Teledyne 102E User Manual

ADDENDUM TO

MODEL 101E

OPERATORS MANUAL

(P/N 04740 REV. A)

FOR

MODEL 102E

TOTAL REDUCED SULFUR ANALYZER

with

MODEL 501 TRS

THERMAL CONVERTER

9480 CARROLL PARK DRIVE SAN DIEGO, CA 92121-5201

USA

Toll-free Phone: 800-324-5190

Phone: 858-657-9800

Fax: 858-657-9816

Email: Api-sales@teledyne.com

Website:

http://www.teledyne-api.com/

M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

TABLE OF CONTENTS

1. PREFACE ...................................................................................................................................... 1

1.1. Reference Numbering convention...............................................................................................2

2. SPECIFICATIONS, APPROVALS AND WARRANTY.......................................................................... 3

2.1. Specifications..........................................................................................................................3

2.1.1. M501-TRS Specifications ....................................................................................................3

2.2. EPA Equivalency Designation.....................................................................................................3

2.3. CE Mark Compliance ................................................................................................................4

3. GETTING STARTED....................................................................................................................... 5

3.1. Unpacking the M102E ..............................................................................................................5

3.2. Unpacking the M501-TRS .........................................................................................................5

3.2.1. M501-TRS Ventilation Clearance: ........................................................................................6

3.3. Internal Layouts......................................................................................................................7

3.4. Internal Pneumatic Flow of the M102E & the M501-TRS ................................................................8

3.5. Rear Panel Layout for the M102E & M501-TRS .............................................................................9

3.6. Initial Setup .........................................................................................................................10

3.6.1. Electrical Connections:..................................................................................................... 10

3.6.1.1. M102E Analog Output Connections.............................................................................. 10

3.6.1.2. M501-TRS Alarm Output Connections .......................................................................... 11

3.6.2. Pneumatic Connections:...................................................................................................11

3.6.2.1. Connections with Internal Valve Options Installed..........................................................14

3.7. Initial Operation ....................................................................................................................17

3.7.1. Startup / Warm Up of the M102E.......................................................................................17

3.7.2. Functional Check of the M102E..........................................................................................17

3.7.3. Startup / Warm Up of the M501-TRS..................................................................................18

3.8. Initial Calibration...................................................................................................................19

4. OPTIONAL HARDWARE AND SOFTWARE .................................................................................... 21

4.1. Rack Mount Kits (Options 20a, 20b, 21, 22 & 81)....................................................................... 21

4.2. Calibration Valves Options ......................................................................................................21

4.2.1. Zero/Span Valves (Option 50) & Internal Zero/Span Gas Generator (Option 51)....................... 21

4.3. Additional Manuals.................................................................................................................24

4.3.1. Printed Manuals (P/N 049880000) ..................................................................................... 24

4.3.2. Addendum on CD (Part number 049880200) ....................................................................... 24

5. M102E OPERATING INSTRUCTIONS........................................................................................... 25

5.1.1. M102E Analog Output Signals ........................................................................................... 25

5.1.2. Setting the M102E Gas Measurement Mode......................................................................... 26

5.2. SETUP – DIAG: Using the Diagnostics Functions......................................................................... 26

5.2.1. M102E Analog I/O Configuration........................................................................................26

5.2.2. M102E Test Channel Output .............................................................................................27

5.3. SETUP – COMM: Setting Up the M102E’s Communication Ports ....................................................27

5.3.1. M102E ID Code............................................................................................................... 27

5.3.2. M102E Ethernet Host Name .............................................................................................. 27

5.4. Remote Operation of the Analyzer............................................................................................28

5.4.1. Control Inputs ................................................................................................................28

5.4.2. Using the M102E with a Hessen Protocol Network ................................................................29

5.4.2.1. M102E Hessen Protocol Gas ID List. ............................................................................29

5.4.2.2. Setting Hessen Protocol Status Flags ...........................................................................30

6. M501-TRS OPERATING INSTRUCTIONS ..................................................................................... 31

6.1. Basic M501-TRS Controls........................................................................................................ 31

6.2. To Display The Current Temperature:....................................................................................... 32

6.3. To Manually Adjust the Converter Oven Temperature: ................................................................ 33

6.4. Autotune the Temperature Controller: ......................................................................................34

6.4.1. Initiating the Autotune Process: ........................................................................................34

6.4.2. Aborting the Autotune Process:.........................................................................................35

6.5. M501TRS Alarm Relay Adjustment ...........................................................................................35

7. CALIBRATION PROCEDURES...................................................................................................... 37

7.1. M102E Calibration .................................................................................................................37

7.2. M501-TRS Calibration ............................................................................................................37

05514 Rev A1 i

M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

8. INSTRUMENT MAINTENANCE..................................................................................................... 39

8.1. Additional and Updated Maintenance Procedures........................................................................40

8.1.1. Maintaining the SO

8.1.1.1. Predicting When the SO

8.1.1.2. Checking the Function of the SO

8.1.1.3. Changing the SO

9. THEORY OF OPERATION............................................................................................................. 43

