YSI 4010-1W Operating Manual

OPERATING MANUAL

4010P-1W

4010-1W

4010P-1W

IDS WA

ba76141e07 08/2018

MultiLab 4010(P)-1(W)

DIGITAL METER FOR (WIRELESS) IDS SENSORS

MultiLab 4010-1W

For the most recent version of the manual, please visit

www.ysi.com

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1725 Brannum Lane Yellow Springs, OH 45387 USA Tel: +1 937-767-7241

800-765-4974 Email: info@ysi.com Internet: www.ysi.com

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MultiLab 4010-1W Contents

Contents

1 Overview. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

1.1 MultiLab 4010-1W . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

1.2 MultiLab 4010P-1W meter with integrated printer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

1.3 Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

1.3.1 IDS sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

1.3.2 Wireless operation of IDS sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

1.3.3 Automatic sensor recognition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

2.1 Safety information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

2.1.1 Safety information in the operating manual . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

2.1.2 Safety signs on the meter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

2.1.3 Further documents providing safety information. . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

2.2 Safe operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

2.2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

2.2.2 Requirements for safe operation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

2.2.3 Unauthorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.1 Scope of delivery . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.2 Power supply . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.3 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

3.3.1 Inserting the batteries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

3.3.2 Connecting the power pack . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

3.3.3 Mounting the stand . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

4.1 General operating principles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

4.1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

4.1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

4.1.3 Status information (meter) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

4.1.4 Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

4.1.5 Sensor info . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

4.2 Switching on. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

4.3 Switching off . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

4.4 Navigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

4.4.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

4.4.2 Measured value display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

4.4.3 Menus and dialogs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

4.4.4 Navigation example 1: Setting the language . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

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4.4.5 Example 2 on navigation: Setting the date and time . . . . . . . . . . . . . . . . . . . . . . . . . 24

5 pH value. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

5.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

5.1.1 Measuring the pH value. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

5.1.2 Measuring the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

5.2 pH calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

5.2.1 Why calibrate?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

5.2.2 When do you have to calibrate? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

5.2.3 Calibration procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

5.2.4 Carrying out automatic calibration (AutoCal) . . . . . . . . . . . . . . . . . . . . . . . . . . 28

5.2.5 Carrying out manual calibration (ConCal) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

5.2.6 Calibration points. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

5.2.7 Calibration data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34

5.2.8 Continuous measurement control (CMC function) . . . . . . . . . . . . . . . . . . . . . . . . 37

5.2.9 QSC function (sensor quality control) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

6 ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

6.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

6.1.1 Measuring the ORP. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

6.1.2 Measuring the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42

6.2 ORP calibration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

7 Dissolved oxygen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

7.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

7.1.1 Measuring D.O. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

7.1.2 Measuring the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46

7.2 FDO Check (checking the FDO 4410) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

7.2.1 Why should you check the sensor?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

7.2.2 When should you check the sensor?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

7.2.3 Perform a FDO Check . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47

7.2.4 Evaluation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

7.3 Calibration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

7.3.1 Why calibrate?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

7.3.2 When to calibrate?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

7.3.3 Calibration procedures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

7.3.4 Calibration in water vapor-saturated air. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

7.3.5 Calibrating with Comparison meas. (e.g. Winkler titration) . . . . . . . . . . . . . . . . . . . . 50

7.3.6 Zero calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52

7.3.7 Calibration data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

8 Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55

8.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55

8.1.1 Measuring the conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55

8.1.2 Measuring the temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57

8.2 Temperature compensation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57

8.3 Calibration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

8.3.1 Why calibrate?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

8.3.2 When to calibrate?. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

8.3.3 Calibration procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

8.3.4 Determining the cell constant (calibration in the check- and calibration standard) . . 58

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8.3.5 Setting the cell constant

(calibration with freely selectable check- and calibration standard). . . . . . . . . . . . . . 60

8.3.6 Calibration data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61

9 Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63

9.1 pH measurement settings. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63

9.1.1 Settings for pH measurements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63

9.1.2 Buffer sets for calibration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64

9.1.3 Calibration interval. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 66

9.2 ORP measurement settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

9.2.1 Settings for ORP measurements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

9.3 D.O. measurement settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

9.3.1 Settings for D.O. sensors

(menu for measurement and calibration settings) . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

