PASCO TD-8564 User Manual

Includes
Teacher's Notes
and
Typical
Experiment Results
THERMAL EFFICIENCY
Instruction Manual and Experiment Guide for the PASCO scientific Model TD-8564
012-05443A
3/94
12.9
12.9
12.4
12.4
12.0
12.0
11.6
11.6
11.2
11.2
10.8
10.8
10.4
10.4
K
K
scientific
5±1%
5±1%
12 VDC MAX
12 VDC MAX
T
°C
°C
K
K
75
75
9.12
9.12
76
76
8.81
8.81
77
77
8.52
8.52
78
78
8.24
8.24
79
79
7.96
7.96
80
80
7.70
7.70
81
81
7.45
7.45
Cold
Reservoir
c
°C
°C
K
K
°C
°C
85
85
6.53
6.53
95
95
86
86
6.33
6.33
96
96
87
87
6.12
6.12
97
97
88
88
5.93
5.93
98
98
89
89
5.74
5.74
99
99
90
90
5.56
5.56
100
100
91
91
5.39
5.39
101
101
Hot
Reservoir
Q
c
W
Q
h
Heat
Engine
T
h
WATER
WATER
PUMP
PUMP
7.5 - 12 VDC
7.5 - 12 VDC
@500mA
@500mA
K
K
°C
°C
461
461
-5
-5
436
436
-4
-4
413
413
-3
-3
391
391
-2
-2
370
370
-1
-1
351
351
0
0
332
332
1
1
PASCO
Model TD-8564
Model TD-8564
THERMAL EFFICIENCY
THERMAL EFFICIENCY
APPARATUS
27.4
27.4
26.4
26.4
25.3
25.3
24.4
24.4
23.4
23.4
22.5
22.5
21.7
21.7
K
K
°C
°C
55
55
56
56
57
57
58
58
59
59
60
60
61
61
APPARATUS
HEATER
2.0Ω2.01.0Ω1.00.5Ω0.5
K
K
°C
°C
18.6
18.6
65
65
17.9
17.9
66
66
17.3
17.3
67
67
16.6
16.6
68
68
16.0
16.0
69
69
15.5
15.5
70
70
14.9
14.9
71
71
THERMISTOR
THERMISTOR
SELECT
SELECT
PELTIER
PELTIER
DEVICE
DEVICE
COOLING
COOLING
WATER
WATER
THERMISTOR TABLETHERMISTOR TABLE
K
K
°C
K
K
°C
°C
K
K
°C
°C
K
K
°C
°C
K
269
269
5
5
161
161
15
255
255
242
242
230
230
218
218
207
207
197
197
15
6
6
153
153
16
16
7
7
146
146
17
17
8
8
139
139
18
18
9
9
133
133
19
19
10
10
126
126
20
20
11
11
120
120
21
21
95.4
95.4
91.1
91.1
87.0
87.0
83.1
83.1
79.4
79.4
75.9
75.9
K
100
100
25
25
63.4
63.4
26
26
60.7
60.7
27
27
58.1
58.1
28
28
55.6
55.6
29
29
53.2
53.2
30
30
51.0
51.0
31
31
48.9
48.9
°C
°C
°C
41.2
41.2
45
45
35
35
39.6
39.6
46
46
36
36
37.9
37.9
47
47
37
37
36.4
36.4
48
48
38
38
34.9
34.9
49
49
39
39
33.5
33.5
50
50
40
40
32.2
32.2
51
51
41
41
© 1991 PASCO scientific $10.00
012-05443A Thermal Efficiency Apparatus
T able of Contents
Copyright, Warranty and Equipment Return...................................................ii
Introduction .....................................................................................................1
Quick Start.......................................................................................................2
Theory ............................................................................................................. 3
HEAT ENGINE:
Introduction ...............................................................................................3
Actual Efficiency.......................................................................................3
Carnot Efficiency.......................................................................................3
Adjusted Efficiency ...................................................................................3
HEAT PUMP (REFRIGERATOR):
Introduction ...............................................................................................4
Actual Coefficient of Performance............................................................ 4
Maximum Coefficient of Performance...................................................... 4
Adjusted Coefficient of Performance ........................................................4
MEASUREMENTS USING THE THERMAL EFFICIENCY APPARATUS:
Direct Measurements.................................................................................5
Temperatures .......................................................................................5
Power Delivered to the Hot Reservoir (PH) ......................................... 6
Power Dissipated by the Load Resistor (PW)....................................... 6
Indirect Measurements ..............................................................................6
Internal Resistance...............................................................................6
Heat Conduction and Radiation...........................................................6
Heat Pumped from the Cold Reservoir................................................7
EXPERIMENTS:
1 — Heat Engine and Temperature Difference ......................................... 9
2 — Heat Engine Efficiency (Detailed Study) .........................................13
3 — Heat Pump Coefficient of Performance............................................17
4 — Thermal Conductivity.......................................................................20
5 — Load for Optimum Performance.......................................................21
Teacher’s Guide..............................................................................................25
Technical Support................................................................. Inside Back Cover
i
Thermal Efficiency Apparatus 012-05443A
Copyright, Warranty and Equipment Return
Please—Feel free to duplicate this manual subject to the copyright restrictions below.
