Hanna Instruments HI 8510 User Manual

Instruction Manual
HI 8510 • HI 8512
HI 8710 • HI 8711
HI 8720
Panel Mounted
pH and ORP
HI 8720E
ORP
mV
DOSAGE
OXID.
MEA
SURE
0 mV
TEST
www.hannainst.com
REDUC.
SET
ΔAL
500 mV
TEST
SLOPE
ΔAL
COARSE
SET
FINE
1
PRELIMINARY EXAMINATION
Dear Customer, Thank you for choosing a HANNA instruments product. Please read this instruction manual carefully before using the instrument.
If you need additional technical information, do not hesitate to e-mail us at tech@hannainst.com. These instruments are in compliance with the
directives.
TABLE OF CONTENTS
Preliminary Examination ............................. 3
General Description..................................... 3
Available Models ......................................... 4
Mechanical Dimensions .............................. 6
Functional Description HI 8510.................... 7
Functional Description HI 8512.................. 10
Functional Description HI 8710.................. 13
Functional Description HI 8711.................. 16
Functional Description HI 8720.................. 20
Specifications............................................ 24
Initial Preparation ...................................... 27
Operational Guide ..................................... 30
pH Calibration ........................................... 34
pH V alues at V arious T emperature............. 36
pH Diagnostic Tests.................................. 37
ORP Diagnostic Tests............................... 39
LED Indication........................................... 40
T aking Redox Measurements .................... 41
Electrode Maintenance.............................. 43
Suggested Installations ............................. 47
Accessories.............................................. 49
Warranty ................................................... 55
®
Remove the instrument from the packing material and examine it carefully to make sure that no damage has occurred during shipping. If there is any noticeable damage, immediately notify your dealer.
Each model is supplied complete with transparent splash-proof front cover, mounting brackets and instruction manual
Note: Save all packing materials until you
are sure that the instrument functions correctly. All defective items must be returned in the original packing materials together with the supplied accessories.
GENERAL DESCRIPTION
HI 8510 and HI8512 pH and ORP panel-
mounted indicators, and HI 8710, HI 8711 and HI 8720 pH and ORP controllers, are ideal for process control monitoring in a wide range of industrial applications.
These instruments have been designed for easy and fast installation, and are provided with membrane keypads on the front panel, large display and autodiagnostic functions.
All connections are made through screw ter­minals on the rear panel.
Two versions are available for each model, to accept either a direct input from a pH or ORP electrode (E version) or from a transmitter through 4-20mA input (T version).
Moreover, you can choose the output configuration for connecting a recorder or a PLC, between 0-20 or 4-20 mA.
2
3
AVAILABLE MODELS
HI 8510E020 pH indicator with electrode
input and 0-20 mA recorder output
HI 8510E420 pH indicator with electrode
input and 4-20 mA recorder output
HI 8510T020 pH indicator with input from
transmitter and 0-20 mA recorder output
HI 8510T420 pH indicator with input from
transmitter and 4-20 mA recorder output
HI 8512E020 ORP indicator with electrode
input and 0-20 mA recorder output
HI 8512E420 ORP indicator with electrode
input and 4-20 mA recorder output
HI 8512T020 ORP indicator with input from
transmitter and 0-20 mA recorder output
HI 8512T420 ORP indicator with input from
transmitter and 4-20 mA recorder output
HI 8710E020 pH controller with electrode
input and 0-20 mA recorder output
HI 8710E420 pH controller with electrode
input and 4-20 mA recorder output
HI 8710T020 pH controller with input from
transmitter and 0-20 mA recorder output
HI 8710T420 pH controller with input from
transmitter and 4-20 mA recorder output
HI 8711E020 pH controller with 2 setpoints,
electrode input and 0-20 mA recorder output
HI 8711E420 pH controller with 2 setpoints,
electrode input and 4-20 mA recorder output
HI 8711T020 pH controller with 2 setpoints,
input from transmitter and 0­20 mA recorder output
HI 8711T420 pH controller with 2 setpoints,
input from transmitter and 4­20 mA recorder output
HI 8720E020 ORP controller with electrode
input and 0-20 mA recorder output
HI 8720E420 ORP controller with electrode
input and 4-20 mA recorder output
HI 8720T020 ORP controller with input from
transmitter and 0-20 mA recorder output
HI 8720T420 ORP controller with input from
transmitter and 4-20 mA recorder output
4
5
MECHANICAL DIMENSIONS
1
m "
2.83"
FUNCTIONAL DESCRIPTION HI 8510
The meters are provided with a black anodized aluminum body, front and back panels in shockproof ABS plastic and a transparent splash-proof front cover.
Front view of the panel-mounted unit
141mm
144m
5.55"
5.67
69mm
2.71"
72mm
The dimensions show the cutout size for the installation.
Side view of the panel-mounted unit
0.25/4mm
0.01/0.160"
ADJUSTABLE LOCATION BRACKET
FRONT PANEL
pH
HI 8510E
pH
SENSOR
TEST
pH 7
TEST
pH 4
TEST
SLOPE
Δ
44mm
5.67"
Keypad
SENSOR TEST
To display the mV reading of the electrode and, therefore, verify its working condition
135mm
5.31"
190mm MIN
7.50"
pH 7 TEST
To verify the internal circuit of the meter in terms of Offset compensation
Adjustable location brackets (supplied with the meter) allow the indicator to slide into the cutout and will hold the unit securely in place. 190 mm (7.50") is the minimum space re­quired to install the indicator with complete wiring.
6
pH 4 TEST
To verify the amplifier circuit of the meter
Trimmers
ΔΔ
ΔO For Offset calibration
ΔΔ
SLOPE For Slope calibration
7
REAR PANEL HI 8510E
5
ELECTRODE INPUT
REAR PANEL HI 8510T
4 3
2
PT100
+
mA OUT
-
220
FUSE
FUSE
L
110
1
1. Fuse holder
2. Power supply terminals
3. Recorder output terminals
4. Connections for Pt100 temperature sensor
5. BNC socket for pH electrode
1. Fuse holder
2. Power supply terminals
3. Recorder output terminals
4. Connections to the transmitter
Unplug the instrument from the power supply before replacing the fuse.
8
Unplug the instrument from the power supply before replacing the fuse.
