pH electrodes for bioreactors with digital
Memosens technology
For biotechnology production processes with ion
trap for long-term stable reference
Application
Hygienic and sterile applications (sterilizable, autoclavable)
• Bioreactor/fermenter
• Biotechnology
• Pharmaceutical industry
• Foods
With ATEX/IECEx, FM, CSA, NEPSI, FDA and USP approval for use in hazardous
areas.
Your benefits
• Biocompatibility with regard to cytotoxicity and bioreactivity has been tested
successfully
• Documentation to certify compliance with requirements of pharmaceutical
industry with serial number of sensor (optional)
• Durable inscription on shaft, verified as non-cytotoxic
• Suitable for CIP/SIP cleaning, autoclavable, up to 140 °C (284 °F) depending on
version
• Pressurized reference, specially for fermentation processes
• Integrated pressure indicator
• Long-term stable reference with ion trap, resulting in a very long service life,
bridging electrolyte free of silver ions
• No change in color of gel
• Ceramic diaphragm
• Integrated temperature sensor for effective temperature compensation
• No materials derived from animals were used in the manufacture of parts in
contact with the process media
Page 2
[Continued from front page]
Other advantages of Memosens technology
• Maximum process safety thanks to non-contact, inductive signal transmission
• Data security thanks to digital data transmission
• Very easy to use as sensor data saved in the sensor
• Recording of sensor load data in the sensor enables predictive maintenance with the Memobase Plus CYZ71D
Page 3
Memosens CPS171D
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Function and system design
Measuring principle
Measuring system
pH measurement
The pH value is used as a unit of measurement for the acidity or alkalinity of a liquid medium. The
membrane glass of the electrode delivers an electrochemical potential that depends on the pH value
of the medium. This potential is generated by the selective penetration of H+ ions through the outer
layer of the membrane. An electrochemical boundary layer with an electric potential forms at this
point. An integrated Ag/AgCl reference system serves as the required reference electrode.
The transmitter converts the measured voltage into the corresponding pH value using the Nernst
equation.
A complete measuring system consists of the following components at least:
• pH electrode CPS171D
• Transmitter, e.g. Liquiline M CM42, CM44x/R
• Memosens data cable CYK10
• Assembly, e.g. Unifit CPA442
A0028291
1Example of a measuring system for pH measurement
1Installation assembly Unifit CPA442
2pH electrode CPS171D
3Memosens data cable CYK10 for Memosens sensors
4Transmitter Liquiline M CM42
Endress+Hauser3
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Memosens CPS171D
Communication and data
processing
Communication with the transmitter
Always connect digital sensors with Memosens technology to a transmitter with Memosens
technology. Data transmission to a transmitter for analog sensors is not possible.
Digital sensors can store measuring system data in the sensor. These include the following:
• Manufacturer data
– Serial number
– Order code
– Date of manufacture
• Calibration data
– Calibration date
– Slope at 25 °C (77 °F)
– Zero point at 25 °C (77 °F)
– Temperature offset
– Number of calibrations
– Serial number of the transmitter used to perform the last calibration
• Operating data
– Temperature application range
– pH application range
– Date of initial commissioning
– Hours of operation under extreme conditions
– Number of sterilizations
– Resistance of glass membrane
Display the data listed above with Liquiline CM42, CM44x/R and Memobase Plus CYZ71D.
4Endress+Hauser
Page 5
Memosens CPS171D
DependabilityReliability
Easy handling
Sensors with Memosens technology have integrated electronics that store calibration data and other
information (such as total hours of operation or operating hours under extreme measuring
conditions). Once the sensor has been connected, the sensor data are transferred automatically to
the transmitter and used to calculate the current measured value. As the calibration data are stored
in the sensor, the sensor can be calibrated and adjusted independently of the measuring point. The
result:
• Easy calibration in the measuring lab under optimum external conditions increases the quality of
the calibration.
• Pre-calibrated sensors can be replaced quickly and easily, resulting in a dramatic increase in the
availability of the measuring point.
• Thanks to the availability of the sensor data, maintenance intervals can be accurately defined and
predictive maintenance is possible.
• The sensor history can be documented on external data carriers and in evaluation programs, such
as Memobase Plus CYZ71D,. Thus, the current application of the sensors can be made to depend
on their previous history.
Integrity
Data security thanks to digital data transmission
Memosens technology digitizes the measured values in the sensor and transmits the data to the
transmitter via a non-contact connection that is free from potential interference. The result:
• Automatic error message if sensor fails or connection between sensor and transmitter is
interrupted
• Immediate error detection increases measuring point availability
Safety
Maximum process safety
With inductive transmission of the measured value using a non-contact connection, Memosens
guarantees maximum process safety and offers the following benefits:
• All problems caused by moisture are eliminated:
– Plug-in connection free from corrosion
– Measured values cannot be distorted by moisture.
