First Aid Only 90599, FAE-4007, 90625, 90620, 90588 User Manual

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SAFETY DATA SHEET
This safety data sheet was created pursuant to the requirements of: US OSHA Hazard
Communication Standard (29 CFR 1910.1200) and Canada WHMIS 2015 which includes
the amended Hazardous Products Act (HPA) and the Hazardous Products Regulation
(HPR)
Issuing Date 08-Mar-2019 Revision Date 02-Jan-2020 Revision Number 1.1
1. Identification
Product identifier Product Name Other means of identification Product Code(s) UN/ID no Synonyms Recommended use of the chemical and restrictions on use Recommended use Restrictions on use Details of the supplier of the safety data sheet Manufacturer Address
WaterJel ® Technologies 50 Broad Street Carlstadt, NJ 07072 P: 201-507-8300
Emergency telephone number Emergency Telephone
Hand Sanitizer
910042.00.006 UN1170 Instant Hand Sanitizer Antiseptic Gel with Vitamin E & Aloe
Hand sanitizer For external use only.
800-275-3433 (8:00 am-5:00 pm EST Weekdays)
2. Hazard(s) identification
Classification
Flammable liquids Category 2
Label elements Danger Hazard statements
Highly flammable liquid and vapor
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Hand Sanitizer Revision Date: 02-Jan-2020
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Precautionary Statements - Prevention
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/eye protection/face protection.
Precautionary Statements - Response
.
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
Fire
In case of fire: Use CO2, dry chemical, or foam to extinguish.
Precautionary Statements - Storage
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant.
Other information
No information available.
3. Composition/information on ingredients
Substance
Not applicable.
Mixture Synonyms
Chemical name CAS No. Weight-%
Ethyl alcohol 64-17-5 45-70 - -
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Instant Hand Sanitizer Antiseptic Gel with Vitamin E & Aloe.
Hazardous Material Information Review
Act registry number
(HMIRA registry #)
4. First-aid measures
Description of first aid measures
Inhalation Eye contact
Remove to fresh air. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area.
Date HMIRA filed and
date exemption
granted (if
applicable)
Skin contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
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Hand Sanitizer Revision Date: 02-Jan-2020
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Ingestion Self-protection of the first aider
Most important symptoms and effects, both acute and delayed Symptoms
Indication of any immediate medical attention and special treatment needed Note to physicians
Clean mouth with water and drink afterwards plenty of water. Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use personal protective equipment as required. See section 8 for more information.
May cause redness and tearing of the eyes. May cause skin irritation in susceptible persons.
Treat symptomatically.
5. Fire-fighting measures
Suitable Extinguishing Media
Unsuitable extinguishing media Specific hazards arising from the
chemical
Explosion data
Sensitivity to mechanical impact Sensitivity to static discharge
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam.
CAUTION: Use of water spray when fighting fire may be inefficient. Risk of ignition. Keep product and empty container away from heat and sources of ignition.
In the event of fire, cool tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
None. Yes.
Special protective equipment for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures Personal precautions
Other information
Methods and material for containment and cleaning up Methods for containment
Methods for cleaning up
Evacuate personnel to safe areas. Use personal protective equipment as required. See section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material.
Ventilate the area.
Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.
Take precautionary measures against static discharges. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
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Hand Sanitizer Revision Date: 02-Jan-2020
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7. Handling and storage
Precautions for safe handling Advice on safe handling
Conditions for safe storage, including any incompatibilities Storage Conditions
Use personal protection equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to package label instructions.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep in properly labeled containers. Do not store near combustible materials. Keep in an area equipped with sprinklers. Store in accordance with the particular national regulations. Store in accordance with local regulations.
8. Exposure controls/personal protection
Control parameters Exposure Limits
Chemical name ACGIH TLV OSHA PEL NIOSH
Ethyl alcohol
64-17-5
Chemical name Alberta British Columbia Ontario Quebec
Ethyl alcohol
64-17-5
.
STEL: 1000 ppm TWA: 1000 ppm
TWA: 1000 ppm
TWA: 1880 mg/m3
STEL: 1000 ppm STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m3
IDLH: 3300 ppm TWA: 1000 ppm
TWA: 1900 mg/m3
TWA: 1880 mg/m3
Appropriate engineering controls Engineering controls
Individual protection measures, such as personal protective equipment Eye/face protection Hand protection
Skin and body protection
Respiratory protection
General hygiene considerations
Showers Eyewash stations Ventilation systems.
Tight sealing safety goggles. Wear suitable gloves. Impervious gloves.
Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron. Antistatic boots.
No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
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recommended. Wash hands before breaks and immediately after handling the product.
9. Physical and chemical properties
Information on basic physical and chemical properties Appearance
Physical state
Color Odor Odor threshold
Property Values Remarks • Method pH Melting point / freezing point Boiling point / boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limit in Air
Upper flammability or explosive limits Lower flammability or explosive
limits Vapor pressure Vapor density Relative density Water solubility Solubility(ies) Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity
Translucent liquid Liquid Clear to semi-clear Characteristic No information available
6.9 - 7.3 @ 25 °C No data available None known
79.4 °C / 174.9 °F
22.2 °C 72 °F CC (closed cup) No data available None known No data available None known
None known
No data available No data available No data available None known
No data available None known
0.87 - 0.91 @25°C Soluble in water No data available None known No data available None known No data available None known No data available None known No data available None known No data available None known
Other information Explosive properties Oxidizing properties Softening point Molecular weight VOC Content (%) Liquid Density Bulk density
No information available. No information available. No information available No information available No information available No information available No information available
10. Stability and reactivity
Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products
None under normal use conditions. Stable under normal conditions. None under normal processing. Heat, flames and sparks. None known based on information supplied. None known based on information supplied.
