................................................................................................................................... 31 Welcome to SuperSystems
................................................................................................................................... 93 Menu and Toolbar
.......................................................................................................................................................... 10Atmosphere Display Area
.......................................................................................................................................................... 11Model Segment Display Area
.......................................................................................................................................................... 13Temperature and Carbon Chart
................................................................................................................................... 155 Users and Security
................................................................................................................................... 176 Parts and Loads
................................................................................................................................... 237 Model and Furnace Settings
................................................................................................................................... 288 Material Selection
.......................................................................................................................................................... 31Specifying a Target Profile
......................................................................................................................................................... 18Entering a Load
......................................................................................................................................................... 19Load History in Control Mode
......................................................................................................................................................... 19Parts in Control Mode
................................................................................................................................... 3913 RealTime Control Mode
No part of this publication may be reproduced, transmitted, transcribed, stored in a retrieval system, or
translated into any language or computer language, in any form or by any means, electronic,
mechanical, magnetic, optical, chemical, manual, or otherwise, without prior written permission of
Super Systems Inc., 7205 Edington Dr., Cincinnati, OH 45249 USA.
CARBCALCII is a software program to be used by the Heat Treater. Super Systems Inc. is not
responsible or liable for any product, process, or damage or injury incurred as a result of using
CARBCALCII. Super Systems Inc. makes no representations or warranties with respect to the
contents hereof and specifically disclaims any implied warranties or merchantability or fitness for any
particular purpose.
CarbCalcII is a Carbon Diffusion Model for use with Batch Furnace Gas Carburizing.
IntroductionCarbCalc II4
Gas Carburizing
low-carbon steel part at a temperature sufficient to render the steel austenitic, followed by quenching
and tempering to form a martensitic microstructure. The resulting gradient in carbon content below the
surface of the part causes a gradient in hardness, producing a strong, wear-resistant surface layer on
a material, usually low-carbon steel, which is readily fabricated into parts. In gas carburizing the source
of carbon is a carbon-rich furnace atmosphere produced either from gaseous hydrocarbons, for
example, methane (CH4), propane (C3H3), and butane (C4H10), or from vaporized hydrocarbon
liquids.
Carbon Sources
Low-carbon steel parts exposed to carbon-rich atmospheres will carburize at temperatures of 850°C
(1560°F) and above. If the carbon source is so rich that the solubility limit of carbon in austenite is
reached at the surface of the steel some carbides may form at the surface. At these "above saturation"
atmospheres soot will deposit on surfaces within the furnace, including the parts. The goal of modern
gas carburizing practice is to control the carbon content of furnace atmospheres such that: The final
carbon concentration at the surface of the parts is below the solubility limit in austenite and Sooting of
the furnace atmosphere is minimized. Endothermic gas (Endogas) is a blend of carbon monoxide,
hydrogen, and nitrogen (with smaller amounts of carbon dioxide water vapor, and methane) produced
by reacting a hydrocarbon gas such as natural, gas (primarily methane), propane or butane with air. A
is a case-hardening process in which carbon is dissolved in the surface layers of a
IntroductionCarbCalc II5
carrier gas similar in composition to Endogas may be produced from methane can be formed from a
nitrogen-methanol blend.
Carburizing Process Variables
The gas carburizing process depends on the control of three principal variables:
·
Temperature
·
Time
·
Atmosphere composition.
Other variables that affect the amount of carbon transferred to parts include the degree of atmosphere
circulation and the alloy content of the parts.
Temperature
. The maximum rate at which carbon can be added to steel is limited by the rate of
diffusion of carbon in austenite. This diffusion rate increases greatly with increasing temperature; the
rate of carbon addition at 925°C (1700°F) is about 40% greater than at 870°C (1600°F). The
temperature most commonly used for carburizing is 925°C (1700°F). This temperature permits a
reasonably rapid carburizing rate without excessively rapid deterioration of furnace equipment. The
carburizing temperature is sometimes raised to 955°C (1750°F) or 980°C (1800°F) to shorten the time
of carburizing for parts requiring deep cases. Conversely, shallow case carburizing is frequently done
at lower temperatures because case depth can be controlled more accurately with the slower rate of
carburizing obtained at lower temperatures. For best results, the workload should be heated to the
carburizing temperature in a near-neutral furnace atmosphere. In batch furnaces, parts can be heated
in Endogas until they reach the furnace temperature; then carburizing can commence with the addition
of the enriching gas.
Time.
The effect of time and temperature on the Carbon vs Depth profile shows that the carburizing
time decreases with increasing carburizing temperature. In addition to the time at the carburizing
temperature, several hours may be required to bring large work pieces or heavy loads of smaller parts
to operating temperature. For a work piece quenched directly from the carburizing furnace, the cycle
may be lengthened further by allowing time for the work piece to cool from the carburizing temperature
to about 843°C (1550°F) prior to quenching. Similarly, additional diffusion and interchange of carbon
with the atmosphere will occur during cooling prior to quenching.
Carbon Potential.
The carbon potential of the furnace atmosphere must be greater than the carbon
potential at the surface of the work piece in order for carburizing to occur. It is the difference in carbon
potential that provides the driving force for carbon transfer into the parts.
Carbon Diffusion.
The combined effects of time, temperature, and carbon concentration on the
diffusion of carbon in austenite can be expressed by Fick's laws of diffusion.
Alloy Effects.
The various alloying elements found in carburizing steels have an influence on the
activity of carbon dissolved in austenite.
Chromium
·
Nickel
·
tends to decrease the activity of carbon
tends to raise the activity of carbon
The primary effect of alloys on the diffusion of carbon is their effect on the driving force at the surface
reaction.
