Noco E403 User Manual

E403 Safety Data Sheet
Section 1 Identification.
Product name: Product code:
NOCO® Battery Cleaner
Other means of identification:
Product type:
Relevant identified uses of the
substance or mixture and
uses advised against:
Manufacturer:
Emergency telephone
number of the company:
Not available.
Aerosol.
Not applicable.
The NOCO Company Glenwillow, OH 44139
(800) 424-9300
Section 2 Hazards identification.
OSHA/HCS status:
Product code:
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 3.1%
E403
GHS label elements:
Hazard pictograms:
Signal word:
Hazard statements:
Precautionary statements:
General:
Danger.
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause damage to organs through prolonged or repeated exposure.
Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.
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Prevention:
Response:
Storage:
Disposal:
Supplemental label elements:
Hazards not otherwise classified:
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Do not breathe dust or mist.
Get medical attention if you feel unwell.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.
Dispose of contents and container in accordance with all local, regional, national and international regulations.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY. Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.
None known.
Section 3 Composition/information on ingredients.
Substance/mixture:
Mixture
Other means of identification:
Not available.
CAS number/other identifiers
Ingredient name % by weight CAS number
Butane 6.8 106-97-8
Sodium Bicarbonate 5.6 144-55-8
Propane 3.1 74-98-6
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8.
Section 4 First aid measures.
Description of necessary first aid measures:
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Eye Contact:
Inhalation:
Skin contact:
Ingestion:
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eye­lids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention following exposure or if feeling unwell.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention following exposure or if feeling unwell. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention following exposure or if feeling unwell. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed potential acute health effects:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Over-exposure signs/symptoms:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
Adverse symptoms may include the following: irritation redness
Adverse symptoms may include the following: respiratory tract irritation coughing
No specific data.
No specific data.
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Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician:
Specific treatments:
Protection of first-aiders:
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
No specific treatment.
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Section 5 Firefighting measures.
Extinguishing media:
Suitable extinguishing media:
Unsuitable extinguishing media:
Specific hazards arising
from the chemical:
Use an extinguishing agent suitable for the surrounding fire.
None known.
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal
decomposition products:
Special protective
actions for fire-fighters:
Special protective
equipment for fire-fighters:
Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
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Section 6 Accidental release measures.
Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For emergency responders:
Environmental precautions:
If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in “For nonemer­gency personnel”.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up:
Small spill:
Large spill:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Section 7 Handling and storage.
Precautions for safe handling:
Protective measures:
Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.
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Advice on general occupational
hygiene:
Conditions for safe storage,
including any incompatibilities:
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.
Section 8 Exposure controls/personal protection.
Control parameters, occupational exposure limits:
Ingredient name Exposure limits
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours. TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 6/2013).
STEL: 1000 ppm 15 minutes.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.
Appropriate engineering controls:
Environmental exposure controls:
Individual protection measures:
Hygiene measures:
Eye/face protection:
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with sideshields.
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Skin protection:
Hand protection:
Body protection:
Other skin protection:
Respiratory protection:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9 Physical and chemical properties.
Appearance:
Physical state:
Color:
Odor:
Odor threshold :
Melting point:
Boiling point:
Flash point:
Evaporation rate:
Flammability (solid, gas):
Liquid.
Not available.
Not available.
Not available.
pH:
7
Not available.
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
0.09 (butyl acetate = 1)
Not available.
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Lower and upper explosive
(flammable) limits:
Vapor pressure:
Vapor density:
Relative density:
Solubility:
Partition coefficient: n- octanol/
Auto-ignition temperature:
Decomposition temperature:
Viscosity:
Aerosol product:
Type of aerosol:
water:
Lower: 1.9% Upper: 9.5%
13.5 kPa (101.325 mm Hg) [at 20°C]
1 [Air = 1]
0.95
Not available.
Not available.
Not available.
Not available.
Kinematic (40°C (104°F)): <0.07 cm
Spray
2/s (>7 cSt)
Heat of combustion:
4.322 kJ/g
Section 10 Stability and reactivity.
Reactivity:
Chemical stability:
Possibility of hazardous reactions:
Conditions to avoid:
Incompatible materials:
Hazardous decomposition
products:
No specific test data related to reactivity available for this product or its ingredients.
The product is stable.
Under normal conditions of storage and use, hazardous reactions will not occur.
