3M 787C User Manual

3M™ Abrasive Products, Cubitron™ II Fibre Discs, 782C and 787C 04/29/18
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Safety Data Sheet
Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
34-9390-5
Version Number:
3.07
Issue Date:
04/29/18
Supercedes Date:
09/21/17
SECTION 1: Identification
1.1. Product identifier
3M™ Abrasive Products, Cubitron™ II Fibre Discs, 782C and 787C
1.2. Recommended use and restrictions on use
Recommended use
Abrasive Product
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Abrasive Systems Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
10% of the mixture consists of ingredients of unknown acute oral toxicity.
10% of the mixture consists of ingredients of unknown acute inhalation toxicity.
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SECTION 3: Composition/information on ingredients
Ingredient
C.A.S. No.
% by Wt
Inorganic Fluoride
14075-53-7
0 - 6
Filler
1317-65-3
1.5 - 5
Ceramic Aluminum Oxide (non-fibrous)
1344-28-1
5 - 25
Inorganic Fluoride
15096-52-3
5 - 15
Titanium Dioxide
13463-67-7
0 - 0.15
Cured Resin
Mixture
5 - 15
Fibre Backing
Mixture
45 - 75
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance
Condition
Carbon monoxide
During Combustion
Carbon dioxide
During Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
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6.1. Personal precautions, protective equipment and emergency procedures
Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Not applicable.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Damaged product can break apart during use and cause serious injury to face or eyes. Check product for damage such as cracks or nicks prior to use. Replace if damaged. Always wear eye and face protection when working at sanding or grinding operations or when near such operations. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Combustible dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.
Ingredient
C.A.S. No.
Agency
Limit type
Additional Comments
Filler
1317-65-3
OSHA
TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3
Aluminum, insoluble compounds
1344-28-1
ACGIH
TWA(respirable fraction):1 mg/m3
A4: Not class. as human carcin
Ceramic Aluminum Oxide (non­fibrous)
1344-28-1
OSHA
TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3
Titanium Dioxide
13463-67-7
ACGIH
TWA:10 mg/m3
A4: Not class. as human carcin
Titanium Dioxide
13463-67-7
OSHA
TWA(as total dust):15 mg/m3
Aluminum, insoluble compounds
15096-52-3
ACGIH
TWA(respirable fraction):1 mg/m3
A4: Not class. as human carcin
FLUORIDES
15096-52-3
ACGIH
TWA(as F):2.5 mg/m3
A4: Not class. as human carcin
FLUORIDES
15096-52-3
OSHA
TWA(as dust):2.5 mg/m3;TWA(as F):2.5 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
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8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
8.2.2. Personal protective equipment (PPE)
Eye/face protection
To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields
Skin/hand protection
Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding.
Respiratory protection
Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Solid
Odor, Color, Grade:
Solid Abrasive Product
Odor threshold
Not Applicable
pH
Not Applicable
Melting point
Not Applicable
Boiling Point
Not Applicable
Flash Point
Not Applicable
Evaporation rate
Not Applicable
Flammability (solid, gas)
Not Classified
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
Not Applicable
Vapor Density
Not Applicable
Specific Gravity
Not Applicable
Solubility In Water
Not Applicable
Solubility- non-water
Not Applicable
Partition coefficient: n-octanol/ water
Not Applicable
3M™ Abrasive Products, Cubitron™ II Fibre Discs, 782C and 787C 04/29/18
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Autoignition temperature
Not Applicable
Decomposition temperature
Not Applicable
Viscosity
Not Applicable
Volatile Organic Compounds
No Data Available
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
No Data Available
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance
Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
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Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Carcinogenicity:
Ingredient
CAS No.
Class Description
Regulation
Titanium Dioxide
13463-67-7
Grp. 2B: Possible human carc.
International Agency for Research on Cancer
Additional Information:
This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered.