9.1. Measurement Principle ...........................................................................................................43

9.1.1. TRS Conversion ..............................................................................................................43

9.1.2. SO

Ultraviolet Fluorescence ............................................................................................. 43

9.2. The UV Light Path..................................................................................................................46

9.2.1. UV Lamp Shutter & PMT Offset.......................................................................................... 46

9.3. Pneumatic Operation..............................................................................................................46

9.3.1. Sample gas Flow.............................................................................................................46

9.3.2. M501 SO

Scrubber ......................................................................................................... 46

9.4. Electronic Operation...............................................................................................................47

9.4.1. Sensor Module................................................................................................................ 47

9.4.1.1. Sample Chamber......................................................................................................48

9.4.1.2. Sample Chamber Heating Circuit.................................................................................48

9.4.2. M501-TRS electronics ......................................................................................................49

9.4.2.1. Thermal Switch ........................................................................................................49

9.4.2.2. Temperature Alarms and Alarm Output ........................................................................ 50

10. TROUBLESHOOTING & REPAIR ................................................................................................ 51

10.1.1. Fault Diagnosis with Warning Messages ............................................................................ 51

10.1.1.1. M102E Warning Messages ........................................................................................ 51

10.1.1.2. M501-TRS Error Codes.............................................................................................51

10.1.2. Fault Diagnosis with Test Functions.................................................................................. 52

10.2. M501-TRS Trouble shooting ..................................................................................................53

10.2.1. TRS Converter Not Heating:............................................................................................ 53

10.3. Other Performance Problems ................................................................................................. 53

10.3.1. Excessive noise.............................................................................................................53

10.4. Subsystem Checkout............................................................................................................ 54

10.4.1. Checking the Efficiency of the M501-TRS SO

10.4.2. Checking the Efficiency of the M501-TRS TRS Æ SO

10.5. Additional Repair Procedures ................................................................................................. 55

10.5.1. UV Lamp Adjustment and/or Replacement ........................................................................55

10.5.1.1. Adjusting the UV Lamp (Peaking the Lamp) ................................................................56

10.5.1.2. Replacing the UV Lamp............................................................................................57

10.5.2. Replacing the UV filter/lens .............................................................................................. 58

10.5.3. Replacing the PMT, HVPS or TEC......................................................................................59

10.5.4. M102E PMT Hardware Calibration (FACTORY CAL) .............................................................. 61

10.5.5. Replacing the TRS Converter Heating Tube .......................................................................63

10.6. Manually Programming the M501-TRS Temperature Controller ...................................................64

10.6.1. Temperature Controller Primary Menu Parameters..............................................................65

10.7. Technical Assistance ............................................................................................................67

Scrubber ...........................................................................................40

Scrubber Material ............................................................................ 41

Scrubber Should Be Replaced. ................................................. 40

Scrubber................................................................... 41

Scrubber....................................................... 54

Converter............................................ 54

LIST OF APPENDICES

APPENDIX A - VERSION SPECIFIC SOFTWARE DOCUMENTATION

APPENDIX A-1: M102E Software Menu Trees, Revision A.2 APPENDIX A-2: Setup Variables For Serial I/O, Revision A.2 APPENDIX A-3: Warnings and Test Functions, Revision A.2 APPENDIX A-4: M102E Signal I/O Definitions, Revision A.2 APPENDIX A-5: M102E iDAS Functions, Revision A.2

APPENDIX B - M102E SPARE PARTS LIST APPENDIX D - ELECTRONIC SCHEMATICS

ii 05514 Rev A1

M102E/M501 TRS PREFACE

(Addendum to M101E Manual - P/N 04740 Rev A)

LIST OF FIGURES

Figure 3-1: M102E Internal Layout ...................................................................................7

Figure 3-2: M501-TRS Internal Layout...............................................................................7

Figure 3-3: Internal Pneumatic Diagram of the M102E Standard Configuration........................ 8

Figure 3-4: M102E Rear Panel Layout................................................................................9

Figure 3-5: M501-TRS Rear Panel Layout...........................................................................9

Figure 3-6: Analog Output Connector .............................................................................. 10

Figure 3-7: Pneumatic Connections–Basic Configuration–Using Gas Dilution Calibrator ........... 12

Figure 3-8: Pneumatic Connections–Basic Configuration–Using Bottled Span Gas .................. 12

Figure 3-9: Basic Pneumatic Connections for Units with Zero/Span Valve Option ................... 15

Figure 3-10: Pneumatic Connections for Formal Calibration of Units with an IZS Valve Option ... 16

Figure 3-11: Pneumatic Connections for Informal Calibration Checks of Units with IZS Valve

Option ...................................................................................................... 16

Figure 3-12: M501-TRS Temperature Controller Startup ..................................................... 18

Figure 4-1: Internal Pneumatic Diagram of the M102E With Z/S Option Installed................... 22

