DYMO 1982171 User Manual

MATERIAL SAFETY DATA SHEET

Lithium Polymer Rechargeable Battery

Model: Lithium-ion Polymer Battery

Prepared by Approved by

Lily Liu Wangmei Zhang

Date： Jan. 03 ，2014 Date： Jan. 03 ，2014

Page 1 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00

Material Safety Data Sheet

p

p

SSeeccttiioonn 11--CChheemmiiccaall PPrroodduucctt aanndd CCoommppaannyy IIddeennttiiffiiccaatti

SSeeccttiioonn 11--CChheemmiiccaall PPrroodduucctt aanndd CCoom

paannyy IIddeennttiiffiiccaattiioonn

m

ioonn

PPrroodduucctt IIddeennttiiffiiccaattiioonn

SP Lithium-Ion Polymer battery

Norminal Voltage ：3.7 V
Equivalent Lithium content ：≤20Wh
Testing Period ：Jan. 02，2014 To Jan. 03，2014

MMaannuuffaaccttuurreerr

SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD
Chaoshun Industrial Zone, Renmin Road, Fumin, Guanlan, Baoan, Shenzhen, Guangdong, China

Postcode ：518110
Telephone ：[phone]-818
Fax ：[phone]
E-mail ：[e-mail]

Chemical Composition Molecular Formula

Lithium Cobalt Oxide LiCoO2

Graphite powder C

Electrolyte

Polyethylene

Cu Cu

Nickel Nickel

Polyvinylidene fluoride

Polypropylene

Aluminum foil Al

Silicon Si

Epoxy Resin

PVC (C2H3Cl)x
Gold Au

Sn Sn

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

SSeeccttiioonn 22--CCoommppoossiittiioonn//IInnffoorrmmaattiioonn oonn IInnggrreeddiieennttss

SSeeccttiioonn 22--CCoom

LiPF6 C

（C

（CH

（C

poossiittiioonn//IInnffoorrmmaattiioonn oonn IInnggrreeddiieennttss

m

Weight

3H4O3 C4H6O3

C3H10O3

2H4）n 0.5～1%

2CF2）n 0.5～2%

3H6）n 2～5%

EP

0.2～0.5%

0.2～0.5%

% CAS No OSHA(PEL) ACGIH(TLV)

35～38%
23～25%

12～15%

5～10%

2～3%

7～10%

1～2%

1.5～2%

0.05～

0.1%

Page 2 of 10

12190-79-3 N/A N/A

7782-42-5 N/A N/A

21324-40-3 N/A N/A

9002-88-4 N/A N/A
7440-50-8 N/A N/A
7440-02-0 N/A N/A

24937-79-9 N/A N/A

9003-07-0 N/A N/A
7429-90-5 N/A N/A
7440-21-3 N/A N/A

38891-59-7 N/A N/A

9002-86-2 N/A N/A
7440-57-5 N/A N/A

7440-31-5 N/A N/A

File No./Rev.: SP-MSDS-0002/E00

Preparation
hazards and
classification
Appearance,
Color, and
Odor
Primary
Route(s) of
Exposure

Potential
Health
Effects:

Medical
Conditions
Aggravated
by
Exposure
Reported as
carcinogen

SSeeccttiioonn 33--HHaazzaarrddss IIddeennttiiffiiccaattiioon

SSeeccttiioonn 33--HHaazzaarrddss IIddeennttiiffiiccaattiioonn

Not dangerous with normal use. Do not dismantle, open or shred Li-ion Battery.
Exposure to the ingredients contained within or their ingredients products could be harmful.

Solid object with no odor, no color.

These chemicals are contained in a sealed stainless steel enclosure. Risk of exposure occurs
only if the cell is mechanically, thermally or electrically abused to the point of
compromising the enclosure. If this occurs, exposure to the electrolyte solution contained
within can occur by Inhalation, Ingestion, Eye contact and Skin contact.
ACUTE (short term): see Section 8 for exposure controls In the event that this battery has
been ruptured, the electrolyte solution contained within the battery would be corrosive and
can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an expected route of
exposure. Vapors or mists from a ruptured battery may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed battery is not an expected route of
exposure. Swallowing the contents of an open battery can cause serious chemical burns of
mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the battery and skin will not cause any harm. Skin contact with
contents of an open battery can cause severe irritation or burns to the skin.
Eye: Contact between the battery and the eye will not cause any harm. Eye contact with
contents of an open battery can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data
Not applicable

Not applicable

n

SSeeccttiioonn 44--FFiirrsstt--aaiidd MMeeaassuurrees

SSeeccttiioonn 44--FFiirrsstt--aaiidd MMeeaassuurreess

Inhalation If contents of an opened battery are inhaled, remove source of contamination or move victim

to fresh air. Obtain medical advice.