The CarbCalcII Model
CARBCALCII is a carbon difussion model for simulation and analysis of gas carburizing process for
low-alloy steels. The interactions of the gas carburizing process cannot be modeled by simple
one-dimensional analysis. In order to accurately predict how a low-alloy steel will react in a controlled
atmosphere process, many factors must be taken into account, including:
Initial carbon profile
CARBCALCII takes as many factors as possible into account for the accurate prediction of (1) transfer
of carbon between gas and steel surface, and (2) diffusion of carbon within the steel.
Possible uses for CARBCALCII include:
·
Computer-aided design of heat treatment processes
·
Optimization of existing cycles
·
"What if" analysis when a change in an existing process or material is contemplated
·
Reconstruction of the effects that an out-of-control process may have had on a load
·
Education of personnel in the intricacies of atmosphere processing
·
Real-Time control with an on-line process
CARBCALCII can pay for itself quickly because process development experiments can be carried out
quickly on the computer instead of weeks in a furnace. When a trial is finally made in the furnace, the
results will be reasonably close to those predicted by the software.
CARBCALCII has thee main operating modes:
1.Simulation
2.RealTime Control
3. Monitor/Replay
The object in all cases is to accurately predict the diffusion gradient that carbon establishes in a given
material from a given set of processing parameters.
SIMULATION
allows construction of a diffusion gradient from complex a set of processing
parameters. For example, in a batch integral quench furnace, one might be interested in the following
sequence:
·
Come to Heat
·
Boost Carburize
·
Diffuse Carburize
·
Equalize for Quench
·
Brief Exposure to Vestibule Atmosphere
REALTIME CONTROL
- CarbCalcII is able to connect to "dumb controllers" via SuperData
communications. In this mode, CarbCalcII becomes the "Recipe Programmer" and sends setpoints to
the Temperature and Carbon Controllers.
MONITOR/REPLAY
running and logged in SuperData. This mode can be integrated with BatchMaster furnace control
systems.
For each segment, define the Segment Name, Temperature, Carbon and End-Of-Segment (EOS)
type.
·
EOS types are:
1. Timed - ends after a specified time.
2. Match Surface Carbon - ends when Surface Carbon matches the Target Surface Carbon.
3. Match Carbon at a specified depth - ends when Diffused Carbon matches Carbon at a
specified depth.
4. Auto Boost - ends when the amount of excess carbon near the surface exceeds the deficient
carbon at depth.
5. Auto Diffuse - ends when the deviation between the diffused profile and the target profile is
minimized (curve matching).
·
Model Temperature units may be displayed in Celsius of Fahrenheit and Measurement units in
inches or mm.
·
Probe Factors may use either the CO Factor or the Process Factor (typical to Marathon
Instruments) .
·
The Type of Material may be selected from a Material Database.
·
The Initial Carbon Profile is based on the material selected and is assumed to be uniform.
·
The Initial Carbon Profile may be customized based on 10 points - useful for modeling "Rework"
recipes.
·
The Target Profile (up to 10 points) may be specified or you can request a recommended profile
based on Surface Carbon, Carbon at Effective Case Depth and Carbon at total Case Depth.
·
After starting the simulation, it may be paused at any time. You can also set it to "AutoPause" at the
end of each segment.
CarbCalcIICarbCalc II8
, CabcalcII is used to develop Batch Carburizing Segment recipes.
RealTime Control mode
In
Controller and is used to Control a running Batch Furnace Carb Cycle.
·
A simple Load Entry system is used
·
The Segment display represents the Carb Cycle Recipe.
·
The Time vs Temperature and Carbon chart displays both the Setpoints and Actual values for
Temperature and Carbon.
·
The Carbon Profile is based on actual data from the instruments.
·
Instrument communication data sources are easily configured from within the application and saved
in a "Furnace" file.
Monitor/Replay mode
In
data logged by the SuperSystems communications datalogger. This mode is useful in analyzing a
comparing a cycle profile with the actual Profile from Lab results.· Display is similar to RealTime mode
but the data source is from the historical logged data.
·
Model runs at high speed similar to simulation mode.
·
Model may be paused, stopped or restarted at any time.
·
Target profile may be used to compare actual Lab measured profile for comparison with the model
results.
·
Analysis may be helpful in "Tuning" the recipe to achieve more precise results.
, CarbCalcII is connected to a Carbon Controller and a Temperature
, CarbCalcII is used to reproduce a cycle based on a Furnace Load and the
All atmosphere values are displayed. Model Inputs (yellow background) are "given" or "assumed"
values. Monitored values (green background) are used only in the RealTime and Replay modes.
Calculated values (blue background) are calculated based on Model Inputs and the assumption that
the atmosphere is in equilibrium.
In simulation mode, the inputs will always be Temperature, %Carbon, Probe Factor and CH4. In
Realtime and Replay modes the model inputs are selectable. In these modes, data that is available
but not selected as a model input may be monitored - in this case, a monitored value will be displayed
next to the model value.
Temperature
·
%Carbon
·
PF or COF
·
O2mV
·
·
·
·
·
·
·
·
dependent on Temperature. When designing recipes, a good rule of thumb is to keep the %C
setpoint below about 90% of the Saturation Carbon.
- Oxygen Probe millivolts
%CO
- %Carbon Monoxide in the furnace atmosphere
%H2
- %Hydrogen Monoxide in the furnace atmosphere
%CO2
- %Carbon Dioxide in the furnace atmosphere
%H2O
- %Water in the furnace atmosphere
%CH4
%C/CH4
Saturation Carbon
- units may be in Fahrenheit or Celsius.
- Carbon Potential (based on water-gas equations)
- Process Factor or CO Factor (depends on type of controller)
- %Hydrocarbon in the furnace atmosphere
- Efective%Carbon with CH4 taken into consideration
- the level at witch free carbon (soot) precipitates in the atmosphere. Primarily