Figure 4-2: Internal Pneumatic Diagram of the M102E with IZS Options Installed.................. 23

Figure 5-1: Analog Output Connector Key ........................................................................ 25

Figure 5-2: Control Inputs with local 5 V power supply ...................................................... 28

Figure 5-3: Control Inputs with external 5 V power supply ................................................. 29

Figure 6–1: M501-TRS Temperature Controls ................................................................... 31

Figure 9-1: UV Absorption in the M102E Reaction Cell ....................................................... 44

Figure 9-2: M102E Sensor Module .................................................................................. 47

Figure 9-3: M102E Sample Chamber............................................................................... 48

Figure 9-4: M501-TRS Electronic Block Diagram ............................................................... 49

Figure 10-1: Shutter Assembly - Exploded View.................................................................. 57

Figure 10-2: Disassembling the Shutter Assembly............................................................... 58

Figure 10-3: PMT Assembly - Exploded View ...................................................................... 59

Figure 10-4: Pre-Amplifier Board Layout............................................................................ 62

LIST OF TABLES

Table 2-1: Model 102E Basic Unit Specifications..................................................................3

Table 3-1: TRS – SO

Table 3–2: Analog output Pin Outs................................................................................... 10

Table 3-3: Inlet / Outlet Connector Nomenclature............................................................. 11

Table 3-4: NIST-SRM's Available for Traceability of H2S & SO

Table 4-1: Zero/Span Valve Operating States.................................................................. 22

Table 4-2: IZS Valve Operating States ........................................................................... 23

Table 5-1 M102E gas Measurement Modes...................................................................... 26

Table 5-2: Analog Output Pin Assignments ....................................................................... 26

Table 5-3: Test Parameters Available for Analog Output A4 ................................................ 27

Table 5-4: M102E Control Input Pin Assignments .............................................................. 28

Table 5-5: M102E Default Hessen Gas ID’s....................................................................... 29

Table 5-6: Default Hessen Status Bit Assignments ............................................................ 30

Table 6-1: M501-TRS Temperature Controls and Definitions ............................................... 32

Table 8-1: M102E Preventive Maintenance Schedule.......................................................... 39

Table 10-1: Test Functions - Possible Causes for Out-Of-Range Values ................................... 51

Table 10-2: Test Functions - Possible Causes for Out-Of-Range Values ................................... 52

Table 10-3 – Temperature Controller – Primary Parameter Settings......................................... 66

Table 10-4 – Temperature Controller – Primary Parameter Settings......................................... 67

Switching Valve Operating Modes....................................................... 8

Calibration Gases .................... 14

05514 Rev A1 iii

M102E/M501 TRS PREFACE

(Addendum to M101E Manual - P/N 04740 Rev A)

1. PREFACE

NOTE

The information contained in this addendum is pertinent to M102E analyzers running

software revision A.2. Some or all of the information may not be applicable to previous

revision of that software.

The software revision your analyzer is running is displayed in the upper left-hand

corner of the display any time the instrument is in SETUP mode.

This addendum is based on the Model 101E Operators Manual (P/N 04740, REV. A). In most ways the M102E is identical to the M102E in design and operation, therefore most of the basic set up information, operating instructions as well as calibration, maintenance, troubleshooting and repair methods are found in that manual.

This addendum documents only those areas where the M102E is different in design or operating method from the M102E.

Specifically:

• Areas where updates and improvements to the M10XE software have been implemented

since the publication date of the M101E Manual - P/N 04740 Rev A.

• Corrections of errors and omissions discovered in the M101E Manual - P/N 04740 Rev A.

• EXTERNAL TRS CONVERSION: Like the M101E, which converts H

measures the amount of SO converts total reduced sulfur (TRS) gases into SO

present using a UV fluorescence technique, the M102E

before measuring the SO2 using the

S to SO2, then

same UV fluorescence method.

Unlike the M102E, which performs the H

S Æ SO2 conversion internally, the M102E

requires an external TRS converter, in this case a Teledyne Instruments M501-TRS.

Therefore this addendum includes instructions and information regarding:

• Areas of operation and setup of the M102 that depart from the method described by

the M101E operator’s manual because the TRS Æ SO

conversion is performed

externally.

• The proper set up and operation on the M501-TRS.

05514 Rev A1 1

PREFACE M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

1.1. Reference Numbering convention

Unless otherwise specified, chapter, section, figure and table reference numbers referred to within this text are relative to this document.

EXAMPLE: “Figure 2-1” refers to the figure, within this document, labeled as 2-1.

References to chapters, sections, figures and tables in the original document will be labeled as such.

EXAMPLE: “Figure 6.1 of the M101E Operators Manual (P/N 04470, REV. A)”.

User Notes:

2 05514 Rev A1

M102E/M501 TRS SPECIFICATIONS, APPROVALS AND WARRANTY

(Addendum to M101E Manual - P/N 04740 Rev A)

2. SPECIFICATIONS, APPROVALS AND WARRANTY

2.1. Specifications

There are no significant differences between the performance specifications for the M102E and the M102E as listed in Section 2.1 of the M101E Manual - P/N 04740 Rev A.

