Weber 44010001 Data Sheet

Material Safety Data Sheet

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

Product Name: DURACELL ALKALINE BATTERIES
Product Identification: Alkaline Manganese Dioxide Cells –
Duracell Designations: 7K67; MN1203; MN1300; MN1400; MN1500; MN2400; MN1604; MN908;

MN918; MN9100; MX1604; MX2500; MX1300; MX1400; MX1500; MX2400

Product Use: Energy Source
MSDS Date of Preparation: August 24, 2009

Company Identification

US Office Canadian Office

Duracell, a division of P&G
Berkshire Corporate Park
14 Research Drive
Bethel, CT USA 06401
[phone]

Emergency Phone Number: INFOTRAC Emergency Response Hotline [phone] (US & Canada)

SECTION 2: HAZARDS IDENTIFICATION

Physical Appearance: Copper top battery.

EMERGENCY OVERVIEW

CAUTION: May explode or leak, and cause burn injury, if recharged, disposed of in fire, mixed with a
different battery type, inserted backwards or disassembled. Replace all used batteries at the same time. Do
not carry batteries loose in your pocket or purse. Do not remove the battery label.

Potential Health Effects:

The chemicals and metals in this product are contained in a sealed can. Exposure to the contents will not
occur unless the battery leaks, is exposed to high temperatures or is mechanically, physically, or
electrically abused. Damaged battery will release concentrated potassium hydroxide, which is caustic.
Anticipated potential leakage of potassium hydroxide is 2 to 20 mL, depending on battery size.

Eye Contact: Contact with battery contents may cause severe irritation and burns. Eye damage is
possible.

Skin Contact: Contact with battery contents may cause severe irritation and burns.

Inhalation: Inhalation of vapors or fumes released due to heat or a large number of leaking batteries may

cause respiratory and eye irritation.

Ingestion: Swallowing is not anticipated due to battery size. Choking may occur if smaller AAA batteries
are swallowed. Ingestion of battery contents (from a leaking battery) may cause mouth, throat and
intestinal burns and damage.

Duracell, a division of P&G
4711 Yonge Street
Toronto, Ontario
Canada M2N 6K8
[phone]

GMEL # 2002.9

Page 1 of 6

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS Number Amount

Manganese Dioxide 1313-13-9 35-40%
Zinc 7440-66-6 10-25%

Potassium Hydroxide (35%) 1310-58-3 5-10%
Graphite (natural or synthetic) 7782-42-5, 7440-44-0 1-5%

SECTION 4: FIRST AID MEASURES

Eye Contact: If battery is leaking and material contacts the eye, flush thoroughly with copious amounts

of running water for 30 minutes. Seek immediate medical attention.

Skin Contact: If battery is leaking and material contacts the skin, remove any contaminated clothing and
flush exposed skin with copious amounts of running water for at least 15 minutes. If irritation, injury or
pain persists, seek medical attention.

Inhaled: If battery is leaking, contents may be irritating to respiratory passages. Move to fresh air. If
irritation persists, seek medical attention.

Swallowed: If battery contents are swallowed, do not induce vomiting. If the victim is alert, have them
rinse their mouth are the surrounding skin with water for at least 15 minutes. Seek immediate medical
attention.

Note: This MSDS does not include or address the small button cell batteries which can be ingested.

SECTION 5: FIRE FIGHTING MEASURES

Fire and Explosion Hazards: Batteries may burst and release hazardous decomposition products when

exposed to a fire situation.

Extinguishing Media: Use any extinguishing media that is appropriate for the surrounding fire.

Special Fire Fighting Procedures: Firefighters should wear positive pressure self-contained breathing

apparatus and full protective clothing. Fight fire from a distance or protected area. Cool fire exposed
batteries to prevent rupture. Use caution when handling fire-exposed containers (containers may rocket or
explode in heat of fire).

Hazardous Combustion Products: Thermal degradation may produce hazardous fumes of zinc and
manganese; hydrogen gas, caustic vapors of potassium hydroxide and other toxic by-products.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Notify safety personnel of large spills. Caustic potassium hydroxide may be released from leaking or
ruptured batteries. Clean-up personnel should wear appropriate protective clothing to avoid eye and skin
contact and inhalation of vapors or fumes. Increase ventilation. Carefully collect batteries and place in an
appropriate container for disposal.

GMEL # 2002.9

Page 2 of 6

SECTION 7: HANDLING AND STORAGE

Avoid mechanical or electrical abuse. DO NOT short circuit or install incorrectly. Batteries may explode,
pyrolize or vent if disassembled, crushed, recharged or exposed to high temperatures. Install batteries in
accordance with equipment instructions. Do not mix battery systems, such as alkaline and zinc carbon, in
the same equipment. Replace all batteries in equipment at the same time. Do not carry batteries loose in a
pocket or bag. Do not remove battery tester or battery label.

Storage: Store batteries in a dry place at normal room temperature. Do not refrigerate – this will not
make them last longer.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

The following occupational exposure limits are provided for informational purposes. No exposure to the
battery components should occur during normal consumer use.

Chemical Name Exposure Limits

Manganese Dioxide 5 mg/m3 Ceiling OSHA PEL

0.2 mg/m3 TWA ACGIH TLV
Zinc None established for zinc metal
Potassium Hydroxide 2 mg/m3 Ceiling ACGIH TLV
Graphite (natural-non-fibrous) 15 mppcf TWA OSHA PEL

2 mg/m3 TWA (respirable dust) ACGIH TLV

Graphite (synthetic non-fibrous) 5 mg/m3 TWA (respirable dust), 15 mg/m3 TWA

(total dust) OSHA PEL
2 mg/m3 TWA (respirable dust) ACGIH TLV

Ventilation: No special ventilation is needed for normal use.

Respiratory Protection: None required for normal use.

