This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 55%
M101S
GHS label elements:
Hazard pictograms:
Signal word:
Hazard statements:
Danger.
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
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M101SSafety Data Sheet
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements:
General:
Prevention:
Response:
Storage:
Disposal:
Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking. Pressurized container: Do not
pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash
hands thoroughly after handling.
Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated
clothing before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical attention.
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label elements:
Hazards not otherwise classified:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can
cause permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This product
contains chemicals known to the State of California to cause cancer and birth defects or
other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health of the environment and hence require reporting in this section. Occupational
exposure limits, if available, are listed in Section 8.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical
attention. If necessary, call a poison center or physician. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Skin contact:
Ingestion:
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the exposed person feels sick as
vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Description of necessary first aid measures:
Eye contact:
Inhalation:
Causes serious eye irritation.
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
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M101SSafety Data Sheet
Most important symptoms/effects, acute and delayed.
Potential acute health effects:
Skin contact:
Ingestion:
Over-exposure signs/symptoms:
Eye contact:
Inhalation:
Skin contact:
Causes skin irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Adverse symptoms may include the following:
pain or irritation
watering
redness
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
irritation
redness
Ingestion:
Adverse symptoms may include the following:
nausea of vomiting
Indication of immediate medical attention and special treatment needed, if necessary.
Notes to physician:
Specific treatments:
Protection of first-aiders:
Treat symptomatically. Contact poison treatment specialist immediately if large quantities
have been ingested or inhaled.
No specific treatment.
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Section 5 Fire-fighting measures.
Extinguishing media:
Suitable extinguishing media:
Unsuitable extinguishing media:
Use an extinguishing agent suitable for the surrounding fire.
None known.
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M101SSafety Data Sheet
Specific hazards arising
from the chemical:
Hazardous thermal
decomposition products:
Special protective
actions for fire-fighters:
Special protective
equipment for fire-fighters:
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. Gas may accumulate in low
or confined areas or travel a considerable distance to a source of ignition and flash back,
causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high
speed. Runoff to sewer may create fire or explosion hazard.
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Promptly isolate the scene by removing all persons from the vicinity of the incident if there
is a fire. No action shall be taken involving any personal risk or without suitable training.
Move containers from fire area if this can be done without risk. Use water spray to keep
fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6 Accidental release measures.
Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel:
No action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. In the
case of aerosols being ruptured, care should be taken due to the rapid escape of the
pressurized contents and propellant. If a large number of containers are ruptured, treat as
a bulk material spillage according to the instructions in the clean-up section. Do not touch
or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames
in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective
equipment.
For emergency responders:
Environmental precautions:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For non-emergency personnel.”
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
Methods and materials for containment and cleaning up:
Small spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
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M101SSafety Data Sheet
Large spill:
Environmental precautions:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for
disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the same
hazard as the spilled product. Note: see Section 1 for emergency contact information and
Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
Section 7 Handling and storage.
Precautions for safe handling:
Protective measures:
Put on appropriate personal protective equipment (see Section 8). Pressurized container:
protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce
or burn, even after use. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any other
ignition source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Empty containers retain product residue and
can be hazardous.
Advice on general
occupational hygiene:
Conditions for safe storage,
including any incompatibilities:
Eating, drinking and smoking should be prohibited in areas where this material is handled,
stored and processed. Workers should wash hands and face before eating, drinking and
smoking. Remove contaminated clothing and protective equipment before entering eating
areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food and
drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion-proof ventilation
equipment.
Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close
to the workstation location.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or
dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection:
Body protection:
Other skin protection:
Respiratory protection:
Hand protection:
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It should be noted that the
time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of
the gloves cannot be accurately estimated.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include
anti-static overalls, boots and gloves.
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based
on known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Causes skin irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Symptoms related to the physical, chemical and toxicological characteristics:
Eye contact:
Inhalation:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact:
Ingestion:
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
nausea or vomiting
Delayed and immediate effects and also chronic effects from short and long term exposure:
Short term exposure:
Potential immediate effects
Potential delayed effects
Not available.
Not available.
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Long term exposure:
Potential immediate effects
Potential delayed effects
Potential chronic health effects:
Not available.
General:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Developmental effects:
Fertility effects:
Numerical measures of toxicity:
Acute toxicity estimates:
Not available.
Not available.
May cause damage to organs through prolonged or repeated exposure.
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
RouteATE value
Oral6201.2 mg/kg
Inhalation (gases) 17676.3 ppm
Section 12 Ecological information.
Toxicity:
Product/ingredient name
Acetone
Xylene
Methyl Ethyl Ketone
Result
Acute EC50 20.565 mg/l Marine water
Acute LC50 6000000 μg/l Fresh water
Acute LC50 10000 μg/l Fresh water
Acute LC50 100 mg/l Fresh water
Chronic NOEC 4.95 mg/l Marine water
Chronic NOEC 0.016 ml/L Fresh water
Chronic NOEC 0.1 ml/L Fresh water
Chronic NOEC 5 μg/l Marine water
Acute LC50 8500 μg/l Marine water
Acute LC50 13400 μg/l Fresh water
Acute EC50 500000 μg/l Marine water
Acute LC50 520000 μg/l Fresh water
Acute LC50 400 ppm Marine water
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
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M101SSafety Data Sheet
Section 14 Transport information.
DOT ClassificationTDG ClassificationMexico
Classification
UN numberUN1950UN1950UN1950UN1950UN1950
UN proper
shipping name
Transport
hazard class(es)
Packing group-----
Environmental
hazards
Additional
information
Special precautions for user:
AEROSOLSAEROSOLSAEROSOLSAEROSOLS,
2.12.12.12.12.1
No.No.No.No.No.
Special provisions
LIMITED
QUANTITY
Special provisions
LIMITED
QUANTITY
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
Special provisions
LIMITED
QUANTITY
IATAIMDG
AEROSOLS
flammable
Special provisions
LIMITED
QUANTITY
Special provisions
LIMITED
QUANTITY
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code:
Not available.
Section 15 Regulatory information.
U.S. Federal regulations:
SARA 313: SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data
Sheet.
State regulations:
California Prop. 65 WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other
reproductive harm.
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M101SSafety Data Sheet
Section 16 Other information.
Prepared on: May 22, 2015
Hazardous Material Information System (U.S.A.):
2
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing
significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may
choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered
mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller
(800) 327-6868. The customer is responsible for determining the PPE code for this material.
*
4
0
Notice to reader:
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as
necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated
with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The
addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that
his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under
the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe
use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in
the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the
proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
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