Material Safety Data Sheet
Issuing Date 5/18/2011 Revision Date 8/6/2012 Revision Number 2
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name
Product Code(s)
Recommended Use
Company
Emergency Telephone Number
OSHA Regulatory Status
DPD #1 TABLET
6903
Test kit reagent for water testing. Industrial (not for food or food contact use).
LaMotte Company, Inc.
802 Washington Avenue
P.O. Box 329
Chestertown, MD 21620
USA
24 Hour Emergency Number (CHEM-TEL):
USA, Canada, Puerto Rico 1-800-255-3924
Outside North American Continent (Call collect) 813-248-0585
2. HAZARDS IDENTIFICATION
Emergency Overview
Harmful if swallowed
May cause skin, eye, and respiratory tract irritation
May produce an allergic reaction
Physical State Solid, TabletAppearance White
While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safe
handling and proper use of the product. This MSDS should be retained and available for
employees and other users of this product.
Odor Odorless
Potential Health Effects
Principle Routes of Exposure
Acute Toxicity
Eyes
Skin
Inhalation
Ingestion
Chronic Effects
Main Symptoms
Aggravated Medical Conditions
Interactions with Other Chemicals
Environmental Hazard
Skin contact, Ingestion.
May cause irritation.
May cause irritation.
May cause irritation of respiratory tract.
May be harmful if swallowed.
May produce an allergic reaction.
Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling
of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing.
None known.
None known.
No information available.
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DPD #1 TABLET Product Code(s) 6903
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
N,N-Diethyl-p-phenylenediamine sulfate
Polyamino carboxylic acid
Aromatic carboxylic acid salt
Phosphate salt -
Boric acid
Carboxylic acid - 15-25
Carbonate salt
Potassium salt Ingredients not specifically listed by name are proprietary to the LaMotte Company, registered under the State of New Jersey
Trade Secret protection law, assigned the NJTSRN#80100291-5002p, and may be disclosed only in a medical emergency.
CAS-No
6283-63-2
- 0 - 10%
- 1-5
10043-35-3 8
- 20-30
Weight %
5-10
25-30
1
4. FIRST AID MEASURES
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
Do not get in eyes, on skin, or on clothing.
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
If irritation persists or develops, contact a physician.
Wash off immediately with soap and plenty of water for at least 15 minutes. If irritation
develops or persists, consult physician.
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
respiration and contact emergency personnel. Call a physician immediately.
Do not induce vomiting without medical advice. Drink plenty of water. Clean mouth with
water. Never give anything by mouth to an unconscious person. Consult a physician.
Protection of First-aiders
Flammable Properties
Flash Point
Suitable Extinguishing Media
Explosion Data
NFPA
HMIS
Personal Precautions
Methods for Containment
Methods for Cleaning Up
Health Hazard 1
Health Hazard 1
Use personal protective equipment. See Section 8 for more detail. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
5. FIRE-FIGHTING MEASURES
Not a fire hazard.
Not applicable
Water spray, dry chemical, carbon dioxide (CO 2), or foam.
Flammability 0
Flammability 0
Stability 0
Stability 0
Physical and Chemical
Hazards N/A
6. ACCIDENTAL RELEASE MEASURES
Refer to Section 8.
Sweep up in a manner that does not dispurse dust and shovel into suitable containers for
disposal. Dispose according to federal, state, and local regulations.
If local regulations permit, dissolve and rinse to drain with excess water. After cleaning,
flush away traces with water.
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DPD #1 TABLET Product Code(s) 6903
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7. HANDLING AND STORAGE
Handling
Handle in accordance with good industrial hygiene and safety practice. Prevent contact with
skin, eyes, and clothing. Do not ingest. Do not eat, drink, or smoke when using this product.
Storage
Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep out of the
reach of children. Keep away from direct sunlight.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Chemical Name ACGIH TLV
N,N-Diethyl-p-phenylenediamine
sulfate
6283-63-2
Polyamino carboxylic acid None Known
Aromatic carboxylic acid salt None Known
Phosphate salt None Known None Known None Known
Boric acid
10043-35-3
Carboxylic acid None Known None Known None Known
Carbonate salt None Known None Known None Known
Potassium salt None Known None Known None Known
Engineering Measures
None Known None Known None Known
= 6 mg/m3 STEL
TWA: 2 mg/m
None under normal use conditions.
