Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Product name
:
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
Recommended use
:
Insecticide
Manufacturer, importer,
supplier
:
S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone
number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887
24 Hour Transport Emergency Phone: (800)424-9300
Hazard classification
Hazard category
Hazards identification
Aerosol
Category 2
Gases under pressure
Liquefied gas
Contains gas under pressure;
may explode if heated.
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling
Hazard symbols
Flame
Gas cylinder
Signal word
Warning
Hazard statements
Flammable aerosol.
Contains gas under pressure; may explode if heated.
Precautionary statements
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Protect from sunlight. Store in a well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.
1/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Other hazards
:
None identified
Chemical Name
CAS-No.
Weight percent
Alkanes, C14-16
90622-46-1
10.00 - 30.00
Propane
74-98-6
5.00 - 10.00
Butane
106-97-8
1.00 - 5.00
Isobutane
75-28-5
1.00 - 5.00
Isopropanol
67-63-0
1.00 - 5.00
Cypermethrin
52315-07-8
0.10 - 1.00
Imiprothrin
72963-72-5
0.0001 - 0.10
Eye contact
:
No special requirements
Skin contact
:
No special requirements
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
Suitable extinguishing
media
:
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Specific hazards during
firefighting
:
Aerosol Product - Containers may rocket or explode in heat of
fire. Do not allow run-off from fire fighting to enter drains or
water courses.
Further information
:
Fight fire from maximum distance or protected area. Although
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
2/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
this product has a flash point below 200 Deg F, it is an
aqueous solution containing an alcohol and does not sustain
combustion. Cool and use caution when approaching or
handling fire-exposed containers. Fight fire with normal
precautions from a reasonable distance. Standard procedure
for chemical fires. Wear full protective clothing and positive
pressure self-contained breathing apparatus. In case of fire
and/or explosion do not breathe fumes.
Personal precautions
:
Remove all sources of ignition.
Wear personal protective equipment.
Wash thoroughly after handling.
Environmental
precautions
:
Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.
Methods and materials
for containment and
cleaning up
:
If damage occurs to aerosol can:
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.
Precautions for safe
handling
:
Avoid contact with skin, eyes and clothing.
Do not enter places where used or stored until adequately
ventilated.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Pressurized container.
Do not pierce or burn, even after use.
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
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Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Advice on protection
against fire and explosion
:
Keep away from sources of ignition - No smoking.
Do not spray on an open flame or other ignition source.
Requirements for storage
areas and containers
:
Protect from sunlight. Do not expose to temperatures
exceeding 50 °C/ 122 °F.
Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Propane
74-98-6
-
1,000 ppm
- ACGIH
TWA
Propane
74-98-6
1,800 mg/m3
1,000 ppm
-
OSHA TWA
Butane
106-97-8
-
1,000 ppm
- ACGIH
STEL
Isobutane
75-28-5
-
1,000 ppm
- ACGIH
STEL
Isopropanol
67-63-0
980 mg/m3
400 ppm
-
OSHA TWA
Isopropanol
67-63-0
-
400 ppm
- ACGIH
STEL
Isopropanol
67-63-0
-
200 ppm
- ACGIH
TWA
Respiratory protection
:
Do not spray in enclosed areas.
Hand protection
:
No special requirements.
Eye protection
:
No special requirements.
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
Storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Personal protective equipment
4/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.
Form
:
aerosol
Form
:
Compressed gas
Color
:
clear
Odor
:
floral
Odour Threshold
:
Test not applicable for this product type
pH
:
Test not applicable for this product type
Melting point/freezing point
:
Test not applicable for this product type
Initial boiling point and
boiling range
:
Test not applicable for this product type
Flash point
:
< 0 °C
< 32 °F
Propellant
18 °C
64.4 °F
liquid
Evaporation rate
:
Test not applicable for this product type
Flammability (solid, gas)
:
Does not sustain combustion.
Upper/lower flammability or
explosive limits
:
Test not applicable for this product type
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
9. PHYSICAL AND CHEMICAL PROPERTIES
5/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Vapour pressure
:
Test not applicable for this product type
Vapour density
:
Test not applicable for this product type
Relative density
:
0.877 g/cm3 at 70 °FCalculated
Solubility(ies)
:
partly soluble
Partition coefficient: noctanol/water
:
Test not applicable for this product type
Auto-ignition temperature
:
does not ignite
Decomposition temperature
:
Test not applicable for this product type
Viscosity, dynamic
:
Test not applicable for this product type
Viscosity, kinematic
:
Test not applicable for this product type
Oxidizing properties
:
Test not applicable for this product type
Volatile Organic
Compounds
Total VOC (wt. %)*
:
12.1 % - additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations
Other information
:
None identified
:
Test not applicable for this product type
Possibility of hazardous
reactions
:
Stable under recommended storage conditions.
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
10. STABILITY AND REACTIVITY
6/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Possibility of hazardous
reactions
:
Stable under recommended storage conditions.
Conditions to avoid
:
Heat, flames and sparks.
Incompatible materials
:
Strong oxidizing agents
Hazardous decomposition
products
:
Thermal decomposition can lead to release of irritating gases
and vapours.