2.1.1. M501-TRS Specifications

Table 2-1: Model 102E Basic Unit Specifications

S >95%

Minimum Converter Efficiency

Maximum TS Concentration for specified conversion efficiency

Sample Flow Rate 650cc/min. ±10% - driven by M102E pneumatic system

Optimum Converter Temperature

Maximum Converter Temperature

Dimensions H x W x D 7" x 17" x 22" (178 mm x 432 mm x 559 mm)

Weight

AC Power Rating

Internal Alarms

Alarm Output Relay

Alarm Output Rating

Environmental Installation category (over-voltage category) II; Pollution degree 2

Certifications

For indoor use at altitudes ≤ 2000m only

COS >90% CS

>90%

20 ppmv

1000°C (factory setup)

1100°C

16 lbs (8 kg) 26 lbs (12 kg) CE version

115 V, 50/60 Hz - 400 Watts; 230 V, 50/60 Hz - 575 Watts; CE Version

High Alarm Point: 1050°C Low Alarm Point: 950°C

SPST - 1 point: Alarm output is energized should either the temperature controller’s high or low internal alarm set points be activated.

220V AC/30V DC, 1A (resistive load)

IEC 1010-1 / 61010-1:93 (includes A1) + A2:95,

2.2. EPA Equivalency Designation

No EPA equivalency standards exist for TRS measurement, however, the M102E analyzer qualifies for EPA equivalency designation as Reference Method Number EQSA-0495-100 per 40 CFR Part 53 when operated under the following conditions:

• Measurement Mode: SO2 single gas mode.

• Range: Any range from 50 parts per billion (ppb) to 10 parts per million (ppm).

• Ambient temperature range of 5

• Line voltage range of 105-125 VAC or 220-240 VAC, at 50 or 60 Hz.

05514 Rev A1 3

C to 40 oC.

SPECIFICATIONS, APPROVALS AND WARRANTY M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

• Sample filter: Equipped with PTFE filter element in the internal filter assembly.

• Sample flow of 650 +/- 65 cc/min.

• Vacuum pump (internal or external) capable of 14"Hg Absolute pressure @ 1 slpm or

better.

• Software settings:

Dynamic span OFF Dynamic zero OFF Dilution factor OFF AutoCal ON or OFF Dual range ON or OFF Auto-range ON or OFF Temp/Pressure compensation ON

Under the designation, the analyzer may be operated with or without the following optional equipment:

• Rack mount with chassis slides.

• Rack mount without slides, ears only.

• Zero/span valve options.

• Internal zero/span (IZS) option with either:

• SO

• 4-20mA isolated analog outputs.

• Status outputs.

• Control inputs.

• RS-232 output.

• Ethernet output.

• Zero air scrubber.

• 4-20mA, isolated output.

permeation tube - 0.4 ppm at 0.7 liter per minute; certified/uncertified.

permeation tube - 0.8 ppm at 0.7 liter per minute; certified/uncertified. Under the

designation, the IZS option cannot be used as the source of calibration.

2.3. CE Mark Compliance

See Section 2.3 of the M101E Manual - P/N 04740 Rev A

User Notes:

4 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

3. GETTING STARTED

3.1. Unpacking the M102E

Unpack the M102E as per the directions ins Section 3.1 of the M101E Manual - P/N 04740 Rev A.

1. There are no shipping screws to be removed in the M102E.

3.2. Unpacking the M501-TRS

2. Inspect the shipping package for external damage. If damaged, please advise the shipper first,

then Teledyne Instruments.

3. Carefully remove the top cover of the converter and check for internal shipping damage.

• Remove the screws fastening the top cover to the unit (four per side).

• Lift the cover straight up.

CAUTION

Never disconnect electronic circuit boards, wiring harnesses or

4. Inspect the interior of the instrument to make sure all components are in good shape and

properly seated.

5. Check the connectors of the various internal wiring harnesses and pneumatic hoses to make

sure they are firmly and properly seated.

6. There are no shipping screws to be removed in the M501-TRS.

7. Replace the top cover.

The M501-TRS will not operate properly with the top cover removed.

electronic subassemblies while the unit is under power.

NOTE

The air cooling required to stabilize the temperature of the converter tube is dependent

on air flow patterns that only exist with the top cover in place.

Without the top cover in place, the thermal cutout may overheat and shut off the

heating element.

05514 Rev A1 5

GETTING STARTED M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

3.2.1. M501-TRS Ventilation Clearance:

Whether the M501-TRS is set up on a bench or installed into an instrument rack, be sure to leave sufficient ventilation clearance.

AREA MINIMUM REQUIRED CLEARANCE

Back of the instrument 10 cm / 4 inches

Sides of the instrument 2.5 cm / 1 inch

Above and below the instrument. 2.5 cm / 1 inch

NOTE

If the M501-TRS is installed in an instrument rack or any type of enclosure, make sure

that the rack/enclosure itself is adequately ventilated.