Skin Protection: None required for normal use. Use neoprene, rubber or latex gloves when handling

leaking batteries.

Eye Protection: None required for normal use. Wear safety goggles when handling leaking batteries.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor: Copper top battery.
Specific Gravity: Not applicable Boiling Point: Not applicable
Water Solubility: Insoluble Melting Point: Not applicable
Vapor Pressure: Not applicable Flash Point: Not applicable
Vapor Density: Not applicable Autoignition Point: Not applicable

SECTION 10: STABILITY AND REACTIVITY

Stability: This product is stable.

Incompatibility/Conditions to Avoid: Contents are incompatible with strong oxidizing agents. Do not

heat, crush, disassemble, short circuit or recharge.

GMEL # 2002.9

Page 3 of 6

Hazardous Decomposition Products: Thermal decomposition may produce hazardous fumes of zinc

and manganese; caustic vapors of potassium hydroxide and other toxic by-products.

Hazardous Polymerization: Will not occur

SECTION 11: TOXICOLOGICAL INFORMATION

Acute Toxicity Data:

Manganese Dioxide: LD50 oral rat >3478 mg/kg
Potassium Hydroxide: LD50 oral rat 273 mg/kg

Chronic Effects: The chemicals in this product are contained in a sealed can and exposure does not
occur during normal handling and use. No chronic effects would be expected from handling a leaking
battery.

Target Organs: Skin, eyes and respiratory system.

Carcinogenicity: None of the components of this product are listed as carcinogens by ACGIH, IARC,

NTP or OSHA.

SECTION 12: ECOLOGICAL INFORMATION

No ecotoxicity data is available. This product is not expected to present an environmental hazard.

SECTION 13: DISPOSAL INFORMATION

Disposal should be in accordance with Federal, state/provincial and local regulations. Products covered
by this MSDS, in their original form, when disposed as waste, are considered non hazardous waste
according to Federal RCRA regulations (40 CFR 261).

Alkaline batteries can be safely disposed of with normal household waste. Due to concerns about mercury
in the municipal solid waste stream, Duracell has voluntarily eliminated all of the added mercury from its
alkaline batteries since 1993. Individual consumers may dispose of spent (used) batteries with household
trash. Duracell does not recommend that spent batteries be accumulated and disposed of in large
quantities. Do not incinerate except for disposal in a controlled incinerator.

Some communities offer recycling or collection of alkaline batteries – contact your local government for
disposal practices in your area.

SECTION 14: TRANSPORT INFORMATION

Products covered by this MSDS, in their original form, are considered “dry cell” batteries and are not
regulated for transportation as “DANGEROUS GOODS.” The batteries must be packaged in a manner
that prevents the generation of a dangerous quantity of heat and short circuits.

For finished packaged product transported by ground (US DOT): – not regulated
For finished packaged product transported by sea (IMDG) – not regulated
For finished packaged product transported by air (IATA): – not regulated

GMEL # 2002.9

Page 4 of 6

Special provisions apply and shippers should consult the most current versions of the transportation
regulations.

Special Provision A123 in the IATA Dangerous Goods Regulations and ICAO Technical Instructions and
Special Provision 130 in 49 CFR 172.102 of the U.S. DOT regulations require alkaline batteries be packed in
such a way to prevent short circuits or generating a dangerous quantity of heat. In addition, the IATA
Dangerous Goods Regulations and ICAO Technical Instructions require the words “not restricted” and the
Special Provision number “A123” be provided on the air waybill, when an air waybill is issued. Special
Provision 304 of the IMDG Code (Amdt. 33-06) provides batteries, dry, containing corrosive electrolyte
which will not flow out of the battery if the battery case is cracked are not subject to the provisions of this
Code provided the batteries are securely packed and protected against short-circuits. Examples of such
batteries are alkali-manganese, zinc-carbon, nickel-metal hydride and nickel-cadmium batteries.

SECTION 15: REGULATORY INFORMATION

United States

OSHA Status: While the finished product(s) is considered an article and not covered by the OSHA

Hazard Communication Standard, 29 CFR 1910.1200, this MSDS contains valuable information critical
to the safe handling and proper use of the product".

EPA TSCA Status: All intentionally-added components of this product are listed on the US TSCA
Inventory.

SARA 313/302/304/311/312 chemicals: Manganese compounds 35-40%, Zinc 10-25%

California: This product has been evaluated and does not require warning labeling under California

Proposition 65.

State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state
worker exposure lists

Ingredient CAS # Level CERCLA

RQ

State
IL MA NJ PA RI

Manganese Dioxide 1313-13-9 35-40% None Y Y N Y Y
Zinc 7440-66-6 10-25% 1000 lb Y Y Y Y N
Potassium Hydroxide 1310-58-3 5-10% 1000 lb Y Y Y Y Y
Graphite 7782-42-5

1-5% None Y Y N Y Y

7440-44-0

Canada All intentionally-added components of this product are listed on the Canadian DSL. This
product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulations (CPR) and this MSDS contains all information required by the Controlled Products
Regulations.

SECTION 16: OTHER INFORMATION

P&G Hazard Rating: Health: 0 Fire: 0 Reactivity: 0

===========================================================================

GMEL # 2002.9

Page 5 of 6

Data supplied is for use only in connection with occupational safety and health.

DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance
regarding the use of this material. The information contained here has been compiled from sources
considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s
knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication
regulations.

This information is offered in good faith. Each user of this material needs to evaluate the conditions of
use and design the appropriate protective mechanisms to prevent employee exposures, property damage
or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or
third persons, or for any damage to any property resulting from misuse of the product.