9.3.2 Enter Sensor cap coefficients (ProOBOD) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69

9.3.3 DO % Saturation local . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69

9.4 Cond measurement settings. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70

9.4.1 Settings for IDS conductivity sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70

9.5 Sensor-independent settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73

9.5.1 System. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73

9.5.2 Data storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74

9.5.3 Automatic Stability control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74

9.5.4 Automatic switch-off function. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74

9.5.5 Display illumination . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

9.6 Reset. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

9.6.1 Resetting the measurement settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

9.6.2 Resetting the system settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77

10 Data storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78

10.1 Manual data storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78

10.2 Automatic data storage at intervals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79

10.3 Measurement data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

10.3.1 Managing the measurement data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

10.3.2 Erasing the measurement data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82

10.3.3 Measurement dataset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82

10.3.4 Storage locations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83

11 Transmitting data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84

11.1 Transmitting data to a PC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84

11.2 MultiLab Importer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85

11.3 BOD Analyst Pro. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86

12 Printer (only MultiLab 4010P-1W) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87

12.1 Commissioning / switching the printer on or off . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87

12.2 Operation / printing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88

12.3 Printer settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88

12.4 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88

12.4.1 Changing the roll of paper (thermal paper) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88

12.5 What to do if... / printer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89

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13 Maintenance, cleaning, disposal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

13.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

13.1.1 General maintenance activities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

13.1.2 Replacing the batteries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

13.2 Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91

13.3 Packing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91

13.4 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91

14 What to do if.... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92

14.1 pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92

14.2 Dissolved oxygen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93

14.3 Conductivity. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94

14.4 General topics. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95

15 Technical data. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96

15.1 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96

15.2 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96

16 Firmware update. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98

16.1 Firmware update for the meter MultiLab 4010-1W . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98

16.2 Firmware-Update for IDS Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99

17 Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100

18 Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103

19 Appendix. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106

19.1 Oxygen solubility table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106

19.2 DO% Calibration values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108

19.3 Calculate the TDS Multiplier . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109

20 Contact Information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111

20.1 Ordering & Technical Support. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111

20.2 Service Information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111

6 ba76141e07 08/2018

MultiLab 4010-1W Overview

4010-1W

1 Overview

1.1 MultiLab 4010-1W

The compact, digital precision meter MultiLab 4010-1W enables you to carry out pH measurements, ORP measurements, conductivity measurements and dissolved oxygen (D.O.) measurements quickly and reliably.

The MultiLab 4010-1W provides the maximum degree of operating comfort, reliability and measuring certainty for all applications.

The MultiLab 4010-1W supports you in your work with the following functions:

 Automatic sensor recognition  CMC (continuous measurement control)  QSC (sensor quality control)  Electronic access control  Data transmission via the USB interface (USB-B).

1 Keypad 2 Display 3 Connectors

ba76141e07 08/2018 7

Overview MultiLab 4010-1W

4010 -1WP

1.2 MultiLab 4010P-1W meter with integrated printer

The integrated printer of the MultiLab 4010P-1W enables to document measurements according to GLP requirements.

The information concerning the printer of the MultiLab 4010P-1W is given in a separate chapter (see section 12 P M

ULTILAB 4010P-1W), page 87).

RINTER (ONLY

1 Keypad 2 Display 3 Connectors 4Printer 5 Control panel of the printer

1.3 Sensors

A measuring system ready to measure consists of the MultiLab 4010-1W meter and a suitable sensor.

Suitable sensors are IDS pH sensors, IDS ORP sensors, IDS conductivity sensors and IDS D.O. sensors.

1.3.1 IDS sensors

IDS sensors

 support the automatic sensor recognition  show only the settings relevant to the specific sensor in the setting menu  process signals in the sensor digitally so that precise and interference-free

measurements are enabled even with long cables

 facilitate to assign a sensor to a measured parameter with differently colored

couplings

8 ba76141e07 08/2018

MultiLab 4010-1W Overview

 have quick-lock couplings with which to fix the sensors to the meter.

Sensor data from

IDS sensors

IDS sensors transmit the following sensor data to the meter:  SENSOR ID

– Sensor name – Sensor series number

 Calibration data  Measurement settings

The calibration data are updated in the IDS sensor after e ach calibration procedure. A message is displayed while the data are being updated in the sensor.

In the measured value display, you can display the sensor name and series number of the selected sensor with the [Info] softkey. You can then display further sensor data stored in the sensor with the [More] softkey (see section 4.1.5 S

ENSOR INFO, page 18).