Failure to provide proper ventilation can result in the ambient temperature exceeding

the maximum operating temperature specification for the M102E (40°C)

6 05514 Rev A1

M102E/M501 TRS GETTING STARTED

g Sy

(Addendum to M101E Manual - P/N 04740 Rev A)

3.3. Internal Layouts

Figures 3-1 & 3-3 supersede Figure 3-9 of the M101E Manual - P/N 04740 Rev A.

Front Panel

Reaction Cell

Hydrocarbon Scrubber

Hidden from view b eneath

Reaction Cell

ON/OFF SWITCH

Particulate Filter

Pump Assy

UV Source Lap

230VAC

Transformer

(Option)

PMT Preamp PCA

PMT Housin

Rela

PMT Coolin

Board

IZS Permeation Tube and Oven

(+12 VDC)

stem

PS2

(Option)

Span/Cal Valves

PS1

(+5 VDC; ±15VDC)

(Option)

104 Card

Rear Panel

Mother

Board

Vacuum

Manifold

Power Supply

UV Lamp

ON/OFF SWITCH

Figure 3-1: M102E Internal Layout

Temperature

Controller

230VAC

Transformer

(Option)

Converter Tube Cover

Converter Heater located

underneath Cover

SO2

Scrubber

Converter Tube

Converter Heater

Control Relay

Alarm

Outputs

Figure 3-2: M501-TRS Internal Layout

05514 Rev A1 7

GETTING STARTED M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

3.4. Internal Pneumatic Flow of the M102E & the

M501-TRS

Figure 3-3 shows the internal pneumatic flow of the M102E in its Standard configuration. For information on instruments in which one of the various zero/span valve options refer to Figures 52 and 5-3.

ANALYZER

TRS

CONVERTER OVEN

FROM

ANALYZER

Scrubbe

FROM

CONVERTER

EXHAUST GAS

OUTLET

SAMPLE GAS

INLET

INSTRUMENT

M102E

CHASSIS

KICKER EXHAUST

PUMP

SAMPLE FILTER

TO PUMP

TRS / SO

MODE VALVE

HYDROCARBON

SCRUBBER

(KICKER)

Gas Flow in SO

phase

of multigas mode or

when i n SO

measurement mode

SAMPLE

CHAMBER

PMT

UV LAMP

M501-TRS

ZERO AIR INLET

SPAN GAS INLET

VACUUM MANIFOLD

EXHAUST TO OUTE

LAYER OF KICKE

FLOW CONTROL ASSY

SAMPLE

PRESSURE

SENSOR

FLOW / PRESSURE

SENSOR PC

FLOW

SENSOR

Figure 3-3: Internal Pneumatic Diagram of the M102E Standard Con figuration.

Switching Valve Operating Modes

Bypasses M501-TRS

CONNECTION

(FIG. 5-2)

2 Æ 3 2 Æ 1

- -

GAS

MODE

TRS

SO2

TRS –SO2

Table 3-1: TRS – SO

CONDITION OF TRS –SO2 SWITCHING VALVE VALVE PORT

Open to SO

Switches between above two states every 10 minutes.

Scrubber and Molybdenum Converter

Open to directly to Sample Chamber.

8 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

3.5. Rear Panel Layout for the M102E & M501-TRS

Figures 3-4 & 3-5 supersede Figure 3-2 of the M101E Manual - P/N 04740 Rev A.

5 Amp

Slow-Blow

Fuse

Figure 3-4: M102E Rear Panel Layout

Alarm Output

Connections

Figure 3-5: M501-TRS Rear Panel Layout

05514 Rev A1 9

GETTING STARTED M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

3.6. Initial Setup

3.6.1. Electrical Connections:

The electrical connections for the M102E are the same as those described in Section 3.1.1 of the M101E Manual - P/N 04740 Rev A except for the test channel analog output:

3.6.1.1. M102E Analog Output Connections

This section supercedes Section 3.1.1.1 of the M101E Manual - P/N 04740 Rev A.

Attach a strip chart recorder and/or data-logger to the appropriate contacts of the analog output connecter on the rear panel of the analyzer.

A1 A2 A3 A4 + - + - + - + -

ANALOG OUT

Figure 3-6: Analog Output Connector

The A1 and A2 channels output a signal that is proportional to the SO

concentration of the

sample gas.

The output, labeled A3 is special. It can be set by the user (see Section 6.9.10 of the M101E Manual - P/N 04740 Rev A) to output any one of the parameters accessible through the <TST TST> keys of the units sample display.

Pin-outs for the Analog Output connector at the rear panel of the instrument are:

Table 3–2: Analog output Pin Outs

PIN ANALOG OUTPUT VOLTAGE OUTPUT CURRENT LOOP OPTION

1 V Out I Out + 2

3 V Out I Out + 4

5 V Out I Out + 6

7 Not Available Not Available 8

Ground I Out -

Not Available Not Available

• The default analog output voltage setting of the M102E UV Fluorescence SO

Analyzer is 0

– 5 VDC with a range of 0 – 500 ppb.