GMEL # 2002.9

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Document Number: Alkaline_Dry_CH_SDS_01_15

SAFETY DATA SHEET

In Accordance with OSHA Standard 1910.1200 App D (USA)

1. Identification

(a) Product identifier used on the label:

LR03(GD) / AAA / 1.5V

LR6(GD) / AA / 1.5V

(b) Other means of identification:

Alkaline

(c) Recommended use of the chemical and restrictions on use:

Do not throw in fire! Not rechargeable!

(d) Name, address, and telephone number of the chemical manufacturer, importer, or other

responsible party:

Supplier:

Address: Unit Nos 03B-06, 13/Fl., No 909 Cheung Sha Wan Road, Cheung Sha Wan,

Kowloon, Hong Kong.

Tel: [phone]

Fax: [phone]

(e) Date of preparation: 1-Jan-2015

Hitachi Maxell Global Limited

2. Hazard(s) identification

(a) Classification of the chemical in accordance with paragraph (d) of §1910.1200

Chemical power source

(b) Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with

paragraph (f) of §1910.1200. (Hazard symbols may be provided as graphical reproductions in

black and white or the name of the symbol, e.g., flame, skull and crossbones)

N/A

(c) Describe any hazards not otherwise classified that have been identified during the classification

process

The chemical materials concluded in the Product is sealed up, thus being stable, safe and

eco-friendly under common conditions, may not cause physical / chemical hazards.

(d) Where an ingredient with unknown acute toxicity is used in a mixture at a concentration 1%

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LR03

LR6

SAFETY DATA SHEET

and the mixture is not classified based on testing of the mixture as a whole, a statement that X%

of the mixture consists of ingredient(s) of unknown acute toxicity is required

No such an ingredient is contained in the product.

3. Composition/information on ingredients

Except as provided for in paragraph (i) of §1910.1200 on trade secrets:

For Substances:

(a) Chemical name

(b) Common name and synonyms

(c) CAS number and other unique identifiers

(d) Impurities and stabilizing additives which are themselves classified and which contribute to the

classification of the substance

Chemical Name

Manganese dioxide MnO2 1313-13-9 38 % 38 %

Graphite C 7782-42-5 4 % 4 %

Zinc Zn 7440-66-6 15 % 15 %

Potassium hydroxide KOH 1310-58-3 5 % 5 %

Steel (shell) Fe 7439-89-6 30 % 29%

Brass (pin) Cu 7440-50-8 4 % 4 %

Nylon (gasket) Nylon 66 32131-17-2 3.2 % 4 %

Polyethylene
terephthalate (label)

Mercury Hg 7439-97-6 Not detected ( 1ppm) Not detected ( 1ppm)

Cadmium Cd 7439-92-1 Not detected (< 5ppm) Not detected (< 5ppm)

Lead Pb 7440-43-9 Not detected (< 20ppm) Not detected (<20ppm)

Common Name

and Synonyms

PET 25038-59-9

CAS #

0.8 % 1%

Content (Wt %)

For Mixtures

In addition to the information required for substances:

(a) The chemical name and concentration (exact percentage) or concentration ranges of all

ingredients which are classified as health hazards in accordance with paragraph (d) of

§1910.1200 and

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SAFETY DATA SHEET

(1) Are present above their cut-off/concentration limits; or

(2) Present a health risk below the cut-off/concentration limits.

No such an ingredient is contained in the product.

(b) The concentration (exact percentage) shall be specified unless a trade secret claim is made in

accordance with paragraph (i) of §1910.1200, when there is batch-to-batch variability in the

production of a mixture, or for a group of substantially similar mixtures (See A.0.5.1.2) with

similar chemical composition. In these cases, concentration ranges may be used.

No such a situation would happen during the production from batch to batch.

For All Chemicals Where a Trade Secret is claimed

Where a trade secret is claimed in accordance with paragraph (i) of §1910.1200, a statement that

the specific chemical identity and/or exact percentage (concentration) of composition has been

withheld as a trade secret is required.

4. First-aid measures

(a) Description of necessary measures, subdivided according to the different routes of exposure, i.e.,

inhalation, skin and eye contact, and ingestion

Inhalation: Not applicable.

Skin Contact: Wash with clean water immediately once leakage happens and the inner liquid

splashes onto skin.

Eye contact: Rinse eyes immediately with running water for at least ten minutes. Consult an

ophthalmologist.

Ingestion: Seek medical assistance or treatment immediately.

(b) Most important symptoms/ effects, acute and delayed

The liquid if leaked from the product may be smelly, mild irritant to skin, etc.

(c) Indication of immediate medical attention and special treatment needed, if necessary

Wash with clean water immediately.

5. Fire-fighting measures

(a) Suitable (and unsuitable) extinguishing media.

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SAFETY DATA SHEET

Carbon dioxide (CO2), foam, or dry chemical powder extinguishing media is suitable.

(b) Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products).

The product is not inflammable; the liquid, if leaked from the product, may cause corrosion to

paper, plastic, or any other tender material(s) near by.

(c) Special protective equipment and precautions for fire-fighters.

The fire-fighters are suggested wearing full protective clothing and using self contained

breathing apparatus.

6. Accidental release measures

(a) Personal precautions, protective equipment, and emergency procedures.

Wear protective clothing. Keep unprotected persons away.

(b) Methods and materials for containment and cleaning up.

Collect spilled material with an insert standard absorbent like sand or silica.

Care for well-Ventilated conditions. Recycle or dispose of the materials in an appropriate way.

7. Handling and storage

(a) Precautions for safe handling.

Obey the common known rules and precautions for handling with chemical power sources.

(b) Conditions for safe storage, including any incompatibilities.

Store product in clean, cool and ventilated place with a temperature between 10℃ and 30℃

(no higher than 40℃ in the ordinary course of events) and a relative humidity no higher than

65%; the storage time should not be too long; the batteries should be well-arranged, and do

avoid sort-circuit caused by the contact of the positive and negative electrodes.