– Can even be connected under water
• The transmitter is galvanically decoupled from the medium. Issues concerning "symmetrical highimpedance" or "asymmetry" or an impedance converter are a thing of the past.
• EMC safety is guaranteed by screening measures for the digital transmission of measured values.
• Intrinsically safe electronics mean operation in hazardous areas is not a problem.
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Input
Memosens CPS171D
Measured variable
Measuring range
pH value
Temperature
pH:1 to 12 pH (measuring range at 0 to 100 °C (32 to 212 °F))/0 to 14 pH (application)
Temperature: 0 to 140 °C (32 to 284 °F)
Pay attention to the operating conditions in the process.
6Endress+Hauser
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Memosens CPS171D
Detail A
pH range
Measuring range:1 to 12 pH
Application range:0 to 14 pH
NOTICE
Risk of damage to electrode!
Never use the electrode outside of the listed specifications!
‣
Performance characteristics
Reference operating
conditions
Reference system
Ag/AgCl reference lead with ion trap, bridging electrolyte 3M KCl, non-cytotoxic, pressurized
approx. 7 bar (102 psi) (abs.); indicated via pressure indicator (→ 2).
A0036310
2Pressure indicator
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Installation
15°
15°
A
B
Memosens CPS171D
Installation instructions
Do not install the electrode upside-down.
NOTICE
The angle of inclination of the electrode must be at least 15° from the horizontal.
A smaller angle of inclination would cause an air bubble to form in the glass ball. There is then no
guarantee that the pH membrane is completely covered with inner electrolyte.
Select the installation angle of the electrode so that it does not drop below 15°.
‣
1.Before screwing in the electrode, make sure the assembly threaded connection is clean and
runs smoothly.
2.Screw in the electrode hand-tight 3 Nm (2.2 lbf ft). (Data apply only if installing with
Endress+Hauser CPA assemblies.)
3.Make sure to also follow the installation instructions in the Operating Instructions of the
assembly used.
3installation angle at least 15° from the horizontal
APermitted orientation
BForbidden orientation
CAUTION
L
Glass electrode with pressurized reference
Possibility of sudden rupture and injury from glass splinters!
Always wear protective goggles when working with these electrodes.
‣
A0024316
8Endress+Hauser
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Memosens CPS171D
0
40
80
50
100
150
200
250
120
160
212
A
400206080100
0
4
6
8
10
2
[°C]
T
[°F]
[psi] p [bar]
120
140
284
1
7
102
15
B
C
Environment
Ambient temperature range
Storage temperature
Degree of protection
Electromagnetic
compatibility
Process temperature range
Process pressure range
(absolute)
NOTICE
Risk of damage from frost!
Do not use the sensor at temperatures below 0 °C (32 °F).
‣
0 to 50 °C (32 to 122 °F)
IP 68:Memosens plug-in head (10 m (33 ft) water column, 25 °C (77 °F), 45 days, 1 M KCl)
Interference emission and interference immunity as per
• EN 61326-1:2013
• EN 61326-2-3:2013
• EN 61326-2-5: 2013
• NAMUR NE21: 2012
Process
• 0 to 100 °C (32 to 212 °F) (sterilizable up to 140 °C (284 °F)
• 0 to 135 °C (32 to 275 °F) for sensors with Ex approval
1 to 7 bar (14.5 to 101.5 psi) (abs.)
0.8 bar (12 psi) (abs.) is possible as minimum.
CAUTION
L
Pressurization of sensor due to prolonged use under increased process pressure
Risk of injury from glass breakage!
Avoid excessive heating of sensors that are used under reduced process pressure or under
‣
atmospheric pressure.
When handling these sensors, wear protective goggles and suitable gloves.
‣
Minimum conductivity
Pressure-temperature
ratings
Endress+Hauser9
Min. 100 μS/cm (at atmospheric pressure, without flow)
4Pressure temperature load curve
AContinuous operation
BShort-term for SIP/ autoclaving
CAtmospheric pressure
A0025632
Page 10
Design, dimensions
8
9
120,
225,
360, 425
(4.72,
8.86,
14.2,
16.7)
12
(0.47)
1
2
3
4
5
6
7
Memosens CPS171D
Mechanical construction
5CPS171D with Memosens plug-in head. Engineering unit: mm (in)
1Memosens plug-in head
2FKM O-ring with thrust collar
3Spacer
4Pressure indicator with air bubble
5Ag/AgCl reference lead with ion trap
6Diaphragm
7Temperature sensor
8Ag/AgCl internal reference lead
9pH membrane
Weight
Materials
0.1 kg (0.2 lb) at a length of 120 mm (4.7 in)
Electrode shaft:
Glass to suit process
pH membrane glasses:Glass to suit process
Metal lead:Ag/AgCl
Diaphragm:Ceramic, sterilizable and autoclavable
Gel:Bridging electrolyte, non-cytotoxic
Nameplate:ceramic metal oxide
Temperature sensor
NTC 30K
Plug-in heads
CPS171D:
Memosens plug-in head for digital, non-contact data transmission,
16 bar (232 psi) (rel.)