OSHA PEL NIOSH IDLH
None Known None Known
None Known None Known
3
None Known None Known
Personal Protective Equipment
Eye/Face Protection
Skin and Body Protection
Respiratory Protection
Hygiene Measures
Appearance
Physical State
Flash Point
Boiling Point/Range
Explosion Limits
Molecular Weight
Stability
Incompatible Products
Safety glasses with side-shields. Avoid contact with eyes.
Wear latex or nitrile gloves.
None required under normal usage.
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes and clothing. Wear suitable gloves and eye/face protection. Wash hands before
breaks and immediately after handling the product.
9. PHYSICAL AND CHEMICAL PROPERTIES
White
Solid, Tablet
Not applicable
No information available
Not applicable
No data available
Odor
pH
Autoignition Temperature
Freezing Point
Water Solubility
Odorless
6 (1 tablet in 10mL of water)
Not applicable
No information available
Soluble in water
10. STABILITY AND REACTIVITY
Stable.
None known based on information supplied.
Conditions to Avoid
Hazardous Decomposition Products
Exposure to air or moisture over prolonged periods. Direct sunlight.
None under normal use.
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DPD #1 TABLET Product Code(s) 6903
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Hazardous Polymerization
Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
LD50 Oral VALUE (mg/kg)
Chemical Name
N,N-Diethyl-p-phenylenediamine
sulfate
Polyamino carboxylic acid
Aromatic carboxylic acid salt
Phosphate salt
Boric acid
Carboxylic acid
Carbonate salt
Potassium salt 2600 mg/kg ( Rat )
Chronic Toxicity
Chronic Toxicity
Chemical Name ACGIH IARC NTP OSHA
N,N-Diethyl-p-phenylenedia
mine sulfate
Polyamino carboxylic acid None Known None Known None Known None Known
Aromatic carboxylic acid salt None Known None Known None Known None Known
Phosphate salt None Known None Known None Known None Known
Boric acid None Known None Known None Known None Known
Carboxylic acid None Known None Known None Known None Known
Carbonate salt None Known None Known None Known None Known
Potassium salt None Known None Known None Known None Known
Product does not present an acute toxicity hazard based on known or supplied information.
Oral Rat LD50: 195mg/kg for N,N-Diethyl-p-phenylenediamine sulfate
LD50 Oral
None Known None Known
2 g/kg ( Rat ) None Known
None Known None Known
None Known 4640 mg/kg ( Rabbit ) None Known
2660 mg/kg ( Rat ) 2000 mg/kg ( Rabbit )
3000 mg/kg ( Rat ) None Known
1440 mg/kg ( Rat ) 1.87 mg/kg ( Rat )
LD50 Dermal
None Known None Known
LC50 Inhalation
None Known
None Known
None Known
None Known
None Known
None Known
May produce an allergic reaction.
None Known None Known None Known None Known
Chemical Name EU - Endocrine Disrupters
N,N-Diethyl-p-phenylenediamine
sulfate
Polyamino carboxylic acid None Known None Known None Known
Aromatic carboxylic acid salt None Known None Known None Known
Phosphate salt None Known None Known None Known
Boric acid None Known None Known None Known
Carboxylic acid None Known None Known None Known
Carbonate salt None Known None Known None Known
Potassium salt None Known None Known None Known
Candidate List
None Known None Known None Known
EU - Endocrine Disruptors -
Evaluated Substances
Japan - Endocrine Disruptor
Information
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DPD #1 TABLET Product Code(s) 6903
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12. ECOLOGICAL INFORMATION
Ecotoxicity
No information available.