Skin contact If skin contact with contents of an open battery occurs, as quickly as possible remove

contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently

Page 3 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00

s

g

flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention.
Completely decontaminate clothing, shoes and leather goods before reuse or discard.

Eye contact If eye contact with contents of an open battery occurs, immediat ely flush the contaminated

eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the eyelids
open. Neutral saline solution may be used as soon as it is available. If necessary, continue
flushing during transport to emergency care facility. Take care not to rinse contaminated
water into the unaffected eye or onto face. Quickly transport victim to an emergency care
facility.

Ingestion If ingestion of contents of an open battery occurs, never give anything by mouth if victim is

rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth
thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL
(2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of
aspiration. Have victim rinse mouth with water again. Quickly transport victim to an
emergency care facility.

ghhttiinngg MMeeaassuurreess

SSeeccttiioonn 55--FFiirree FFi

i

Flammable
Properties

Suitable
extinguishing
Media
Unsuitable
extinguishing
Media
Explosion
Data
Specific
Hazards
arising from
the chemical
Protective
Equipment
and
precautions
for firefighters
NFPA Health: 0 Flammability: 0 Instability: 0

In the event that this battery has been ruptured, the electrolyte solution contain within the
battery would be flammable. Like any sealed container, battery cells may rupture when
exposed to excessive heat; this could result in the release of flammable or corrosive
materials.
Use extinguishing media suitable for the materials that are burning.

Not available

Sensitivity to Mechanical Impact: This may result in rupture in extreme cases
Sensitivity to Static Discharge: Not Applicable
Fires involving Li-ion Battery can be controlled with water. When water is used, however,
hydrogen gas may evolve. In a confined space, hydrogen gas can form an explosive mixture.
In this situation, smothering agents are recommended to extinguish the fire

As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
pressure-demand, self-contained breathing apparatus and full protective gear.
Fight fire from a protected location or a safe distance. Use NIOSH/MSHA approved
full-face self-contained breathing apparatus(SCBA) with full protective gear.

Page 4 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00

g

R

Reelleeaassee MMeeaassuurreess

SSeeccttiioonn 66--AAcccciiddeennttaal

SSeeccttiioonn 66--AAcccciiddeennttaall RReelleeaassee MMeeaassuurreess

l

Personal Precautions, protective equipment, and
emergency procedures

Environmental Precautions

Methods and materials for Containment

Methods and materials for cleaning up Absorb spilled material with an inert absorbent (dry

Restrict access to area until completion of
clean-up. Do not touch the spilled material. Wear
adequate personal protective equipment as
indicated in Section 8.

Prevent material from contaminating soil and
from entering sewers or waterways.
Stop the leak if safe to do so. Contain the spilled
liquid with dry sand or earth. Clean up spills
immediately.

sand or earth). Scoop contaminated absorbent into an
acceptable waste container.
Collect all contaminated absorbent and dispose of
according to directions in Section 13. Scrub the area
with detergent and water; collect all contaminated
wash water for proper disposal.

Handling

Storage

SSeeccttiioonn 77--HHaannddlliin

g aanndd SSttoorraaggee

n

Don’t handling Li-ion Battery with metalwork. Do not
open, dissemble, crush or burn battery.
Ensure good ventilation/ exhaustion at the workplace.
Prevent formation of dust. Information about
protection against explosions and fires: Keep ignition
sources away- Do not smoke.
If the Li-ion Battery are subjec t to storage for such a
long term as more than 3 months, it is recommended
to recharge the Li-ion Battery periodically.
3 months: -10 ℃ ~+40 ℃ , 45 to 85%RH And
recommended at 0℃~+35℃ for long period storage.
The capacity recovery rate in the delivery state (50%
capacity of fully charged) after storage is assumed to
be 80% or more. The voltage for a long time storage
shall be 3.7V~4.2V range.