10 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

• TO change these settings, see Sections 6.9.4 and 6.7 of the M101E Manual - P/N 04740

Rev A respectively.

3.6.1.2. M501-TRS Alarm Output Connections

The rear panel of the M501-TRS includes a terminal strip by which connections can be made to the converters internal temperature alarm for more information on this alarm see Section 6.5).

• Connect the input leads to your alarm-sensing device (e.g. datalogger) to the center two

pins of the alarm output connector (see Figure 3-5).

• Make sure the load does not exceed the rated capacity of the relay.

3.6.2. Pneumatic Connections:

This section supercedes the information contained in Section 3.1.2 of the M101E Manual

- P/N 04740 Rev A.

CAUTION

To prevent dust from getting into the analyzer, it was shipped with small plugs inserted

into each of the pneumatic fittings on the rear panel. Make sure that all dust plugs are

removed before attaching exhaust and supply gas lines.

Sample and calibration gases should only come into contact with PTFE (Teflon) or glass materials. They should not come in contact with FEP or stainless steel materials.

Figures 3-7 and 3-8 show the most common configurations for gas supply and exhaust lines to the Model 102E Analyzer. Figures 3-9, 3-10 & 3-11 show the connections for units with valve options installed.

Please refer to Figures 3-1 & 3.3 for the location of pneumatic connections at the rear panel of the M102E and the M501-TRS.

Table 3-3: Inlet / Outlet Connector Nomenclature

M102E PNEMATIC CONNECTERS

REAR PANEL LABEL FUNCTION

SAMPLE

EXHAUST

SPAN

ZERO AIR

TO CONVERTER Sample gas leaves the M102E to be conditioned by the M501-TRS via this port.

FROM CONVERTER

Connects the sample gas to the analyzer. When operating the analyzer without zero/span option, this is also the inlet for any calibration gases.

Exhausts the gas sampled by the analyzer. Connect to an outside area away from people.

On units with zero/span/shutoff valve options installed, connect a gas line to the source of calibrated span gas here.

On Units with zero/span valve or IZS option installed, this port connects the zero air gas or the zero air cartridge to the analyzer.

Sample gas returns to the M102E after being conditioned by the M501-TRS via this port.

M501-TRS PNEMATIC CONNECTERS

REAR PANEL LABEL FUNCTION

05514 Rev A1 11

GETTING STARTED M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

FROM ANALYZER Sample gas enters the M501-TRS from the M102E via this port.

TO ANALYZER Sample gas leaves the M501-TRS to return to the M102E via this port.

Calibrated

span GAS

(At high

concentration)

MODEL 701

Zero Air

Generator

MODEL 700

Gas Dilutio n

Calibrator

(with Ozone

Bench Option)

VENT

M501-TRS

From Analyzer

To Analyzer

Source of

SAMPLE Gas

Removed

Calibration

Sample Exhaust Span

Zero Air To Converter

From Converter

during

MODEL

102E

Figure 3-7: Pneumatic Connections–Basic Configuration–Using Gas Dilution Calibrator

MODEL 701

Zero Air

Calibrated

span GAS

Generator

Valve

Needle

valve to

control

flow

VENT

Source of

SAMPLE Gas

Removed

during

Calibration

Sample Exhaust Span

MODEL

102E

M501-TRS

From Analyzer

To Analyzer

Zero Air To Converter

From Converter

Figure 3-8: Pneumatic Connections–Basic Configuration–Using Bottled Span Gas

8. Attach the 1/4" exhaust line to the exhaust port.

12 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

CAUTION

The exhaust from the instrument needs to be vented outside the immediate area or shelter surrounding the instrument and conform to all safety requirements using a maximum of 10 meters of 1/4” PTFE tubing.

9. Attach the sample line to the sample inlet port. Ideally, the pressure of the sample gas should be equal to ambient atmospheric pressure.

NOTE

Maximum pressure of any gas at the sample inlet should not exceed 1.5 in-Hg above

ambient pressure and ideally should equal ambient atmospheric pressure.

In applications where the sample gas is received from a pressurized manifold, a vent

must be provided to equalize the sample gas with ambient atmospheric pressure before

it enters the analyzer. The vented gas needs to be routed outsi de the immediate area or

shelter surrounding the instrument.

10. Attach zero air and span gas supply lines as appropriate (see Figures 3-5 & 3.5).

• Zero air and span gas inlets should supply their respective gases in excess of the 700

/min demand of the analyzer. Supply and vent lines should be of sufficient length and

cc diameter to prevent back diffusion and pressure effects.