11. Toxicological information
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Information on likely routes of exposure
Inhalation
Eye contact
Skin contact Ingestion
Symptoms related to the physical, chemical and toxicological characteristics Symptoms
Acute toxicity Numerical measures of toxicity
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) ATEmix (inhalation-dust/mist)
Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Ethyl alcohol = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h
Specific test data for the substance or mixture is not available. Vapors may be irritating to eyes, nose, throat, and lungs.
Specific test data for the substance or mixture is not available. May cause redness, itching, and pain.
Specific test data for the substance or mixture is not available. May cause irritation. Specific test data for the substance or mixture is not available. May cause gastrointestinal
discomfort if consumed in large amounts.
May cause redness and tearing of the eyes. May cause skin irritation in susceptible persons.
10,844.90 mg/kg
191.60 mg/l
Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical name ACGIH IARC NTP OSHA
Ethyl alcohol
64-17-5
Legend
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
May cause mild to moderate irritation. May cause mild to moderate irritation. No information available. No information available. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
alcoholic beverage.
A3 Group 1 Known X
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Reproductive toxicity STOT - single exposure STOT - repeated exposure Target organ effects Aspiration hazard
12. Ecological information
Ecotoxicity
Chemical name Algae/aquatic plants Fish Toxicity to
Ethyl alcohol
64-17-5
Persistence and degradability Bioaccumulation
No information available. No information available. No information available. liver, Respiratory system, Eyes, Skin, Central nervous system, blood, Reproductive System. No information available.
.
Crustacea
microorganisms
- LC50: 12.0 - 16.0mL/L (96h, Oncorhynchus
mykiss) LC50: 13400 -
15100mg/L (96h, Pimephales promelas) LC50: >100mg/L (96h, Pimephales promelas)
No information available. There is no data for this product.
- LC50: 9268 ­14221mg/L (48h,
Daphnia magna) EC50:
=2mg/L (48h, Daphnia
magna)
Component Information
Chemical name Partition coefficient
Ethyl alcohol
64-17-5
Mobility in soil Mobility Other adverse effects
13. Disposal considerations
Waste treatment methods Waste from residues/unused
products Contaminated packaging
US EPA Waste Number
California Hazardous Waste Status
-0.32
No information available. No information available. No information available.
Should not be released into the environment. Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Empty containers pose a potential fire and explosion hazard. Do not cut, puncture or weld containers.
D001.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical name California Hazardous Waste Status
Ethyl alcohol Toxic
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64-17-5 Ignitable
14. Transport information
DOT
UN/ID no Proper shipping name Hazard class Packing group Special Provisions Description Emergency Response Guide Number
TDG
UN/ID no Proper shipping name Hazard class Packing group Special Provisions Description
MEX
UN/ID no Proper shipping name Hazard class Special Provisions Packing group Description
IATA
UN number UN proper shipping name Transport hazard class(es) Packing group ERG Code Special Provisions Description
UN1170 ETHANOL SOLUTION 3 II 24, IB2, T4, TP1 UN1170, ETHANOL SOLUTION, 3, II 127
UN1170 ETHANOL SOLUTION 3 II 150 UN1170, ETHANOL SOLUTION, 3, II
UN1170 ETHANOL SOLUTION 3 144 II UN1170, ETHANOL SOLUTION, 3, II
UN1170 Ethanol solution 3 II 3L A180, A3, A58 UN1170, Ethanol solution, 3, II
IMDG
UN number UN proper shipping name Transport hazard class(es) Packing group EmS-No Special Provisions Description
Not regulated UN1170 ETHANOL SOLUTION 3 II F-E, S-D 144 UN1170, ETHANOL SOLUTION, 3, II, (22.2°C C.C.)
15. Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture International Regulations The Montreal Protocol on Substances that Deplete the Ozone Layer Not applicable The Stockholm Convention on Persistent Organic Pollutants Not applicable The Rotterdam Convention Not applicable
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International Inventories TSCA DSL/NDSL
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications.
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
Contact supplier for inventory compliance status. Contact supplier for inventory compliance status.
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.
US State Regulations California Proposition 65
Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage.
U.S. State Right-to-Know Regulations US State Regulations
Chemical name New Jersey Massachusetts Pennsylvania
Ethyl alcohol
64-17-5
Propane-1,2-diol
57-55-6
U.S. EPA Label Information EPA Pesticide Registration Number
X X X X - X
Not applicable
16. Other information
NFPA Health hazards 1 Flammability 3 Instability 0 Physical and chemical
properties -
HMIS Health hazards 2 Flammability 3 Physical hazards 0 Key or legend to abbreviations and acronyms used in the safety data sheet
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Personal protection X
Hand Sanitizer Revision Date: 02-Jan-2020
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Legend Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value * Skin designation
Key literature references and sources for data used to compile the SDS
U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) Japan GHS Classification Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organization for Economic Co-operation and Development Environment, Health, and Safety Publications Organization for Economic Co-operation and Development High Production Volume Chemicals Program Organization for Economic Co-operation and Development Screening Information Data Set World Health Organization
Issuing Date Revision Date Revision Note Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
08-Mar-2019 02-Jan-2020 SDS sections updated: 14.
End of Safety Data Sheet
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