1.3.2 Wireless operation of IDS sensors

With the aid of the adapters in the IDS WA Kit, IDS sensors with plug head connectors (variant P) can be wirelessly connected to your MultiLab 4010-1W. (MultiLab 4010-1 IDS: from software version V2.00)

Two adapters, one at the IDS meter (IDS WA-M) and one at the sensor (IDS WA-S), replace the sensor cable with an energy-saving Bluetooth LE radio connection.

Further information on the wireless operation of IDS sensors:

 Web resources  Operating manual of the IDS WA Kit.

1.3.3 Automatic sensor recognition

The automatic sensor recognition for IDS sensors allows

 to operate an IDS sensor with different meters without recalibrating  to assign measurement data to an IDS sensor

– Measurement datasets are always stored and output with the sensor

name and sensor serial number.

 to assign calibration data to an IDS sensor

– Calibration data and calibration history are always stored and output with

the sensor name and sensor series number.

 to hide menus automatically that do not concern this sensor

ba76141e07 08/2018 9

Overview MultiLab 4010-1W

To be able to use the automatic sensor recognition, a meter that supports the automatic sensor recognition (e.g. MultiLab 4010-1W) and a digital IDS sensor are required.

In digital IDS sensors, sensor data are stored that clearly identify the sensor. The sensor data are automatically taken over by the meter.

10 ba76141e07 08/2018

MultiLab 4010-1W Safety

2 S afety

2.1 Safety information

2.1.1 Safety information in the operating manual

This operating manual provides important information on the safe operation of the meter. Read this operating manual thoroughly and make yourself familiar with the meter before putting it into operation or working with it. The operating manual must be kept in the vicinity of the meter so you can always find the information you need.

Important safety instructions are highlighted in this operating manual. They are indicated by the warning symbol (triangle) in the left column. The signal word (e.g. "Caution") indicates the level of danger:

WARNING

indicates a possibly dangerous situation that can lead to serious (irreversible) injury or death if the safety instruction is not followed.

CAUTION

indicates a possibly dangerous situation that can lead to slight (reversible) injury if the safety instruction is not followed.

NOTE

indicates a possibly dangerous situation where goods might be damaged if the actions mentioned are not taken.

2.1.2 Safety signs on the meter

Note all labels, information signs and safety symbols on the meter and in the battery compartment. A warning symbol (triangle) without text refers to safety information in this operating manual.

2.1.3 Further documents providing safety information

The following documents provide additional information, which you should observe for your safety when working with the measuring system:

• Operating manuals of sensors and other accessories

• Safety datasheets of calib ration or maintenance accessories (such as buffer solutions, electrolyte solutions, etc.)

ba76141e07 08/2018 11

Safety MultiLab 4010-1W

2.2 Safe operation

2.2.1 Authorized use

The authorized use of the meter consists exclusively of the measurement of the pH, ORP, conductivity and dissolved oxygen in a laboratory environment.

Only the operation and running of the meter according to the instructions and technical specifications given in this operating manual is authorized (see section 15 T

96).

Any other use is considered unauthorized.

2.2.2 Requirements for safe operation

Note the following points for safe operation:

• The meter may only be operated accord ing to the authorized use specified above.

• The meter may only be supplied with power by the energy sources mentioned in this operating manual.

• The meter may only be operated under the environmental conditions mentioned in this operating manual.

• The meter may only be opened if this is explicitly described in this operating manual (example: Inserting the batteries).

ECHNICAL DATA, page

2.2.3 Unauthorized use

The meter must not be put into operation if:

• it is visibly damaged (e.g. after being transported)

• it was stored under adverse conditions for a lengthy period of time (storing conditions, see section 15 T

ECHNICAL DATA, page 96).

12 ba76141e07 08/2018

MultiLab 4010-1W Commissioning

3 C ommissioning

3.1 Scope of delivery

 MultiLab 4010-1W / MultiLab 4010P-1W  4 batteries 1.5 V Mignon type AA  Power pack  USB cable (A plug on mini B plug)  Stand  Stand holder  Comprehensive operating manual  Short instructions  CD-ROM with

– USB drivers – detailed operating manual – Software MultiLab Importer

3.2 Power supply

The MultiLab 4010-1W is supplied with power in the following ways:  Line power operation via the supplied power pack

A sensor with stirrer can only be operated with line power.