9
FUNCTIONAL DESCRIPTION HI 8512
FRONT PANEL
HI 8512E
ORP
mV
SLOPE
500 mV
0 mV
TEST
TEST
REAR PANEL HI 8512E
4
+
3
2
mA OUT
-
220
L
110
ELECTRODE INPUT
FUSE
FUSE
1
Keypad
0 mV TEST To verify the instrument cali-
bration at 0 mV
500 mV TEST To verify the slope at 500 mV
Trimmers
SLOPE For slope calibration
10
10£
1. Fuse holder
2. Power supply terminals
3. Recorder output terminals
4. BNC socket for ORP electrode
Unplug the instrument from the power supply before replacing the fuse.
11
FUNCTIONAL DESCRIPTION HI 8710
REAR PANEL HI 8512T
1. Fuse holder
2. Power supply terminals
3. Recorder output terminals
4. Connections to the transmitter
Unplug the instrument from the power supply before replacing the fuse.
12
12£
FRONT PANEL
pH
HI 8710E
pH
BASE
SET
ΔAL
pH 4
TEST
13
SLOPE
Δ
0
ΔAL
COARSE
SET
FINE
ACID
MEA
SURE
SENSOR
TEST
pH 7
TEST
Keypad
SET To set the pH dosage limit MEASURE To enter measurement mode
and to enable diagnostic tests
SENSOR TEST To display electrode mV reading
and verify its working condition
ΔΔ
ΔAL To display & set alarm tolerance
ΔΔ
pH 7 TEST To verify Offset compensation pH 4 TEST To verify amplifier circuit
Trimmers
ΔΔ
ΔO For Offset calibration
ΔΔ
SLOPE For Slope calibration
ΔΔ
ΔAL To set the alarm tolerance
ΔΔ
SET/COARSE To coarsely adjust the setpoint SET/FINE To finely adjust the setpoint
LEDs
ACID Show that acid dosage is active BASE Show that basic dosage is active
ΔΔ
ΔAL (blinking) Indicate an active alarm
ΔΔ
REAR PANEL HI 8710E
9
ELECTRODE INPUT
REAR PANEL HI 8710T
8 7 3
5
4
6
2
PT100
+
mA OUT
-
OPEN: ACID SHORT: BASE
SET
CONSENT
ALARM
220
FUSE
FUSE
L
110
1
1. Fuse holder
2. Power supply terminals
3. Acid/Basic dosage selection terminals
4. Red/ox dosage consent terminals
5. Connections for dosing pump
6. Alarm contacts
7. Recorder output contacts
8. Connections for Pt100 temperature sensor
9. BNC socket for pH electrode
1. Fuse holder
2. Power supply terminals
3. Acid/Basic dosage selection terminals
4. Red/ox dosage consent terminals
5. Connections for dosing pump
6. Alarm contacts
7. Recorder output contacts
8. Connections to the transmitter
Unplug the instrument from the power supply before replacing the fuse.
14
14£
Unplug the instrument from the power supply before replacing the fuse.
15
FUNCTIONAL DESCRIPTION HI 8711
FRONT PANEL
pH
HI 8711E
ΔΔ
ΔAl To display and set the
ΔΔ
alarm tolerance
pH 7 TEST To verify Offset compen-
sation
pH 4 TEST To verify amplifier circuit
pH
SLOPE
ACID
SET
MEA
SURE
SENSOR
TEST
pH 7
TEST
HI 8711E
BASE
SET
ΔAL
pH 4
TEST
Δ
ΔAL
COARSE
ACID SET
FINE
COARSE
BASE SET
FINE
Keypad
ACID SET To set the working point
of acid dosage
BASE SET To set the working point
of basic dosage
MEASURE To enter measurement
mode and to enable diagnostic tests
SENSOR TEST To display electrode mV
reading and, therefore, verify its working condition
Trimmers
ΔΔ
ΔO For Offset calibration
ΔΔ
SLOPE For Slope calibration
ΔΔ
ΔAL To set the tolerance of the
ΔΔ
alarm
ACID SET/COARSE To coarsely adjust
acid setpoint
ACID SET/FINE To finely adjust acid
setpoint
BASE SET/COARSE To coarsely adjust
basic setpoint
BASE SET/FINE To finely adjust basic
setpoint
LEDs
ACID SET (Blinking) Show that acid dos-
age is active
BASE SET (Blinking) Show that basic
dosage is active
ΔΔ
ΔAL (Blinking) Indicate active alarm
ΔΔ
16
16£
17
REAR PANEL HI 8711E
8
ELECTRODE INPUT
REAR PANEL HI 8711T
7 6
4
3
5
2
PT100
+
mA OUT
-
BASE
ACID
ALARM
220
FUSE
FUSE
L
110
1
1. Fuse holder
2. Power supply terminals
3. Connections for dosing pump for acid
4. Connections for dosing pump for base
5. Alarm contacts
6. Recorder output contacts
7. Connections for Pt100 temperature sensor
8. BNC socket for pH electrode
1. Fuse holder
2. Power supply terminals
3. Connections for dosing pump for acid
4. Connections for dosing pump for base
5. Alarm contacts
6. Recorder output contacts
7. Connections to the transmitter
Unplug the instrument from the power supply before replacing the fuse.
18
18£
Unplug the instrument from the power supply before replacing the fuse.
19
FUNCTIONAL DESCRIPTION HI 8720
FRONT PANEL
HI 8720E
ORP
mV
SLOPEDOSAGE
OXID. REDUC.
MEA
SET
SURE
0 mV
TEST
ΔAL
500 mV
TEST
COARSE
ΔAL
SET
FINE
Trimmers
SLOPE For Slope calibration
ΔΔ
ΔAL To display and set the alarm
ΔΔ
tolerance
SET/COARSE To coarsely adjust the
setpoint
SET/FINE To finely adjust the setpoint
LEDs
OXID Show that the oxidant dosage is
active
REDUC Show that the reductant dosage
is active
ΔΔ
ΔAL (blinking) Indicate an active alarm
ΔΔ
Keypad
SET To set the working point of ORP
dosage
MEASURE To enter measurement mode and
to enable diagnostic tests
ΔΔ
ΔAl To display and set the alarm
ΔΔ
tolerance
0 mV TEST To verify the instrument
calibration at 0 mV
500 mV TEST To verify the slope at
500mV
20
20£
21
REAR PANEL HI 8720E
8
ELECTRODE INPUT
REAR PANEL HI 8720T
4
7 3
5
6
2
CONSENT
+
mA OUT
-
OPEN: OXD SHORT: RDX
SET
ALARM
220
FUSE
FUSE
L
110
1. Fuse holder
2. Power supply terminals
3. Ox/Red dosage selection terminals
4. Ox/red dosage consent terminals
5. Connections for dosing pump
6. Alarm contacts
7. Recorder output contacts
8. BNC socket for ORP electrode
1
1. Fuse holder
2. Power supply terminals
3. Ox/Red dosage selection terminals
4. Ox/red dosage consent terminals
5. Connections for dosing pump
6. Alarm contacts
7. Recorder output contacts
8. Connections to the transmitter
Unplug the instrument from the power supply before replacing the fuse.
