3M 60440282378, XC-9911-8793-8, 60440282535 User Manual

3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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Safety Data Sheet
Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
30-2823-0
Version Number:
1.06
Issue Date:
01/29/16
Supercedes Date:
01/18/16
SECTION 1: Identification
1.1. Product identifier
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27
1.2. Recommended use and restrictions on use
Recommended use
Abrasive Product
1.3. Supplier’s details MANUFACTURER:
3M
DIVISION:
Abrasive Systems Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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55% of the mixture consists of ingredients of unknown acute oral toxicity.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Aluminum Oxide (non-fibrous) 1344-28-1 50 - 80 Inorganic Fluoride 14484-69-6 10 - 25 Silicon Carbide Mineral 409-21-2 1 - 10 Magnesium Oxide 1309-48-4 0.1 - 8 Titanium Dioxide 13463-67-7 0 - 0.75 Carbon Black 1333-86-4 0.01 - 0.4 Lubricant 8042-47-5 0 - 0.1 Cured resin Mixture 10 - 20 Fiberglass Mesh Scrims Mixture 5 - 10 Metal Reinforced Steel Bushing Mixture 1 - 5
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If Swallowed:
No need for first aid is anticipated.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion Carbon dioxide During Combustion
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Observe precautions from other sections.
6.2. Environmental precautions
Not applicable.
6.3. Methods and material for containment and cleaning up
Not applicable.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Damaged product can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks prior to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or when near such operations. Sparks and particles flying from the product during sanding or grinding can cause injury and fire. Combustible dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Magnesium Oxide 1309-48-4 OSHA TWA(as total particulates):15
mg/m3
Magnesium Oxide 1309-48-4 ACGIH TWA(inhalable fraction):10
mg/m3
A4: Not class. as human
carcin Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3 Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3 Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3
mg/m3
A3: Confirmed animal
carcin. Aluminum Oxide (non-fibrous) 1344-28-1 CMRG TWA:1 fiber/cc Aluminum Oxide (non-fibrous) 1344-28-1 OSHA TWA(as total dust):15
mg/m3;TWA(respirable fraction):5 mg/m3
Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1
mg/m3
A4: Not class. as human
carcin Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5
mg/m3
Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human
carcin Silicon Carbide Mineral 409-21-2 OSHA TWA(as total dust):15
mg/m3;TWA(respirable
fraction):5 mg/m3 Paraffin oil 8042-47-5 OSHA TWA(as mist):5 mg/m3 MINERAL OILS, HIGHLY­REFINED OILS
8042-47-5 ACGIH TWA(inhalable fraction):5
mg/m3
A4: Not class. as human carcin
ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide appropriate local exhaust ventilation for cutting, grinding, sanding or machining. Provide local exhaust at process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that dust­handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
8.2.2. Personal protective equipment (PPE)
Eye/face protection
To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields
Skin/hand protection
Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding.
Respiratory protection
Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties General Physical Form:
Solid
Odor, Color, Grade:
Solid Abrasive Product
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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Odor threshold
Not Applicable
pH
Not Applicable
Melting point
Not Applicable
Boiling Point
Not Applicable
Flash Point
Not Applicable
Evaporation rate
Not Applicable
Flammability (solid, gas)
Not Classified
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
Not Applicable
Vapor Density
Not Applicable
Specific Gravity
Not Applicable
Solubility In Water
Not Applicable
Solubility- non-water
Not Applicable
Partition coefficient: n-octanol/ water
Not Applicable
Autoignition temperature
Not Applicable
Decomposition temperature
Not Applicable
Viscosity
Not Applicable
Molecular weight
No Data Available
Percent volatile
Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
No known health effects.
Carcinogenicity:
Ingredient CAS No. Class Description Regulation
Carbon Black 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer
Additional Information:
This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered.
