Raid 305739 User Manual

Product name

:

Recommended use

Restrictions on use

Manufacturer, importer,

Telephone

Emergency telephone

Hazard classification

Hazard category

Hazards identification

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

1. PRODUCT AND COMPANY IDENTIFICATION

Product information

supplier

number

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg.
No. 1021-2570-4822)

: Insecticide

: Use only as directed on label

: S.C. Johnson & Son, Inc.

1525 Howe Street
Racine WI 53403-2236

: [phone]

: 24 Hour Medical Emergency Phone: [phone]

24 Hour International Emergency Phone: [phone]
24 Hour Transport Emergency Phone: [phone]

Print Date 06/07/2018

GEN_SOF Number 61221

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Globally Harmonized System (GHS) Classification

Aerosol Category 2 Flammable aerosol.
Gases under pressure Compressed gas Contains gas under pressure;

Flammable aerosols Category 2 Flammable aerosol.

Labelling

Hazard symbols

Flame
Gas cylinder

Signal word

may explode if heated.

1/15

Other hazards

Eye contact

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

Warning

Hazard statements
Flammable aerosol.
Contains gas under pressure; may explode if heated.

Precautionary statements

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.
Store in a well-ventilated place.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.

: Intentional misuse by deliberately concentrating and inhaling

contents can be harmful or fatal.

Print Date 06/07/2018

GEN_SOF Number 61221

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS-No. Weight percent
Isobutane 75-28-5 10.00 - 30.00
n-Octyl bicycloheptene dicarboximide 113-48-4 1.00 - 5.00
Distillates (petroleum), hydrotreated
light
D-Phenothrin 26002-80-2 0.10 - 1.00

The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Description of first aid measures

: No special requirements

64742-47-8

1.00 - 5.00

2/15

Skin contact

Inhalation

Ingestion

Suitable extinguishing

Specific hazards during

Further information

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

: Wash off with plenty of water. If skin irritation or rash occurs:

Get medical advice/ attention.

: No special requirements.

: No special requirements

Most important symptoms and effects, both acute and delayed

Eyes : May irritate eyes.

Skin effect : May cause allergic skin reaction.

No adverse effects expected when used as directed.

Inhalation : Intentional misuse by deliberately concentrating and inhaling

contents can be harmful or fatal.
May cause allergic respiratory reaction.

Ingestion : May cause irritation to mouth, throat and stomach.

May cause abdominal discomfort.
No adverse effects expected when used as directed.

Indication of any immediate medical attention and special treatment needed

See Description of first aid measures unless otherwise stated.

Print Date 06/07/2018

GEN_SOF Number 61221

5. FIREFIGHTING MEASURES

media

firefighting

: Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide.

: Aerosol Product - Containers may rocket or explode in heat of

fire. Do not allow run-off from fire fighting to enter drains or
water courses.

: Fight fire from maximum distance or protected area. Cool and

use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure
self-contained breathing apparatus. In case of fire and/or

3/15

Personal precautions

Environmental

Methods and materials

Precautions for safe

Advice on protection

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

explosion do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES

: Remove all sources of ignition.

Wear personal protective equipment.
Wash thoroughly after handling.

: Do not flush into surface water or sanitary sewer system.

precautions

for containment and
cleaning up

7. HANDLING AND STORAGE

Use appropriate containment to avoid environmental
contamination.
Outside of normal use, avoid release to the environment.

: If damage occurs to aerosol can:

Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Dike large spills.
Clean residue from spill site.

Print Date 06/07/2018

GEN_SOF Number 61221

Handling

handling

: Avoid contact with skin, eyes and clothing.

Do not enter places where used or stored until adequately
ventilated.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Pressurized container.
Do not pierce or burn, even after use.
Contaminated work clothing should not be allowed out of the
workplace.
Avoid breathing vapours, mist or gas.

: Keep away from sources of ignition - No smoking.

4/15

against fire and explosion

Requirements for storage

Other data

Respiratory protection

Hand protection

Eye protection

Skin and body protection

Hygiene measures

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

Do not spray on an open flame or other ignition source.

Storage

: Protect from sunlight. Do not expose to temperatures

areas and containers

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Components CAS-No. mg/m3

Isobutane 75-28-5 -

Distillates
(petroleum),
hydrotreated light

Personal protective equipment

64742-47-8 1,200 mg/m3

exceeding 50 °C/ 122 °F.
Keep away from food, drink and animal feedingstuffs.
Keep in a dry, cool and well-ventilated place.
Protect from sunlight.
Store in a well-ventilated place.

: Stable under normal conditions.