8. Exposure controls/personal protection

(a) OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial

Hygienists (ACGIH) Threshold Limit Value (TLV), and any other exposure limit used or

recommended by the chemical manufacturer, importer, or employer preparing the safety data

sheet, where available.

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SAFETY DATA SHEET

N/A

(b) Appropriate engineering controls.

Do not disassemble the product without professional basis.

(c) Individual protection measures, such as personal protective equipment.

No special equipment is required for handling, carrying or using the product.

The chemical materials concluded in the Product is sealed up, thus being stable, safe and

eco-friendly under common conditions.

9. Physical and chemical properties

(a) Appearance (physical state,

color, etc.)

(b) Odor

(c) Odor threshold

Cylindrical battery with PET label in white, blue,

:

golden and black colours, etc.

not applicable

:

:

not applicable

(d) pH

(e) Melting point/ freezing point

(f) Initial boiling point and

boiling range

(g) Flash point

(h) Evaporation rate

(i) Flammability (solid, gas)

(j) Upper/lower flammability or

explosive limits

not applicable

:

: not applicable

not applicable

:

:

not applicable

not applicable

:

: not applicable

not applicable

:

(k) Vapor pressure

(l) Vapor density

(m) Relative density

(n) Solubility(ies)

(o) Partition coefficient:

n-octanol/ water

:

not applicable

not applicable

:

: not applicable

not applicable

:

:

not applicable

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SAFETY DATA SHEET

(p) Auto-ignition temperature

(q) Decomposition temperature

(r) Viscosity

10. Stability and reactivity

(a) Reactivity

N/A

(b) Chemical stability

Stable.

The chemical materials concluded in the Product are sealed up, thus being stable, safe and

eco-friendly under common conditions.

(c) Possibility of hazardous reactions

No.

not applicable

:

: not applicable

not applicable

:

(d) Conditions to avoid (e.g., static discharge, shock, or vibration)

Environmental temperature higher than 40℃, relative humidity below 45% or higher than 65%

is recommended to be avoided for product storage or working.

(e) Incompatible materials

N/A

(f) Hazardous decomposition products

No.

11. Toxicological information

Description of the various toxicological (health) effects and the available data used to identify those

effects, including

(a) Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact)

The chemical materials concluded in the Product are sealed up, thus being stable, safe and

eco-friendly under common conditions;

The liquid (alkaline solution), if leaked from the product, may cause corrosion to paper, plastic,

or any other tender material(s) near by, but not toxicological.

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SAFETY DATA SHEET

(b) Symptoms related to the physical, chemical and toxicological characteristics

People might feel itching, if the inner liquid splashes onto skin.

(c) Delayed and immediate effects and also chronic effects from short- and long-term exposure

N/A

(d) Numerical measures of toxicity (such as acute toxicity estimates)

N/A

(e) Whether the hazardous chemical is listed in the National Toxicology Program (NTP) Report on

Carcinogens (latest edition) or has been found to be a potential carcinogen in the International

Agency for Research on Cancer (IARC) Monographs (latest edition), or by OSHA

No.

12. Ecological information (Non-mandatory)

(a) Ecotoxicity (aquatic and terrestrial, where available): N/A

(b) Persistence and degradability: N/A

(c) Bio-accumulative potential: N/A

(d) Mobility in soil: N/A

(e) Other adverse effects (such as hazardous to the ozone layer) : No.

13. Disposal considerations (Non-mandatory)

Description of waste residues and information on their safe handling and methods of disposal,

including the disposal of any contaminated packaging.

The used product (waste) is recommended to be disposed-of in separate collection, so as to

avoid improper disassembly or recycling method that may lead to pollution or corrosion caused

by the alkaline solution inside it.

14. Transport information (Non-mandatory)

In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a
safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that
batteries be packaged in a manner that prevents short circuits and be contained in “strong outer

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Document Number: Alkaline_Dry_CH_SDS_01_15

Regulatory Body

SAFETY DATA SHEET

packaging” that prevents spillage of contents. All original packaging for Maxell alkaline batteries has
been designed to be compliant with these regulatory concerns.

Alkaline batteries (sometimes referred to as “Dry cell” batteries) are not listed as dangerous goods
under the ADR European Agreement Concerning the International Carriage of Dangerous Goods by
Road, the IMDG International Maritime Dangerous Goods Code, UN Dangerous Good Regulations,
IATA Dangerous Goods Regulations 56th edition, ICAO Technical Instructions and the U.S.
hazardous materials regulations (49 CFR). These batteries are not subject to the dangerous goods
regulations provided they meet the requirements contained in the following special provisions

.
ADR Not regulated
IMDG Not regulated
UN Not regulated
US DOT 49 CFR 172.102 Provision 130
IATA A123 (56th Edition)
ICAO Not regulated

All Maxell alkaline batteries are packed in such a way to prevent short circuits or the generation
dangerous quantities of heat and meet the special provisions listed above. In addition, the IATA
Dangerous Goods Regulations and ICAO Technical Instructions require the words “not restricted”
and the Special Provision number A123 be provided on the air waybill, when an air waybill is issued.

Special Provisions

(a) UN number: N/A

(b) UN proper shipping name: N/A

(c) Transport hazard class(es) : N/A

(d) Packing group, if applicable: N/A

(e) Environmental hazards (e.g., Marine pollutant (Yes/No)) No.

(f) Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code)

The product can be treated as ordinary goods in transportation;

Products in bulk shall be packed in inner packaging in such a manner that can prevent

movement or short-circuit effectively.

(g) Special precautions which a user needs to be aware of, or needs to comply with, in connection

with transport or conveyance either within or outside their premises

Avoid high-temperature, high-humidity condition.

