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i
Thermal Efficiency Apparatus012-05443A
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ä
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Credits
This manual authored by: Ann Hanks
This manual edited by: Ann Hanks and Eric Ayars
Teacher’s Guide written by: Eric Ayars
The Thermal Efficiency Apparatus can be used as a
heat engine or a heat pump. When used as a heat
engine, heat from the hot reservoir is used to do work
by running a current through a load resistor. The
actual efficiency of this real heat engine can be obtained and compared to the theoretical maximum
efficiency . When used as a heat pump to transfer heat
from the cold reservoir to the hot reservoir, the actual
coefficient of performance and the theoretical maximum coefficient of performance can be obtained.
The apparatus is built around a thermoelectric converter called a Peltier device. To simulate the theoretical heat engines found in textbooks which have infinite
hot and cold reservoirs, one side of the Peltier device
is maintained at a constant cold temperature by pumping ice water through the block and the other side of
the Peltier device is maintained at a constant hot
temperature using a heater resistor imbedded in the
block. The temperatures are measured with thermistors which are imbedded in the hot and cold blocks.
Additional Equipment Needed
Then, in 1834, Jean-Charles-Athanase Peltier discovered the opposite of the Seebeck Effect, that a current
flowing through a junction of dissimilar metals causes
heat to be absorbed or freed, depending on the direction in which the current is flowing.
2
Since the Thermal Efficiency Apparatus is operated in this manner
the thermoelectric converter is called a Peltier device.
However, the Thermal Efficiency Apparatus also
exhibits the Seebeck Effect because the two sides of
the device are maintained at different temperatures.
Today the Seebeck Effect is achieved using pn junctions. The arrangement of the dissimilar semiconductors is as seen in Figure 1. If the left side of the device
is maintained at a higher temperature than the right
side, then holes generated near the junction drift across
the junction into the p region and electrons drift into
the n region. At the cold junction on the right side, the
same process occurs but at a slower rate so the net
effect is a flow of electrons in the n region from the
hot side to the cold side. Thus there is a current from
the cold side to hot side in the n region.
3
To perform the experiments in this manual, you will
need the following equipment in addition to the
Thermal Efficiency Apparatus.
• 1 DC power supply capable of 2.5A at 12V
(SF-9584)
• 3 kg (7 lbs) ice and a bucket for the ice-water bath
• Ohmmeter (SB-9624)
• 1 Ammeter (up to 3A) (SB-9624A)
• 2 Voltmeters (SB-9624A)
• Patch Cords (SE-9750-51)
History
The principle upon which the Thermal Efficiency
Apparatus operates has been known since the 1800’s
but has only become practical since the recent development of semiconductors.
In 1821 the Russian-German physicist Thomas Johann
Seebeck discovered that when a junction of dissimilar
metals is heated, a current is produced.
enon is now known as the Seebeck Effect and is the
basis of the thermocouple.
1
This phenom-
Cold
)
(T
Hot
(Th)
p
n
p
n
Copper
Figure 1: Arrangement of Thermocouples
1
Timetables of Science, by Alexander Hellemans and
c
I
I
I
I
I
Load resistor
Bryan Bunch, Simon & Schuster, NY, 1988, p.281.
2
IBID, p.301.
3
Circuits, Devices, and Systems, 3rd ed., by Ralph J.
Smith, Wiley, 1976, p.543.
1
Thermal Efficiency Apparatus012-05443A
Quick Start
The following sections of this manual are essential to
operate the Thermal Efficiency Apparatus and will
give the user the minimum amount of information
necessary to get started quickly:
Theory
Heat Engine
• Introduction
• Actual Efficiency
• Carnot Efficiency
Measurements Using the Thermal
Efficiency Apparatus
Direct Measurements
• Temperatures
• Power to the Hot Reservoir
• Power Used by the Load Resistor
Experiment — 1: Heat Engine Efficiency
and Temperature Difference
The other portions of the manual provide a more
detailed explanation of the operation of the Thermal
Efficiency Apparatus in other modes as well as the
heat engine mode.