22
22£
Unplug the instrument from the power supply before replacing the fuse.
23
SPECIFICATIONS
HI 8510E HI 8510T
Range 0.00 to 14.00 pH Resolution 0.01 pH Accuracy ±0.02 pH ±0.5% Typical EMC Dev. ±0.1 pH / ±0.2 mA Installation Category II Input 1012 Ohm 4 to 20 mA Calibration Offset: ±2 pH with Δ0 trimmer
Slope: 80 to 110% with slope trimmer
Temperature Fixed or automatic with Pt100 Compensation from 0 to 100°C (32 to 212°F)
Recorder Output 0-20 mA or 4-20 mA (isolated) Power Supply 115 or 230 Vac; 50/60 Hz Environment -10 to 50°C (14 to 122°F);
RH max 95% non condensing
Panel Cutout 141 x 69 mm (5.6 x 2.7'') Weight 1 kg (2.2 lb.)
HI 8512E HI 8512T
Range ±1000 mV Resolution 1 mV Accuracy ±5 mV ±0.5% Typical EMC Dev. ±6 mV / ±0.2 mA Installation Category II Input 1012 Ohm 4 to 20 mA Calibration Slope: 90 to 110% with slope trimmer Recorder Output 0-20 mA or 4-20 mA (isolated) Power Supply 115 or 230 Vac; 50/60 Hz Environment -10 to 50°C (14 to 122°F);
RH max 95% non condensing
Panel Cutout 141 x 69 mm (5.6 x 2.7'') Weight 1 kg (2.2 lb.)
24
24£
HI 8710E HI 8710T
Range 0.00 to 14.00 pH Resolution 0.01 pH Accuracy ±0.02 pH ±0.5% Typical EMC Dev. ±0.1 pH / ±0.2 mA Installation Category II Input 1012 Ohm 4 to 20 mA Calibration Offset: ±2 pH with Δ0 trimmer
Slope: 80 to 110% with slope trimmer
Temperature Fixed or automatic with Pt100 Compensation from 0 to 100°C (32 to 212°F)
Relays 1 for setpoint and 1 for alarm,
max 2A, 240 V resistive load (isolated)
Recorder Output 0-20 mA or 4-20 mA (isolated) Power Supply 115 or 230 Vac; 50/60 Hz Environment -10 to 50°C (14 to 122°F);
RH max 95% non condensing
Panel Cutout 141 x 69 mm (5.6 x 2.7'') Weight 1 kg (2.2 lb.)
HI 8711E HI 8711T
Range 0.00 to 14.00 pH Resolution 0.01 pH Accuracy ±0.02 pH ±0.5% Typical EMC Dev. ±0.1 pH / ±0.2 mA Installation Category II Input 1012 Ohm 4 to 20 mA Calibration Offset: ±2 pH with Δ0 trimmer
Slope: 80 to 110% with slope trimmer
Temperature Fixed or automatic with Pt100 Compensation from 0 to 100°C (32 to 212°F)
Relays 2 for setpoint and 1 for alarm,
max 2A, 240 V resistive load (isolated)
Recorder Output 0-20 mA or 4-20 mA (isolated) Power Supply 115 or 230 Vac; 50/60 Hz Environment -10 to 50°C (14 to 122°F);
RH max 95% non condensing
Panel Cutout 141 x 69 mm (5.6 x 2.7'') Weight 1 kg (2.2 lb.)
25
INITIAL PREPARATION
HI 8720E HI 8720T
Range ±1000 mV Resolution 1 mV Accuracy ±5 mV ±0.5% Typical EMC Dev. ±6 mV / ±0.2 mA Installation Category II Input 1012 Ohm 4 to 20 mA Calibration Slope: 90 to 110% with slope trimmer Relays 1 for setpoint and 1 for alarm,
max 2A, 240 V resistive load (isolated)
Recorder Output 0-20 mA or 4-20 mA (isolated) Power Supply 115 or 230 Vac; 50/60 Hz Environment -10 to 50°C (14 to 122°F);
RH max 95% non condensing
Panel Cutout 141 x 69 mm (5.6 x 2.7'') Weight 1 kg (2.2 lb.)
Connect a 3-wire cable to
the power supply terminal according to the voltage level as indicated, and pay par­ticular attention to the correct live, earth and neutral connections.
For E models, connect the electrode to the BNC plug on the rear panel.
For T models, connect the 2 signal wires of the analog transmitter to the "IN/OUT TRANSMITTER" terminals, while paying attention to the indicated polarity.
Recorder output terminals: these contacts are used for connection to a recorder. The output can be 0-20 mA or 4-20 mA depending on model, and is proportional to the pH or ORP reading.
Pt100 terminals: these con­tacts are used to connect the Pt100 temperature sensor for automatic tem­perature compensation of pH readings. If temperature com­pensation is not required, connect a 110 Ohm/0.25W resistor across the terminals (equivalent to a fixed tem­perature of 25°C/77°F).
FUSE
L
110
220
FUSE
ELECTRODE INPUT
+
mA OUT
-
PT100
26
26£
27
The HI 8710 models are single dosage controllers with acid/alkaline selection.
If acid dosage is needed (e.g. in chromium VI reduction), leave open the ACID/BASE selection
OPEN: ACID SHORT: BASE
terminals (see picture), while for alkaline dosage (e.g. in cyanide oxidation), make a short circuit across the ACID/BASE selection
OPEN: ACID SHORT: BASE
terminals with a jumper wire.
The HI 8720 models are single dosage controllers with oxidant/reductant selection.