 Battery operation (4 batteries, 1.5 V Mignon type AA)  USB operation via a connected USB-B cable

3.3 Initial commissioning

Perform the following activities:

 Insert the supplied batteries  For mains operation: Connect the power pack  If necessary, mount the stand  Switch on the meter (see

section 4.2 S

WITCHING ON, page 19)

 Set the date and time (see

section 4.4.5 E

24)

ba76141e07 08/2018 13

XAMPLE 2 ON NAVIGATION: SETTING THE DATE AND TIME, page

Commissioning MultiLab 4010-1W

3.3.1 Inserting the batteries

You can operate the meter either with normal batteries or with rechargeable batteries (Ni-MH). In order to charge the batteries, an external charging device is required.

1. Open the battery compartment (1) on the underside of the

meter.

1 Battery compartment

CAUTION

Make sure that the poles of the batteries are positioned correctly.

± signs on the batteries must correspond to the ± signs in

The the battery compartment.

2. Place four batteries (type Mignon AA) in the battery compartment.

3. Close the battery compartment (1).

4. Set the date and time

(see section 4.4.5 E page 24).

XAMPLE 2 ON NAVIGATION: SETTING THE DATE AND TIME,

14 ba76141e07 08/2018

MultiLab 4010-1W Commissioning

3.3.2 Connecting the power pack

CAUTION

The line voltage at the operating site must lie within the input voltage range of the original power pack (see section 15.2

ENERAL DATA, page 96).

CAUTION

Use original power packs only (see section 15.2 GENERAL DATA, page 96).

1. Connect the plug of the power pack to the socket for the power pack on

the MultiLab 4010-1W.

2. Connect the original power pack to an easily accessible power outlet.

3.3.3 Mounting the stand

The stand base can be mounted at the right side of the meter.

ba76141e07 08/2018 15

Operation MultiLab 4010-1W

4Operation

4.1 General operating principles

4.1.1 Keypad

In this operating manual, keys are indicated by brackets <..> . The key symbol (e.g. and release) in this operating manual. A long keystroke (press and keep depressed for approx. 2 sec) is indicated by the underscore behind the key symbol (e.g.

<ENTER>) generally indicates a short keystroke (press

<ENTER__>).

<F1>: <F1__>:

Softkeys providing situation dependent functions, e.g.:

<F1>/[

]: View information on a sensor

<F2>: <F2__>:

<On/Off>: Switches the meter on or off

<M>: Selects the measured parameter / Quits the settings

<CAL>: <CAL__>:

<STO>: <STO_ >:

<RCL>: <RCL__>:

<><>: <__>< __>:

<ENTER>: <ENTER__>:

Calls up the calibration procedure Displays the calibration data

Saves a measured value manually Opens the menu for the automatic save function

Displays the manually stored measured values Displays the automatically stored measured values

Menu control, navigation Increments, decrements values Increments, decrements values continuously

Opens the menu for measurement settings / confirms entries Opens the menu for system settings

<AR> Freezes the measured value (HOLD function)

Switches the AutoRead measurement on or off

16 ba76141e07 08/2018

MultiLab 4010-1W Operation

HOLD AR

AutoCal TEC

03.04.2013 08:00

USB output

YSI

4.1.2 Display

Example

1 Status information (sensor) 2 Measured value 3 Measured parameter 4 Continuous measurement control (CMC function) 5 Sensor symbol (calibration evaluation, calibration interval) 6 Measured temperature (with unit) 7 Status information (meter) 8 Softkeys and date + time

4.1.3 Status information (meter)

AR Stability control (AutoRead) is active HOLD Measured value is frozen (

<AR> key)

ZeroCal The zero point is calibrated.

Batteries are almost empty

Data are automatically output to the USB-B interface at intervals

ba76141e07 08/2018 17

Operation MultiLab 4010-1W

25.0

7.007

°C

01.02.2014 08:00

USB output

4.1.4 Socket field

1 IDS sensors: (pH, ORP, conductivity, D.O.) 2 USB B (device) interface 3 Stirrer (interface for BOD sensor) 4 Power pack 5 Service interface

CAUTION

Only connect sensors to the meter that cannot return any voltages or currents that are not allowed (> SELV and > current circuit with current limiting). YSI IDS sensors and IDS adapters meet these requirements.