Chemical Name
N,N-Diethyl-p-phenylenedia
mine sulfate
Polyamino carboxylic acid
Aromatic carboxylic acid salt None Known
Phosphate salt None Known None Known None Known None Known
Boric acid None Known None Known None Known EC50 658 - 875 mg/L 48 h
Carboxylic acid None Known LC50= 1516 mg/L Lepomis
Carbonate salt None Known None Known None Known None Known
Potassium salt EC50 = 2500 mg/L 72 h LC50= 2010 mg/L Lepomis
Chemical Name Log Pow
N,N-Diethyl-p-phenylenediamine sulfate None Known
Polyamino carboxylic acid None Known
Aromatic carboxylic acid salt None Known
Phosphate salt None Known
Boric acid
Carboxylic acid -1.72 20 °C
Carbonate salt
Potassium salt None Known
Toxicity to Algae Toxicity to Fish
None Known
None Known LC50= 159 mg/L Lepomis
= -0.757 25 °C
None Known None Known
macrochirus 96 h
LC50= 320 mg/L Poecilia
reticulata 96 h
None Known None Known
macrochirus 96 h
LC50= 440 mg/L Leuciscus
idus 96 h
macrochirus 96 h
None Known
Microtox Daphnia Magna (Water
EC50 = 56 mg/L 8 h None Known
EC50 = 115.0 mg/L 48 h
EC50 = 14 mg/L 15 min EC50 = 120 mg/L 72 h
None Known EC50 = 825 mg/L 48 h
Flea)
None Known
None Known
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method
Contaminated Packaging
Chemical Name
N,N-Diethyl-p-phenylenedia
mine sulfate - 6283-63-2
Polyamino carboxylic acid -
Aromatic carboxylic acid salt
-
Phosphate salt - None Known None Known None Known
Boric acid - 10043-35-3 None Known None Known None Known None Known
Carboxylic acid - None Known None Known None Known None Known
Carbonate salt - None Known None Known None Known None Known
Potassium salt - None Known None Known None Known None Known
RCRA - Halogenated
Organic Compounds
Dispose of in accordance with local regulations.
Dispose of in accordance with local regulations.
RCRA - P Series Wastes
None Known None Known None Known
None Known None Known None Known None Known
None Known None Known None Known None Known
RCRA - F Series Wastes RCRA - K Series Wastes
None Known
None Known
14. TRANSPORT INFORMATION
DOT
IATA
IMDG/IMO
Not regulated
Not regulated
Not regulated
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DPD #1 TABLET Product Code(s) 6903
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15. REGULATORY INFORMATION
International Inventories
Component
N,N-Diethyl-p-phenyle
nediamine sulfate
6283-63-2 ( 1 )
Polyamino carboxylic
acid
( 0 - 10% )
Aromatic carboxylic
acid salt
( 1-5 )
Phosphate salt
( 5-10 )
Boric acid
10043-35-3 ( 8 )
Carboxylic acid
( 15-25 )
Carbonate salt
( 20-30 )
Potassium salt
( 25-30 )
TSCA DSL
TSCA
Present X
Present
Present X
Present
Present X X 2-1318 X KE-20831
Present X X 1-153 X KE-29083 X X
Present X X 1-228 X KE-29086 X X
DSL X 3-243 X
X X
X X
EINECS/ELINCSENCS
X 2-1265
3-1272;
3-1293
X 1-452
1-63 X
IECSC
X KE-13651
X
X KE-28622 X X
KECL
KECL X X
KE-02710 X
KE-03499 X
PICCS AICS
X X
X
X
X
X
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Chemical Name CAS-No Weight % SARA 313 - Threshold
N,N-Diethyl-p-phenylenediamine sulfate 6283-63-2 1 None Known
Polyamino carboxylic acid 0 - 10% None Known
Aromatic carboxylic acid salt 1-5 None Known
Phosphate salt 5-10 None Known
Boric acid 10043-35-3 8 None Known
Carboxylic acid 15-25 None Known
Carbonate salt 20-30 None Known
Potassium salt 25-30 None Known
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
Yes
No
No
No
No
Values %
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
Component CWA - Reportable
N,N-Diethyl-p-phenylenediamine
sulfate
6283-63-2 ( 1 )
Polyamino carboxylic acid
( 0 - 10% )
Aromatic carboxylic acid salt
( 1-5 )
Quantities
None Known None Known None Known None Known
None Known None Known None Known None Known
None Known None Known None Known None Known
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
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DPD #1 TABLET Product Code(s) 6903
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Phosphate salt
( 5-10 )
Boric acid
10043-35-3 ( 8 )
Carboxylic acid
( 15-25 )
Carbonate salt
( 20-30 )
Potassium salt
( 25-30 )
None Known
None Known
None Known
None Known
None Known
None Known None Known
None Known None Known
None Known None Known
None Known
None Known None Known
None Known None Known
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.
