E404 Safety Data Sheet
Section 1 Identification.
Product name: Product code:
NOCO® Battery Cleaner and Acid Detector
Other means of identification:
Product type:
Relevant identified uses of the
substance or mixture and
uses advised against:
Manufacturer:
Emergency telephone
number of the company:
Not available.
Aerosol.
Not applicable.
The NOCO Company Glenwillow, OH 44139
(800) 424-9300
Section 2 Hazards identification.
OSHA/HCS status:
Product code:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 3.2%
E404
GHS label elements:
Hazard pictograms:
Signal word:
Hazard statements:
Precautionary statements:
General:
Danger.
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
May cause damage to organs through prolonged or repeated exposure.
Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
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Prevention:
Response:
Storage:
Disposal:
Supplemental label elements:
Hazards not otherwise classified:
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on
an open flame or other ignition source. Do not breathe dust or mist.
Get medical attention if you feel unwell.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in
a well-ventilated place.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Please refer to
the SDS for additional information. Keep upright in a cool, dry place. Do not discard
empty can in trash compactor.
None known.
Section 3 Composition/information on ingredients.
Substance/mixture:
Other means of identification:
Mixture
Not available.
CAS number/other identifiers
Ingredient name % by weight CAS number
Butane 6.8 106-97-8
2-Propanol 5.9 67-63-0
Propane 3.1 74-98-6
Sodium Bicarbonate 3.0 144-55-8
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4 First aid measures.
Description of necessary first aid measures:
Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eye-
lids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Get medical attention following exposure or if feeling unwell.
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E404 Safety Data Sheet
Inhalation:
Skin contact:
Ingestion:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if
feeling unwell. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed potential acute health effects:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Over-exposure signs/symptoms:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician:
Specific treatments:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
No specific treatment.
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E404 Safety Data Sheet
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Section 5 Firefighting measures.
Extinguishing media:
Suitable extinguishing media:
Unsuitable extinguishing media:
Specific hazards arising from the
chemical:
Hazardous thermal
decomposition products:
Special protective actions for
fire-fighters:
Use an extinguishing agent suitable for the surrounding fire.
None known.
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective equipment for
fire-fighters:
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6 Accidental release measures.
Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
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For emergency responders:
Environmental precautions:
If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in “For nonemergency personnel”.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up:
Small spill:
Large spill:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Section 7 Handling and storage.
Precautions for safe handling:
Protective measures:
Advice on general occupational
hygiene:
Conditions for safe storage,
including any incompatibilities:
Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Do not breathe vapor or mist. Do not ingest. Avoid
contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use
away from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Empty containers retain product residue and can be hazardous.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Eliminate all ignition sources. Use appropriate
containment to avoid environmental contamination.
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E404 Safety Data Sheet
Section 8 Exposure controls/personal protection.
Control parameters, occupational exposure limits:
Ingredient name Exposure limits
Butane
2-Propanol ACGIH TLV (United States, 6/2013).
Propane NIOSH REL (United States, 10/2013).
Appropriate engineering controls:
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 6/2013).
STEL: 1000 ppm 15 minutes.
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Environmental exposure controls:
Individual protection measures:
Hygiene measures:
Eye/face protection:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with sideshields.
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E404 Safety Data Sheet
Skin protection:
Hand protection:
Body protection:
Other skin protection:
Respiratory protection:
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic
protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Section 9 Physical and chemical properties.
Appearance:
Physical state:
Color:
Odor:
Odor threshold :
Melting point:
Boiling point:
Flash point:
Evaporation rate:
Flammability (solid, gas):
Liquid.
Not available.
Not available.
Not available.
pH:
7
Not available.
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
1.44 (butyl acetate = 1)
Not available.
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E404 Safety Data Sheet
Lower and upper explosive
(flammable) limits:
Vapor pressure:
Vapor density:
Relative density:
Solubility:
Partition coefficient: n- octanol/
Auto-ignition temperature:
Decomposition temperature:
Viscosity:
Aerosol product:
Type of aerosol:
water:
Lower: 1.9%
Upper: 12.7%
13.5 kPa (101.325 mm Hg) [at 20°C]
1 [Air = 1]
0.92
Not available.
Not available.
Not available.
Not available.
Kinematic (40°C (104°F)): <0.07 cm
Spray
2/s (>7 cSt)
Heat of combustion:
6.056 kJ/g
Section 10 Stability and reactivity.
Reactivity:
Chemical stability:
Possibility of hazardous reactions:
Conditions to avoid:
Incompatible materials:
Hazardous decomposition
products:
No specific test data related to reactivity available for this product or its ingredients.
The product is stable.
Under normal conditions of storage and use, hazardous reactions will not occur.
Avoid all possible sources of ignition (spark or flame).
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 11 Toxicological information.