This product contains titanium dioxide. Cancer of the lungs has been observed in rats that inhaled high levels of titanium dioxide. No exposure to inhaled titanium dioxide is expected during the normal handling and use of this product. Titanium dioxide was not detected when air sampling was conducted during simulated use of similar products containing titanium dioxide. Therefore, the health effects associated with titanium dioxide are not expected during the normal use of this product.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name
Route
Species
Value
Overall product
Inhalation­Dust/Mist(4 hr)
No data available; calculated ATE >12.5 mg/l
Overall product
Ingestion
No data available; calculated ATE >5,000 mg/kg
Ceramic Aluminum Oxide (non-fibrous)
Dermal
LD50 estimated to be > 5,000 mg/kg
Ceramic Aluminum Oxide (non-fibrous)
Inhalation­Dust/Mist (4 hours)
Rat
LC50 > 2.3 mg/l
Ceramic Aluminum Oxide (non-fibrous)
Ingestion
Rat
LD50 > 5,000 mg/kg
Inorganic Fluoride
Dermal
Rabbit
LD50 > 2,100 mg/kg
Inorganic Fluoride
Inhalation­Dust/Mist (4 hours)
Rat
LC50 4.5 mg/l
Inorganic Fluoride
Ingestion
Rat
LD50 5,000 mg/kg
Inorganic Fluoride
Dermal
LD50 estimated to be > 5,000 mg/kg
Inorganic Fluoride
Inhalation­Dust/Mist (4 hours)
Rat
LC50 > 5.3 mg/l
Inorganic Fluoride
Ingestion
Rat
LD50 5,854 mg/kg
Filler
Dermal
Rat
LD50 > 2,000 mg/kg
Filler
Inhalation­Dust/Mist (4 hours)
Rat
LC50 3 mg/l
Filler
Ingestion
Rat
LD50 6,450 mg/kg
Titanium Dioxide
Dermal
Rabbit
LD50 > 10,000 mg/kg
Titanium Dioxide
Inhalation­Dust/Mist (4 hours)
Rat
LC50 > 6.82 mg/l
Titanium Dioxide
Ingestion
Rat
LD50 > 10,000 mg/kg
ATE = acute toxicity estimate
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Skin Corrosion/Irritation
Name
Species
Value
Ceramic Aluminum Oxide (non-fibrous)
Rabbit
No significant irritation
Inorganic Fluoride
Multiple animal species
No significant irritation
Inorganic Fluoride
Rabbit
No significant irritation
Filler
Rabbit
No significant irritation
Titanium Dioxide
Rabbit
No significant irritation
Serious Eye Damage/Irritation
Name
Species
Value
Ceramic Aluminum Oxide (non-fibrous)
Rabbit
No significant irritation
Inorganic Fluoride
Rabbit
Mild irritant
Inorganic Fluoride
Rabbit
No significant irritation
Filler
Rabbit
No significant irritation
Titanium Dioxide
Rabbit
No significant irritation
Skin Sensitization
Name
Species
Value
Titanium Dioxide
Human and animal
Not classified
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name
Route
Value
Ceramic Aluminum Oxide (non-fibrous)
In Vitro
Not mutagenic
Titanium Dioxide
In Vitro
Not mutagenic
Titanium Dioxide
In vivo
Not mutagenic
Carcinogenicity
Name
Route
Species
Value
Ceramic Aluminum Oxide (non-fibrous)
Inhalation
Rat
Not carcinogenic
Titanium Dioxide
Ingestion
Multiple animal species
Not carcinogenic
Titanium Dioxide
Inhalation
Rat
Carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Species
Test Result
Exposure Duration
Filler
Ingestion
Not classified for development
Rat
NOAEL 625 mg/kg/day
premating & during gestation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Species
Test Result
Exposure Duration
Filler
Inhalation
respiratory system
Not classified
Rat
NOAEL
0.812 mg/l
90 minutes
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Specific Target Organ Toxicity - repeated exposure
Name
Route
Target Organ(s)
Value
Species
Test Result
Exposure Duration
Ceramic Aluminum Oxide (non-fibrous)
Inhalation
pneumoconiosis
Some positive data exist, but the data are not sufficient for classification
Human
NOAEL Not available
occupational exposure
Ceramic Aluminum Oxide (non-fibrous)
Inhalation
pulmonary fibrosis
Not classified
Human
NOAEL Not available
occupational exposure
Inorganic Fluoride
Inhalation
bone, teeth, nails, and/or hair
Causes damage to organs through prolonged or repeated exposure
Rat
NOAEL
0.0005 mg/l
5 months
Inorganic Fluoride
Inhalation
respiratory system
Causes damage to organs through prolonged or repeated exposure
Rat
NOAEL
0.00021 mg/l
90 days
Inorganic Fluoride
Ingestion
bone, teeth, nails, and/or hair
Causes damage to organs through prolonged or repeated exposure
Rat
LOAEL 0.58 mg/kg/day
14 weeks
Filler
Inhalation
respiratory system
Not classified
Human
NOAEL Not available
occupational exposure
Titanium Dioxide
Inhalation
respiratory system
Some positive data exist, but the data are not sufficient for classification
Rat
LOAEL 0.01 mg/l
2 years Titanium Dioxide
Inhalation
pulmonary fibrosis
Not classified
Human
NOAEL Not available
occupational exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted industrial waste facility.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to
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transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
EPCRA 311/312 Hazard Classifications:
Physical Hazards
Not applicable
Health Hazards
Not applicable
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification Health: 0 Flammability: 1 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
Document Group:
34-9390-5
Version Number:
3.07
Issue Date:
04/29/18
Supercedes Date:
09/21/17
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic
3M™ Abrasive Products, Cubitron™ II Fibre Discs, 782C and 787C 04/29/18
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transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M
3M USA SDSs are available at www.3M.com
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