Raid 697329 User Manual

Page 1
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Product name
:
RAID® ANT BAITS III
Recommended use
:
Insecticide
Manufacturer, importer, supplier
:
S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236
Telephone
:
+18005585252
Emergency telephone number
:
24 Hour Medical Emergency Phone: (866)231-5406
24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300
Hazard classification
Hazard category
Hazards identification
Skin sensitisation
Category 1
May cause an allergic skin reaction.
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Globally Harmonized System (GHS) Classification
Labelling Hazard symbols
Exclamation mark
Signal word Warning
Hazard statements
May cause an allergic skin reaction.
Precautionary statements
If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Specific treatment (see supplemental first aid instructions on this label). IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/ attention. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved incineration plant.
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Page 2
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Other hazards
:
None identified
Chemical Name
CAS-No.
Weight percent
Sucrose
57-50-1
5.00 - 10.00
Hydrocarbon Wax, Bauxite Filtered
64742-42-3
1.00 - 5.00
Abamectin
71751-41-2
0.0001 - 0.10
Eye contact
:
No special requirements
Skin contact
:
Wash off with plenty of water. If skin irritation or rash occurs: Get medical advice/ attention.
Inhalation
:
No special requirements.
Ingestion
:
No special requirements
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
:
Do not allow run-off from fire fighting to enter drains or water courses.
Further information
:
Fight fire from maximum distance or protected area. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not
Wear protective gloves. Avoid breathing spray. Contaminated work clothing should not be allowed out of the workplace.
3. COMPOSITION/INFORMATION ON INGREDIENTS
The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
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Page 3
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
breathe fumes.
Personal precautions
:
Wear personal protective equipment. Wash thoroughly after handling.
Environmental precautions
:
Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.
Methods and materials for containment and cleaning up
:
Sweep up and shovel into suitable containers for disposal. Clean residue from spill site.
Precautions for safe handling
:
Avoid contact with skin, eyes and clothing. Do not enter places where used or stored until adequately ventilated. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Contaminated work clothing should not be allowed out of the workplace. Avoid breathing vapours, mist or gas.
Advice on protection against fire and explosion
:
Normal measures for preventive fire protection.
Requirements for storage areas and containers
:
Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place.
Other data
:
Stable under normal conditions. Stable under recommended storage conditions.
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
Handling
Storage
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Page 4
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Sucrose
57-50-1
5 mg/m3
-
-
OSHA TWA
Sucrose
57-50-1
15 mg/m3
-
-
OSHA TWA
Sucrose
57-50-1
10 mg/m3
-
- ACGIH
TWA
Components
CAS-No.
mg/m3
ppm
Non-
standard
units
Basis
Sucrose
57-50-1
5 mg/m3
-
-
OSHA TWA
Sucrose
57-50-1
15 mg/m3
-
-
OSHA TWA
Sucrose
57-50-1
10 mg/m3
-
- ACGIH
TWA
Respiratory protection
:
Do not spray in enclosed areas.
Hand protection
:
Wear suitable gloves.
Eye protection
:
No special requirements.
Skin and body protection
:
No special requirements.
Hygiene measures
:
Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Occupational Exposure Limits
Personal protective equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
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Page 5
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Form
:
paste
Color
:
brown tan
Odor
:
mild
Odour Threshold
:
No data available
pH
:
No data available
Melting point/freezing point
:
No data available
Initial boiling point and boiling range
:
Not applicable
Flash point
:
>= -273.00 °C >= -459.4 °F
Evaporation rate
:
Not applicable
Flammability (solid, gas)
:
The product is not flammable.
Upper/lower flammability or explosive limits
:
No data available
Vapour pressure
:
No data available
Vapour density
:
No data available
Relative density
:
9.115 lb/gal
Solubility(ies)
:
negligible
Partition coefficient: n­octanol/water
:
No data available
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Page 6
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Auto-ignition temperature
:
No data available
Decomposition temperature
:
No data available
Viscosity, dynamic
:
Very viscous
Viscosity, kinematic
:
Very viscous
Oxidizing properties
:
No data available
Volatile Organic Compounds Total VOC (wt. %)*
:
0 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
Other information
:
None identified
:
No data available
Possibility of hazardous reactions
:
Stable under recommended storage conditions.