Copyright Notice
The PASCO scientific Model TD-8564 Thermal Effi­ciency Apparatus manual is copyrighted and all rights reserved. However, permission is granted to non-profit educational institutions for reproduction of any part of this manual providing the reproductions are used only for their laboratories and are not sold for profit. Reproduc­tion under any other circumstances, without the written consent of PASCO scientific, is prohibited.
Limited Warranty
PASCO scientific warrants this product to be free from defects in materials and workmanship for a period of one year from the date of shipment to the customer. PASCO will repair or replace, at its option, any part of the product which is deemed to be defective in material or workman­ship. This warranty does not cover damage to the product caused by abuse or improper use. Determination of whether a product failure is the result of a manufacturing defect or improper use by the customer shall be made solely by PASCO scientific. Responsibility for the return of equipment for warranty repair belongs to the customer. Equipment must be properly packed to prevent damage and shipped postage or freight prepaid. (Damage caused by improper packing of the equipment for return ship­ment will not be covered by the warranty.) Shipping costs for returning the equipment, after repair, will be paid by PASCO scientific.
Equipment Return
Should the product have to be returned to PASCO scientific for any reason, notify PASCO scientific by letter, phone, or fax BEFORE returning the product. Upon notification, the return authorization and shipping instructions will be promptly issued.
ä
NOTE: NO EQUIPMENT WILL BE
ACCEPTED FOR RETURN WITHOUT AN AUTHORIZATION FROM PASCO.
When returning equipment for repair, the units must be packed properly. Carriers will not accept responsibility for damage caused by improper packing. To be certain the unit will not be damaged in shipment, observe the following rules:
The packing carton must be strong enough for the
item shipped.
Make certain there are at least two inches of
packing material between any point on the apparatus and the inside walls of the carton.
Make certain that the packing material cannot shift
in the box or become compressed, allowing the instrument come in contact with the packing carton.
Credits
This manual authored by: Ann Hanks This manual edited by: Ann Hanks and Eric Ayars Teacher’s Guide written by: Eric Ayars
Address: PASCO scientific
10101 Foothills Blvd. Roseville, CA 95747-7100
Phone: (916) 786-3800 FAX: (916) 786-3292 email: techsupp@pasco.com web: www.pasco.com
ii
012-05443A Thermal Efficiency Apparatus
Introduction
The Thermal Efficiency Apparatus can be used as a heat engine or a heat pump. When used as a heat engine, heat from the hot reservoir is used to do work by running a current through a load resistor. The actual efficiency of this real heat engine can be ob­tained and compared to the theoretical maximum efficiency . When used as a heat pump to transfer heat from the cold reservoir to the hot reservoir, the actual coefficient of performance and the theoretical maxi­mum coefficient of performance can be obtained.
The apparatus is built around a thermoelectric con­verter called a Peltier device. To simulate the theoreti­cal heat engines found in textbooks which have infinite hot and cold reservoirs, one side of the Peltier device is maintained at a constant cold temperature by pump­ing ice water through the block and the other side of the Peltier device is maintained at a constant hot temperature using a heater resistor imbedded in the block. The temperatures are measured with ther­mistors which are imbedded in the hot and cold blocks.
