Page 1
SAFETY DATA SHEET
Issuing date No data available Revision Date 17-Nov-2014 Version 1
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Label Name
Other means of identification
UPC Code
Product code
Synonyms
Recommended use of the chemical
and restrictions on use
Recommended Use
Uses advised against
Supplier's details
Supplier Address
Sun Products Corporate Office
60 Danbury Road
Wilton, CT 06897
USA
701120887- POWDER LAUNDRY BLEACH
Not applicable
701120887
None
All-fabric bleach powder for clothes washing machines.
Follow label instructions. Not recommended for any use except intended use.
Emergency telephone number
Company Phone Number
Company Emergency Phone
Number
Emergency telephone
General - 1-800-776-6702 (Monday – Friday, 8:30AM to 6:00PM EST)
Prosar: 1-800-565-5597 (24 hours)
Chemtrec (US/CA) 1-800-424-9300 (24 hour)
Poison Control 1-800-222-1222 (24 hour)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Serious eye damage/eye irritation Category 2
GHS Label elements, including
precautionary statements
Emergency Overview
Warning
Hazard Statements
Causes serious eye irritation
_____________________________________________________________________________________________
Page 1 / 8
Page 2
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Appearance FREE-FLOWING POWDER
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear eye/face protection
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Hazards not otherwise classified (HNOC)
Other information
• May be harmful if swallowed
• May be harmful in contact with skin
• Harmful to aquatic life
Physical state powder Odor Lemon
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight % Trade Secret
Sodium carbonate 497-19-8 > 70 *
*The exact percentage (concentration) of composition has been withheld as a trade secret
4. FIRST AID MEASURES
First aid measures for different exposure routes
General advice
Eye contact
Skin contact
Toxic - Inhalation
Ingestion
Protection of First-aiders
Most important symptoms/effects, acute and delayed
If symptoms persist, call a physician.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
symptoms persist, call a physician. Rinse thoroughly with plenty of water for at least 15
minutes and consult a physician. Immediately flush with plenty of water. After initial
flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye
wide open while rinsing.
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,
call a physician. Immediate medical attention is not required. Wash off immediately with
soap and plenty of water while removing all contaminated clothes and shoes.
Move to fresh air. If symptoms persist, call a physician. Immediate medical attention is not
required. Move to fresh air in case of accidental inhalation of vapors.
Immediate medical attention is not required. Rinse mouth. Drink plenty of water. Do NOT
induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give
anything by mouth to an unconscious person. Consult a physician.
Use personal protective equipment.
_____________________________________________________________________________________________
Page 2 / 8
Page 3
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Main Symptoms
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
No information available.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
Specific hazards arising from the chemical
No information available.
Hazardous Combustion
Products
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
CAUTION: Use of water spray when fighting fire may be inefficient.
No information available.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and materials for containment and cleaning up
Methods for Containment
Methods for cleaning up
Use personal protective equipment. Avoid contact with the skin and the eyes. Evacuate
personnel to safe areas. Keep people away from and upwind of spill/leak.
Prevent entry into waterways, sewers, basements or confined areas. Do not flush into
surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so.
Prevent product from entering drains. See Section 12 for additional Ecological Information.
Prevent further leakage or spillage if safe to do so.
Use personal protective equipment. Cover powder spill with plastic sheet or tarp to minimize
spreading and keep powder dry. Take up mechanically and collect in suitable container for
disposal. Avoid dust formation. Clean contaminated surface thoroughly. Soak up with inert
absorbent material. Dam up. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Ensure adequate ventilation. Wear personal protective equipment. Use only in area
provided with appropriate exhaust ventilation. Do not breathe vapors or spray mist.
Technical measures/Storage
conditions
Packaging material
Keep container tightly closed. Keep out of the reach of children. Keep containers tightly
closed in a cool, well-ventilated place. Keep in properly labeled containers.
Keep consumer product in packaging product is initially sold in.
_____________________________________________________________________________________________
Page 3 / 8
Page 4
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Incompatible products
None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Appropriate engineering controls
Engineering Measures
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Skin and body protection
Respiratory protection
Hygiene measures
This product does not contain any hazardous materials with occupational exposure limits
established by the region specific regulatory bodies.
Showers
Eyewash stations
Ventilation systems.
Tightly fitting safety goggles. Face-shield.
No special protective equipment required.
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
When using, do not eat, drink or smoke. Remove and wash contaminated clothing before
re-use. Provide regular cleaning of equipment, work area and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and chemical properties
Physical state
Appearance
Color
Property Values Remarks • Methods
pH
Melting point
Boiling point/boiling range
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper Flammability Limit
Lower Flammability Limit
Vapor pressure
Vapor density
Specific Gravity
Water solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Viscosity, kinematic
Viscosity, dynamic
Explosive properties
Oxidizing Properties
powder
FREE-FLOWING POWDER
No information available
11.00 PH - 1% SOLUTION
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Soluble in water
No information available
No information available
No information available
No information available
200 cps
No information available
No information available
No information available
Odor
Odor Threshold
Lemon
No information available
Other information
Softening point
No information available
_____________________________________________________________________________________________
Page 4 / 8
Page 5
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Molecular weight
VOC Content(%)
Density VALUE
Bulk Density VALUE
No information available
No information available
0.820
No information available
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
None under normal processing.