Conditions to avoid
:
Direct sources of heat.
Incompatible materials
:
None known.
Hazardous decomposition products
:
Thermal decomposition can lead to release of irritating gases and vapours.
Emergency Overview
:
Warning
Acute oral toxicity
:
LD50 Oral
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
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Page 7
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
estimated > 5,000 mg/kg
Acute inhalation toxicity
:
No data available
Acute dermal toxicity
:
LD50 Dermal > 5,000 mg/kg
GHS Properties
Classification
Routes of entry
Acute toxicity
No classification proposed
-
Skin corrosion/irritation
No classification proposed
-
Serious eye damage/eye irritation
No classification proposed
-
Skin sensitisation
Category 1 -
Respiratory sensitisation
No classification proposed
-
Germ cell mutagenicity
No classification proposed
-
Carcinogenicity
No classification proposed
-
Reproductive toxicity
No classification proposed
-
Specific target organ toxicity - single exposure
No classification proposed
-
Specific target organ toxicity - repeated exposure
No classification proposed
-
Aspiration hazard
No classification proposed
-
Aggravated Medical Condition
:
None known.
12. ECOLOGICAL INFORMATION
Product : The product itself has not been tested. Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
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Page 8
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Sucrose
No data available
Hydrocarbon Wax, Bauxite Filtered
No data available
Abamectin
No data available
Sucrose
No data available
Hydrocarbon Wax, Bauxite Filtered
No data available
Abamectin
No data available
Sucrose
No data available
Hydrocarbon Wax, Bauxite
Filtered
No data available
Abamectin
No data available
Component
Biodegradation
Exposure time
Summary
Components
End point
Species
Value
Exposure time
Components
End point
Species
Value
Exposure time
Components
End point
Species
Value
Exposure time
expected when used according to label directions.
Toxicity to fish
Toxicity to aquatic invertebrates
Toxicity to aquatic plants
Persistence and degradability
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Page 9
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Sucrose
No data available
Hydrocarbon Wax, Bauxite Filtered
No data available
Abamectin
No data available
Not readily biodegradable.
Component
Bioconcentration
factor (BCF)
Partition Coefficient n-
Octanol/water (log)
Sucrose
No data available
-3.67
Hydrocarbon Wax, Bauxite Filtered
No data available
No data available
Abamectin
52
4.4
Component
End point
Value
Sucrose
No data available
Hydrocarbon Wax, Bauxite Filtered
No data available
Abamectin
Koc 5638
Component
Results
Sucrose
Not fulfilling PBT and vPvB criteria
Hydrocarbon Wax, Bauxite Filtered
Not fulfilling PBT and vPvB criteria
Abamectin
Not fulfilling PBT and vPvB criteria
Other adverse effects
:
No data available
PESTICIDAL WASTE: For disposal information, please read and follow Disposal instructions on the pesticide label.
Bioaccumulative potential
Mobility
PBT and vPvB assessment
13. DISPOSAL CONSIDERATIONS
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Page 10
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Consumer may discard empty container in trash, or recycle where facilities exist.
Notification status
:
All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status
:
All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Land transport
Not classified as dangerous in the meaning of transport regulations.
Sea transport
Not classified as dangerous in the meaning of transport regulations.
Air transport
Not classified as dangerous in the meaning of transport regulations.
15. REGULATORY INFORMATION
FIFRA Labeling
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
CAUTION: Harmful if absorbed through skin. Causes moderate eye irritation.
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Page 11
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
California Prop. 65
:
This product is not subject to the reporting requirements under California's Proposition 65.
Registration # / Agency
4822-529/US/EPA
Health
1
Flammability
0
Reactivity
0
Health
1
Fire
0
Reactivity
0
Special
-
16. OTHER INFORMATION
HMIS Ratings
NFPA Ratings
This information is being provided in accordance with the Occupational Safety and Health Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information
SC Johnson Special Warning SEN - Sensitizer
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
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Page 12
Safety Data Sheet
according to Hazard Communication Standard; 29 CFR 1910.1200
Version 1.1
Print Date 03/04/2015
Revision Date 02/24/2015
SDS Number 350000015810
Prepared by
SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
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