DYMO 1835374 User Manual

Prepared by

Approved by

Yansu Liu

Jinyong Xie

Date： Aug. 5 ，2016

Date： Aug. 5 ，2016

SSeeccttiioonn 11--CChheemmiiccaall PPrroodduucctt aanndd CCoommppaannyy IIddeennttiiffiiccaattiioon

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MATERIAL SAFETY DATA SHEET

Lithium Cylindrical Rechargeable Battery

Model: Lithium-ion Cylindrical Battery

18500-1400mAh-2S

SSeeccttiioonn 11--CChheemmiiccaall PPrroodduucctt aanndd CCoommppaannyy IIddeennttiiffiiccaattiioon

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Material Safety Data Sheet

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Page 1 of 10

Chemical

Composition

Molecular Formula

Weight%

CAS No

OSHA(PEL)

ACGIH(TLV)

Co

Co

<40%

7440-48-4

N/A

N/A

Polyvinylidene

fluoride

（CH2CF2）n

<2%

24937-79-9

N/A

N/A

Graphite powder

C

<30%

7782-42-5

N/A

N/A

Electrolyte

LiPF6 C3H4O3 C4H6O3 C3H10O3

<20%

21324-40-3

N/A

N/A

Polyethylene

（C2H4）n

0.5-5%

9002-88-4

N/A

N/A

Copper foil

Cu

<10%

7440-50-8

N/A

N/A

Nickel

Nickel

0.5-5%

7440-02-0

N/A

N/A

Aluninum foil

Al

0.5-5%

7429-90-5

N/A

N/A

Preparation

hazards and

Not dangerous with normal use. Do not dismantle, open or shred Li-ion Battery.
Exposure to the ingredients contained within or their ingredients products could be harmful.

SSeeccttiioonn 22--CCoommppoossiittiioonn//IInnffoorrmmaattiioonn oonn IInnggrreeddiieenntts

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SSeeccttiioonn 33--HHaazzaarrddss IIddeennttiiffiiccaattiioonn

PPrroodduucctt IIddeennttiiffiiccaattiioonn

Lithium-Ion Cylindrical battery

18500-1400mAh-2S

Norminal Voltage ： 7.4V
Equivalent Lithium content ： 10.36Wh

MMaannuuffaaccttuurreerr

Huizhou Highpower Technology Co.,LTD

Xinhu Industrial Zone,Maan Town,HuiCheng District,Huizhou,Guangdong, China

Postcode ： 518110
Telephone ： [phone]-8008
Fax ： [phone]
E-mail ：[e-mail]

SSeeccttiioonn 22--CCoommppoossiittiioonn//IInnffoorrmmaattiioonn oonn IInnggrreeddiieennttss

SSeeccttiioonn 33--HHaazzaarrddss IIddeennttiiffiiccaattiioonn

Page 2 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

classification

Appearance,
Color, and
Odor

Solid object with no odor, no color.

Primary
Route(s) of
Exposure

These chemicals are contained in a sealed stainless steel enclosure. Risk of exposure occurs
only if the cell is mechanically, thermally or electrically abused to the point of
compromising the enclosure. If this occurs, exposure to the electrolyte solution contained
within can occur by Inhalation, Ingestion, Eye contact and Skin contact.

Potential
Health
Effects:

ACUTE (short term): see Section 8 for exposure controls In the event that this battery has
been ruptured, the electrolyte solution contained within the battery would be corrosive and
can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an expected route of
exposure. Vapors or mists from a ruptured battery may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed battery is not an expected route of
exposure. Swallowing the contents of an open battery can cause serious chemical burns of
mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the battery and skin will not cause any harm. Skin contact with
contents of an open battery can cause severe irritation or burns to the skin.
Eye: Contact between the battery and the eye will not cause any harm. Eye contact with
contents of an open battery can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological data

Medical
Conditions
Aggravated
by
Exposure

Not applicable

Reported as
carcinogen

Not applicable

Inhalation

If contents of an opened battery are inhaled, remove source of contamination or move victim
to fresh air. Obtain medical advice.

Skin contact

If skin contact with contents of an open battery occurs, as quickly as possible remove
contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently
flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention.
Completely decontaminate clothing, shoes and leather goods before reuse or discard.