If oxidant dosage is needed (e.g. in cyanide oxidation), leave open the OX/RED selection terminals (see
OPEN: OXD SHORT: RDX
picture), while for reductant dosage (e.g. in chromium VI reduction), make a short circuit across the OX/RED selection terminals with a
OPEN: OXD SHORT: RDX
jumper wire.
Set contacts (HI 8710 and HI 8720): these contacts (max. 2A, 240 V) are used to connect the dosing pump, and act only
SET
FUSE
FUSE
as a switch for the power to the drive.
Acid contacts (HI 8711): these contacts are used to connect the dosing pump for acid, and act as a switch
ACID
FUSE
FUSE
for the power to the drive.
Base contact (HI 8711): these contacts are used to connect the dosing pump for base, and act as a
BASE
FUSE
FUSE
switch for the power to the drive.
Consent contacts (HI 8710 and HI 8720): these contacts (max. 2A, 240V) are used for reduction and oxidation reactions when the pH controller works in conjunction with an ORP controller and vice versa. In these applications, the consent contacts of both meters are connected together to link the ORP and pH controllers, so that ORP dosage will occur only if the actual pH value is correct. This feature avoids overdosages which may lead to undesirable pollution. For HI 8710, the "Consent" contacts can be left open if the instrument is used independently as pH controller only. For HI 8720, the "Consent" contacts should be shorted if the instrument is used inde­pendently as ORP controller only.
Alarm contacts (HI 8710, HI 8711 and HI 8720): if the
ALARM
pH or ORP measurement is not within the set value
FUSE
FUSE
tolerance, the alarm contact is closed.
Note: All external cables connected to the rear
panel should be ended with cable lugs.
28
28£
29
OPERATIONAL GUIDE
ΔAL
ΔAL
All instrument settings are made via front panel keys and trimmers.
When each key is pressed, the corresponding LED lights up to show the operating function.
If using a model with input from electrode, make sure that the meter is calibrated before starting any operation (see "Calibration" section for details).
Using a small screwdriver adjust the ACID SET COARSE and FINE trimmers to display the desired acid set value.
ACID
BASE
SET
SET
COARSE
ACID SET
FINE
pH
To set the working point for alkaline dosage, press the BASE SET key and the display will show the set value for base dosage.
SET POINTS (HI 8710 and HI 8720)
To set the working point for pH or ORP dosage, press SET and the display will show the set value.
SET
COARSE
SET
FINE
pH
Using a small screwdriver adjust the COARSE and FINE trimmers to display the desired set value.
SET
COARSE
SET
FINE
pH
SET POINTS (HI 8711)
To set the working point for acid dosage, press the ACID SET key and the display will show the set value for acid dosage.
ACID
BASE
SET
SET
COARSE
BASE SET
FINE
pH
Using a small screwdriver adjust the BASE SET COARSE and FINE trimmers to display the desired base set value.
ACID
BASE
SET
SET
pH
BASE SET
COARSE
FINE
ALARMS (HI 8710, HI 8711 and HI 8720)
To set the alarm tolerance, press ΔAL key and the display will show the current value.
pH
ACID
BASE
SET
SET
COARSE
ACID SET
FINE
30
pH
30£
Using a small screwdriver adjust the ΔAL trimmer to display the desired tolerance.
31
ΔAL
ΔAL
pH
the ACID LED lights up, while during alkaline dosage, the BASE LED turns on (HI 8710 only).
ACID BASE
MEA
SURE
SLOPEDOSAGE
ΔAL
SET
COARSE
SET
FINE
When acid dosage is active,
Examples: For HI 8710, if the set value is pH 3 and the
ΔAlarm is 1.5 pH, the instrument generates an alarm every time the pH reading is higher than 4.5 pH or lower than 1.5pH.
For HI 8711, if the set values are pH 7 and pH 8, and the Δ Alarm is 1.5 pH, the instru­ment generates an alarm every time the pH reading is higher than 9.5 pH or lower than
5.5 pH. For HI 8720, if the set value is 300 mV and the
ΔAlarm is 100 mV, the instrument generates an alarm every time the ORP reading is higher than 400 mV or lower than 200 mV.
MEASUREMENTS
After setting the pH (or ORP) and alarm (if available) thresholds, immerse the elec-
MEA
SURE
COARSE
SET
FINE
trode in the solution to be tested and press MEASURE.
The actual pH or ORP value of the test solu­tion is displayed.
When oxidant dosage is active, the OXID LED lights up, while during reductant dosage, the REDUC LED turns on (HI 8720 only).
OXID. REDUC.
MEA
SURE
SLOPEDOSAGE
ΔAL
SET
COARSE
SET
FINE
pH
32
mV
32£
33
pH CALIBRATION
Make sure that the instrument is in measurement mode (MEASURE LED is on) before proceeding with calibration.
Rinse pH electrode and thermometer probe thoroughly with water, then immerse them in pH4.01 (HI 7004) or pH 10.01 (HI 7010) buffer solution.
MEA
SURE
COARSE
SET
FINE
Note: For accurate readings, use pH 4.01 if
you are going to measure acid samples or pH 10.01 for alkaline measurements.
Measure the temperature of the calibration buffer with a
°C
ChecktempC or another accurate thermometer.
Remove the protective cap from the electrode, rinse and
HI 7007
(1½")
4 cm
immerse in pH 7.01 solution (HI 7007).
Note: The electrode should be
submerged at least 4
°C
cm (1½") into the solu­tion. The thermometer should be located as close as possible to the
HI 7004
(1½")
4 cm
pH electrode.
Shake briefly and wait one minute before adjusting the Δ0 trimmer to display the buffer solution value, i.e. "pH 7.01" at 25°C (77°F).
DOSAGE
SLOPE
ACID BASE
ΔO
MEA
SET
SURE
COARSE
SET
FINE
pH
Shake briefly and wait one minute before adjusting the slope trimmer to display the ph value of the buffer solution, i.e. pH 4.01 (or
10.01) at 25°C (77°F).
DOSAGE
SLOPE
ACID BASE
ΔO
MEA
SET
SURE
COARSE
SET
FINE
pH
If the buffer solution temperature is different from 25°C (77°F), refer to the "pH vs. temperaturare" chart on page 36 for the ap­propriate pH value at the noted temperature.
The calibration is now complete and the in­strument is ready for use.
