Raid 300816 User Manual

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Product name

:

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®)
(EPA Reg. No. 4822-569)

Recommended use

:

Insecticide

Manufacturer, importer,
supplier

:

S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236

Telephone

:

[phone]

Emergency telephone
number

:

24 Hour Medical Emergency Phone: [phone]

24 Hour International Emergency Phone: [phone]
24 Hour Transport Emergency Phone: [phone]

Hazard classification

Hazard category

Hazards identification

Aerosol

Category 2

Flammable aerosol.

Gases under pressure

Liquefied gas

Contains gas under pressure;
may explode if heated.

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

1. PRODUCT AND COMPANY IDENTIFICATION

Product information

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Globally Harmonized System (GHS) Classification

Labelling
Hazard symbols

Flame
Gas cylinder

Signal word
Warning

Hazard statements

Flammable aerosol.
Contains gas under pressure; may explode if heated.

Precautionary statements

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Other hazards

:

None identified

Chemical Name

CAS-No.

Weight percent

Hydrocarbons, C14-C18, n-alkanes,
isoalkanes, cyclics, <2% aromatics

64742-47-8

10.00 - 30.00

Butane

106-97-8

5.00 - 10.00

Propane

74-98-6

5.00 - 10.00

Isobutane

75-28-5

5.00 - 10.00

d-Phenothrin

188023-86-1

0.10 - 1.00

Prallethrin

23031-36-9

0.10 - 1.00

Eye contact

:

No special requirements

Skin contact

:

No special requirements

Inhalation

:

No special requirements.

Ingestion

:

No special requirements

Suitable extinguishing

:

Use water spray, alcohol-resistant foam, dry chemical or

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Protect from sunlight. Store in a well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Do not spray on an open flame or other ignition source.
Do not pierce or burn, even after use.

3. COMPOSITION/INFORMATION ON INGREDIENTS

The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

5. FIREFIGHTING MEASURES

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

media

carbon dioxide.

Specific hazards during
firefighting

:

Container may melt and leak in heat of fire. Do not allow run-off
from fire fighting to enter drains or water courses.

Further information

:

Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure
self-contained breathing apparatus. In case of fire and/or
explosion do not breathe fumes.

Personal precautions

:

Remove all sources of ignition.
Wear personal protective equipment.
Wash thoroughly after handling.

Environmental
precautions

:

Do not flush into surface water or sanitary sewer system.
Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.

Methods and materials
for containment and
cleaning up

:

If damage occurs to aerosol can:
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

Precautions for safe
handling

:

Avoid contact with skin, eyes and clothing.
Do not enter places where used or stored until adequately
ventilated.
For personal protection see section 8.

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

Handling

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

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Revision Date 00/00/0000

SDS Number 350000016793

Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Pressurized container.
Do not pierce or burn, even after use.

Advice on protection
against fire and explosion

:

Keep away from sources of ignition - No smoking.
Do not spray on an open flame or other ignition source.

Requirements for storage
areas and containers

:

Protect from sunlight. Do not expose to temperatures
exceeding 50 °C/ 122 °F.
Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.
Protect from sunlight.
Store in a well-ventilated place.

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

Storage

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Components

CAS-No.

mg/m3

ppm

Non-

standard

units

Basis

Hydrocarbons,
C14-C18, n­alkanes,
isoalkanes, cyclics,
<2% aromatics

64742-47-8

1,200 mg/m3

152 ppm

-

SUPPLIER

Butane

106-97-8

-

1,000 ppm

- ACGIH

STEL

Propane

74-98-6

1,800 mg/m3

1,000 ppm

-

OSHA TWA

Propane

74-98-6

- - - ACGIH

TWA

Isobutane

75-28-5

-

1,000 ppm

- ACGIH

STEL

Respiratory protection

:

Do not spray in enclosed areas.

Hand protection

:

No special requirements.

Eye protection

:

No special requirements.

Skin and body protection

:

No special requirements.