SSeeccttiioonn 44--FFiirrsstt--aaiidd MMeeaassuurreess

SSeeccttiioonn 44--FFiirrsstt--aaiidd MMeeaassuurreess

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Page 3 of 10

Eye contact

If eye contact with contents of an open battery occurs, immediately flush the contaminated
eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the eyelids
open. Neutral saline solution may be used as soon as it is available. If necessary, continue
flushing during transport to emergency care facility. Take care not to rinse contaminated
water into the unaffected eye or onto face. Quickly transport victim to an emergency care
facility.

Ingestion

If ingestion of contents of an open battery occurs, never give anything by mouth if victim is
rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth
thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL
(2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of
aspiration. Have victim rinse mouth with water again. Quickly transport victim to an
emergency care facility.

Flammable
Properties

In the event that this battery has been ruptured, the electrolyte solution contain within the
battery would be flammable. Like any sealed container, battery cells may rupture when
exposed to excessive heat; this could result in the release of flammable or corrosive
materials.

Suitable
extinguishing
Media

Use extinguishing media suitable for the materials that are burning.

Unsuitable
extinguishing
Media

Not available
Explosion
Data

Sensitivity to Mechanical Impact: This may result in rupture in extreme cases
Sensitivity to Static Discharge: Not Applicable

Specific
Hazards
arising from
the chemical

Fires involving Li-ion Battery can be controlled with water. When water is used, however,
hydrogen gas may evolve. In a confined space, hydrogen gas can form an explosive mixture.
In this situation, smothering agents are recommended to extinguish the fire

Protective
Equipment
and
precautions
for firefighters

As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
pressure-demand, self-contained breathing apparatus and full protective gear.
Fight fire from a protected location or a safe distance. Use NIOSH/MSHA approved
full-face self-contained breathing apparatus(SCBA) with full protective gear.
NFPA

Health: 0 Flammability: 0 Instability: 0

SSeeccttiioonn 66--AAcccciiddeennttaall RReelleeaassee MMeeaassuurreess

SSeeccttiioonn 55--FFiirree FFiigghhttiinngg MMeeaassuurreess

SSeeccttiioonn 66--AAcccciiddeennttaall RReelleeaassee MMeeaassuurreess

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Page 4 of 10

Personal Precautions, protective equipment, and
emergency procedures

Restrict access to area until completion of
clean-up. Do not touch the spilled material. Wear
adequate personal protective equipment as
indicated in Section 8.

Environmental Precautions

Prevent material from contaminating soil and
from entering sewers or waterways.

Methods and materials for Containment

Stop the leak if safe to do so. Contain the spilled
liquid with dry sand or earth. Clean up spills
immediately.

Methods and materials for cleaning up

Absorb spilled material with an inert absorbent (dry
sand or earth). Scoop contaminated absorbent into an
acceptable waste container.
Collect all contaminated absorbent and dispose of
according to directions in Section 13. Scrub the area
with detergent and water; collect all contaminated
wash water for proper disposal.

Handling

Don’t handling Li-ion Battery with metalwork. Do not
open, dissemble, crush or burn battery.
Ensure good ventilation/ exhaustion at the workplace.
Prevent formation of dust. Information about
protection against explosions and fires: Keep ignition
sources away- Do not smoke.

Storage

If the Li-ion Battery are subject to storage for such a
long term as more than 3 months, it is recommended
to recharge the Li-ion Battery periodically.
3 months: -10 ℃ ~+40 ℃ , 45 to 85%RH And
recommended at 0℃~+35℃ for long period storage.
The capacity recovery rate in the delivery state (50%
capacity of fully charged) after storage is assumed to
be 80% or more. The voltage for a long time storage
shall be7.4V~8.4V range.

Do not storage Li-ion Battery haphazardly in a box or
drawer where they may short-circuit each other or be
short-circuited by other metal objects.
Keep out of reach of children.
Do not expose Li-ion Battery to heat or fire.
Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic

SSeeccttiioonn 77--HHaannddlliinngg aanndd SSttoorraaggee

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Page 5 of 10

materials.