Page 5 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00

p

y

Do not storage Li-ion Battery haphazardly in a box or

drawer where they may short-circuit each other or be
short-circuited by other metal objects.
Keep out of reach of children.
Do not expose Li-ion Battery to heat or fire.
Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic
materials.

SSeeccttiioonn 88--EExxppoossuurree CCoonnttrroollss//PPeerrssoonnaall PPrrootteeccttiioonn

SSeeccttiioonn 88--EEx

Engineering Controls Use local exhaust ventilation or other engineering

Personal Protective Equipment Respiratory Protection: Not necessary under

Other Protective Equipment

Hygiene Measures

poossuurree CCoonnttrroollss//PPeerrssoonnaall PPrrootteeccttiioonn

x

controls to control sources of dust, mist, fumes and
vapor. Keep away from heat and open flame. Store in
a cool, dry place.

normal conditions.
Skin and body Protection: Not necessary under
normal conditions, Wear neoprene or nitrile rubber
gloves if handling an open or leaking battery.
Hand protection: Wear neoprene or natural rubber
material gloves if handling an open or leaking
battery.
Eye Protection: Not necessary under normal
conditions, Wear safety glasses if handling an open or
leaking battery.
Have a safety shower and eye wash fountain readily
available in the immediate work area.
Do not eat, drink, or smoke in work area.
Maintain good housekeeping.

yssiiccaall aanndd CChheemmiiccaall PPrrooppeerrttiieess

SSeeccttiioonn 99--PPh

SSeeccttiioonn 99--PPhhyyssiiccaall aanndd CChheemmiiccaall PPrrooppeerrttiieess

Physical
State

Change in condition:

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

Form: Solid

Color: White
Odour: Monotony

h

Page 6 of 10

File No./Rev.: SP-MSDS-0002/E00

pH, with indication of the concentration Not applicable

y

Melting point/freezing point Not available.
Boiling Point, initial boiling point and Boiling

range:
Flash Point Not available.

Upper/lower flammability or explosive limits Not available.
Vapor Pressure: Not applicable
Vapor Density: (Air = 1) Not applicable
Density/relative desity Not available.
Solubility in Water: Insoluble
n-octanol/water partition coefficient Not available.
Auto-ignition temperature 130℃
Decomposition temperature Not available.
Odout threshold Not available.
Evaporation rate Not available.
Flammability (soil, gas) Not available.

Not available.

Viscosity Not applicable

SSeeccttiioonn 1100-- SSttaabbiilliittyy aanndd RReeaaccttiivviittyy

SSeeccttiioonn 1100-- SSttaabbiilliit

Stability The product is stable under normal conditions.

Conditions to Avoid (e.g. static discharge, shock or
vibration)

Incompatible Materials Not Available
Hazardous Decomposition Products This material may release toxic fumes if burned

Possibility of Hazardous Reaction Not Available

y aanndd RReeaaccttiivviittyy

t

Do not subject Li-ion Battery to mechanical shock.
Vibration encoutered during transportation does not
cause leakage, fire or explosion.
Do not disassemble, crush, short or install with
incorrect polarity. Avoid mechanical or electrical
abuse.

or exposed to fire

Page 7 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00

g

p

g

SSeeccttiioonn 1111--TTooxxiiccoollooggiiccaall IInnffoorrmmaattiioonn

SSeeccttiioonn 1111--TTooxxiiccoollo

Irritation Risk of irritation occurs only if the cell is

Sensitization Not Available
Neurological Effects Not Available

Teratoaenicitv Not Available

Reproductive Toxicity Not Available

Mutagenicity (Genetic Effects) Not Available

To xicologically Synergistic Materials Not Available

General note: Water hazard class 1(Self-assessment): slightly

Anticipated behavior of a chemical product in
environment/possible environmental
impace/ecotoxicity
Mobility in soil Not Available

SSeeccttiioonn 1122--EEccoollo

giiccaall IInnffoorrmmaattiioonn

o

mechanically, thermally or electrically abused to the
point of compromising the enclosure. If this occurs,
irritation to the skin, eyes and respiratory tract may
occur.

giiccaall IInnffoorrmmaattiioonn

o

hazardous for water.
Do not allow undiluted product or large quantities
of it to reach ground water, water course or
sewage system.
Not A vailable

Persistence and Degradability Not Available

Bioaccumulation potential Not Available

Other Adverse Effects Not A vailable

SSeeccttiioonn 1133--DDiissppoossaall CCoonnssiiddeerraattiioonnss

SSeeccttiioonn 1133--DDiis

Product disposal recommendation: Observe local, state and federal laws and regulations. Packaging disposal
recommendation: Be aware discarded batteries may cause fire, tape the battery terminals to insulate them. Don’t
disassembly the battery. Completely discharge containers (no tear drops, no powder rest, scraped carefully).
Containers may be recycled or re-used. Observe local, state and federal laws and regulations.