2
012-05443AThermal Efficiency Apparatus
Theory
Heat Engine
Introduction
A heat engine uses the temperature difference between
a hot reservoir and a cold reservoir to do work. Usually the reservoirs are assumed to be very large in size
so the temperature of the reservoir remains constant
regardless of the amount of heat extracted or delivered
to the reservoir. This is accomplished in the Thermal
Efficiency Apparatus by supplying heat to the hot side
using a heating resistor and by extracting heat from the
cold side using ice water.
In the case of the Thermal Efficiency Apparatus, the
heat engine does work by running a current through a
load resistor. The work is ultimately converted into
heat which is dissipated by the load resistor (Joule
heating).
A heat engine can be represented by a diagram (Figure
2). The law of Conservation of Energy (First Law of
Thermodynamics) leads to the conclusion that
Q
= W + QC, the heat input to the engine equals the
H
work done by the heat engine on its surroundings plus
the heat exhausted to the cold reservoir.
Cold
Reservoir
Q
c
Q
Hot
Reservoir
h
➤ NOTE: Since you will be measuring the rates
at which energy is transferred or used by the
Thermal Efficiency Apparatus all measurements
will be power rather than energy. So
P
= dQH/dt and then the equation
H
QH = W + QC becomes PH=PW+PC and the
efficiency becomes
P
W
e =
P
H
Carnot Efficiency
Carnot showed that the maximum efficiency of a heat
engine depends only on the temperatures between
which the engine operates, not on the type of engine.
– T
T
H
e
=
Carnot
where the temperatures must be in Kelvin. The only
engines which can be 100% efficient are ones which
operate between TH and absolute zero. The Carnot
efficiency is the best a heat engine can do for a given
pair of temperatures, assuming there are no energy
losses due to friction, heat conduction, heat radiation,
and Joule heating of the internal resistance of the
device.
C
T
H
T
c
W
Figure 2: Heat Engine
Heat
Engine
T
h
Actual Efficiency
The efficiency of the heat engine is defined to be the
work done divided by the heat input
W
e =
Q
H
So if all the heat input was converted to useful work,
the engine would have an efficiency of one (100%
efficient). Thus, the efficiency is always less than one.
Adjusted Efficiency
Using the Thermal Efficiency Apparatus, you can
account for the energy losses and add them back into
the powers PW and PH. This shows that, as all losses
are accounted for, the resulting adjusted efficiency
approaches the Carnot efficiency, showing that the
maximum efficiency possible is not 100%.
3
Thermal Efficiency Apparatus012-05443A
W
Heat Pump (Refrigerator)
Introduction
A heat pump is a heat engine run in reverse. Normally,
when left alone, heat will flow from hot to cold. But a
heat pump does work to pump heat from the cold reservoir to the hot reservoir, just as a refrigerator pumps heat
out of its cold interior into the warmer room or a heat
pump in a house in winter pumps heat from the cold
outdoors into the warmer house.
In the case of the Thermal Efficiency Apparatus, heat is
pumped from the cold reservoir to the hot reservoir by
running a current into the Peltier device in the direction
opposite to the direction in which the Peltier device will
produce a current.
A heat pump is represented in a diagram such as Figure 3.
➤NOTE: The arrows are reversed compared to the
heat in Figure 2. By conservation of energy,
Q
+ W = QH,
or in terms of power
C
PC+PW=PH.
This is similar to efficiency because it is the ratio of
what is accomplished to how much energy was expended to do it. Notice that although the efficiency is
always less than one, the COP is always greater than
one.
Maximum Coefficient of Performance
As with the maximum efficiency of a heat engine, the
maximum COP of a heat pump is only dependent on
the temperatures.
T
=
TH– T
C
C
κ
max
where the temperatures are in Kelvin.
Adjusted Coefficient of Performance
If all losses due to friction, heat conduction, radiation,
and Joule heating are accounted for, the actual COP
can be adjusted so it approaches the maximum COP.
Ohmmeter
Ω
h
Hot
Reservoir
T
h
Cold
Reservoir
T
c
Q
c
W
Q
Heat
Pump
Figure 3: Heat Pump
Actual Coefficient of Performance
Instead of defining an efficiency as is done for a heat
engine, a coefficient of performance (COP) is defined
for a heat pump. The COP is the heat pumped from the
cold reservoir divided by the work required to pump it
P
κ
= COP =
C
.