4.1.5 Sensor info

You can display the current sensor data and sensor settings of a connected sensor at any time. The sensor data are available in the measured value display with the

<F1>/[Info] softkey.

1. In the measured value display: Display the sensor data (sensor name, series number) with [

18 ba76141e07 08/2018

<F1>Info].

MultiLab 4010-1W Operation

25.0

7.007

°C

4110

B09250001

pH resolution 0.001 mV resolution 0.1 Buffer YSI Calibration interval 7d Unit for slope mV/pH QSC: off Software version V 1.00

4110 B092500013

03.04.2013 08:00

Back

25.0

7.007

°C

01.02.2014 08:00

USB output

2. Display further sensor data (settings) with <F1>/[More].

ba76141e07 08/2018 19

4.2 Switching on

1. Switch the meter on with The meter performs a self-test.

2. Connect the sensor. The meter is ready to measure.

4.3 Switching off

1. Switch the meter off with

<On/Off>.

Operation MultiLab 4010-1W

4.4 Navigation

4.4.1 Operating modes

Operating mode

Measuring The measurement data of the connected sensor are shown

Calibration The course of a calibration with calibration information, func-

Storing in memory

Transmitting data

Setting The system menu or a sensor menu with submenus, set-

4.4.2 Measured value display

In the measured value display, you can  open the menu for calibration and measurement settings with

(short

keystroke)

Explanation

in the measured value display

tions and settings is displayed The meter stores measuring data automatically or manually

The meter transmits measuring data and calibration records to a USB-B interface automatically or manually.

tings and functions is displayed

<ENTER>

 open the system menu with the sensor-independent settings by pressing

<ENTER>Storage & config for a <ENTER__>long keystroke, approx.

2s).

 change the display in the selected measuring screen (e. g. pH ><− mV) by

pressing

4.4.3 Menus and dialogs

The menus for settings and dialogs in procedures contain further sube lements. The selection is done with the played with a frame.

 Submenus

The name of the submenu is displayed at the upper edge of the frame. Su bmenus are opened by confirming with

<M>.

<><> keys. The current selection is dis-

<ENTER>. Example:

20 ba76141e07 08/2018

MultiLab 4010-1W Operation

General Interface Clock function Service information Reset

System

03.04.2013 08:00

Back

Language: Deutsch Audio signal: off Illumination: on Contrast: 12 Shutoff time: 1 h Temperature unit: °C Stability control

: on

General

03.04.2013 08:00

Back

Calibration record Calibration data storage Buffer: YSI Single-point calibration: yes Calibration interval: 7 d Unit for slope: mV/pH

[

] 4.00 7.00 10.00 (25 °C)

03.04.2013 08:00

Back

 Settings

Settings are indicated by a colon. The current setting is displayed on the right-hand side. The setting mode is opened with the setting can be changed with

<>< > and <ENTER>. Example:

<ENTER>. Subsequently,

ba76141e07 08/2018 21

 Functions

Functions are designated by the name of the function. They are immediately carried out by confirming with

<ENTER>. Example: Display the Calibration

record function.

 Messages

Information is marked by the [

] symbol. It cannot be selected. Example:

Operation MultiLab 4010-1W

Calibration record Calibration data storage Buffer: YSI Single-point calibration: yes Calibration interval: 7 d Unit for slope: mV/pH

[

] 4.00 7.00 10.00 (25 °C)

03.04.2013 08:00

Back

25.0

7.007

°C

01.02.2014 08:00

USB output

System Data storage

Storage & config

03.04.2013 08:00

Back

4.4.4 Navigation example 1: Setting the language

1. Press the

<On/Off> key.

The measured value display appears. The instrument is in the measuring mode.

2. Open the Storage & config menu with The instrument is in the setting mode.

<ENTER__>.

22 ba76141e07 08/2018

3. Select the System submenu with

<><>.

The current selection is displayed with a frame.

4. Open the System submenu with

<ENTER>.

MultiLab 4010-1W Operation

General Interface Clock function Service information Reset

System

03.04.2013 08:00

Back

Language: Deutsch Audio signal: off Illumination: on Contrast: 50 % Shutoff time: 1 h Temperature unit: °C Stability control

: on

General

03.04.2013 08:00

Back

Language: Deutsch Audio signal: off Illumination: on Contrast: 50 % Shutoff time: 1 h Temperature unit: °C Stability control

: on

General

03.04.2013 08:00

Back

5. Select the General submenu with <><>.

The current selection is displayed with a frame.