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

poossaall CCoonnssiiddeerraattiioonnss

s

Page 8 of 10

File No./Rev.: SP-MSDS-0002/E00

p

The potential effects on the environment and human health of the substances used in batteries and accumulations; the
desirability of not disposing of waste batteries and accumulators as unsorted municipal waste and of participating in
their separate collection so as to facilitate treatment and recycling.

poorrtt IInnffoorrmmaattiioonn

SSeeccttiioonn 1144--TTrraanns

SSeeccttiioonn 1144--TTrraannssppoorrtt IInnffoorrmmaattiioonn

This report applies to by sea, by air and by land;
The Li-ion Battery tested according to the requirements of the 5th revised edition of the UN manual of tests and
Criteria, Part Ⅲ, subsection 38.3；
Lithium ion battery was protected so as to prevent short circuits. This includes protection against contact with
conductive materials within the same packaging that could lead to short circuit;
The LITHIUM ION BATTERY according to Section II of PACKING INSTRUCTION 965~967 of the 2014 IATA
Dangerous Goods regulations 55th Edition may be transported and applicable U.S.DOT regulations for the safe
transport of Li-ion Battery.
More information concerning shipping, testing, marking and packaging can be obtained from label master at
http://www.labelmaster.com/.
The packaging shall be adequate to avoid mechanical damage during transport, handling and stacking. The materials
and pack design shall be chosen so as to prevent the development of unintentional electrical conduction, corrosion of
the terminals and ingress of moisture.
The package must be handled with care and that a flammability hazard exists if the package is damaged; Each
package must be labeled with a Li-ion Battery handling label or in addition to the Class 9 hazard label. With regard to
transport, the following regulations are cited and considered:

- The International Civil Aviation Organization (ICAO) Technical Instructions.

- The International Air transport Association (IATA) Dangerous Goods Regulations. UN number of lithium
battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in
equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous;
Marine pollutant (Y/N): N;

- The International Maritime Dangerous Goods (IMDG) Code.
For lithium-ion batteries by sea, provided that packaging is strong and prevent the products from short-circuit. UN
number of lithium battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in
equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous; Marine pollutant (Y/N): Y;
Special Provision: International maritime dangerous goods code (IMDG) 188, 230, 310, 348, 957;

- The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA

- The Office of Hazardous Materials Safety within the US Department of Transportations’ (DOT) Research and
Special Programs Administration (RSPA)

s

Page 9 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00

R

SSeeccttiioonn 1155--RReegguullaattoorryy IInnffoorrmmaattiioonn

SSeeccttiioonn 1155-

OSHA hazard communication standard (29 CFR 1910.1200)

The information above is believed to be accurate and represents the best information currently available to us.
However, concorde makes no warranty of merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. Although reasonable precautions have been
taken in the preparation of the data contained herein, it is offered solely for your information, consideration of
investigation. This material safety data sheet provides guidelines for the safe handling and use of this product; it does
not and cannot advise on all possible situations, therefore, your specific use of this product should be evaluated to
determine if additional precautions are required.

The data/information contained herein has been reviewed and approved for general release on the basis that this
document contains no export controlled information.

Hazardous V Non-hazardous

SSeeccttiioonn 1166--OOtthheerr IInnffoorrmmaattiioonn

SSeeccttiioonn 1166--OOtthheerr IInnffoorrmmaattiioon

Reegguullaattoorryy IInnffoorrmmaattiioonn

-

n

Page 10 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation.
SPRINGPOWER TECHOLOGY SHENZHEN CO.,LTD. makes no warranty, expressed or implied, with respect to this information and

disclaims all liabilities from reliance on it ---

File No./Rev.: SP-MSDS-0002/E00