P
9V Power
Supply In
Rubber
Hoses
WATER
PUMP
7.5 - 12 VDC
@500mA
In
COOLING
WATER
THERMISTOR
SELECT
PELTIER
DEVICE
Out
THERMISTOR TABLE
KΩ
°C
KΩ
°C
KΩ
°C
KΩ
°C
KΩ
°C
461
-5
269
5
436
413
391
370
351
332
315
298
283
161
-4
255
6
153
-3
242
7
146
-2
230
8
139
-1
218
9
133
0
207
10
126
1
197
11
120
2
187
12
115
3
178
13
109
4
169
14
104
KΩ
15
100
25
63.4
16
95.4
26
60.7
17
91.1
27
58.1
18
87.0
28
55.6
19
83.1
29
53.2
20
79.4
30
51.0
21
75.9
31
48.9
22
72.5
32
46.8
23
69.3
33
44.9
24
66.3
34
43.0
KΩ
°C
41.2
45
27.4
35
39.6
46
26.4
36
37.9
47
25.3
37
36.4
48
24.4
38
34.9
49
23.4
39
33.5
50
22.5
40
32.2
51
21.7
41
30.9
52
20.9
42
29.7
53
20.1
43
28.5
54
19.3
44
Figure 4: Thermal Efficiency Apparatus
scientific
PASCO
Model TD-8564
THERMAL EFFICIENCY
APPARATUS
HEATE R
°C
55
56
57
58
59
60
61
62
63
64
5Ω±1%
12 VDC MAX
2.0Ω1.0Ω0.5Ω
KΩ
°C
KΩ
°C
18.6
65
12.9
75
17.9
66
12.4
76
17.3
67
12.0
77
16.6
68
11.6
78
16.0
69
11.2
79
15.5
70
10.8
80
14.9
71
10.4
81
14.4
72
10.1
82
13.8
73
9.76
83
13.4
74
9.43
84
KΩ
°C
KΩ
°C
9.12
85
6.53
95
8.81
86
6.33
96
8.52
87
6.12
97
8.24
88
5.93
98
7.96
89
5.74
99
7.70
90
5.56
100
7.45
91
5.39
101
7.21
92
5.22
102
6.98
93
5.06
103
6.75
94
4.91
104
4
012-05443AThermal Efficiency Apparatus
C
Measurements Using the Thermal Efficiency Apparatus
Direct Measurements
Three quantities may be directly measured with the
Thermal Efficiency Apparatus: temperatures, the power
delivered to the hot reservoir, and the power dissipated by
the load resistors. The details of how these measurements
are made follow.
Temperatures
The temperatures of the hot and cold reservoirs are
determined by measuring the resistance of the thermistor
imbedded in the hot or cold block. To do this, connect an
ohmmeter to the terminals located as shown in Figure 4.
The switch toggles between the hot side and the cold side.
The thermistor reading can be converted to a temperature
Table 1: Resistance to Temperature Conversion Chart
kΩ°CkΩ°CkΩ°CkΩ°CkΩ°C
461-5
436-4
413-3
14617
13918
13319
53.239
51.040
48.941
by using the chart located on the front of the Thermal
Efficiency Apparatus and in Table 1. Notice that as the
temperature increases, the thermistor resistance decreases
(100 kΩ is a higher temperature than 200 kΩ).
➤ NOTE: To get the exact temperature reading
the user must interpolate between numbers on the
chart. For example, suppose the ohmmeter reads
118.7 kΩ. This reading lies between
120 kΩ = 21°C and 115 kΩ = 22°C. The reading is
120-118.7 = 1.3 kΩ above 21°C which is
The hot reservoir is maintained at a constant temperature
by running a current through a resistor. Since the resistance changes with temperature, it is necessary to measure the current and the voltage to obtain the power input.
Then P
= IHVH.
H
Power Dissipated by the Load Resistor (PW)
The power dissipated by the load resistor is determined
by measuring the voltage drop across the known load
resistance and using the formula
2
V
PW=
.
R
The load resistors have a tolerance of 1%.