Hazardous Polymerization
None under normal processing.
Conditions to Avoid
Extremes of temperature and direct sunlight.
Incompatible Materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Toxic - Inhalation
Eye contact
Skin contact
There is no data available for this product.
There is no data available for this product.
Avoid contact with skin. May cause irritation. Prolonged contact may cause redness and
irritation. Prolonged or repeated contact may dry skin and cause irritation.
Ingestion
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Sodium carbonate
497-19-8
Water
7732-18-5
Sodium disilicate
1344-09-8
SODIUM PERCARBONATE
15630-89-4
2-Propenoic acid, telomer with
sodium hydrogen sulfite, sodium
salt
68479-09-4
There is no data available for this product.
= 4090 mg/kg ( Rat ) 2210 mg/kg ( rat ) = 2300 mg/m3 ( Rat ) 2 h
> 90 mL/kg ( Rat ) 90 mL/kg ( Rat )
= 1153 mg/kg ( Rat ) > 4640 mg/kg ( Rabbit )
= 1034 mg/kg ( Rat ) >1000 mg/kg ( rat ) 4580 mg/kg ( rat ) 1 h
5000 mg/kg ( rat ) 5000 mg/kg ( rabbit )
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation
Eye damage/irritation
No information available.
No information available.
_____________________________________________________________________________________________
Page 5 / 8
Page 6
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Sensitization
Germ Cell Mutagenicity
Carcinogenicity
Reproductive toxicity
Developmental Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic toxicity
Aspiration hazard
No information available.
No information available.
No information available.
No information available.
No information available.
No information available.
No information available.
Avoid repeated exposure.
No information available.
Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
3397 mg/kg
2602 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
0.10801% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other
Sodium carbonate
497-19-8
Sodium Chloride
7647-14-5
Sodium disilicate
1344-09-8
SODIUM PERCARBONATE
15630-89-4
300: 96 h Lepomis macrochirus
mg/L LC50 static 310 - 1220: 96 h
Pimephales promelas mg/L LC50
static
5560 - 6080: 96 h Lepomis
macrochirus mg/L LC50
flow-through 12946: 96 h Lepomis
macrochirus mg/L LC50 static 7050:
96 h Pimephales promelas mg/L
LC50 semi-static 6020 - 7070: 96 h
Pimephales promelas mg/L LC50
static 4747 - 7824: 96 h
Oncorhynchus mykiss mg/L LC50
flow-through 6420 - 6700: 96 h
Pimephales promelas mg/L LC50
static
301 - 478: 96 h Lepomis
macrochirus mg/L LC50 3185: 96 h
Brachydanio rerio mg/L LC50
semi-static
70.7: 96 h Pimephales promelas
mg/L LC50 static
aquatic invertebrates
265: 48 h Daphnia magna mg/L
EC50
1000: 48 h Daphnia magna mg/L
EC50 340.7 - 469.2: 48 h Daphnia
magna mg/L EC50 Static
4.9: 48 h Daphnia pulex mg/L EC50
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Chemical Name Partition coefficient
Other adverse effects
Sodium carbonate
497-19-8
No information available
-
13. DISPOSAL CONSIDERATIONS
Waste treatment
Waste Disposal Methods
_____________________________________________________________________________________________
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Page 6 / 8
Page 7
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Contaminated packaging
Do not re-use empty containers.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Sodium carbonate
497-19-8
Corrosive
14. TRANSPORT INFORMATION
DOT
TDG
MEX
ICAO
IATA
IMDG
RID
ADR
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
Not regulated
ADN
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
-
-
-
-
-
-
-
-
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Yes
No
No
No
_____________________________________________________________________________________________
Page 7 / 8
Page 8
701120887- POWDER LAUNDRY BLEACH
Revision Date 17-Nov-2014
_____________________________________________________________________________________________
Reactive Hazard
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
No
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
This product does not contain any substances regulated by state right-to-know regulations
U.S. EPA Label information
EPA Pesticide Registration Number
Not applicable
16. OTHER INFORMATION
NFPA Health hazard 2 Flammability 0 Instability 0
HMIS Health hazard 2 Flammability 0
Physical Hazard 0 Personal protection X
Physical and chemical
hazards -
Prepared By
Revision Date
Revision Note
No information available
Disclaimer
The (M)SDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material.
The information contained here has been compiled from sources considered by Sun Products Corporation to be
dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all-inclusive document on
worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design
the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment.
Sun Products Corporation assumes no responsibility for injury to the recipient of third persons, or for any damage to any
property resulting from misuse of the product.
.
Sun Products Corporation
Regulatory Affairs
17-Nov-2014
End of Material Safety Data Sheet
_____________________________________________________________________________________________
Page 8 / 8
Loading...