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SAFETY DATA SHEET

15. Regulatory information (Non-mandatory)

Safety, health and environmental regulations specific for the product in question

The product is eco-friendly and in accordance with the safety regulations in ANSI C18.1M_

Part2 Standard, and complying with the environmental requirements in EU Directives

2006/66/EC (Battery Directive).

16. Other information, including date of preparation or last revision

The date of preparation of the SDS or the last change to it

This Safety Date Sheets (SDS) is issued on 1-Jan-2015 as a first version according to

requirements of the USA’s OSHA Standard 1910.1200 App D.

For any other question, please contact the manufacturer for further information.

Page 9 of 9

SAFETY DATA SHEET

Issuing Date

Revision Date

Revision Number

2

_____________________________________________________________________________________________

_____________________________________________________________________________________________

_____________________________________________________________________________________________

Page

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14

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

Product identifier

Product Name

E91BP

-

4, E91BP

-

4UP, E91BP

-

8, E91BP

-

12, E91BP

-

20W

Other means of identification

Synonyms

Recommended use of the chemical and restrictions on use

Recommended Use

Uses advised against

Details of the supplier of the safety data sheet

Supplier Name

Supplier Address

Supplier Phone Number

Supplier Email

Emergency telephone number

Company Emergency Phone

2. HAZARDS IDENTIFICATION

Classification

Number

15-Jun-2015

The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.

13-Apr-2016

COMPANY/UNDERTAKING

None

Alkaline battery

No information available

Energizer Battery

533 Maryville University Drive
St. Louis
MO
63141
US

Phone:[phone]

[e-mail]

314-985-1500

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This
product is an article which is a sealed battery and as such does not require an MSDS per the OSHA hazard communication
standard unless ruptured. The hazards indicated are for a ruptured battery.

1004983

Revision Date

2016

_____________________________________________________________________________________________

_____________________________________________________________________________________________

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14

GHS Label elements, including precautionary statements

Emergency Overview

Signal word

Danger

Hazard Statements

Appearance

Physical state

Odor

None

Precautionary Statements

- Prevention

Precautionary Statements

- Response

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

13-Apr-

Acute toxicity - Oral Category 4
Acute toxicity - Inhalation (Gases) Category 2
Acute toxicity - Inhalation (Vapors) Category 2
Acute toxicity - Inhalation (Dusts/Mists) Category 2
Skin corrosion/irritation Category 1 Sub-category A
Serious eye damage/eye irritation Category 1
Skin sensitization Category 1
Carcinogenicity Category 1A
Reproductive Toxicity Category 1A
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 1

Harmful if swallowed
Fatal if inhaled
Causes severe skin burns and eye damage
May cause an allergic skin reaction
May cause cancer
May damage fertility or the unborn child
May cause respiratory irritation. May cause drowsiness or dizziness

This product is an article which contains a chemical substance. Safety information is given for exposure to the article as sold.

Intended use of the product should not result in exposure to the chemical substance. This is a battery. In case of rupture: the

above hazards exist.

Silver

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Wear respiratory protection
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves

Solid

Specific treatment is urgent (see .? on this label)
Immediately call a POISON CENTER or doctor/physician

1004983

Revision Date

2016

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Eyes

Skin

Inhalation

Ingestion

Precautionary Statements

- Storage

Precautionary Statements

- Disposal

Hazards not otherwise classified (HNOC)

Unknown Toxicity

Other information

Interactions with Other Chemicals

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name

CAS No

Weight

-%

Trade Secret

4. FIRST AID MEASURES

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

13-Apr-

Specific treatment (see supplemental first aid instructions on this label)

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
If skin irritation or rash occurs: Get medical advice/attention

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Immediately call a POISON CENTER or doctor/physician
Call a POISON CENTER or doctor/physician if you feel unwell

IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Do NOT induce vomiting

Store locked up
Store in a well-ventilated place. Keep container tightly closed

Dispose of contents/container to an approved waste disposal plant

Not applicable

6 % of the mixture consists of ingredient(s) of unknown toxicity

Very toxic to aquatic life with long lasting effects
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons

No information available.

Manganese dioxide 1313-13-9 30 - 60 *
Zinc 7440-66-6 10 - 30 *
Steel manufacture, chemicals 65997-19-5 10 - 30 *
Potassium hydroxide 1310-58-3 5 - 10 *
Graphite 7782-42-5 3 - 7 *

*The exact percentage (concentration) of composition has been withheld as a trade secret

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First aid measures

General Advice

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep

Skin contact

Inhalation

Ingestion

Self-protection of the first aider

with a one

Most important sympt

oms and effects, both acute and delayed

Most Important Symptoms and

Indication of any immediate medical attention and special treatment needed

Notes to Physician

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

This is a battery. In case of rupture:. Immediate medical attention is required. Show this
safety data sheet to the doctor in attendance.

eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present
and easy to do. Continue rinsing. Seek immediate medical attention/advice.

Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Seek immediate medical attention/advice. May cause an allergic skin
reaction.

Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical
attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. If breathing is difficult, (trained personnel
should) give oxygen. Delayed pulmonary edema may occur. Get medical attention
immediately if symptoms occur. Do not breathe dust.

Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give
anything by mouth to an unconscious person. Call a physician or poison control center
immediately.

Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or
clothing. Use personal protective equipment as required. Wear personal protective clothing
(see section 8). Do not breathe dust. Do not use mouth-to-mouth method if victim ingested
or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped

-way valve or other proper respiratory medical device.

13-Apr-

Effects

Burning sensation. Coughing and/ or wheezing. Difficulty in breathing. Itching. Rashes.
Hives.

Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
Possible perforation of stomach or esophagus should be investigated. Do not give
chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood
pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause
sensitization in susceptible persons. Treat symptomatically.

