Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
1/8
Product Name (Product code)
:
LC20EM(LK9834001), LC22EM(LK9846001), LC23EM(LKB451001), LC201M(LK9290001),
LC203M(LK77
LC215M(LK8646001), LC221M(LK9318001), LC223M(LK8388001), LC225XLM(LK8420001),
LC231M(LKB288001), LC233M(LK8898001), LC235XLM(LK8922001), LC261M(LKB324001),
LC263M(LKB264001), LC645M, LC663M(L
LC673M(LK9078001), LC675XLM(LK9048001), LC695XLM(LK9665001)
Use of the substance/mixture
:
These products are dark red ink in a cartridge for Brother Industries, Ltd. inkjet multifunction
devices and fax receivers. The cartridge should be used as supplied by Brother and for use in
the products stated. Information provided on this SDS is only consistent with the use specified by
Brother
Emergency number
:
CHEMTREC
+1
+1
For France only:
Antipoison Center telephone number: ORFILA +33
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
SECTION 1: Identification of the substance/mixture and of the compan y/undertaking
1.1. Product identifier
Date of issue: 26 September
Revision date: 1 April 201
48001), LC205M(LK8310001), LC211M(LK9346001), LC213M(LK8548001),
SDS No:BHM026–01-
Version: 3
K8946001), LC665XLM(LK8970001),
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Manufacturer Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada) Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe) Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address sds.info@brother.co.jp
1.4. Emergency telephone number
-703-527-3887 (International)
-800-424-9300 (North America)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Not classified
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
-1-45-425-959
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
2/8
Hazard pictograms
:
None.
Signal Word
:
None.
Hazard Statements
:
EUH208 - Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
Precautionary statements
:
None.
Name
Product identifier
%
Classification
67/548/EEC
Classification
1272/2008 [CLP]
glycerol
56-81-5
(EC no) 200-289-5
10-20
Not classified
Not classified
Magenta Dye
(CAS No) *
(EC no) *
< 2.5
N; R51/53
Aquatic Chronic 2, H411
Water
7732-18-5
(EC no) 231-791-2
65-80
Not classified
Not classified
1,2-benzisothiazol-3(2H)-one
(CAS No) 2634-33-5
< 0.05
Xn; R22
N; R50
Acute Tox. 4 (Oral), H302
Aquatic Acute 1, H400
First-aid measures general
:
If symptoms persist, obtain medical attention.
First-aid measures after inhalation
:
Obtain medical attention. In case of accident by inhalation : remove casualty to fresh air and
keep at rest.
First-aid measures after skin contact
:
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap
and water.
First-aid measures after eye contact
:
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.
First-aid measures after ingestion
:
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to
drink.
Symptoms/injuries after inhalation
:
Unlikely route of exposure.
Symptoms/injuries after skin contact
:
Repeated and/or prolonged skin contact may cause irritation.
Symptoms/injuries after eye contact
:
May cause eye irritation.
Symptoms/injuries after ingestion
:
Ingestion may cause irritation of the gastrointestinal tract. Unlikely route of exposure.
Suitable extinguishing media
:
Extinguish preferably with dry chemical, carbon dioxide, water spray, foam.
Unsuitable extinguishing media
:
None.
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP]
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
SECTION 3: Composition/information on ingredients
3.2. Mixture
Date of issue: 26 September
Revision date: 1 April 201
Version: 3
SDS No:BHM026–01-
(CAS No)
(CAS No)
(EC no) 220-120-9
(EC index no) 613-088-00-6
*Registered
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
4.2. Most important symptoms and effects, both acute and delayed
according to
Directive
Xi; R41
Xi; R38
R43
according to
Regulation (EC) No.
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
3/8
Fire hazard
:
Thermal decomposition of organic components may result in occurrence of oxides of carbon.
Hazardous decomposition products in case of
:
Toxic gases may be formed upon combustion and represents a hazard to firefighters.
Combustion products: See Section
Firefighting instructions
:
Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure selfcontained breathing apparatus (SCBA) during the attack phase of firefighting operations and
duri
having suitable respiratory protection must leave the area to prevent significant exposure to toxic
combustion gases from any source.
Emergency procedures
:
Ensure adequate ventilation. Avoid contact with eyes.
Emergency procedures
:
Ensure adequate ventilation. Avoid contact with eyes.
For containment
:
Wipe up ink with absorbent towel.
Methods for cleaning up
:
Wash with water to remove remaining traces of ink.
Precautions for safe handling
:
Keep out of the reach of children. Avoid contact with skin, eyes and clothing.