Additional Equipment Needed
Then, in 1834, Jean-Charles-Athanase Peltier discov­ered the opposite of the Seebeck Effect, that a current flowing through a junction of dissimilar metals causes heat to be absorbed or freed, depending on the direc­tion in which the current is flowing.
2
Since the Ther­mal Efficiency Apparatus is operated in this manner the thermoelectric converter is called a Peltier device. However, the Thermal Efficiency Apparatus also exhibits the Seebeck Effect because the two sides of the device are maintained at different temperatures.
Today the Seebeck Effect is achieved using pn junc­tions. The arrangement of the dissimilar semiconduc­tors is as seen in Figure 1. If the left side of the device is maintained at a higher temperature than the right side, then holes generated near the junction drift across the junction into the p region and electrons drift into the n region. At the cold junction on the right side, the same process occurs but at a slower rate so the net effect is a flow of electrons in the n region from the hot side to the cold side. Thus there is a current from the cold side to hot side in the n region.
3
To perform the experiments in this manual, you will need the following equipment in addition to the Thermal Efficiency Apparatus.
• 1 DC power supply capable of 2.5A at 12V (SF-9584)
• 3 kg (7 lbs) ice and a bucket for the ice-water bath
• Ohmmeter (SB-9624)
• 1 Ammeter (up to 3A) (SB-9624A)
• 2 Voltmeters (SB-9624A)
• Patch Cords (SE-9750-51)
History
The principle upon which the Thermal Efficiency Apparatus operates has been known since the 1800’s but has only become practical since the recent devel­opment of semiconductors.
In 1821 the Russian-German physicist Thomas Johann Seebeck discovered that when a junction of dissimilar metals is heated, a current is produced. enon is now known as the Seebeck Effect and is the basis of the thermocouple.
1
This phenom-
Cold
)
(T
Hot (Th)
p
n
p
n
Copper
Figure 1: Arrangement of Thermocouples
1
Timetables of Science, by Alexander Hellemans and
c
I
I
I
I
I
Load resistor
Bryan Bunch, Simon & Schuster, NY, 1988, p.281.
2
IBID, p.301.
3
Circuits, Devices, and Systems, 3rd ed., by Ralph J. Smith, Wiley, 1976, p.543.
1
Thermal Efficiency Apparatus 012-05443A
Quick Start
The following sections of this manual are essential to operate the Thermal Efficiency Apparatus and will give the user the minimum amount of information necessary to get started quickly:
Theory
Heat Engine
• Introduction
• Actual Efficiency
• Carnot Efficiency
Measurements Using the Thermal Efficiency Apparatus
Direct Measurements
• Temperatures
• Power to the Hot Reservoir
• Power Used by the Load Resistor
Experiment — 1: Heat Engine Efficiency and Temperature Difference
The other portions of the manual provide a more detailed explanation of the operation of the Thermal Efficiency Apparatus in other modes as well as the heat engine mode.
2
012-05443A Thermal Efficiency Apparatus
Theory
Heat Engine
Introduction
A heat engine uses the temperature difference between a hot reservoir and a cold reservoir to do work. Usu­ally the reservoirs are assumed to be very large in size so the temperature of the reservoir remains constant regardless of the amount of heat extracted or delivered to the reservoir. This is accomplished in the Thermal Efficiency Apparatus by supplying heat to the hot side using a heating resistor and by extracting heat from the cold side using ice water.
In the case of the Thermal Efficiency Apparatus, the heat engine does work by running a current through a load resistor. The work is ultimately converted into heat which is dissipated by the load resistor (Joule heating).
A heat engine can be represented by a diagram (Figure
2). The law of Conservation of Energy (First Law of Thermodynamics) leads to the conclusion that Q
= W + QC, the heat input to the engine equals the
H
work done by the heat engine on its surroundings plus the heat exhausted to the cold reservoir.
Cold
Reservoir
Q
c
Q
Hot
Reservoir
h
NOTE: Since you will be measuring the rates at which energy is transferred or used by the Thermal Efficiency Apparatus all measurements will be power rather than energy. So P
= dQH/dt and then the equation
H
QH = W + QC becomes PH=PW+PC and the efficiency becomes
P
W
e =
P
H
Carnot Efficiency
Carnot showed that the maximum efficiency of a heat engine depends only on the temperatures between which the engine operates, not on the type of engine.
