pH electrodes, digital with Memosens technology,
and analog
For process engineering with ceramic diaphragm
and KCl liquid electrolyte, optionally available with
integrated temperature sensor
Application
Media with very low conductivity or a high proportion of organic solvents or alcohol:
• Chemical industry
• Organic chemicals
• Power stations
• Food industry
• Laboratory measurements
With ATEX- and FMapproval for use in hazardous areas
Your benefits
• KCl liquid electrolyte, can therefore be used with very low conductivity values
(≥ 0.1 μS/cm)
• Ceramic diaphragm with specified KCl flow rate
• If counterpressure applied, can be used up to 11 bar (160 psi) abs. pressure
• Poison-resistant thanks to separate reference capillary
• Suitable for CIP / SIP
• pH membrane glass for applications involving steam sterilization
• Four lengths: 120, 225, 360 and 425 mm
• Available with integrated Pt100, Pt1000 temperature sensor for analog sensors or
NTC30K for digital sensors
Other advantages of Memosens technology
• Maximum process safety thanks to non-contact, inductive signal transmission
• Data security thanks to digital data transmission
• Very easy to use as sensor data saved in the sensor
• Recording of sensor load data in the sensor enables predictive maintenance with
the Memobase Plus CYZ71D
Function and system design
2
3
1
5
4
Ceraliquid CPS41D and CPS41
Measuring principle
Measuring system
pH measurement
The pH value is used as a unit of measurement for the acidity or alkalinity of a liquid medium. The
membrane glass of the electrode supplies an electrochemical potential which is dependent upon the
pH value of the medium. This potential is generated by the selective penetration of H+ ions through
the outer layer of the membrane. An electrochemical boundary layer with an electric potential forms
at this point. An integrated Ag/AgCl reference system serves as the required reference electrode.
The transmitter converts the measured voltage into the corresponding pH value using the Nernst
equation.
A complete measuring system consists of the following components at least:
• pH electrode CPS41D or CPS41
• Transmitter, e.g. Liquiline CM42, CM44x/R, Mycom153, Liquisys M CPM2x3
• Memosens data cable CYK10 or CYK20 for Memosens sensors or CPK9 for analog sensors
• Immersion, flow or retractable assembly, e.g. Unifit CPA442
• Electrolyte vessel CPY7
1Example of a measuring system for pH measurement
1Electrolyte vessel CPY7
2Liquiline M CM42 two-wire transmitter for hazardous area
3Memosens data cable CYK10
4pH electrode CPS41D
5Process assembly Unifit CPA442
2Endress+Hauser
A0027761
Ceraliquid CPS41D and CPS41
Communication and data processing CPS41D
Communication with the transmitter
Always connect digital sensors with Memosens technology to a transmitter with Memosens
technology. Data transmission to a transmitter for analog sensors is not possible.
Digital sensors can store measuring system data in the sensor. These include the following:
• Manufacturer data
– Serial number
– Order code
– Date of manufacture
• Calibration data
– Calibration date
– Slope at 25 °C (77 °F)
– Zero point at 25 °C (77 °F)
– Number of calibrations
– Serial number of the transmitter used to perform the last calibration
• Operating data
– Temperature application range
– pH application range
– Date of initial commissioning
– Maximum temperature value
– Hours of operation under extreme conditions
– Number of sterilizations
– Resistance of glass membrane
You can display the above-mentioned data using the Liquiline CM44x, CM42 and Memobase Plus
CYZ71D.
Dependability
Reliability
IntegrityData security thanks to digital data transmission
Easy handling
Sensors with Memosens technology have an integrated electronics unit that stores calibration data
and other information (e.g. total operating hours and operating hours under extreme measuring
conditions). Once the sensor has been connected, the sensor data are transferred automatically to
the transmitter and used to calculate the current measured value. As the calibration data are stored
in the sensor, the sensor can be calibrated and adjusted independently of the measuring point. The
result:
• Easy calibration in the measuring lab under optimum external conditions increases the quality of
the calibration.
• Pre-calibrated sensors can be replaced quickly and easily, resulting in a dramatic increase in the
availability of the measuring point .
• Maintenance intervals can be defined based on all stored sensor load and calibration data and
predictive maintenance is possible.
• The sensor history can be documented on external data carriers and in evaluation programs, e.g.
Memobase Plus CYZ71D. Thus, the current application of the sensors can be made to depend on
their previous history.
Memosens technology digitizes the measured values in the sensor and transmits the data to the
transmitter using a non-contact connection that is free from potential interference. The result:
• Automatic error message if sensor fails or connection between sensor and transmitter is
interrupted
• Immediate error detection increases measuring point availability
Endress+Hauser3
Ceraliquid CPS41D and CPS41
Safety
Measured values
Measuring range
Maximum process safety
With inductive transmission of the measured value using a non-contact connection, Memosens
guarantees maximum process safety and offers the following benefits:
• All problems caused by moisture are eliminated:
– Plug-in connection free from corrosion
– Measured values cannot be distorted by moisture.
– Can even be connected under water
• The transmitter is galvanically decoupled from the medium. Issues concerning "symmetrical highimpedance" or "asymmetry" or an impedance converter are a thing of the past.
• EMC safety is guaranteed by screening measures for the digital transmission of measured values.
• Intrinsically safe electronics mean operation in hazardous areas is not a problem.
Input
pH value
Temperature
Electrode version AB and AC (for water / wastewater):
pH:1 to 12
Temperature:-15 to 80 °C (5 to 176 °F)
Electrode version BB and BC (for process, suitable for sterilization):
pH:0 to 14
Temperature:0 to 135 °C (32 to 275 °F)
Please note the process operating conditions.
4Endress+Hauser
Ceraliquid CPS41D and CPS41
15°
15°
A
B
Installation
Installation instructions
Do not install the electrodes upside down. The angle of inclination must be at least 15° from the
horizontal. A smaller inclination angle is not permitted as it could cause an air bubble to form in the
glass sphere and prevent the inner electrolyte from completely wetting the pH diaphragm.
NOTICE
Before screwing in the electrode, make sure the threaded connection of the assembly is clean
and runs smoothly.
Screw in the electrode finger-tight (3 Nm)! (Data apply only if installing with Endress+Hauser
‣
assemblies.)
Make sure to follow the installation instructions in the Operating Instructions of the used
‣
assembly.
A0024316
2Electrode installation; installation angle at least 15° from the horizontal
APermitted orientation
BForbidden orientation
Endress+Hauser5
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