This product contains titanium dioxide. Cancer of the lungs has been observed in rats that inhaled high levels of titanium dioxide. No exposure to inhaled titanium dioxide is expected during the normal handling and use of this product. Titanium dioxide was not detected when air sampling was conducted during simulated use of similar products containing titanium dioxide. Therefore, the health effects associated with titanium dioxide are not expected during the normal use of this product.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Aluminum Oxide (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide (non-fibrous) Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 2.3 mg/l
Aluminum Oxide (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg Inorganic Fluoride Dermal Rabbit LD50 > 2,000 mg/kg Inorganic Fluoride Inhalation-
Dust/Mist (4 hours)
Rat LC50 1.2 mg/l
Inorganic Fluoride Ingestion Rat LD50 2,150 mg/kg Silicon Carbide Mineral Dermal Rat LD50 > 2,000 mg/kg Silicon Carbide Mineral Ingestion Rat LD50 > 2,000 mg/kg Magnesium Oxide Dermal Professio
nal judgeme
LD50 estimated to be 2,000 - 5,000 mg/kg
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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nt Magnesium Oxide Ingestion Rat LD50 3,870 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 6.82 mg/l
Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Carbon Black Dermal Rabbit LD50 > 3,000 mg/kg Carbon Black Ingestion Rat LD50 > 8,000 mg/kg Lubricant Dermal Rabbit LD50 > 2,000 mg/kg Lubricant Ingestion Rat LD50 > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Aluminum Oxide (non-fibrous) Rabbit No significant irritation Inorganic Fluoride Rabbit No significant irritation Silicon Carbide Mineral Rat No significant irritation Magnesium Oxide Professio
nal
judgeme
nt
No significant irritation
Titanium Dioxide Rabbit No significant irritation Carbon Black Rabbit No significant irritation Lubricant Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Aluminum Oxide (non-fibrous) Rabbit No significant irritation Inorganic Fluoride Rabbit Corrosive Silicon Carbide Mineral Professio
nal
judgeme
nt
No significant irritation
Titanium Dioxide Rabbit No significant irritation Carbon Black Rabbit No significant irritation Lubricant Rabbit Mild irritant
Skin Sensitization
Name Species Value
Titanium Dioxide Human
and
animal
Not sensitizing
Lubricant Guinea
pig
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Aluminum Oxide (non-fibrous) In Vitro Not mutagenic Magnesium Oxide In Vitro Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Carbon Black In Vitro Not mutagenic Carbon Black In vivo Some positive data exist, but the data are not
sufficient for classification
Lubricant In Vitro Not mutagenic
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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Carcinogenicity
Name Route Species Value
Aluminum Oxide (non-fibrous) Inhalation Rat Not carcinogenic Magnesium Oxide Not
Specified
Human and animal
Some positive data exist, but the data are not sufficient for classification
Titanium Dioxide Ingestion Multiple
animal species
Not carcinogenic
Titanium Dioxide Inhalation Rat Carcinogenic Carbon Black Dermal Mouse Not carcinogenic Carbon Black Ingestion Mouse Not carcinogenic Carbon Black Inhalation Rat Carcinogenic Lubricant Dermal Mouse Not carcinogenic Lubricant Inhalation Multiple
animal species
Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Inorganic Fluoride Ingestion Some positive developmental data exist,
but the data are not sufficient for classification
Mouse NOAEL 100
mg/kg/day
during organogenesi s
Lubricant Ingestion Not toxic to female reproduction Rat NOAEL 4,350
mg/kg/day
13 weeks
Lubricant Ingestion Not toxic to male reproduction Rat NOAEL 4,350
mg/kg/day
13 weeks
Lubricant Ingestion Not toxic to development Rat NOAEL 4,350
mg/kg/day
during gestation
Lactation
Name Route Species Value
Inorganic Fluoride Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Magnesium Oxide Inhalation respiratory system All data are negative Human NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Aluminum Oxide (non­fibrous)
Inhalation pneumoconiosis |
pulmonary fibrosis
Some positive data exist, but the data are not sufficient for classification
Human NOAEL Not
available
occupational exposure
Inorganic Fluoride Inhalation respiratory system Causes damage to organs through
prolonged or repeated exposure
Rat LOAEL
0.003 mg/l
28 days
Titanium Dioxide Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Rat LOAEL 0.01
mg/l
2 years
Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not
available
occupational exposure
Carbon Black Inhalation pneumoconiosis Some positive data exist, but the
data are not sufficient for
Human NOAEL Not
available
occupational exposure
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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classification
Lubricant Ingestion hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
1,381 mg/kg/day
90 days
Lubricant Ingestion liver | immune
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
1,336 mg/kg/day
90 days
Aspiration Hazard
Name Value
Lubricant Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification Health: 0 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:
30-2823-0
Version Number:
1.06
Issue Date:
01/29/16
Supercedes Date:
01/18/16
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M
3M USA SDSs are available at www.3M.com
3M™ Abrasive Products, High Performance Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™ II: Cut off Wheels and Depressed Center Grinding Wheels; Cubitron™II Cut and Grind Wheels Type 27 01/29/16
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