Engineering Controls

Use local exhaust ventilation or other engineering
controls to control sources of dust, mist, fumes and
vapor. Keep away from heat and open flame. Store in
a cool, dry place.

Personal Protective Equipment

Respiratory Protection: Not necessary under
normal conditions.
Skin and body Protection: Not necessary under
normal conditions, Wear neoprene or nitrile rubber
gloves if handling an open or leaking battery.
Hand protection: Wear neoprene or natural rubber
material gloves if handling an open or leaking
battery.
Eye Protection: Not necessary under normal
conditions, Wear safety glasses if handling an open or
leaking battery.

Other Protective Equipment

Have a safety shower and eye wash fountain readily
available in the immediate work area.

Hygiene Measures

Do not eat, drink, or smoke in work area.
Maintain good housekeeping.

Physical
State

Form: Solid

Color: Green

Odour: Monotony
Change in condition:

pH, with indication of the concentration

Not applicable

Melting point/freezing point

Not available.

Boiling Point, initial boiling point and Boiling
range:

Not available.
Flash Point

Not available.

Upper/lower flammability or explosive limits

Not available.

SSeeccttiioonn 88--EExxppoossuurree CCoonnttrroollss//PPeerrssoonnaall PPrrootteeccttiioonn

SSeeccttiioonn 99--PPhhyyssiiccaall aanndd CChheemmiiccaall PPrrooppeerrttiieess

SSeeccttiioonn 88--EExxppoossuurree CCoonnttrroollss//PPeerrssoonnaall PPrrootteeccttiioonn

SSeeccttiioonn 99--PPhhyyssiiccaall aanndd CChheemmiiccaall PPrrooppeerrttiieess

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Page 6 of 10

Vapor Pressure:

Not applicable

Vapor Density: (Air = 1)

Not applicable

Density/relative desity

Not available.

Solubility in Water:

Insoluble

n-octanol/water partition coefficient

Not available.

Auto-ignition temperature

If possible remove cell(s)from fire fighting area.if
heated above 130℃ ,cell(s)can explode/ent. Cell is
not flammable but internal organic material will burn
if the cell is incinerated.

Decomposition temperature

Not available.

Odout threshold

Not available.

Evaporation rate

Not available.

Flammability (soil, gas)

Not available.

Viscosity

Not applicable

Stability

The product is stable under normal conditions.

Conditions to Avoid (e.g. static discharge, shockor
vibration)

Do not subject Li-ion Batteryto mechanical shock.
Vibration encoutered during transportation does not
cause leakage, fire or explosion.
Do not disassemble, crush, short or install with
incorrect polarity. Avoid mechanical or electrical
abuse.

Incompatible Materials

Not Available

Hazardous Decomposition Products

This material may release toxic fumes if burned
or exposed to fire

Possibility of Hazardous Reaction

Not Available

SSeeccttiioonn 1100-- SSttaabbiilliittyy aanndd RReeaaccttiivviitty

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SSeeccttiioonn 1111--TTooxxiiccoollooggiiccaall IInnffoorrmmaattiioon

n

SSeeccttiioonn 1100-- SSttaabbiilliittyy aanndd RReeaaccttiivviittyy

SSeeccttiioonn 1111--TTooxxiiccoollooggiiccaall IInnffoorrmmaattiioonn

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Page 7 of 10

Irritation

Risk of irritation occurs only if the cell is
mechanically, thermally or electrically abused to the
point of compromising the enclosure. If this occurs,
irritation to the skin, eyes and respiratory tract may
occur.

Sensitization

Not Available

Neurological Effects

Not Available

Teratoaenicity

Not Available

Reproductive Toxicity

Not Available

Mutagenicity (Genetic Effects)

Not Available

Toxicologically Synergistic Materials

Not Available

General note:

Water hazard class 1(Self-assessment): slightly
hazardous for water.
Do not allow undiluted product or large quantities
of it to reach ground water, water course or
sewage system.