None Known
None Known
None Known
None Known
Chemical Name
N,N-Diethyl-p-phenyle
nediamine sulfate
Polyamino carboxylic
acid
Aromatic carboxylic
acid salt
Phosphate salt 5-10
Boric acid 10043-35-3
Carboxylic acid 15-25
Carbonate salt 20-30 None Known None Known None Known None Known
Potassium salt 25-30 None Known None Known None Known None Known
CAS-No Weight %
6283-63-2
1 None Known None Known None Known
0 - 10%
1-5 None Known
8 None Known None Known
HAPS data VOC Chemicals
None Known None Known
None Known None Known
None Known None Known
None Known
None Known None Known
Class 1 Ozone
Depletors
None Known None Known
None Known None Known
None Known None Known
Class 2 Ozone
Depletors
None Known
None Known
None Known
CERCLA
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs
N,N-Diethyl-p-phenylenediamine sulfate None Known None Known
Polyamino carboxylic acid None Known None Known
Aromatic carboxylic acid salt None Known None Known
Phosphate salt None Known None Known
Boric acid None Known None Known
Carboxylic acid None Known None Known
Carbonate salt None Known None Known
Potassium salt None Known None Known
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
Chemical Name CAS-No California Prop. 65
N,N-Diethyl-p-phenylenediamine sulfate 6283-63-2 None Known
Polyamino carboxylic acid None Known
Aromatic carboxylic acid salt None Known
Phosphate salt None Known
Boric acid 10043-35-3 None Known
Carboxylic acid None Known
Carbonate salt None Known
Potassium salt None Known
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island
N,N-Diethyl-p-phenylenedia
mine sulfate
Polyamino carboxylic acid None Known None Known None Known None Known None Known
Aromatic carboxylic acid salt None Known None Known None Known None Known None Known
Phosphate salt None Known None Known None Known None Known None Known
None Known None Known None Known None Known None Known
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Product Code(s) 6903DPD #1 TABLET
_____________________________________________________________________________________________
Boric acid None Known
Carboxylic acid
Carbonate salt
Potassium salt None Known
None Known
None Known
X None Known
None Known
None Known None Known
None Known None Known
None Known
None Known None Known
None Known
None Known None Known
None Known None Known
None Known
International Regulations
Mexico - Grade
Canada
Chemical Name Carcinogen Status
N,N-Diethyl-p-phenylenediamine sulfate
Polyamino carboxylic acid None Known None Known
Aromatic carboxylic acid salt
Phosphate salt None Known None Known
Boric acid None Known None Known
Carboxylic acid None Known None Known
Carbonate salt None Known None Known
Potassium salt None Known None Known
Component WHMIS Hazard Class
N,N-Diethyl-p-phenylenediamine sulfate
6283-63-2 ( 1 )
Polyamino carboxylic acid
( 0 - 10% )
Aromatic carboxylic acid salt
( 1-5 )
Phosphate salt
( 5-10 )
Boric acid
10043-35-3 ( 8 )
Carboxylic acid
( 15-25 )
Carbonate salt
( 20-30 )
Potassium salt
( 25-30 )
None Known None Known
None Known None Known
Not determined
Uncontrolled product according to WHMIS classification criteria
Not determined
Uncontrolled product according to WHMIS classification criteria
Uncontrolled product according to WHMIS classification criteria
Exposure Limits
1 %
D2A
1 %
E
1 %
D2B E
16. OTHER INFORMATION
HMISNFPA
PPE
Transport Symbol
(Bad file name)
Prepared By
Issuing Date
Revision Date
Revision Note
_____________________________________________________________________________________________
Published Date: 07-Aug-2012
Regulatory Affairs Department
5/18/2011
07-Aug-2012
Initial Release. (M)SDS sections updated. 3.
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DPD #1 TABLET Product Code(s) 6903
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Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.
End of MSDS
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