• For this type of analyzer, zero air and span gas are defined as follows:

SPAN GAS

• While it is possible to calibrate the M102E using SO

the analyzers gas measurement mode to SO

, Teledyne Instruments recommends that H2S

as the span calibration gas by setting

be used and that calibration operations be carried out with the analyzer’s TRS gas measurement mode selected. Please note that verifying converter efficiency requires that the instrument be calibrated on both TRS and SO between the TRS and SO

• It is recommended that the H

modes.

S span gas be equal to 90% of the analyzer’s selected

, and the slope factors compared

reporting range.

• O2 is a quenching agent in fluorescent Sulfur analyzers. If the balance gas is pure

nitrogen, then false positive readings will result, both at zero and span. Therefore the user should either use cylinders with zero air as the balance gas, or should use higher concentration cylinders with an N2 balance, and dilute further with zero air using a calibrator, such as the TAPI M700.

EXAMPLE: If the selected reporting rang is 0 ppb Æ 500 ppb, an appropriate span gas concentration would be 450 ppb H

Cylinders of calibrated H

S gas traceable to NIST-Standard Reference Material specifications

(also referred to as SRM’s or EPA protocol calibration gases) are commercially available. Table 3-4 lists specific NIST-SRM reference numbers for various concentrations of H

05514 Rev A1 13

GETTING STARTED M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

Table 3-4: NIST-SRM's Available for Traceability of H2S & SO2 Calibration Gases

NIST-SRM4 TYPE

2730 2731

Hydrogen sulfide in N Hydrogen sulfide in N2

NOMINAL

CONCENTRATION

5000 ppb

20 ppm

ZERO AIR

• A gas that is similar in chemical composition to the earth’s atmosphere but without the

gas(es) being measured by the analyzer, in this case total reduced sulfur (TRS). While TRS typically includes Hydrogen sulfide (H (CH

and Methyl mercaptan (MeSH), CH4S many other gases fall into this category as

3)2S2

S), Dimethyl sulfide (CH3)2 , Dimethyl disulfide

well. In addition other interferent gases may be present in ambient air as well.

To ensure that high quality zero air is available a zero air generator such as the Teledyne Instruments Model 701 should be used.

• If your analyzer is equipped with an IZS option, it is capable of creating zero air that is

adequate for performing informal calibration checks, but a zero air generator such as the Teledyne Instruments Model 701 is still recommended for performing formal calibration operations.

11. Once the appropriate pneumatic connections have been made, check all pneumatic fittings for leaks using a procedure similar to that defined in Section 11.5.1 of the M101E Manual - P/N 04740 Rev A.

3.6.2.1. Connections with Internal Valve Options Installed

If your analyzer is equiped with either the zero/span valve option (Option 50) or the internal zero/span option (Option 51), the pneumatic connections should be made as shown in Figures 3-9; 3-10 & 3-11:

14 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

Zero/Span Valves – Option 50

VENT if input is pressurized

Sam

Exhaust

Zero Air

To Converter

From Converter

MODEL

102E

MODEL 700

Gas Dilution Calibrator

(with O3 generator option)

Calibrated SO

or H2S

gas

(At high

concentration)

VENT

MODEL 701

Zero Air

Generator

Source of

SAMPLE Gas

External Zero

Air Scrubber

M501-TRS

Filter

To Analyze

From Analyze

Figure 3-9: Basic Pneumatic Connections for Units with Zero/Span Valve Option

05514 Rev A1 15

GETTING STARTED M102E/M501 TRS

(

)

(Addendum to M101E Manual - P/N 04740 Rev A)

MODEL 700

Gas Dilution Calibrator

(with O3 generator option)

Calibrated

H2S gas

(At high

concentration)

VENT

MODEL 701

Zero Air

Generator

Source of

SAMPLE Gas

External Zero

Air Scrubber

M501-TRS

To Analyze

From Analyze

Filter

VENT if input is pressurized

Sam

Exhaust

MODEL

102E

Zero Air

To Converter

From Converter

Figure 3-10: Pneumatic Connections for Formal Calibration of Units with an IZS Valve

Option

Source of

SAMPLE Gas

VENT if input is pressurized

Sam

Ambient

Air

M501-TRS

From Analyze

To Analyzer

Exhaust

Zero Air

To Converter

From Converter

MODEL

102E

Scrubber

Figure 3-11: Pneumatic Connections for Informal Calibration Checks of Units with IZS

Valve Option

NOTE

Gas flow must be maintained at all times for units with IZS Options installed. The IZS

option requires a permeation tube ( customer supplied ) which emits H2S. Insufficient

gas flow can build up H2S to levels that will damage the instrument.

Remove the permeation device when taking the analyzer out of operation.

16 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

3.7. Initial Operation

3.7.1. Startup / Warm Up of the M102E

Startup procedures and warm up behavior of the M102E are identical to those described in Sections 3.2.1 and 3.2.2 of the M101E Manual - P/N 04740 Rev A.

Possible Warning Messages at Start-Up

Warning messages for the M102E is the same as the list of warning messages included in

appendix A—3 of the M101E Manual - P/N 04740 Rev A with the exception that there is no CONV

TEMP WARNING (converter Temperature Warning).