Print Date 06/07/2018

GEN_SOF Number 61221

ppm

1,000 ppm

152 ppm

Non-

standard

units

-

-

Basis

ACGIH

STEL

SUPPLIER

: Do not spray in enclosed areas.

: Wear suitable gloves.

: No special requirements.

: No special requirements.

: Handle in accordance with good industrial hygiene and safety

practice. Wash thoroughly after handling.

5/15

Form

Color

Odour

Odour Threshold

pH

Melting point/freezing point

Initial boiling point and

Flash point

Evaporation rate

Flammability (solid, gas)

Upper/lower flammability or

Vapour pressure

Vapour density

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

9. PHYSICAL AND CHEMICAL PROPERTIES

: aerosol

: off-white

: solvent-like

: No data available

: 5.3

Print Date 06/07/2018

GEN_SOF Number 61221

: 0 C

: No data available

boiling range

explosive limits

: 93.3 °C

199.94 °F
Method: Tag Closed Cup (TCC)

: No data available

: Sustains combustion

: No data available

: Organic compounds with vapour pressure > 0.01 Kpa at 20 °C

: 0.962

6/15

Relative density

Solubility(ies)

Partition coefficient: n

-

Auto

-

ignition temperature

Decomposition temperature

Viscosity, dynamic

Viscosity, kinematic

Oxidizing properties

Volatile Organic

Other information

Reactivity

Chemical stability

Possibility of hazardous

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

: 1.00 g/cm3 at 20 °C

: partly miscible

: No data available

octanol/water

: does not ignite

Print Date 06/07/2018

GEN_SOF Number 61221

: No data available

: 5.33 mPa.s

: No data available

: not determined

: 12.6 % - additional exemptions may apply

Compounds
Total VOC (wt. %)*

*as defined by US Federal and State Consumer Product
Regulations

: None identified :

10. STABILITY AND REACTIVITY

reactions

: No dangerous reaction known under conditions of normal use.

: Stable under recommended storage conditions.

: If accidental mixing occurs and toxic gas is formed, exit area

immediately. Do not return until well ventilated.

7/15

Conditions to avoid

Incompatible materials

Hazardous decomposition

Acute oral toxicity

Acute inhalation toxicity

Acute dermal toxicity

GHS Properties

Classification

Routes of entry

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

products

11. TOXICOLOGICAL INFORMATION

: Heat, flames and sparks.

: Strong oxidizing agents

Do not mix with bleach or any other household cleaners.
Strong bases

: Thermal decomposition can lead to release of irritating gases

and vapours.

: LD50 > 5000 mg/kg
: LC50 > 10 mg/L

: LD50 > 5000 mg/kg

Print Date 06/07/2018

GEN_SOF Number 61221

Acute toxicity No classification proposed Oral

Acute toxicity No classification proposed Dermal

Acute toxicity No classification proposed Inhalation - Dust and Mist

Acute toxicity No classification proposed Inhalation - Vapour

Acute toxicity No classification proposed Inhalation - Gas

Skin corrosion/irritation No classification proposed

Serious eye
damage/eye irritation
Skin sensitisation

Respiratory No classification proposed -

No classification proposed

8/15

-

-

-

Target Organs

Aggravated Medical

Components

End point

Species

Value

Exposur

e

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

sensitisation
Germ cell mutagenicity No classification proposed

Carcinogenicity No classification proposed

Carcinogenicity No classification proposed

Reproductive toxicity No classification proposed

Specific target organ
toxicity - single
exposure

Specific target organ
toxicity - repeated
exposure
Aspiration hazard No classification proposed

Condition

12. ECOLOGICAL INFORMATION

No classification proposed

No classification proposed

: Skin

: None known.

Print Date 06/07/2018

GEN_SOF Number 61221

-

-

-

-

-

-

-

Product : The product itself has not been tested.

Toxicity

The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

Toxicity to fish

time

Isobutane LC50

QSAR

n-Octyl bicycloheptene
dicarboximide

LC50

Fish

27.98 mg/l

1.4 - 2.4
mg/l

96 h

9/15

Components

End point

Species

Value

Exposure

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

Distillates (petroleum),
hydrotreated light

static test
LC50
OECD
Test
Guideline
203

Oncorhynchus mykiss
(rainbow trout)

Print Date 06/07/2018

GEN_SOF Number 61221

> 1,000
mg/l

96 h

D-Phenothrin No data

available

Toxicity to aquatic invertebrates

Isobutane LC50

QSAR

n-Octyl bicycloheptene
dicarboximide

Distillates (petroleum),
hydrotreated light

No data
available

EC50
OECD
Test
Guideline
202

Daphnid

Daphnia (water flea)