Anticipated behavior of a chemical product in
environment/possible environmental
impace / ecotoxicity

Not Available

Mobility in soil

Not Available

Persistence and Degradability

Not Available

Bioaccumulation potential

Not Available

Other Adverse Effects

Not Available

SSeeccttiioonn 1122--EEccoollooggiiccaall IInnffoorrmmaattiioon

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SSeeccttiioonn 1133--DDiissppoossaall CCoonnssiiddeerraattiioonns

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SSeeccttiioonn 1133--DDiissppoossaall CCoonnssiiddeerraattiioonnss

Product disposal recommendation: Observe local, state and federal laws and regulations. Packaging disposal
recommendation: Be aware discarded batteries may cause fire, tape the battery terminals to insulate them. Don’t
disassembly the battery. Completely discharge containers (no tear drops, no powder rest, scraped carefully).
Containers may be recycled or re-used. Observe local, state and federal laws and regulations.

The potential effects on the environment and human health of the substances used in batteries and accumulations; the
desirability of not disposing of waste batteries and accumulators as unsorted municipal waste and of participating in
their separate collection so as to facilitate treatment and recycling.

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

Page 8 of 10

SSeeccttiioonn 1155--RReegguullaattoorryy IInnffoorrmmaattiioon

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SSeeccttiioonn 1144--TTrraannssppoorrtt IInnffoorrmmaattiioon

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SSeeccttiioonn 1144--TTrraannssppoorrtt IInnffoorrmmaattiioonn

This report applies to by sea, by air and by land;
The Li-ion Battery tested according to the requirements of the 5th revised edition of the UN manual of tests and
Criteria, Part Ⅲ, subsection 38.3；
Lithium ion battery was protected so as to prevent short circuits. This includes protection against contact with
conductive materials within the same packaging that could lead to short circuit;
The LITHIUM ION BATTERY according to Section II of PACKING INSTRUCTION 965-967 of the 2016 IATA
Dangerous Goods regulations 57th Edition may be transported and applicable U.S.DOT regulations for the safe
transport of Li-ion Battery.
More information concerning shipping, testing, marking and packaging can be obtained from label master at
http://www.labelmaster.com/.
The packaging shall be adequate to avoid mechanical damage during transport, handling and stacking. The materials
and pack design shall be chosen so as to prevent the development of unintentional electrical conduction, corrosion of
the terminals and ingress of moisture.
The package must be handled with care and that a flammability hazard exists if the package is damaged; Each
package must be labeled with a Li-ion Battery handling label or in addition to the Class 9 hazard label. With regard to
transport, the following regulations are cited and considered:

- The International Civil Aviation Organization (ICAO) Technical Instructions.

- The International Air transport Association (IATA) Dangerous Goods Regulations. UN number of lithium
battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in
equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous;
Marine pollutant (Y/N): N;

- The International Maritime Dangerous Goods (IMDG) Code.
For lithium-ion batteries by sea, provided that packaging is strong and prevent the products from short-circuit. UN
number of lithium battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries contained in
equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous; Marine pollutant (Y/N): Y;
Special Provision: International maritime dangerous goods code (IMDG) 188, 230, 310, 348, 957;

- The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA

- The Office of Hazardous Materials Safety within the US Department of Transportations’ (DOT) Research and
Special Programs Administration (RSPA)

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OSHA hazard communication standard (29 CFR 1910.1200)

Page 9 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01

SSeeccttiioonn 1166--OOtthheerr IInnffoorrmmaattiioon

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Hazardous V Non-hazardous

SSeeccttiioonn 1166--OOtthheerr IInnffoorrmmaattiioonn

The information above is believed to be accurate and represents the best information currently available to us.
However, concorde makes no warranty of merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. Although reasonable precautions have been
taken in the preparation of the data contained herein, it is offered solely for your information, consideration of
investigation. This material safety data sheet provides guidelines for the safe handling and use of this product; it does
not and cannot advise on all possible situations, therefore, your specific use of this product should be evaluated to
determine if additional precautions are required.

The data/information contained herein has been reviewed and approved for general release on the basis that this
document contains no export controlled information.

Page 10 of 10

The information and recommendations set forth are made in good faith and believed to be accurate as of the date of preparation. Huizhou
Highpower Technology Co.,LTD makes no warranty, expressed or implied, with respect to this information and disclaims all liabilities
from reliance on it --- File No./Rev.: HP-MSDS-16088/A01