000TA is for indoor use in a general purpose area. It is
NOT for hazardous environments of any type.
The standard model is designed for flush panel mounting. Figure 3-1 is
an illustration of the 3000TA standard front panel and mounting bezel.
There are four mounting holes—one in each corner of the rigid frame.
Drawing number D-62928, at the back of this manual, contains a panel
cutout diagram.
On special order, a 19" rack-mounting panel can be provided. For rack
mounting, one or two 3000 series analyzers are flush-panel mounted on the
rack panel. See Appendix for dimensions of the mounting panel.
Teledyne Analytical Instruments
3-1
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