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5. FIRE

-

FIGHTING MEASURES

Suitable Extinguishing Media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Explosion Data

Sensitivity to Mechanical Impact

Sensitivity to Static Discharge

Protective equipment and precautions for firefighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions

Other Information

Environmental precautions

Environmental precautions

Methods and material for containment and cleaning up

Methods for containment

Methods for cleaning up

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

13-Apr-

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

CAUTION: Use of water spray when fighting fire may be inefficient.

The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases
and vapors. In the event of fire and/or explosion do not breathe fumes. Product is or contains a sensitizer. May cause sensitization
by skin contact.

None.

None.

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Use personal protective equipment as required. Evacuate personnel to safe
areas. Keep people away from and upwind of spill/leak. Avoid generation of dust. Do not
breathe dust.

Refer to protective measures listed in Sections 7 and 8.

Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

Pick up and transfer to properly labeled containers.

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7. HANDLING AND STORAGE

Precautions for safe handling

Handling

Conditions for safe storage, including any incompatibilities

Storage

Incompatible Products

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical name

ACGIH TLV

OSHA PEL

NIOSH IDLH

3

3

3

3

3

Zr

3

total dust synthetic

3

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

In case of rupture. Handle in accordance with good industrial hygiene and safety practice.
Avoid contact with skin, eyes or clothing. Use personal protection equipment.

Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from
moisture. Store locked up. Keep out of the reach of children. Store away from other
materials.

Acids. Bases. Oxidizing agent.

13-Apr-

Manganese dioxide

1313-13-9

Zinc

7440-66-6

Steel manufacture,

chemicals

65997-19-5

Potassium hydroxide

1310-58-3

Graphite

7782-42-5

TWA: 0.02 mg/m3 Mn

TWA: 0.1 mg/m

3

Mn

STEL: 10 mg/m3 respirable fraction

TWA: 2 mg/m3 respirable fraction

TWA: 0.05 mg/m

STEL: 10 mg/m

3

Be inhalable fraction TWA: 1

mg/m

3

mg/m

Cu dust and mist TWA: 0.2

3

mg/m

Se TWA: 1 mg/m3 Y TWA: 5

3

Zr TWA: 0.02 mg/m3 Mn

mg/m

TWA: 0.1 mg/m

3

Mn TWA: 0.5 mg/m3

Zr

3

Pb TWA: 0.00005

Hf
S*

Ceiling: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3

TWA: 2 mg/m3 respirable fraction all

forms except graphite fibers

(vacated) Ceiling: 5 mg/m

Ceiling: 5 mg/m

TWA: 5 mg/m

TWA: 15 mg/m

TWA: 5 mg/m

TWA: 50 µg/m

TWA: 0.2 mg/m

3

respirable fraction

Pb TWA: 2 µg/m3 Be

3

Se TWA: 5 mg/m3

fume

3

total dust

3

Mn

Action Level: 30 µg/m3 Pb Poison,

See 29 CFR 1910.1025

(vacated) TWA: 2 µg/m

TWA: 0.2 mg/m

mg/m

(vacated) STEL: 25 µg/m

(vacated) STEL: 10 mg/m

(vacated) Ceiling: 5 µg/m

Ceiling: 5 mg/m

Ceiling: 5 µg/m

3

3

Be (vacated)

Se (vacated) TWA: 5

3

Zr

3

30 min

3

Zr

3

(vacated)

3

3

Be Ceiling: 5 mg/m3

Mn

TWA: 15 mg/m3

TWA: 5 mg/m3 respirable fraction

synthetic

IDLH: 500 mg/m

TWA: 1 mg/m

STEL: 3 mg/m

IDLH: 500 mg/m3

Ceiling: 15 mg/m

TWA: 5 mg/m

3

STEL: 10 mg/m

IDLH: 4 mg/m

IDLH: 100 mg/m

IDLH: 500 mg/m

IDLH: 1 mg/m

IDLH: 500 mg/m

IDLH: 25 mg/m

IDLH: 100 mg/m

IDLH: 10 mg/m
IDLH: 50 mg/m

Ceiling: 0.05 mg/m

15 min

Ceiling: 0.0005 mg/m

TWA: 1 mg/m

3

Cu dust and mist

TWA: 1 mg/m

TWA: 0.2 mg/m

hexafluoride Se

TWA: 1 mg/m

TWA: 5 mg/m

3

tetrachloride Zr

TWA: 0.050 mg/m

TWA: 0.015 mg/m

carbonyl Ni

TWA: 0.5 mg/m

STEL: 3 mg/m

STEL: 10 mg/m

IDLH: 1250 mg/m

TWA: 2.5 mg/m

Mn

3

Mn

3

Mn

3

dust

dust and fume

3

fume

Be

3

Cu dust and mist

3

Mn

3

Se

3

Y

3

Zr

3

Pb

3

Ni

3

Hf

3

V dust and fume

3

Be

3

Mn

3

except Selenium

3

Y

except Zirconium

3

Pb

3

except Nickel

3

Hf

3

Mn

3

Zr

3

respirable dust

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respirable

total dust

ACGIH TLV: American Conference of Governmental Industrial Hygienists

Administration

Other Exposure Guidelines

Appropriate engineering controls

Engineering Measures

Individual protection measures, such as personal protective equipment

Eye/face protection

Skin and body protection

Respiratory protection

Hygiene Measures

9. PHYSICAL AN

D CHEMICAL PROPERTIES

Physical and Chemical Properties

Physical state

Appearance

Odor

Color

Odor Threshold

No information available

Property

Values

Remarks Method

pH

Melting / freezing point

Boiling point / boiling range

Flash Point

Evaporation Rate

Flammability (solid, gas)

Flammability Limit in Air

Upper flammability limit

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

(vacated) TWA: 2.5 mg/m3

(vacated) TWA: 10 mg/m

(vacated) TWA: 5 mg/m

- Permissible Exposure Limits Immediately Dangerous to Life or Health

Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d
962 (11th Cir., 1992)

Showers
Eyewash stations
Ventilation systems

Face protection shield.