Note: If a Pt100 temperature sensor is used,
immerse it into the buffer solutions during calibration.
If the buffer solution temperature is different from 25°C (77°F), refer to the "pH vs. temperaturare" chart on page 36 for the ap­propriate pH value at the noted temperature.
34
34£
35
pH VALUES AT VARIOUS
SENSOR
TEST
TEMPERATURE
pH DIAGNOSTIC TESTS
Temperature has an effect on the pH. The calibration buffer solutions are affected by temperature changes to a lesser degree than normal solutions.
Please refer to the following chart to perform the pH calibration:
TEMP pH VALUE
°C °F 4.01 6.86 7.01 9.18 10.01
0
32
4.01
10 15 20 25 30 35 40 45 50 55 60 65 70
6.98
5
41
4.00
6.95
50
4.00
6.92
59
4.00
6.90
68
4.00
6.88
77
4.01
6.86
86
4.02
6.85
95
4.03
6.84
104
4.04
6.84
113
4.05
6.83
122
4.06
6.83
131
4.07
6.84
140
4.09
6.84
149
4.11
6.85
158
4.12
6.85
7.13
7.10
7.07
7.04
7.03
7.01
7.00
6.99
6.98
6.98
6.98
6.98
6.98
6.99
6.99
9.46
9.39
9.33
9.27
9.22
9.18
9.14
9.10
9.07
9.04
9.01
8.99
8.97
8.95
8.93
10.32
10.24
10.18
10.12
10.06
10.01
9.96
9.92
9.88
9.85
9.82
9.79
9.77
9.76
9.75
HI 8510, HI 8710 and HI 8711 are provided with autodiagnostic functions that allow to check and troubleshoot any malfunctioning.
The functions are made via front panel keys to isolate the cause of malfunction whether it is due to pH electrode contamination, internal offset circuit or amplifier circuit.
Follow the procedure described below. First press the MEASURE
key, then one of the following keys.
MEA
SURE
COARSE
SET
FINE
A) Sensor Test
Immerse the electrode in pH7.01 buffer solution (HI 7007), press SENSOR
HI 7007
(1½")
4 cm
TEST key and the display shows the mV response of the electrode.
mV
If the electrode is in good working condi­tion, the value should be within ±30 mV.
For instance, if the buffer temperature is 25°C (77°F), calibrate to read on the display pH
4.01 or 7.01 or 10.01. If the buffer temperature is 20°C, calibrate to
read on the display pH 4.00 or 7.03 or 10.06. If the buffer temperature is 50°C, calibrate to
A value between 30 and 60 mV or -60 and
-30 mV, indicates some contamination of the electrode.
If the value is higher than 60mV or lower than -60 mV, the contamination is too high and the electrode should be replaced.
read on the display pH 4.06 or 6.98 or 9.82.
36
36£
37
B) Internal Offset Circuit Test
Press the pH7 TEST key and the display should show a value within 7±1 pH, to verify the internal circuit of the meter in terms of the offset compensation.
pH 7 TEST
pH
ORP DIAGNOSTIC TESTS
HI 8512 and HI 8720 are ORP controllers
provided with autodiagnostic functions that allow to check and troubleshoot any malfunctioning. The functions are made via front panel keys to isolate the cause of malfunction.
C) Amplifier Circuit Test
Press the pH4 TEST key and the display should show a value within the 3.30 to
4.30 pH range, to verify the amplifier circuit of the meter.
pH 4
TEST
pH
For HI 8720 only, press MEASURE key before proceeding with the following tests.
A) 0 mV Test
Press the 0 mV TEST key and the display should show a value of 0±10 mV, to verify the "zero" calibration of the instrument.
B) 500 mV Test
Press the 500 mV TEST key and the display should show a value of 500±20 mV, to verify the slope at 500 mV.
MEA
SURE
COARSE
SET
FINE
mV
500 mV
0 mV
TEST
TEST
mV
500 mV
0 mV
TEST
TEST
38
38£
39
LED INDICATION
TAKING REDOX MEASUREMENTS
All LEDs above the keys indicate the state of each function, whether it is active or the display is indicating the mode.
For HI 8711 only
Each LED can be in one of the following states:
A)Light on The mode is displayed
on the LCD but is not active, e.g. the alarm setpoint is displayed but the alarm contact is open.
B)Light blinking 25% on, 75% off
The mode is not dis­played but it is active, e.g. the alarm contact is closed but the alarm setpoint is not displayed.
C)Light blinking 75% on, 25% off
The mode is active and being displayed.
D)Light off The function is neither
active nor displayed.
40
40£
Redox measurements allow the quantifica­tion of the solution oxidizing/reducing power, and are commonly expressed in mV.
Oxidation may be defined as the process during which a molecule (or an ion) loses electrons and reduction as the process by which electrons are gained.
Oxidation is always coupled together with reduction, so that as one element gets oxi­dized, the other is automatically reduced, therefore the term oxidation-reduction is fre­quently used.
Redox potentials are measured by an elec­trode capable of absorbing or releasing elec­trons without causing any chemical reaction.
The most common ORP electrodes are provided with gold or platinum surfaces; gold features a higher resistance than platinum in conditions of strong oxidation, while platinum is preferred for measuring oxidizing solutions containing halides, and for general purposes.
When a platinum electrode is immersed in an oxidizing solution, a monomolecular layer of oxygen is developed on its surface. This layer does not prevent the electrode from function­ing, but it increases the response time. The opposite effect is obtained when the platinum surface absorbs hydrogen in the presence of reducing mediums. This phenomenon is rough on the electrode.
To make correct redox measurements, it is necessary that the surface of the electrode is clean and smooth, and that a preventive treatment is performed.
Because the Pt/PtO system depends on the solution pH level, the electrode pre-treatment may be determined by the pH and the redox potential of the solution to be measured.
41
Generally, if the ORP (mV) reading corre­sponding to the pH solution value is higher than the value in the table below, an oxidizing pre-treatment is necessary; otherwise a re­ducing pre-treatment is necessary:
pH m V pH m V pH mV pH m V p H mV 0 990 1 920 2 860 3 800 4 740 5 680 6 640 7 580 8 520 9 460 10 400 11 340 12 280 13 220 14 16 0
Reducing pre-treatment: immerse the elec­trode for some minutes in HI 7091 solution.