Hygiene measures

:

Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Personal protective equipment

9. PHYSICAL AND CHEMICAL PROPERTIES

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

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Revision Date 00/00/0000

SDS Number 350000016793

Form

:

aerosol

Form

:

Compressed gas

Color

:

translucent

Odor

:

pleasant

Odour Threshold

:

No data available

pH

:

Not applicable

Melting point/freezing point

:

No data available

Initial boiling point and
boiling range

:

No data available

Flash point

:

-7 °C

19.4 °F
Propellant

Evaporation rate

:

No data available

Flammability (solid, gas)

:

No data available

Upper/lower flammability or
explosive limits

:

No data available

Vapour pressure

:

No data available

Vapour density

:

No data available

Relative density

:

0.82 g/cm3

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Solubility(ies)

:

dispersible

Partition coefficient: n­octanol/water

:

No data available

Auto-ignition temperature

:

No data available

Decomposition temperature

:

Test not applicable for this product type

Viscosity, dynamic

:

No data available

Viscosity, kinematic

:

No data available

Oxidizing properties

:

No data available

Volatile Organic
Compounds
Total VOC (wt. %)*

:

19 % - additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations

Other information

:

None identified

:

No data available

Possibility of hazardous
reactions

:

Stable under recommended storage conditions.

Conditions to avoid

:

Heat, flames and sparks.

Incompatible materials

:

Strong oxidizing agents

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

10. STABILITY AND REACTIVITY

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

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Revision Date 00/00/0000

SDS Number 350000016793

Hazardous decomposition
products

:

Thermal decomposition can lead to release of irritating gases
and vapours.

Emergency Overview

:

Warning

Acute oral toxicity

: Acute inhalation toxicity

:

Acute dermal toxicity

:

GHS Properties

Classification

Routes of entry

Acute toxicity

No classification proposed

-

Skin corrosion/irritation

No classification proposed

-

Serious eye
damage/eye irritation

No classification proposed

-

Skin sensitisation

No classification proposed

-

Respiratory
sensitisation

No classification proposed

-

Germ cell mutagenicity

No classification proposed

-

Carcinogenicity

No classification proposed

-

Reproductive toxicity

No classification proposed

-

Specific target organ
toxicity - single
exposure

No classification proposed

-

Specific target organ
toxicity - repeated
exposure

No classification proposed

-

Aspiration hazard

No classification proposed

-

Aggravated Medical
Condition

:

None known.

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

11. TOXICOLOGICAL INFORMATION

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

LC50

Fish

> 1,028
mg/l

96 h
Butane

LC50
QSAR

Fish

27.98 mg/l

96 h

Propane

LC50

Fish

27.98 mg/l

96 h

Isobutane

LC50
QSAR

Fish

27.98 mg/l

96 h

d-Phenothrin

LC50

Oncorhynchus mykiss
(rainbow trout)

0.0027
mg/l

96 h

NOEC

Oncorhynchus mykiss
(rainbow trout)

> 0.0011
mg/l

90 d

Prallethrin

LC50

Oncorhynchus mykiss
(rainbow trout)

0.012 mg/l

96 h

Components

End point

Species

Value

Exposure
time

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.
Toxicity

The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

Toxicity to fish

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

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Revision Date 00/00/0000

SDS Number 350000016793

flow­through
test
NOEC

Oncorhynchus mykiss
(rainbow trout)

0.003 mg/l

90 d

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

EC50

Daphnid

> 3,193
mg/l

48 h

Butane

No data
available

Propane

LC50

Daphnid

14.22 mg/l

48 h

Isobutane

LC50
QSAR

Daphnid

16.33 mg/l

48 h

d-Phenothrin

EC50

Daphnia (water flea)

0.0043
mg/l

48 h
NOEC

Daphnia (water flea)

0.00047
mg/l

21 d

Prallethrin

EC50

Daphnia magna (Water
flea)