3.7.2. Functional Check of the M102E

To performing an initial functional check of the M102E follow the steps contained in Section 3.2.4 of the M101E Manual - P/N 04740 Rev A.

Test Functions

The following diagram supercedes the one found in Step 2 of Section 3.2.4 of the M101E Manual P/N 04740 Rev A.

SAMPLE RANGE = 500.0 PPB TRS = X.X < TST TST > CAL SETUP

RANGE

TRS STB

PRES

Toggle <TST TST> keys to

scroll throu

Only appears if IZS option is

installed.

Only appears if analog output A4

is actively reporting a test function.

Shown as they appear when analyzer

is in TRS mode. In SO

h list of functions

mode appear as SO2 STB, SO2 OFFS &

SAMP FL PMT NORM PMT UV LAMP LAMP RATIO STR. LGT DARK PMT DARK LAMP TRS SLOPE TRS OFFS HVPS RCELL TEMP BOX TEMP PMT TEMP IZS TEMP TEST TIME

SO2 SLOPE. In multigas mode, both versions appear.

Refer to Section

6.2.1 of the M101E

Manual - P/N 04740

Rev A for definitions

of these test

functions.

05514 Rev A1 17

GETTING STARTED M102E/M501 TRS

(Addendum to M101E Manual - P/N 04740 Rev A)

3.7.3. Startup / Warm Up of the M501-TRS

After electrical and pneumatic connections are made, turn on the instrument and pump power. The exhaust fan should start.

The M501-TRS’ temperature controller is preprogrammed at the factory so no special setup operation is required. The temperature controller (see Figure 3-12) should immediately come on in operation mode: the current temperature of the converter oven should the display immediately appear in the display area and the process

It may take as much as 30 minutes for the oven to reach its nominal operating temperature.

During that initial warm up period the high and low alarms and the M501-TRS single alarm output are disabled. Both the internal alarms and the alarm output will be automatically enabled once the converter oven temperature rises above the lower alarm limit.

value (PV) LED should be lit.

Process Variable

LED

High Alarm LED

Low Alarm LED

Display area

Figure 3-12: M501-TRS Temperature Controller Startup

18 05514 Rev A1

M102E/M501 TRS GETTING STARTED

(Addendum to M101E Manual - P/N 04740 Rev A)

3.8. Initial Calibration

Initial calibration of the M102E should be performed with:

• Zero air supplied by a zero air generator such as the Teledyne Instruments’ M701;

• Calibrated H

• With external pneumatic connections as described in Figures 3-7 through 3-11 of this

addendum, and;

• Using the information and procedure included in Section 3.3 of the M101E Manual - P/N

04740 Rev A.

No initial calibration of the M501-TRS temperature controller is required.

Once you have completed the above set-up procedures, please fill out the quality

questionnaire that was shipped with your unit and return it to Teledyne Instruments.

This information is vital to our efforts in continuously improving our service and our

S span gas of the appropriate concentration:

NOTE

products. Thank you.

User Notes:

05514 Rev A1 19

M102E/M501 TRS OPTIONAL HARDWARE AND SOFTWARE

(Addendum to M101E Manual - P/N 04740 Rev A)

4. OPTIONAL HARDWARE AND SOFTWARE

This section includes descriptions of the hardware and software options available for the Model 102E analyzer and M501-TRS converter that are different from or not included in Chapter 5 of the M101E Manual - P/N 04740 Rev A. For all other available options see that document.

For assistance with ordering these options please contact the sales department of Teledyne Instruments at:

TOLL-FREE: 800-324-5190

TEL: +1 858-657-9800

FAX: +1 858-657-9816

E-MAIL: apisales@teledyne.com

WEB SITE: http://www.teledyne-api.com

4.1. Rack Mount Kits (Options 20a, 20b, 21, 22 & 81)

The following table supercedes the one included in Section 5.1 of the M101E Manual - P/N 04740 Rev A.

OPTION NUMBER DESCRIPTION

OPT 20A Rack mount brackets with 26 in. chassis slides. OPT 20B Rack mount brackets with 24 in. chassis slides.

OPT 21 Rack mount brackets only OPT 22 Rack Mount for M501-TRS OPT 81 Rack Mount for M501-TRS with slides

4.2. Calibration Valves Options

4.2.1. Zero/Span Valves (Option 50) & Internal Zero/Span Gas

Generator (Option 51)

The description of the construction and operation for the zero span and IZS valve options for the M102E TRS is identical to that information contained in Section 5.4of the M101E Manual - P/N 04740 Rev A.

The internal pneumatic flow or the M102E with either of these options installed is however different. See:

• Figure 4-1 for an illustration of the M102E internal gas flow with the zero/span valves

(option 50), and;

• Figure 4-2 for an illustration of the M102E internal gas flow with the IZS valve (option 1).

05514 Rev A1 21

+ 63 hidden pages