Oxidizing pre-treatment: immerse the elec­trode for some minutes in HI 7092 solution.
If no pre-treatment is performed, the elec­trode will have long response times.
If working with refillable electrodes, always check the internal electrolyte level and refillwith HI 7071 solution, if necessary (the level must be at least 2.5 cm below the filling hole).
If measurements are taken in solutions con­taining sulfides or proteins, the cleaning of the electrode junction must be performed (see "Cleaning Procedure" section for details).
To check the correct functioning of the ORP electrode, immerse it into HI 7020 test solution and verify that the reading is within 200 and 275 mV.
After the test, rinse the electrode thoroughly with water and proceed with the oxidizing or reducing pre-treatment before taking any measurement.
When not in use, the electrode tip should be kept moist and far from any type of mechani­cal stress which might cause damage. For this reason, it is reccommended to store the electrode with a few drops of HI 70300 storage solution in the supplied protective cap.
ELECTRODE MAINTENANCE
Reference Filling Hole
Reference Filling Hole
Fill Hole Screw
Sensitive Wire
Reference Wire
Reference Junction
Glass Bulb
Reference Wire
Reference Junction
Platinum or Gold tip
Plastic Body
pH Electrode
Reference
Plastic Body
ORP Electrode
Glass Body
pH Electrode
Wire
Glass Body
ORP Electrode
Reference
Wire
Sensitive
Wire
Reference
Junction
Glass
Bulb
Reference
Junction
Platinum or
Gold tip
PREPARATION
Remove the protective cap. DO NOT BE ALARMED IF ANY SALT DE-
POSITS ARE PRESENT. This is normal with electrodes and they will disappear when rinsed with water.
During transport tiny air bubbles may form in­side the glass bulb, and the electrode cannot function properly under these conditions. Remove the bubbles by "shaking down" the electrode as you would do with a glass thermometer.
42
42£
43
If the bulb and/or junction are dry, soak the electrode in HI 70300 storage solution for at least one hour.
For refillable electrodes:
If the internal electrolyte solution is more than 1cm (½") below the filling hole, add HI 7082 solution (3.5M KCl) for double junction electrodes or HI 7071 (3.5M KCl+AgCl) for single junction electrodes.
For a faster response unscrew the filling hole screw during measurements.
For AmpHel® electrodes:
If the electrode does not respond to pH changes, the battery is run down and the electrode should be replaced.
MEASUREMENT
Rinse the electrode tip with distilled water. Immerse the electrode tip (4 cm) in the sample
and stir gently for approximately 30 seconds. For a faster response and to avoid cross
contaminations, before taking measurements, rinse the electrode tip with some solution to be tested.
STORAGE
To minimize clogging and assure a quick response time, the electrode glass bulb and junction should be kept moist at any time.
Store the electrode with a few drops of HI70300 storage solution in the protective cap (in its absence, use HI 7071 electrolyte for single junction, or HI 7082 for double junc­tion electrodes).
Follow the above "Preparation Procedure" be­fore taking measurements.
Note: NEVER STORE THE ELECTRODE IN
DISTILLED WATER OR DRY.
PERIODIC MAINTENANCE
Inspect electrode and cable. The cable used for the connection to the meter must be intact and there must be no points of broken insula­tion on the cable or cracks on the electrode stem or bulb.
Connectors must be perfectly clean and dry. If any scratches or cracks are noted, replace the electrode.
Rinse off any salt deposits with water.
For refillable electrodes:
Refill the electrode with fresh electrolyte solution (HI 7071 for single junction electrodes or HI 7082 for double junction). Allow the electrode to stand upright for 1 hour.
Follow the above "Storage Procedure".
CLEANING PROCEDURE
General Soak in HI 7061 general cleaning
solution for approximately 1 hour.
Removal of films, dirt or deposits on the mem­brane/junction:
Protein Soak in Hanna HI 7073 protein
cleaning solution for 15 minutes.
Inorganic Soak in Hanna HI 7074 inorganic
cleaning solution for 15 minutes.
Oil/grease Rinse with Hanna HI 7077 oil &
fat cleaning solution.
IMPORTANT: After performing any of the cleaning procedures, rinse the electrode thor­oughly with distilled water, drain and refill the reference chamber with fresh electrolyte, (not necessary for gel-filled electrodes) and soak the electrode in HI 70300 storage solution for at least 1 hour before taking measurements.
AmpHel® is a registered Trademark of "Hanna Instruments"
44
44£
45
TROUBLESHOOTING
Evaluate your electrode performance based on the following:
Noise (readings fluctuate up and down) could be due to:
- Clogged/Dirty Junction: refer to the
above "Cleaning Procedure"
- Loss of shielding due to low electrolyte
level (in refillable electrodes only): refill with HI 7071 solution for single junction or HI 7082 for double junction electrodes
Dry Membrane/Junction: soak in HI70300 storage solution for at least 1 hour
Drifting: soak the electrode tip in warm HI7082 solution for one hour and rinse the
tip with distilled water; refill with fresh electrolyte (HI 7071 for single junction and
HI 7082 for double junction electrodes)
Low Slope: refer to the above "Cleaning
Procedure"
No Slope: check the electrode for cracks in glass stem or bulb (replace the elec­trode if cracks are found)
Slow Response/Excessive Drift: soak the tip in HI 7061 solution for 30 minutes, rinse thoroughly in distilled water and then follow the above "Cleaning Procedure"
For ORP Electrodes: polish the metal tip with a light abrasive paper (pay attention not to scratch the surface) and rinse thoroughly with water
SUGGESTED INSTALLATIONS
SHORT DISTANCE, INDOOR INSTALLATION
Due to the low current involved, a very high grade of insulation is required. A dry environment is needed in order to ob­tain a insulation level not lower than 1012Ω. This type of connection is very delicate and requires constant attention to maintain proper operating conditions. Conventional electrodes should be used in indoor applications only, with a cable not longer than 10 m (33').