16.33 mg/l

2.3 mg/l

> 1,000
mg/l

time

48 h

48 h

D-Phenothrin No data

available

Toxicity to aquatic plants

10/15

Component

Biodegradation

Exposure

Summary

Component

Bioconcentration

Partition Coefficient n

-

Components

End point

Species

Value

Exposure

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

Isobutane EC50

QSAR

n-Octyl bicycloheptene
dicarboximide
Distillates (petroleum),
hydrotreated light

D-Phenothrin No data

Persistence and degradability

Isobutane 70 % < 10 d Readily biodegradable.

n-Octyl bicycloheptene
dicarboximide
Distillates (petroleum),
hydrotreated light
D-Phenothrin No data available

Bioaccumulative potential

No data
available

ErC50
OECD
Test
Guideline
201

available

No data available

69 % 28 d Readily biodegradable.

Green algae

Pseudokirchneriella
subcapitata (green algae)

Print Date 06/07/2018

GEN_SOF Number 61221

8.57 mg/l 96 h

> 1,000
mg/l

time

time

72 h

factor (BCF)

Isobutane 1.57 - 1.97 2.8
n-Octyl bicycloheptene
dicarboximide
Distillates (petroleum),
hydrotreated light
D-Phenothrin No data available No data available

No data available 3.7 Measured

61 - 159 No data available

Octanol/water (log)

11/15

Component

End point

Value

Component

Results

Other adverse effects

:

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

Mobility

Isobutane No data available
n-Octyl bicycloheptene

dicarboximide
Distillates (petroleum),

hydrotreated light
D-Phenothrin No data available

PBT and vPvB assessment

Isobutane Not fulfilling PBT and vPvB criteria

n-Octyl bicycloheptene
dicarboximide
Distillates (petroleum),
hydrotreated light

13. DISPOSAL CONSIDERATIONS

No data available

No data available

Not fulfilling PBT and vPvB criteria

Not fulfilling PBT and vPvB criteria

None known.

Print Date 06/07/2018

GEN_SOF Number 61221

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

PESTICIDAL WASTE:
For disposal information, please read and follow Disposal instructions on the pesticide label.
Consumer may discard empty container in trash, or recycle where facilities exist.

12/15

Land transport

Sea transport

Air transport

UN number

UN proper

Transport hazard

Packing group

Environmental

Special

Transport in

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

shipping name

class(es)

hazards

precautions for
user

bulk according
to Annex II of
MARPOL 73/78
and the IBC
Code

15. REGULATORY INFORMATION

1950 1950 1950
Aerosols, Flammable
(d-Phenothrin)

2.1 2 2.1

-

- Marine pollutant

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

Product not
transported as bulk.

Aerosols, Flammable
(d-Phenothrin)

Limited quantities
derogation may be
applicable to this
product, please
check transport
documents.
Product not
transported as bulk.

Print Date 06/07/2018

GEN_SOF Number 61221

Aerosols, Flammable (d­Phenothrin)

-

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

Product not transported
as bulk.

-

-

FIFRA Labeling

This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ from
the classification criteria and hazard information required for safety data sheets, and for workplace
labels of non-pesticide chemicals.

Following is the hazard information as required on the pesticide label:

CAUTION:

13/15

Notification status

California Prop. 65

Health

Flammability

Reactivity

Health

Fire

Reactivity

Special

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

Harmful if swallowed.
Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
CONTENTS UNDER PRESSURE.
Exposure to temperatures above 130° F may cause bursting.

: All ingredients of this product are listed or are excluded from

listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

: This product is not subject to the reporting requirements under

California's Proposition 65.

Print Date 06/07/2018

GEN_SOF Number 61221

16. OTHER INFORMATION

HMIS Ratings

1

4

NFPA Ratings

This information is being provided in accordance with the Occupational Safety and Health
Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for
workplaces where product use and frequency of exposure exceeds that established for the labeled
consumer use.

Further information

0

1

4

0

-

14/15

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

Raid Max Foaming Crack & Crevice Bed Bug Killer (EPA Reg. No.
1021-2570-4822)

Version 1.1

Revision Date 05/24/2018 SDS Number 350000033475

This document has been prepared using data from sources considered to be technically reliable. It
does not constitute a warranty, expressed or implied, as to the accuracy of the information contained
herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all
available information when using product for any particular use and to comply with all Federal, State,
Provincial and Local laws and regulations.

Print Date 06/07/2018

GEN_SOF Number 61221

Prepared by SC Johnson Global Safety Assessment &

Regulatory Affairs (GSARA)

15/15