– T
T
H
e
=
Carnot
where the temperatures must be in Kelvin. The only engines which can be 100% efficient are ones which operate between TH and absolute zero. The Carnot efficiency is the best a heat engine can do for a given pair of temperatures, assuming there are no energy losses due to friction, heat conduction, heat radiation, and Joule heating of the internal resistance of the device.
C
T
H
T
c
W
Figure 2: Heat Engine
Heat
Engine
T
h
Actual Efficiency
The efficiency of the heat engine is defined to be the work done divided by the heat input
W
e =
Q
H
So if all the heat input was converted to useful work, the engine would have an efficiency of one (100% efficient). Thus, the efficiency is always less than one.
Adjusted Efficiency
Using the Thermal Efficiency Apparatus, you can account for the energy losses and add them back into the powers PW and PH. This shows that, as all losses are accounted for, the resulting adjusted efficiency approaches the Carnot efficiency, showing that the maximum efficiency possible is not 100%.
3
Thermal Efficiency Apparatus 012-05443A
W
Heat Pump (Refrigerator)
Introduction
A heat pump is a heat engine run in reverse. Normally, when left alone, heat will flow from hot to cold. But a heat pump does work to pump heat from the cold reser­voir to the hot reservoir, just as a refrigerator pumps heat out of its cold interior into the warmer room or a heat pump in a house in winter pumps heat from the cold outdoors into the warmer house.
In the case of the Thermal Efficiency Apparatus, heat is pumped from the cold reservoir to the hot reservoir by running a current into the Peltier device in the direction opposite to the direction in which the Peltier device will produce a current.
A heat pump is represented in a diagram such as Figure 3.
NOTE: The arrows are reversed compared to the heat in Figure 2. By conservation of energy,
Q
+ W = QH,
or in terms of power
C
PC+PW=PH.
This is similar to efficiency because it is the ratio of what is accomplished to how much energy was ex­pended to do it. Notice that although the efficiency is always less than one, the COP is always greater than one.
Maximum Coefficient of Performance
As with the maximum efficiency of a heat engine, the maximum COP of a heat pump is only dependent on the temperatures.
T
=
TH– T
C
C
κ
max
where the temperatures are in Kelvin.
Adjusted Coefficient of Performance
If all losses due to friction, heat conduction, radiation, and Joule heating are accounted for, the actual COP can be adjusted so it approaches the maximum COP.
Ohmmeter
h
Hot
Reservoir
T
h
Cold
Reservoir
T
c
Q
c
W
Q
Heat
Pump
Figure 3: Heat Pump
Actual Coefficient of Performance
Instead of defining an efficiency as is done for a heat engine, a coefficient of performance (COP) is defined for a heat pump. The COP is the heat pumped from the cold reservoir divided by the work required to pump it
P
κ
= COP =
C
.