MAXIMUM 10 METERS
DRY ENVIRONMENT
LESS THAN 80%
RELATIVE HUMIDITY
pH METER
pH-ORP METER
WITH CONVENTIONAL ELECTRODES
MEASUREMENTS CAN BE
TAKEN FROM DISTANCES UP TO
10 METERS (33 FEET)
MEDIUM DISTANCE, INDOOR/OUTDOOR INSTALLATION
When an outdoor installation is required, to obtain accurate readings at distances from 10 to 50 m (33-165'), it is necessary to install a transmitter. Since the introduction of AmpHel® electrodes, these distances are no longer a problem. You can now connect the meter directly to an AmpHel® electrode, saving the cost of a transmitter or expensive coaxial cable. The standard cable length for AmpHel electrodes is 5 m (16.5'). Additional lengths
®
46
46£
47
of regular cable up to 50 m (165'), can be installed without special connectors. AmpHel® electrodes feature a built-in a micro­amplifier to boost the signal, drastically re­ducing susceptibility to noise and drift. The sealed electrode body can stand a mois­ture up to 100% RH without any effect on the signal.
MAXIMUM 50 METERS
WET ENVIRONMENT
RELATIVE HUMIDITY UP TO 100%
pH-ORP METER
pH METER
WITH AN AmpHel ELECTRODE
MEASUREMENTS CAN BE
TAKEN FROM DISTANCES UP TO
®
50 METERS (165 FEET)
LONG DISTANCE INSTALLATIONS, ISOLATED OUTPUT FOR PC INTERFACE
If the needed installation distance is greater than 50 m (165'), it is necessary the use of a transmitter. HANNA instruments® offers a full line of pH and ORP transmitters with or without display.
3m
RELATIVE HUMIDITY UP TO 100%
AmpHel® is a registered Trademark of "Hanna Instruments"
MAXIMUM 300 METERS
WET ENVIRONMENT
WITH A pH TRANSMITTER AND
TAKEN FROM DISTANCES UP TO
48
pH-ORP METER
pH METER
CONVENTIONAL ELECTRODE
MEASUREMENTS CAN BE
300 METERS (1000 FEET)
48£
ACCESSORIES
pH CALIBRATION SOLUTIONS
HI 7004M pH 4.01 buffer solution, 230 mL HI 7004L pH 4.01 buffer solution, 500 mL HI 7006M pH 6.86 buffer solution, 230 mL HI 7006L pH 6.86 buffer solution, 500 mL HI 7007M pH 7.01 buffer solution, 230 mL HI 7007L pH 7.01 buffer solution, 500 mL HI 7009M pH 9.18 buffer solution, 230 mL HI 7009L pH 9.18 buffer solution, 500 mL HI 7010M pH 10.01 buffer solution, 230mL HI 7010L pH 10.01 buffer solution, 500 mL
ORP SOLUTIONS
HI 7020M ORP test solution @200/275 mV,
230 mL bottle
HI 7020L ORP test solution @200/275 mV,
500 mL bottle
HI 7091M Pre-treatment reducing solution,
230 mL bottle
HI 7091L Pre-treatment reducing solution,
500 mL bottle
HI 7092M Pre-treatment oxidizing solution,
230 mL bottle
HI 7092L Pre-treatment oxidizing solution,
500 mL bottle
ELECTRODE MAINTENANCE SOLUTIONS
HI 70300M Storage solution, 230 mL bottle HI 70300L Storage solution, 500 mL bottle HI 7061M General cleaning, 230 mL bottle HI 7061L General cleaning, 500 mL bottle HI 7073M Protein cleaning solution, 230 mL HI 7073L Protein cleaning solution, 500 mL HI 7074M Inorganic cleaning, 230 mL HI 7074L Inorganic cleaning, 500 mL HI 7077M Oil & fat cleaning, 230 mL HI 7077L Oil & fat cleaning,500 mL HI 7071 3.5M KCl+AgCl electrolyte
solution (4 x 50 mL)
HI 7072 1M KNO3 electrolyte (4 x 50 mL) HI 7082 3.5M KCl electrolyte solution (4
x 50 mL)
49
PG13.5 THREAD
110mm30mm
D
3/4 x 16 UNF
D
3/4 x 16 UNF
D
DIA 9.5mm
110mm
D
3/4 x 16 UNF
pH ELECTRODES
PG13.5 THREAD
m
110mm30mm
DIA 9.5mm
3
110mm
D
M13 x 1.5
A 6 m
mm
mm
PG13.5 THREAD
m
110mm30mm
D
3/4 x 16 UNF
M13 x 1.5
A 6 m
mm
mm
150mm
DIA 16.5mm
M13 x 1.5
A
6 m
mm
mm
HI 1090T Screwcap PG13.5 connector,
double junction, glass body
φ 12mm φ 9.5m
HI 1110S Screw connector, single junction,
glass body
HI 1130B/3 BNC connector, 3 m (9.9') cable,
single junction, glass body
/4 x 16 UNF
DI
IA 20.5mm
1
m
25
7
HI 1110S HI 1130B/3
38.5mm
DIA 12mm
HI 1110T Screwcap PG13.5 connector,
double junction, glass body
φ 12mm φ 9.5m
5mm DIA 7.6mm
DI
1
m
25
7
HI 1115S HI 1135B/3
25mm
DIA 12mm
HI 1210T Screwcap PG13.5 connector,
double junction, plastic body
φ 12mm
HI 1910B BNC connector, 1 m (3.3') cable,
double junction, plastic body, built­in amplifier
DIA 12mm
IA 20.5mm
38.5mm
110mm
HI 1911B BNC connector, 1 m (3.3') cable,
double junction, plastic body, built­in amplifier
DIA 12mm
HI 1114S Screw connector, double junction,
plastic body
HI 1134B/3 BNC connector, 3 m (9.9') cable,
double junction plastic body
DIA 12mm
DI
1
IA 20.5mm
m
25
7
HI 1114S HI 1134B/3
38.5mm
110mm
HI 1115S Screw connector, single junction,
glass body
HI 1135B/3 BNC connector, 3 m (9.9') cable,
single junction, glass body
50
50£
IA 20.5mm
38.5mm
110mm
HI 1912B BNC connector, 1 m (3.3') cable,
double junction, plastic body, built­in amplifier
3/4 x 16 UNF
IA 20.5mm
38.5mm
DIA 12mm
HI 1912B/5 BNC connector, 5 m (16.5') cable,
double junction, plastic body, built­in amplifier
DIA 12mm
IA 20.5mm
38.5mm
51
110mm
PG13.5 THREAD
110mm30mm
D
3/4 x 16 UNF
M13 x 1.5
A
6 m
mm
mm
3/4 x 16 UNF
110mm
D
3/4 x 16 UNF
110mm
M13 x 1.5
DIA
16
mm
7
mm
25
mm
3/4 x 16 UNF
110mm
HI 2114B/5 BNC connector, 5 m (16.5') cable,
D
3/4 x 16 UNF
D
3/4 x 16 UNF
D
3/4 x 16 UNF
110mm
M13 x 1.5
A 6 m
mm
mm
PG13.5 THREAD
m
110mm30mm