0.0062
mg/l

48 h

NOEC

Daphnia magna

0.00065
mg/l

21 d

Components

End point

Species

Value

Exposure
time

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

Toxicity to aquatic invertebrates

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

EC50

Skeletonema costatum

> 3,198
mg/l

72 h

Butane

EC50
QSAR

Green algae

7.71 mg/l

96 h
Propane

No data
available

Isobutane

EC50
QSAR

Green algae

8.57 mg/l

96 h

d-Phenothrin

EbC50

Algae

> 0.011
mg/l

72 h

Prallethrin

EC50

Pseudokirchneriella
subcapitata (green algae)

2 mg/l

96 h

Component

Biodegradation

Exposure
time

Summary

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

74 %

28 d

Readily biodegradable
Butane

100 %

385.5 h

Readily biodegradable

Propane

70 %

< 10 d

Readily biodegradable

Isobutane

70 %

< 10 d

Readily biodegradable

d-Phenothrin

1 %

28 d

Not readily
biodegradable.

Prallethrin

No data available

Not readily
biodegradable.

Components

End point

Species

Value

Exposure
time

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

Toxicity to aquatic plants

Persistence and degradability

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

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Revision Date 00/00/0000

SDS Number 350000016793

Component

Bioconcentration

factor (BCF)

Partition Coefficient n-

Octanol/water (log)

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

61 - 159

No data available

Butane

No data available

2.89

Propane

No data available

2.36

Isobutane

1.57 - 1.97

2.8

d-Phenothrin

2,506 - 3,192
Measured

6.8

Prallethrin

No data available

4.49

Component

End point

Value

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

No data available
Butane

No data available

Propane

No data available

Isobutane

No data available

d-Phenothrin

Koc 125893
Prallethrin

No data available

Component

Results

Hydrocarbons, C14-C18, n­alkanes, isoalkanes, cyclics,
<2% aromatics

Not fulfilling PBT and vPvB criteria
Butane

Not fulfilling PBT and vPvB criteria

Propane

Not fulfilling PBT and vPvB criteria

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

Bioaccumulative potential

Mobility

PBT and vPvB assessment

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Safety Data Sheet

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Revision Date 00/00/0000

SDS Number 350000016793

Isobutane

Not fulfilling PBT and vPvB criteria

d-Phenothrin

Not fulfilling PBT and vPvB criteria

Prallethrin

Not fulfilling PBT and vPvB criteria

Other adverse effects

:

No data available

PESTICIDAL WASTE:
For disposal information, please read and follow Disposal
instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle
where facilities exist.

Land transport

Sea transport

Air transport

UN number

1950

1950

1950

UN proper
shipping name

AEROSOLS,
Flammable

AEROSOLS,
Flammable

AEROSOLS,
Flammable

Transport hazard
class(es)

2.1 2 2.1

Packing group

- - -

Environmental
hazards

-

- -

Special
precautions for
user

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

Limited quantities
derogation may be
applicable to this
product, please
check transport
documents.

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Notification status

:

All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

California Prop. 65

:

This product is not subject to the reporting requirements under
California's Proposition 65.

Registration # / Agency

4822-569/US/EPA

Health

2

Flammability

4

Reactivity

0

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

15. REGULATORY INFORMATION

FIFRA Labeling

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to
certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels of
non-pesticide chemicals.

Following is the hazard information as required on the pesticide label:
CAUTION:

Causes moderate eye irritation.
CONTENTS UNDER PRESSURE.
Exposure to temperatures above 130° F may cause bursting.
Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas.
This product is highly toxic to fish and aquatic invertebrates.

16. OTHER INFORMATION

HMIS Ratings

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Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Version 0.0

Print Date 09/06/2016

Revision Date 00/00/0000

SDS Number 350000016793

Health

2

Fire

4

Reactivity

0

Special

-

Prepared by

SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)

RAID® FLYING INSECT KILLER 7 (OUTDOOR FRESH®) (EPA Reg. No.
4822-569)

NFPA Ratings

This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.

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