P
9V Power Supply In
Rubber
Hoses
WATER
PUMP
7.5 - 12 VDC @500mA
In
COOLING
WATER
THERMISTOR
SELECT
PELTIER DEVICE
Out
THERMISTOR TABLE
K
°C
K
°C
K
°C
K
°C
K
°C
461
-5
269
5 436 413 391 370 351 332 315 298 283
161
-4
255
6
153
-3
242
7
146
-2
230
8
139
-1
218
9
133
0
207
10
126
1
197
11
120
2
187
12
115
3
178
13
109
4
169
14
104
K
15
100
25
63.4
16
95.4
26
60.7
17
91.1
27
58.1
18
87.0
28
55.6
19
83.1
29
53.2
20
79.4
30
51.0
21
75.9
31
48.9
22
72.5
32
46.8
23
69.3
33
44.9
24
66.3
34
43.0
K
°C
41.2
45
27.4
35
39.6
46
26.4
36
37.9
47
25.3
37
36.4
48
24.4
38
34.9
49
23.4
39
33.5
50
22.5
40
32.2
51
21.7
41
30.9
52
20.9
42
29.7
53
20.1
43
28.5
54
19.3
44
Figure 4: Thermal Efficiency Apparatus
scientific
PASCO
Model TD-8564 THERMAL EFFICIENCY APPARATUS
HEATE R
°C 55
56 57 58 59 60 61 62 63 64
5Ω±1%
12 VDC MAX
2.01.00.5
K
°C
K
°C
18.6
65
12.9
75
17.9
66
12.4
76
17.3
67
12.0
77
16.6
68
11.6
78
16.0
69
11.2
79
15.5
70
10.8
80
14.9
71
10.4
81
14.4
72
10.1
82
13.8
73
9.76
83
13.4
74
9.43
84
K
°C
K
°C
9.12
85
6.53
95
8.81
86
6.33
96
8.52
87
6.12
97
8.24
88
5.93
98
7.96
89
5.74
99
7.70
90
5.56
100
7.45
91
5.39
101
7.21
92
5.22
102
6.98
93
5.06
103
6.75
94
4.91
104
4
012-05443A Thermal Efficiency Apparatus
C
Measurements Using the Thermal Efficiency Apparatus
Direct Measurements
Three quantities may be directly measured with the Thermal Efficiency Apparatus: temperatures, the power delivered to the hot reservoir, and the power dissipated by the load resistors. The details of how these measurements are made follow.
Temperatures
The temperatures of the hot and cold reservoirs are determined by measuring the resistance of the thermistor imbedded in the hot or cold block. To do this, connect an ohmmeter to the terminals located as shown in Figure 4. The switch toggles between the hot side and the cold side. The thermistor reading can be converted to a temperature
Table 1: Resistance to Temperature Conversion Chart
k °C k °C k °C k °C k °C
461 -5 436 -4 413 -3
146 17 139 18 133 19
53.2 39
51.0 40
48.9 41
by using the chart located on the front of the Thermal Efficiency Apparatus and in Table 1. Notice that as the temperature increases, the thermistor resistance decreases (100 k is a higher temperature than 200 k).
NOTE: To get the exact temperature reading the user must interpolate between numbers on the chart. For example, suppose the ohmmeter reads
118.7 k. This reading lies between 120 k = 21°C and 115 k = 22°C. The reading is 120-118.7 = 1.3 k above 21°C which is
1.3kΩ×
1°C
120 – 115k
= 0.26°
Therefore 118.7 k is 21.26°C.
21.7 61
20.9 62
20.1 63
9.76 83
9.43 84
9.12 85 391 -2 370 -1 351 0 332 1 315 2 298 3 283 4 269 5 255 6 242 7 230 8 218 9 207 10 197 11 187 12 178 13 169 14 161 15
126 20 120 21 115 22 109 23 104 24 100 25
95.4 26
91.1 27
87.0 28
83.1 29
79.4 30
75.9 31
72.5 32
69.3 33
66.3 34
63.4 35
60.7 36
58.1 37
46.8 42
44.9 43
43.0 44
41.2 45
39.6 46
37.9 47
36.4 48
34.9 49
33.5 50
32.2 51
30.9 52
29.7 53
28.5 54
27.4 55
26.4 56
25.3 57
24.4 58
23.4 59
19.3 64
18.6 65
17.9 66
17.3 67
16.6 68
16.0 69
15.5 70
14.9 71
14.4 72
13.8 73
13.4 74
12.9 75
12.4 76
12.0 77
11.6 78
11.2 79
10.8 80
10.4 81
8.81 86
8.52 87
8.24 88
7.96 89
7.70 90
7.45 91
7.21 92
6.98 93
6.75 94
6.53 95
6.33 96
6.12 97
5.93 98
5.74 99
5.56 100
5.39 101
5.22 102
5.06 103 153 16
55.6 38
22.5 60
5
10.1 82
4.91 104
Thermal Efficiency Apparatus 012-05443A
Power Delivered to the Hot Reservoir (PH)
The hot reservoir is maintained at a constant temperature by running a current through a resistor. Since the resis­tance changes with temperature, it is necessary to mea­sure the current and the voltage to obtain the power input. Then P
= IHVH.
H
Power Dissipated by the Load Resistor (PW)
The power dissipated by the load resistor is determined by measuring the voltage drop across the known load resistance and using the formula
2
V
PW=
.