Information on toxicological effects:
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E404 Safety Data Sheet
Acute toxicty:
Product/ingredient name Result Species Dose Exposure
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
2-Propanol LD50 Dermal
LD50 Oral
Sodium Bicarbonate LD50 Oral Rat 4220 mg/kg -
Rabbit
Rat
12800 mg/kg
5000 mg/kg
Irritation/corrosion:
Product/ingredient
name
2-Propanol Eyes - Moderate irritant
Sodium Bicarbonate Eyes - Mild irritant
Result Species Score Exposure Observation
Eyes - Moderate irritant
Eyes - Severe irritant
Skin - Mild irritant
Skin - Mild irritant
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Human
-
-
-
-
-
-
24 hours 100mg
10mg
100mg
500mg
0.5 minutes 100mg
72 hours 30mg
Intermittent
Sensitization:
Not available.
Mutagenicity:
-
-
-
-
Not available.
Carcinogenicity:
Not available.
Classification:
Product/ingredient
name
2-Propanol - 3 -
OSHA IARC NTP
Reproductive toxicity:
Not available.
Teratogenicity:
Not available.
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E404 Safety Data Sheet
Specific target organ toxicity (single exposure):
Name Category Route of exposure Target organs
Butane
2-Propanol
Propane
3
3
3
Not applicable.
Not applicable.
Not applicable.
Respiratory tract irritation and narcotic effects.
Respiratory tract irritation and narcotic effects.
Respiratory tract irritation and narcotic effects.
Specific target organ toxicity (repeated exposure):
Name Category Route of exposure Target organs
Butane
2-Propanol
Propane
2
2
2
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Aspiration hazard:
Name Result
Propane ASPIRATION HAZARD - Category 1
Information on the likely
routes of exposure:
Not available.
Potential acute health effects:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Symptoms related to the physical, chemical, and toxicological characteristics:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
No specific data.
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Delayed and immediate effects and also chronic effects from short term exposure:
Potential immediate effects:
Potential delayed effects:
Not available.
Not available.
Delayed and immediate effects and also chronic effects from long term exposure:
Potential immediate effects:
Potential delayed effects:
Not available.
Not available.
Potential chronic health effects:
Chronic health effects:
General:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Developmental effects:
Fertility effects:
Not available.
May cause damage to organs through prolonged or repeated exposure.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Numerical measures of toxicity.
Acute toxicity estimates:
Route ATE value
Oral 52884.9 mg/kg
Section 12 Ecological information.
Toxicity:
Product/ingredient
name
2-Propanol Acute LC50 1400000 μg/l Marine water
Result Species Exposure
Acute LC50 1400000 μg/l
Crustaceans - Crangon crangon
Fish - Gambusia affinis
48 hours
96 hours
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E404 Safety Data Sheet
Product/ingredient
name
Sodium Bicarbonate Acute EC50 650000 μg/l Fresh water
Result Species Exposure
Acute LC50 767.87 mg/l Marine water
Acute LC50 7550 ppm Fresh water
Chronic NOEC 576 mg/l Fresh water
Persistence and degradability:
Not available.
Bioaccumulative potential:
Not available.
Mobility in soil:
Soil/water partition
coefficient (KOC):
Not available.
Algae - Navicula seminulum
Crustaceans - Americamysis bahia
Fish - Gambusia affinis - Adult
Daphnia - Daphnia magna - Neonate
96 hours
48 hours
96 hours
3 weeks
Other adverse effects:
No known significant effects or critical hazards.
Section 13 Disposal considerations.
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
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E404 Safety Data Sheet
Section 14 Transport information.
DOT Classification TDG Classification Mexico Classification IATA IMDG
UN number UN1950 UN1950 UN1950 UN1950 UN1950
UN proper
shipping name
Transport hazard
class(es)
Packing group -
Environmental
hazards
Additional
information
Special precautions for user:
AEROSOLS AEROSOLS AEROSOLS AEROSOLS,
2.1 2.1 2.1 2.1 2.1
No. No. No. No. No.
Special
provisions
LIMITED
QUANTITY
AEROSOLS
flammable
-
Special
provisions
LIMITED
QUANTITY
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
- - -
Special
provisions
(ERG#126)
Special
provisions
LIMITED
QUANTITY
Emergency
schedules (EmS)
LIMITED QUANTITY,
F-D, S-U
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code:
Not available.
Section 15 Regulatory information.
U.S. Federal regulations:
State regulations:
California Prop. 65: WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
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Section 16 Other information.
Prepared on: May 20, 2015
Hazardous Material Information System (U.S.A.):
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing
significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may
choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered
mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller
(800) 327-6868. The customer is responsible for determining the PPE code for this material.
2
2
0
Notice to reader:
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources,
as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein.
However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped.
The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure
that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not
under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the
safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions.
Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.
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