Wear protective gloves and protective clothing. Long sleeved clothing. Chemical resistant
apron. Impervious gloves.

If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.

Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do
not eat, drink or smoke when using this product. Take off contaminated clothing and wash
before reuse. Contaminated work clothing should not be allowed out of the workplace.
Regular cleaning of equipment, work area and clothing is recommended. Wash hands
before breaks and immediately after handling the product. For environmental protection,
remove and wash all contaminated protective equipment before re-use. Do not breathe
dust.

- Threshold Limit Value OSHA PEL: Occupational Safety and Health

dust natural

synthetic

3

3

respirable

fraction synthetic

TWA: 15 mppcf natural

13-Apr-

Solid
Silver

None

No information available

No data available
No data available
No data available
No data available
No data available
No data available

No data available

None known
None known
None known
None known
None known
None known

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Lower flammability limit

Vapor pressure

Vapor density

Specific Gravity

Water Solubility

Solubility in other solvents

Partition coefficient: n

-

octanol/water

Autoignition temperature

Decomposition temperature

Kinematic viscosity

Dynamic viscosity

Explosive properties

Oxidizing properties

Other Information

Softening Point

VOC Content (%)

Particle Size

Particle Size Distribution

10. STABILITY AND REACTIVITY

Reactivity

Chemical stability

Possibility of Hazardous Reactions

Conditions to avoid

Incompatible materials

Hazardous Decomposition Products

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation

corrosive fumes/gases may cause coughing, choking,

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

No data available
No data available
No data available
No data available
Insoluble in water
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available

No data available
No data available
No data available

13-Apr-

None known
None known
None known
None known
None known
None known
None known
None known
None known
None known

No data available.

Stable under recommended storage conditions.

None under normal processing.

Exposure to air or moisture over prolonged periods. Excessive heat.

Acids. Bases. Oxidizing agent.

None known based on information supplied.

Product does not present an acute toxicity hazard based on known or supplied information.
In case of rupture:.

Specific test data for the substance or mixture is not available. Corrosive by inhalation.
(based on components). Inhalation of
headache, dizziness, and weakness for several hours. Pulmonary edema may occur with
tightness in the chest, shortness of breath, bluish skin, decreased blood pressure, and
increased heart rate. Inhaled corrosive substances can lead to a toxic edema of the lungs.
Pulmonary edema can be fatal. May cause irritation of respiratory tract. Fatal if inhaled.

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Eye contact

Skin conta

ct

Ingestion

blood. Blood pressure may decrease. Brownish or yellowish stains may be seen around the

Component Information

Chemical name

Oral LD50

Dermal LD50

Inhalation LC50

Information on toxicological effects

Symptoms

Delayed and immediate effects as well as chronic effects from short and long

-

term exposure

Sensitization

Mutagenic Effects

Carcinogenicity

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical name

ACGIH

IARC

NTP OSHA

Reproductive toxicity

STOT

- single exposure

STOT

- repeated exposure

Chronic Toxicity

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

Specific test data for the substance or mixture is not available. Causes burns. (based on
components). Corrosive to the eyes and may cause severe damage including blindness.
Causes serious eye damage. May cause irreversible damage to eyes.

Specific test data for the substance or mixture is not available. Corrosive. (based on
components). Causes burns.

Specific test data for the substance or mixture is not available. Causes burns. (based on
components). Ingestion causes burns of the upper digestive and respiratory tracts. May
cause severe burning pain in the mouth and stomach with vomiting and diarrhea of dark

mouth. Swelling of the throat may cause shortness of breath and choking. May cause lung
damage if swallowed. May be fatal if swallowed and enters airways. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea. Harmful if swallowed.

13-Apr-

Manganese dioxide
1313-13-9
Potassium hydroxide
1310-58-3

Steel manufacture,
chemicals
65997-19-5

= 9000 mg/kg ( Rat ) - -

= 284 mg/kg ( Rat ) - -

Erythema (skin redness). Burning. May cause blindness. Coughing and/ or wheezing.
Difficulty in breathing. Itching. Rashes. Hives.

May cause sensitization in susceptible persons. May cause sensitization by skin contact.

No information available.

A1
A3

Group 1
Group 2A
Group 2B

Group 3

Reasonably Anticipated

Known

X

Contains a known or suspected reproductive toxin.

No information available.

Causes damage to organs through prolonged or repeated exposure. Based on
classification criteria from the 2012 OSHA Hazard Communication Standard (29 CFR

1910.1200), this product has been determined to cause systemic target organ toxicity from
chronic or repeated exposure. (STOT RE).

Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw
necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are
common. Gastrointestinal disturbances may also be seen. Effects from this product
caused by acute exposure may cause permanent damage to target organs and/or may

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sible risk of irreversible effects. Avoid repeated exposure.

Target Organ Effects

Aspiration Hazard

Numerical measures of toxicity Product Information

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral)

ATEmix (inhalation

-

gas)

ATEmix (inhalation

-

dust/mist)

ATEmix (inhalation

-

vapor)

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

307.00 mg/kg

435.00 ppm (4 hr)

0.21 mg/l

2.00 ATEmix

13-Apr-

cause chronic conditions. Contains a known or suspected carcinogen. Contains a known or
suspected reproductive toxin. Pos
Prolonged exposure may cause chronic effects.

Eyes. Respiratory system. Skin. Gastrointestinal tract (GI). Systemic Toxicity. Reproductive
System.

No information available.

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12. ECOLOGICAL INFORMATION

Ecotoxicity

Chemical name

Toxicity to Algae

Toxicity to Fish

Toxicity to

Daphnia Magna (Water

mg/L (Oncorhynchus mykiss)

Persistence and Degradability

Bioaccumulation

Chemical name

Log Pow

Other adverse effects

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

Harmful to aquatic life. Very toxic to aquatic life with long lasting effects.