DIA 16.5mm
M13 x 1.5
DIA
16
mm
7
mm
25
mm
double junction, plastic body
DIA 12mm
IA 20.5mm
HI 3210T Screwcap PG13.5 connector, Pt,
plastic body
φ 12mm
38.5mm
110mm
HI 2910B/5 BNC connector, 5 m (16.5') cable,
double junction, plastic body, built­in amplifier
DIA 12mm
IA 20.5mm
38.5mm
110mm
ORP ELECTRODES
HI 2930B/5 BNC connector, 5 m (16.5') cable,
Pt, plastic body, built-in amplifier
HI 3110S Screw connector, Pt, glass body HI 3130B/3 BNC connector, 3 m (9.9') cable,
Pt, glass body
DIA 12mm
DI
IA 20.5mm
1
m
25
7
HI 3110S HI 3130B/3
38.5mm
HI 3110T Screwcap PG13.5 connector, Pt,
glass body
φ 12mm φ 1m
HI 3115S Screw-type connector, side-arm,
Pt, glass body
HI 3135B/3 BNC connector, 3 m (9.9') cable,
side-arm, Pt, glass body
5mm DIA 7.6mm
DIA 12mm
HI 3410S Screw connector, Pt, plastic body HI 3430B/3 BNC connector, 3 m (9.9') cable,
Pt, plastic body
DIA 12mm
DI
IA 20.5mm
1
m
25
7
HI 3410S HI 3430B/3
38.5mm
110mm
HI 3932B/5 BNC connector, 5 m (16.5') cable,
Pt, plastic body, built-in amplifier
DIA 12mm
DIA 20.5mm
38.5mm
HI 4110S Screw connector, Au, glass body HI 4130B/3 BNC connector, 3 m (9.9') cable,
Au, glass body
DIA 12mm
IA 20.5mm
38.5mm
HI 4110S HI 4130B/3
HI 4932B/5 BNC connector, 5 m (16.5') cable,
Au, plastic body, built-in amplifier
DIA 12mm
DIA 20.5mm
38.5mm
25mm
HI 3115S HI 3135B/3
52
150mm
52£
53
OTHER ACCESSORIES
HI 98501 ChecktempC thermometer with
penetration probe and 0.1°C resolution (-50.0 to 150.0°C)
HI 8614 pH transmitter HI 8614L pH transmitter with display HI 8615 ORP transmitter HI 8615L ORP transmitter with display BL PUMPS Dosing pumps with flow rate from
1.5 to 20 lph
HI 7871 & HI 7873
Level controllers
HI 6050 & HI 6051
Submersible electrode holders
HI 6054 & HI 6057
Electrode holders for in-line applications
HI 778P Coaxial cable and connectors for
screw-type electrodes
HI 8427 pH/ORP electrode simulator with
1 m (3.3') coaxial cable ending with female BNC connectors (HI 7858/1)
HI 931001 pH/ ORP electrode simulator with
display and 1 m (3.3') coaxial cable ending with female BNC connectors (HI 7858/1)
WARRANTY
All Hanna Instruments meters are warranted for two years against defects in workmanship
and materials when used for their intended purpose and maintained according to instructions.
Probes, electrodes and sensors are warranted for a period of six months.
Damages due to accident, misuse, tampering or lack of prescribed maintenance are not covered. This warranty is limited to repair or replacement free of charge.
If service is required, contact the dealer from whom you purchased the instrument. If under warranty, report the model number, date of purchase, serial number and the nature of the failure. Obtain a Returned Goods Authorization from the Customer Service department first and then return the instrument with the Authorization # included along with shipment costs prepaid. If the repair is not covered by the warranty, you will be notified of the charge for repair or replacement. When shipping any instrument, make sure it is properly packaged for complete protection.
Recommendations for Users
Before using these products, make sure that they are entirely suitable for the environment in which they are used. Operation of these instruments in residential area could cause unacceptable interferences to radio and TV equipments, requiring the operator to take all necessary steps to correct interferences. The trimmers are sensitive to electrostatic discharges. It is recommended to use antistatic screwdrivers. Any variation introduced by the user to the supplied equipment may degrade the instruments' EMC performance. To avoid electrical shock, do not use these instruments when voltages at the measurement surface exceed 24 Vac or 60 Vdc. To avoid damages or burns, do not perform any measurement in microwave ovens.
54
54£
All rights are reserved. Reproduction in whole or in part is prohibited without the written consent of the copyright owner.
HANNA instruments reserves the right to modify
the design, construction and appearance of its
products without advance notice.
55
SALES & TECHNICAL SERVICE
Australia:
Tel. (03) 9769.0666 • Fax (03) 9769.0699
China:
Tel. (10) 88570068 • Fax (10) 88570060
Egypt:
Tel. & Fax (02) 2758.683
Germany:
Tel. (07851) 9129-0 • Fax (07851) 9129-99
Greece:
Tel. (210) 823.5192 • Fax (210) 884.0210
Indonesia:
Tel. (21) 4584.2941 • Fax (21) 4584.2942
Japan:
Tel. (03) 3258.9565 • Fax (03) 3258.9567
Korea:
Tel. (02) 2278.5147 • Fax (02) 2264.1729
Malaysia:
Tel. (603) 5638.9940 • Fax (603) 5638.9829
Singapore:
Tel. 6296.7118 • Fax 6291.6906
South Africa:
Tel. (011) 615.6076 • Fax (011) 615.8582
Taiwan:
Tel. 886.2.2739.3014 • Fax 886.2.2739.2983
Thailand:
Tel. 66.2619.0708 • Fax 66.2619.0061
United Kingdom:
Tel. (01525) 850.855 • Fax (01525) 853.668
USA:
Tel. (401) 765.7500 • Fax (401) 765.7575
For e-mail contacts and complete list of Sales and Technical offices, please see www.hannainst.com
56
MANPROCR3 10/05
56£
Loading...