Emergency Overview
:
Warning
Acute oral toxicity
:
NA GHS LD50
estimated
> 5,000 mg/kg
see user defined free text
Acute inhalation toxicity
:
NA GHS LC50 (dust and mist)
estimated
> 5.1 mg/l
see user defined free text
Acute dermal toxicity
:
NA GHS LD50
estimated
> 5,000 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Serious eye
damage/eye irritation
No classification proposed
-
Skin sensitisation
No classification proposed
-
Respiratory
sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
11. TOXICOLOGICAL INFORMATION
7/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ
toxicity - single
exposure
No classification proposed
-
Specific target organ
toxicity - repeated
exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical
Condition
:
None known.
Alkanes, C14-16
No data
available
Propane
LC50
Fish
27.98 mg/l
96 h
Butane
No data
available
Isobutane
LC50
Fish
27.98 mg/l
96 h
Isopropanol
LC50
Pimephales promelas
(fathead minnow)
9,640 mg/l
96 h
Components
End point
Species
Value
Exposure
time
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested.
Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.
Toxicity to fish
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Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Cypermethrin
LC50
Oncorhynchus mykiss
(rainbow trout)
0.00283
mg/l
96 h
NOEC
Pimephales promelas
(fathead minnow)
0.00001
mg/l
28 d
Imiprothrin
LC50
Oncorhynchus mykiss
(rainbow trout)
0.038 mg/l
96 h
Alkanes, C14-16
No data
available
Propane
LC50
Daphnid
14.22 mg/l
48 h
Butane
No data
available
Isobutane
LC50
Daphnid
16.33 mg/l
48 h
Isopropanol
EC50
Daphnia magna (Water
flea)
13,299
mg/l
48 h
Cypermethrin
EC50
Daphnia magna (Water
flea)
0.00471
mg/l
48 h
Components
End point
Species
Value
Exposure
time
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
Toxicity to aquatic invertebrates
9/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
NOEC
Daphnia magna (Water
flea)
0.00004
mg/l
21 d
Imiprothrin
EC50
Daphnia magna (Water
flea)
0.051 mg/l
48 h
Alkanes, C14-16
No data
available
Propane
No data
available
Butane
No data
available
Isobutane
EC50
Green algea
8.57 mg/l
96 h
Isopropanol
EC50
Desmodesmus
subspicatus (green algae)
> 1,000
mg/l
72 h
Cypermethrin
ErC50
No data
available
> 0.0033
mg/l
72 h
Imiprothrin
NOEC
Pseudokirchneriella
subcapitata (green algae)
1.3 mg/l
72 h
Component
Biodegradation
Exposure
time
Summary
Alkanes, C14-16
82 %
28 d
Readily biodegradable
Propane
70 %
< 10 d
Readily biodegradable
Butane
100 %
385.5 h
Readily biodegradable
Isobutane
70 %
< 10 d
Readily biodegradable
Isopropanol
53 %
5 d
Readily biodegradable
Components
End point
Species
Value
Exposure
time
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
Toxicity to aquatic plants
Persistence and degradability
10/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Cypermethrin
0.6 - 1.4 %
33 d
Not readily
biodegradable.
Imiprothrin
58 %
28 d
Not readily
biodegradable.
Component
Bioconcentration
factor (BCF)
Partition Coefficient nOctanol/water (log)
Alkanes, C14-16
No data available
No data available
Propane
No data available
2.36
Butane
No data available
2.89
Isobutane
1.57 - 1.97
2.8
Isopropanol
0.96 estimated
0.05
Cypermethrin
373.4 Measured
5.3 - 5.6
Imiprothrin
58.2 Calculated
2.9
Component
End point
Value
Alkanes, C14-16
No data available
Propane
No data available
Butane
No data available
Isobutane
No data available
Isopropanol
No data available
Cypermethrin
Koc 80653 - 574360
Imiprothrin
Koc 268
Component
Results
Alkanes, C14-16
Not fulfilling PBT and vPvB criteria
Propane
Not fulfilling PBT and vPvB criteria
Butane
Not fulfilling PBT and vPvB criteria
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
Bioaccumulative potential
Mobility
PBT and vPvB assessment
11/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Isobutane
Not fulfilling PBT and vPvB criteria
Isopropanol
Not fulfilling PBT and vPvB criteria
Cypermethrin
Not fulfilling PBT and vPvB criteria
Imiprothrin
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
None known.
PESTICIDAL WASTE:
For disposal information, please read and follow Disposal
instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle
where facilities exist.
Land transport
Sea transport
Air transport
UN number
1950
1950
1950
UN proper
shipping name
AEROSOLS,
Flammable, 2.1
AEROSOLS,
Flammable, 2.1
AEROSOLS,
Flammable, 2.1
Transport hazard
class(es)
2.1 2 2.1
Packing group
- - -
Environmental
hazards
-
- -
Special
precautions for
user
Limited quantities
derogation may be
applicable to this
product, please check
transport documents.
Limited quantities
derogation may be
applicable to this
product, please
check transport
documents.
Limited quantities
derogation may be
applicable to this
product, please check
transport documents.
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
15. REGULATORY INFORMATION
12/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Notification status
:
All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.
California Prop. 65
:
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
Registration # / Agency
4822-596/US/EPA
Health
2
Flammability
4
Reactivity
0
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
FIFRA Labeling
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels of
non-pesticide chemicals.
Following is the hazard information as required on the pesticide label:
CAUTION:
Contents under pressure.
Exposure to temperatures above 130° F may cause bursting.
Flammable.
16. OTHER INFORMATION
HMIS Ratings
13/14
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000026010
Health
2
Fire
4
Reactivity
0
Special
-
Prepared by
SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)
RAID® ANT & ROACH KILLER 26 (OUTDOOR FRESH®)
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.
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