10Endress+Hauser
A0019104
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Memosens CPS171D
Process connections
Ex approval
Biocompatibility
Pg 13.5
Certificates and approvals
IECEx
Ex ia IIC T3/T4/T6 Ga
ATEX
II 1G Ex ia IIC T3/T4/T6 Ga
NEPSI
Ex ia IIC T3/T4/T6 Ga
FM
IS/NI CL. I. Div 1, Group A-D
CSA
IS/NI CL. I. Div 1, Group A-D
Hazardous area versions of the digital sensors with Memosens technology are indicated by a
red/orange ring on the plug-in head.
Biocompatibility successfully tested with regard to
• Biological reactivity, in vitro (cytotoxicity) according to USP <87>
For process-sealing O-ring, bridging electrolyte and inscription on shaft
• Biological reactivity, in vivo according to USP <88> Class VI, 121 °C (250 °F)
For process-sealing O-ring
TÜV certificate for
Memosens plug-in head
Pressure resistance 16 bar (232 psi) (rel.), minimum three times the safety pressure
Endress+Hauser11
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Ordering information
Memosens CPS171D
Product page
Product Configurator
Scope of delivery
www.endress.com/cps171d
On the product page there is a Configure button to the right of the product image.
1.Click this button.
The Configurator opens in a separate window.
2.Select all the options to configure the device in line with your requirements.
In this way, you receive a valid and complete order code for the device.
3.Export the order code as a PDF or Excel file. To do so, click the appropriate button on the right
above the selection window.
For many products you also have the option of downloading CAD or 2D drawings of the
selected product version. Click the CAD tab for this and select the desired file type using
picklists.
The delivery comprises:
• Sensor in the version ordered
• Operating Instructions
• Safety instructions for hazardous area
Accessories
The following are the most important accessories available at the time this documentation was
issued.
For accessories not listed here, please contact your Service or Sales Center.
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Assemblies
Unifit CPA442
• Installation assembly for food, biotechnology and pharmaceutics
• With EHEDG and 3A certificate
• Product Configurator on the product page: www.endress.com/cpa442
Technical Information TI00306C
Cleanfit CPA875
• Retractable process assembly for sterile and hygienic applications
• For in-line measurement with standard sensors with 12 mm diameter, e.g. for pH, ORP, oxygen
• Product Configurator on the product page: www.endress.com/cpa875
Technical Information TI01168C
Cleanfit CPA475
• Retractable assembly for pH/ORP measurement in tanks and pipes under sterile measuring
conditions
• Product Configurator on the product page: www.endress.com/cpa475
Technical Information TI00240C
Dipfit CPA140
• pH/ORP immersion assembly with flange connection for very demanding processes
• Product Configurator on the product page: www.endress.com/cpa140
Technical Information TI00178C
12Endress+Hauser
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Memosens CPS171D
Buffer solutions
Measuring cable
Software
Handheld instrument
High-quality buffer solutions from Endress+Hauser - CPY20
The secondary buffer solutions have been referenced to primary reference material of the PTB
(German Federal Physico-technical Institute) or to standard reference material of NIST (National
Institute of Standards and Technology) according to DIN 19266 by a laboratory accredited by the
DAkkS (German accreditation body) according to DIN 17025.
Product Configurator on the product page: www.endress.com/cpy20
Memosens data cable CYK10
• For digital sensors with Memosens technology
• Product Configurator on the product page: www.endress.com/cyk10
Technical Information TI00118C
Memosens laboratory cable CYK20
• For digital sensors with Memosens technology
• Product Configurator on the product page: www.endress.com/cyk20
Memobase Plus CYZ71D
• PC software to support laboratory calibration
• Visualization and documentation of sensor management
• Sensor calibrations saved in the database
• Product Configurator on the product page: www.endress.com/cyz71d
Technical Information TI00502C
Liquiline To Go CYM290, CYM291
• Portable multiparameter device for Memosens pH, conductivity and oxygen sensors
• Product Configurator on the product page: www.endress.com/cym290, www.endress.com/cym291
Technical Information TI01198C
Refer to the Operating Instructions for CYM290 or CYM291 for information on the sensors that
can be connected.
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