13-Apr-

Zinc

7440-66-6

Potassium hydroxide

1310-58-3

No information available.

No information available

Manganese dioxide

Potassium hydroxide

96h EC50: 0.11 - 0.271

mg/L (Pseudokirchneriella

subcapitata) 72h EC50:

0.09 - 0.125 mg/L

(Pseudokirchneriella

subcapitata)

1313-13-9

1310-58-3

96h LC50: = 3.5 mg/L
(Lepomis macrochirus) 96h
LC50: = 7.8 mg/L (Cyprinus

carpio) 96h LC50: = 0.24

96h LC50: = 0.59 mg/L

(Oncorhynchus mykiss) 96h

LC50: = 0.41 mg/L

(Oncorhynchus mykiss) 96h

LC50: 0.211 - 0.269 mg/L

(Pimephales promelas) 96h

LC50: = 2.66 mg/L

(Pimephales promelas) 96h

LC50: = 30 mg/L (Cyprinus

carpio) 96h LC50: = 0.45

mg/L (Cyprinus carpio) 96h

LC50: 2.16 - 3.05 mg/L

(Pimephales promelas)

96h LC50: = 80 mg/L

(Gambusia affinis)

Microorganisms

<0

0.83

Flea)

48h EC50: 0.139 - 0.908

mg/L

No information available.

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13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal methods

comes in contact with a hazardous waste, if chemical additions are made to this material, or

Contaminated Packaging

California Hazardous Waste Codes

Chemical name

California Hazardous Waste

14. TRANSPORT INFORMATION

DOT

Proper Shipping Name

Hazard Class

TDG

MEX

ICAO

IATA

Proper Shipping Name

Hazard Class

IMDG/IMO

Hazard Class

RID

ADR

ADN

15. REGULATORY INFORMATION

International Inventories

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise

if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.

Do not reuse empty containers.

141

This product contains one or more substances that are listed with the State of California as a hazardous waste.

13-Apr-

Zinc

7440-66-6

Steel manufacture, chemicals

65997-19-5

Potassium hydroxide

1310-58-3

Ignitable powder Toxic

Toxic

Toxic

Corrosive

NOT REGULATED
NON REGULATED
N/A

Not regulated

Not regulated

Not regulated

Not regulated
NON REGULATED

N/A

Not regulated
N/A

Not regulated

Not regulated

Not regulated

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TSCA

DSL/NDSL

US Federal Regulations

SARA 313

tion Act of 1986 (SARA). This product does not contain any

Chemical name

CAS No

Weight

-%

SARA 313

- Threshold

SARA 311/312 Hazard Categories

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

Sudden release of pressure hazard

Reactive Hazard

CWA (Clean Water Act)

Chemical name

CWA

- Reportable

CWA

- Toxic Pollutants

CWA

- Priority Pollutants

CWA

- Hazard

ous

CERCLA

Chemical name

Hazardous Substances RQs

Extremely Hazardous Substances

RQ

US State Regulations

California Proposition 65

U.S. State Right

-to-

Know Regulations

Chemical name

New Jersey

Massachusetts

Pennsylvania

Rhode Island

Illinois

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

13-Apr-

TSCA Complies
DSL All components are listed either on the DSL or NDSL.

- United States Toxic Substances Control Act Section 8(b) Inventory

- Canadian Domestic Substances List/Non-Domestic Substances List

Section 313 of Title III of the Superfund Amendments and Reauthoriza
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Values %

Manganese dioxide - 1313-13-9 1313-13-9 30 - 60 1.0
Zinc - 7440-66-6 7440-66-6 10 - 30 1.0
Steel manufacture, chemicals - 65997-19-5 65997-19-5 10 - 30 1.0

0.1

No
No
No
No
No

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)

Zinc

7440-66-6

Steel manufacture,

chemicals

65997-19-5

Potassium hydroxide

1310-58-3

Quantities

1000 lb

X X

X

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Substances

X

RQs

Zinc

7440-66-6

Potassium hydroxide

1310-58-3

1000 lb

1000 lb

RQ 454 kg final RQ
RQ 1000 lb final RQ
RQ 1000 lb final RQ

RQ 454 kg final RQ

This product does not contain any Proposition 65 chemicals.

This product does not contain any substances regulated by state right-to-know regulations.

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International Regulations

Chemical name

Carcinogen Status

Exposure Limits

Canada

WHMIS Hazard Class

16. OTHER INFORMATION

NFPA

Health Hazards

Flammability

Instability

Physical and

HMIS

Health Hazards

Flammability

Physical Hazard

Personal Protection

Prepared By

Issuing Date

Revision Date

Revision Note

Disclaimer

information relates only to the specific material designated and may not be valid for such material used in combination

with any other materials or in any proces

End of Safety Data Sheet

-

E91BP-4, E91BP-4UP, E91BP-8, E91BP-12, E91BP-20W

Zinc

7440-66-6

Potassium hydroxide

1310-58-3

Manganese dioxide

1313-13-9

Graphite

7782-42-5

X X X X

X X X X

X X X

X X X

13-Apr-

Steel manufacture, chemicals A3

Not determined

Manganese dioxide

Graphite

A2

1

0

Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
15-Jun-2015
13-Apr-2016
No information available

0

0

Mexico: TWA= 0.2 mg/m3

Mexico: TWA 0.15 mg/m3

Mexico: TWA 0.002 mg/m

Mexico: TWA 0.2 mg/m

Mexico: TWA 5 mg/m

Mexico: STEL 10 mg/m

Mexico: TWA= 2 mg/m3

0

3

3

3

3

Chemical Hazards -

0

X

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The

s, unless specified in the text