6. Open the General

submenu with <ENTER>.

7. Open the setting mode for the Language with

<ENTER>.

ba76141e07 08/2018 23

8. Select the required language with

9. Confirm the setting with

<ENTER>.

The meter switches to the measuring mode. The selected language is active.

<><>.

Operation MultiLab 4010-1W

Date format: dd.mm.yy Date: 03.04.2013 Time: 14:53:40

Clock function

03.04.2013 08:00

Back

4.4.5 Example 2 on navigation: Setting the date and time

The meter has a clock with a date function. The date and time are indicated in the status line of the measured value display. When storing measured values and calibrating, the current date and time are automatically stored as well.

The correct setting of the date and time and date format is important for the following functions and displays:

 Current date and time  Calibration date  Identification of stored measured values.

Therefore, check the time at regular intervals.

The date and time are reset to default after a fall of the supply voltage (empty batteries).

Setting the date,

time and date format

The date format can be switched from the display of day, month, year (dd.mm.yy) to the display of month, day, year (mm/dd/yy or mm.dd.yy).

1. In the measured value display: Open the Storage & config menu with

<ENTER__>.

The instrument is in the setting mode.

2. Select and confirm the System / Clock function menu with

<><> and

<ENTER>.

The setting menu for the date and time opens up.

24 ba76141e07 08/2018

3. Select and confirm the Time menu with The hours are highlighted.

4. Change and confirm the setting with

<><> and <ENTER>.

The minutes are highlighted.

5. Change and confirm the setting with

<><> and <ENTER>.

The seconds are highlighted.

<><> and <ENTER>.

MultiLab 4010-1W Operation

6. Change and confirm the setting with <><> and <ENTER>. The time is set.

7. If necessary, set the Date and Date format. The setting is made similarly to that of the time.

8. To make further settings, switch to the next higher menu level with or Switch to the measured value display with

<M>.

The instrument is in the measuring mode.

<F1>.

ba76141e07 08/2018 25

pH value MultiLab 4010-1W

25.0

7.007

°C

01.02.2014 08:00

USB output

5 pH value

5.1 Measuring

5.1.1 Measuring the pH value

NOTE

When connecting a grounded PC/printer, measurements cannot be performed in grounded media as the values would be incorrect. The USB interface is not galvanically isolated.

1. Connect the IDS pH sensor to the meter. The pH measuring window is displayed.

Stability control

(AutoRead)

& HOLD function

2. If necessary, select the measured parameter with

3. Adjust the temperature of the solutions and measure the current temperature if the measurement is made without a temperature sensor.

4. If necessary, calibrate or check the IDS pH sensor.

5. Immerse the IDS pH sensor in the test sample.

The stability control function (AutoRead) continually checks the stability of the measurement signal. The stability has a considerable impact on the reproducibility of measured values.

<M>.

26 ba76141e07 08/2018

Hold function

The measured parameter flashes on the display

 as soon as the measured value is outside the stability range  when the automatic Stability control is switched off.

You can start the Stability control manually at any time, irrespective of the setting for automatic Stability control (see section 9.5.3 A

TROL, page 74) in the System menu.

To start the Stability control function manually, the HOLD function must be enabled.

1. Freeze the measured value with <AR>. The [HOLD] status indicator is displayed. The HOLD function is active.

UTOMATIC STABILITY CON-

MultiLab 4010-1W pH value

You can terminate the HOLD function and the Stability control func- tion with

<AR> or <M> at any time.

Stability control

2. Using <ENTER>, activate the Stability control function manually. The [AR] status indicator appears while the measured value is assessed as not stable. A progress bar is displayed and the display of the measured parameter flashes. The [HOLD][AR] status indicator appears as soon as a stable measured value is recognized. The progress bar disappears, the display of the measured parameter stops flashing, and there is a beep. The current measurement data is output to the interface. Measurement data meeting the stability control criterion is marked by AR.

You can prematurely terminate the Stability control function manually with

<ENTER> at any time. If the Stability control function is

prematurely terminated, the current measurement data are output to the interface without the AutoRead info.

3. Using

You can switch off the beep (see section 9.5 S

SETTINGS, page 73).

<ENTER>, start a further measurement with stability control.

ENSOR-INDEPENDENT

or Release the frozen measured value again with

<AR> or <M>.

The [AR] status display disappears. The display switches back to the previous indication.