Avoid all possible sources of ignition (spark or flame).
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 11 Toxicological information.
Information on toxicological effects:
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Acute toxicity:
Product/ingredient name Result Species Dose Exposure
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Sodium Bicarbonate LD50 Oral Rat 4220 mg/kg -
Irritation/corrosion:
Product/ingredient name Result Species Score Exposure Observation
Sodium Bicarbonate Eyes - Mild irritant
Skin - Mild irritant
Sensitization:
Not available.
Mutagenicity:
Not available.
Carcinogenicity:
Not available.
Reproductive toxicity:
Not available.
Teratogenicity:
Rabbit
Human
-
-
0.5 minutes 100mg
72 hours 30mg Intermittent
-
-
Not available.
Specific target organ toxicity (single exposure):
Name Category Route of exposure Target organs
Butane
Propane
3
3
Not applicable.
Not applicable.
Respiratory tract irritation and narcotic effects.
Respiratory tract irritation and narcotic effects.
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Specific target organ toxicity (repeated exposure):
Name Category Route of exposure Target organs
Butane
Propane
2
2
Not determined.
Not determined.
Aspiration hazard:
Name Result
Propane ASPIRATION HAZARD - Category 1
Information on the likely
routes of exposure:
Not available.
Potential acute health effects:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Not determined.
Not determined.
Symptoms related to the physical, chemical, and toxicological characteristics:
Eye contact:
Inhalation:
Skin contact:
Ingestion:
Adverse symptoms may include the following: irritation redness
Adverse symptoms may include the following: respiratory tract irritation coughing
No specific data.
No specific data.
Delayed and immediate effects and also chronic effects from short term exposure:
Potential immediate effects:
Potential delayed effects:
Not available.
Not available.
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Delayed and immediate effects and also chronic effects from long term exposure:
Potential immediate effects:
Potential delayed effects:
Potential chronic health effects:
Chronic health effects:
General:
Carcinogenicity:
Mutagenicity:
Teratogenicity:
Developmental effects:
Fertility effects:
Numerical measures of toxicity.
Acute toxicity estimates:
Not available.
Not available.
Not available.
May cause damage to organs through prolonged or repeated exposure.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Route ATE value
Oral 74955.6 mg/kg
Section 12 Ecological information.
Toxicity:
Product/ingredient name
Sodium Bicarbonate Acute EC50 650000 μg/l Fresh water
Result Species Exposure
Acute LC50 767.87 mg/l Marine water
Acute LC50 7550 ppm Fresh water
Chronic NOEC 576 mg/l Fresh water
Algae - Navicula seminulum
Crustaceans - Americamysis bahia
Fish - Gambusia affinis - Adult
Daphnia - Daphnia magna - Neonate
96 hours
48 hours
96 hours
3 weeks
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Persistence and degradability:
Not available.
Bioaccumulative potential:
Not available.
Mobility in soil:
Soil/water partition
coefficient (KOC):
Other adverse effects:
Not available.
No known significant effects or critical hazards.
Section 13 Disposal considerations.
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.
Section 14 Transport information.
DOT Classification TDG Classification Mexico Classification IATA IMDG
UN number UN1950 UN1950 UN1950 UN1950 UN1950
UN proper shipping name
Transport hazard class(es)
Packing group -
Environmental hazards
AEROSOLS AEROSOLS AEROSOLS AEROSOLS,
flammable
2.1 2.1 2.1 2.1 2.1
-
No. No. No. No. No.
- - -
AEROSOLS
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DOT Classification TDG Classification Mexico Classification IATA IMDG
Additional information
Special precautions for user:
Transport in bulk according to
Annex II of MARPOL 73/78 and
Special provisions LIMITED QUANTITY
the IBC Code:
Special provisions LIMITED QUANTITY
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.
Not available.
Section 15 Regulatory information.
U.S. Federal regulations:
Special provisions (ERG#126)
Special provisions LIMITED QUANTITY
Emergency schedules (EmS) LIMITED QUANTITY, F-D, S-U
SARA 313: SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data
Sheet.
State regulations:
California Prop. 65: WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
Section 16 Other information.
Prepared on: May 20, 2015
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Hazardous Material Information System (U.S.A.):
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material.
1
2
0
Notice to reader:
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associ­ated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are sub­ject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsi­ble for SDSs obtained from any other source.
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