2
V
➤ NOTE: We may use the equation
PW=
for
R
measuring the power in the load resistor because
the temperature (and therefore resistance) of this
resistor does not change significantly. We may not
use this equation to measure power in the heating
resistor, since its temperature (and resistance)
changes.
When the Thermal Efficiency Apparatus is operated as a
heat pump rather than as a heat engine, the load resistors
are not used so it is necessary to measure both the current
and the voltage. So the current into the Peltier device is
measured with an ammeter, and the voltage across the
Peltier device is measured with a voltmeter and the power
input is calculated with the formula P
= IWVW.
W
Indirect Measurements
It will be necessary to know three additional quantities in
the experiments:
device;
➁ The amount of heat conducted through the
device and the amount radiated away;
Figure 5: Procedure for Finding Internal Resistance
➀ The internal resistance of the Peltier
➂ The amount of
Peltier Device
R
r
V
l
l
V
s
heat pumped from the cold reservoir. These quantities
may be determined indirectly with the Thermal Efficiency Apparatus in the following ways.
Internal Resistance
Before the adjusted efficiency can be calculated, it is
necessary to calculate the internal resistance. This is
accomplished by measuring the voltage drop across the
Peltier device when an external load is applied.
First run the Thermal Efficiency Apparatus with a load
resistor (R) as in figure 6. The electrical equivalent of this
setup is shown in figure 5. Kirchoff’s Loop Rule gives
VS– Ir – IR =0
Next, run the Thermal Efficiency Apparatus with no load,
as in Figure 7. Since there is no current flowing through
the internal resistance of the Peltier Device, the voltage
drop across the internal resistance is zero and the voltage
measured will just be VS.
Since we have measured V
rather than I in the heat
w
engine mode, the equation above becomes
V
w
Vs–
r – Vw=0
R
Solving this for the internal resistance gives us
– V
V
s
r =
w
R
V
.
w
You may also find the resistance by measuring the
currents for two different load resistors and then solving
the resulting loop rule equations simultaneously.
Heat Conduction and Radiation
The heat that leaves the hot reservoir goes two places:
part of it is actually available to be used by the heat
engine to do work while the other part bypasses the
engine either by being radiated away from the hot
reservoir or by being conducted through the Peltier device
to the cold side. The portion of the heat which bypasses
the engine by radiation and conduction would be transferred in this same manner whether or not the device is
connected to a load and the heat engine is doing work.
The Thermal Efficiency Apparatus is run with a load
connected to measure P
disconnected and the power input into the hot reservoir is
adjusted to maintain the temperatures (less power is needed
when there is no load since less heat is being drawn from
the hot reservoir). See Figure 7. P
(Figure 6) and then the load is
H
is the power input
H(open)
6
012-05443AThermal Efficiency Apparatus
to the hot reservoir when no load is present. Since, while
there is no load, the hot reservoir is maintained at an
equilibrium temperature, the heat put into the hot reservoir by the heating resistor must equal the heat radiated
and conducted away from the hot reservoir. So measuring
the heat input when there is no load determines the heat
loss due to radiation and conduction. It is assumed this
loss is the same when there is a load and the heat engine
is operating.
Heat Pumped from the Cold Reservoir
When the Thermal Efficiency Apparatus is operated as a
heat pump, conservation of energy yields that the rate at
which heat is pumped from the cold reservoir, PC, is equal
to the rate at which heat is delivered to the hot reservoir,
PH, minus the rate at which work is being done, P
W
(Figure 3).
Ω
The work can be measured directly but the heat delivered
to the hot reservoir has to be measured indirectly. Notice
that when the heat pump is operating, the temperature of
the hot reservoir remains constant. Therefore, the hot
reservoir must be in equilibrium and the heat delivered to
it must equal the heat being conducted and radiated away.
So a measurement of the heat conducted and radiated
away at a given temperature difference will also be a
measurement of the heat delivered to the hot reservoir.
The heat conducted and radiated is measured by running
the device with no load and measuring the heat input
needed to maintain the temperature of the hot side
(Figure 7).
T
H
Conducted
Power
V
Engine
Ω
A
Power
Supply
V
Figure 6: Heat Engine With A Load
V
A
Conducted
Power
PH (open)
Power
Supply
P
W
T
C
T
H
V
Figure 7: No Load
7
T
C
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