Criteria for a stable

measured value

The Stability control function checks whether the measured values are stable within the monitored time interval.

Measured parameter

pH value 15 seconds Temperature 15 seconds

Time interval Stability in the time inter-

val

∆ : better than 0.01 pH ∆ : better than 0.5 °C

The minimum duration until a measured value is assessed as stable is the monitored time interval. The actual duration is mostly longer.

5.1.2 Measuring the temperature

For reproducible pH measurements, it is essential to measure the temperature of the test sample.

IDS sensors measure the temperature with a temperature sensor integrated in the IDS sensor.

ba76141e07 08/2018 27

pH value MultiLab 4010-1W

5.2 pH calibration

5.2.1 Why calibrate?

pH electrodes age. This changes the zero point (asymmetry) and slope of the pH electrode. As a result, an inexact measured value is displayed. Calibration determines and stores the current values of the zero point and slope of the electrode. Thus, you should calibrate at regular intervals.

5.2.2 When do you have to calibrate?

 Routinely within the framework of the company quality assurance  When the calibration interval has expired

5.2.3 Calibration procedure

The MultiLab 4010-1W provides 2 calibration procedures:  Automatic calibration (AutoCal)

The buffer solutions used are automatically identified during the calibration procedure. The relevant nominal values are used automatically.

Prerequisite: The buffer set used has been set in the meter (see section

9.1.2 B

 Manual calibration (ConCal)

Any buffer solutions can be used. The nominal values of the buffer solutions are manually entered by the user during the calibration procedure.

5.2.4 Carrying out automatic calibration (AutoCal)

Make sure that, in the menu for measurement and calibration settings (in the menu pH/ (see section 9.1.1 S

UFFER SETS FOR CALIBRATION, page 64).

For most applications, automatic calibration (AutoCal) is the safest and most convenient way of executing a calibration.

<ENTER>/Calibration / Buffer), the correct buffer set is selected

ETTINGS FOR PH MEASUREMENTS, page 63).

Use one to five buffer solutions of the selected buffer set in any order. Below, calibration with YSI buffers (YSI) is described. When other buffer sets

are used, other nominal buffer values are displayed. Apart from that, the procedure is identical.

If single-point calibration was set in the menu, the calibration procedure is automatically finished with the measurement of buffer solution 1 and the calibration record is displayed.

28 ba76141e07 08/2018

MultiLab 4010-1W pH value

pH 1

-180.0

24.8 °C

AutoCal YSI

01.07.2011 08:00

Buffer

-180.0

24.8 °C

AutoCal YSI

10.000

01.07.2011 08:00

Buffer

1. Connect the pH sensor to the meter. The pH measuring window is displayed.

2. Keep the buffer solutions ready.

3. Start the calibration with The calibration display for the first buffer appears (voltage display).

4. Thoroughly rinse the sensor with deionized water.

5. Immerse the sensor in the first buffer solution.

6. Start the measurement with The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes.

<CAL>.

<ENTER>.

ba76141e07 08/2018 29

7. Wait for the end of the measurement with stability control (beep, [HOLD][AR] status indicator) or take over the calibrated value with

<ENTER>.

The calibration display for the next buffer appears (voltage display).

8. If necessary, finish the calibration procedure as a single-point calibration with The calibration record is displayed.

<M>.

For single-point calibration, the instrument uses the Nernst slope (-59.2 mV/pH at 25 °C) and determines the zero point of the IDSpH sensor.

pH value MultiLab 4010-1W

0.0

24.8 °C

AutoCal YSI

7.000

01.07.2011 08:00

Buffer

180.0

24.8 °C

AutoCal YSI

4.000

01.07.2011 08:00

Buffer

Continuing with two-

point calibration

9. Thoroughly rinse the sensor with deionized water.

10. Immerse the pH sensor in buffer solution 2.

11. Start the measurement with The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes.

12. Wait for the end of the measurement with stability control (beep, [HOLD][AR] status indicator), or take over the calibrated value with

<ENTER>.

The calibration display for the next buffer appears (voltage display).

Continuing with

three- to five-point

calibration

1 3. If necessary, finish the calibration procedure as a two-point calibration

<M>.

with The calibration record is displayed.

14. Thoroughly rinse the sensor with deionized water.

15. Immerse the sensor in the next buffer solution.

16. Start the measurement with The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes.

<ENTER>.

30 ba76141e07 08/2018

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