R
The load resistors have a tolerance of 1%.
2
V
NOTE: We may use the equation
PW=
for
R
measuring the power in the load resistor because the temperature (and therefore resistance) of this resistor does not change significantly. We may not use this equation to measure power in the heating resistor, since its temperature (and resistance) changes.
When the Thermal Efficiency Apparatus is operated as a heat pump rather than as a heat engine, the load resistors are not used so it is necessary to measure both the current and the voltage. So the current into the Peltier device is measured with an ammeter, and the voltage across the Peltier device is measured with a voltmeter and the power input is calculated with the formula P
= IWVW.
W
Indirect Measurements
It will be necessary to know three additional quantities in the experiments: device;
The amount of heat conducted through the
device and the amount radiated away;
Figure 5: Procedure for Finding Internal Resistance
The internal resistance of the Peltier
The amount of
Peltier Device
R
r
V
l
l
V
s
heat pumped from the cold reservoir. These quantities may be determined indirectly with the Thermal Effi­ciency Apparatus in the following ways.
Internal Resistance
Before the adjusted efficiency can be calculated, it is necessary to calculate the internal resistance. This is accomplished by measuring the voltage drop across the Peltier device when an external load is applied.
First run the Thermal Efficiency Apparatus with a load resistor (R) as in figure 6. The electrical equivalent of this setup is shown in figure 5. Kirchoff’s Loop Rule gives
VS– Ir – IR =0
Next, run the Thermal Efficiency Apparatus with no load, as in Figure 7. Since there is no current flowing through the internal resistance of the Peltier Device, the voltage drop across the internal resistance is zero and the voltage measured will just be VS.
Since we have measured V
rather than I in the heat
w
engine mode, the equation above becomes
V
w
Vs–
r – Vw=0
R
Solving this for the internal resistance gives us
– V
V
s
r =
w
R
V
.
w
You may also find the resistance by measuring the currents for two different load resistors and then solving the resulting loop rule equations simultaneously.
Heat Conduction and Radiation
The heat that leaves the hot reservoir goes two places: part of it is actually available to be used by the heat engine to do work while the other part bypasses the engine either by being radiated away from the hot reservoir or by being conducted through the Peltier device to the cold side. The portion of the heat which bypasses the engine by radiation and conduction would be trans­ferred in this same manner whether or not the device is connected to a load and the heat engine is doing work.
The Thermal Efficiency Apparatus is run with a load connected to measure P disconnected and the power input into the hot reservoir is adjusted to maintain the temperatures (less power is needed when there is no load since less heat is being drawn from the hot reservoir). See Figure 7. P
(Figure 6) and then the load is
H
is the power input
H(open)
6
012-05443A Thermal Efficiency Apparatus
to the hot reservoir when no load is present. Since, while there is no load, the hot reservoir is maintained at an equilibrium temperature, the heat put into the hot reser­voir by the heating resistor must equal the heat radiated and conducted away from the hot reservoir. So measuring the heat input when there is no load determines the heat loss due to radiation and conduction. It is assumed this loss is the same when there is a load and the heat engine is operating.
Heat Pumped from the Cold Reservoir
When the Thermal Efficiency Apparatus is operated as a heat pump, conservation of energy yields that the rate at which heat is pumped from the cold reservoir, PC, is equal to the rate at which heat is delivered to the hot reservoir, PH, minus the rate at which work is being done, P
W
(Figure 3).
The work can be measured directly but the heat delivered to the hot reservoir has to be measured indirectly. Notice that when the heat pump is operating, the temperature of the hot reservoir remains constant. Therefore, the hot reservoir must be in equilibrium and the heat delivered to it must equal the heat being conducted and radiated away. So a measurement of the heat conducted and radiated away at a given temperature difference will also be a measurement of the heat delivered to the hot reservoir. The heat conducted and radiated is measured by running the device with no load and measuring the heat input needed to maintain the temperature of the hot side (Figure 7).
T
H
Conducted
Power
V
Engine
A
Power
Supply
V
Figure 6: Heat Engine With A Load
V
A
Conducted
Power
PH (open)
Power Supply
P
W
T
C
T
H
V
Figure 7: No Load
7
T
C
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