Storage conditions
:
Keep away from oxidizing agents.
glycerol (56-81-5)
Belgium
Local name
Glycérine (brouillard)
Belgium
Limit value (mg/m³)
10 mg/m³
Czech Republic
Local name
Glycerol, mlha
Czech Republic
Exposure limits (PEL) (mg/m³)
10 mg/m³
Czech Republic
Exposure limits (PEL) (ppm)
2.4 ppm
Czech Republic
Exposure limits (NPK-P) (mg/m³)
15 mg/m³
Czech Republic
Exposure limits (NPK-P) (p pm)
3.7 ppm
Finland
Local name
Glyseroli
Finland
HTP-arvo (8h) (mg/m³)
20 mg/m³
France
Local name
Glycérine (aérosols de)
France
VME (mg/m³)
10 mg/m³
Ireland
Local name
Glycerol, mist
Ireland
OEL (8 hours ref) (mg/m³)
10 mg/m³
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
5.2. Special hazards arising from the substance or mixture
Date of issue: 26 September
Revision date: 1 April 201
SDS No:BHM026–01-
Version: 3
fire
5.3. Advice for firefighters
: 10.
ng cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
6.1.2. For emergency responders
6.2. Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water drains.
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
Cartridge containing water based ink for inkjet printing machine.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
4/8
glycerol (56-81-5)
Poland
Local name
Glicerol aerozole
Poland
NDS (mg/m³)
10 mg/m³
Portugal
Local name
Glicerina, névoas
Portugal
OEL TWA (mg/m³)
10 mg/m³
United Kingdom
Local name
Glycerol, mist
United Kingdom
WEL TWA (mg/m³ )
10 mg/m³
USA - ACGIH
Local name
Glycerin mist
USA - ACGIH
ACGIH TWA (mg/m³)
10 mg/m³ mist
USA - ACGIH
Remark (ACGIH)
URT irr
USA - OSHA
OSHA PEL (TWA) (mg/m³)
15 mg/m³ Total dust
Appropriate engineering controls
:
Good general ventilation should be sufficient under normal use.
Personal protective equipment
:
Not normally required. For use other than in normal operating procedures (such as in the event
of large spill), the following should be applied:
Hand protection
:
protective gloves.
Eye protection
:
Safety goggles.
Skin and body protection
:
Long sleeved clothing and long pants.
Respiratory protection
:
In case of large spillages: Wear suitable respiratory protective equipment.
Environmental exposure controls
:
Avoid release to the environment.
Physical state
:
Liquid
Appearance
:
Dark red
Color
:
Dark red
Odor
:
Slight odor
Odor threshold
:
No information available
pH : 7 - 9 Relative evaporation rate (butyl acetate=1)
:
No information available
Relative evaporation rate (ether=1)
:
Not available
Melting point
:
< 5 °C
Freezing point
:
No data available
Boiling point
:
> 100 °C
Flash point
:
Does not flash at 93.3°C or lower (Tag closed cup & Cleveland opened cup)
Auto-ignition temperature
:
> 400 °C
Decomposition temperature
:
Not available
Flammability (solid, gas)
:
Not applicable
Vapor pressure
:
Not available
Relative vapor density at 20 °C
:
Not available
Relative density
:
No data available
Specific gravity / density
:
1 - 1.1 g/ml
Solubility
:
Soluble in water
Log Pow
:
No data available
Log Kow
:
No data available
Viscosity, kinematic
:
2 - 5 mPa·s
Viscosity, dynamic
:
No data available
Explosive properties
:
Not explosive
Oxidizing properties
:
Not available
Explosion limits
:
Not available
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
Date of issue: 26 September
Revision date: 1 April 201
SDS No:BHM026–01-
Version: 3
8.2. Exposure controls
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
5 mg/m³ Respirable Fraction
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
5/8
Acute toxicity
:
Not classified
LD50 oral rat
> 2000 mg/kg (OECD 420 method)
Skin corrosion/irritation
:
Non-irritant. (OECD 404 method)
pH
Serious eye damage/irritation
:
Minimal irritant to the eye. (OECD 405 method)
pH
Respiratory or skin sensitization
:
It is not a skin sensitizer. (OECD 429 method)
Germ cell mutagenicity
:
Negative. (OECD 471 method)
Carcinogenicity
:
Ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA
Reproductive toxicity
:
Not classified
Specific target organ toxicity (single exposure)
:
Not classified
Specific target organ toxicity (repeated
:
Not classified
Aspiration hazard
:
Not classified
glycerol (56-81-5)
LC50 fish
51 - 57 ml/l 96 h - Oncorhynchus mykiss
EC50 Daphnia
> 500 mg/l 24 h - Daphnia magna
Persistence and degradability
No information available.
glycerol (56-81-5)
Log Pow
-1.76
Ecology - soil
No information available.
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
No information available.
10.4. Conditions to avoid
No information available.
10.5. Incompatible ma t e r ials
Strong oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide.
Date of issue: 26 September
Revision date: 1 April 201
SDS No:BHM026–01-
Version: 3
SECTION 11: Toxicological information
11.1. Information on toxicological effects
: 7 - 9
: 7 - 9
exposure)
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
6/8
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
Results of PBT assessment
Not available
Other adverse effects
:
No information available.
Waste disposal recommendations
:
Dispose in accordance with federal, state and local regulations.
Proper Shipping Name (ADR/RID)
:
None
Proper Shipping Name (IATA)
:
None
Proper Shipping Name (IMDG)
:
None
Other information
:
None
Special transport precautions
:
None
IBC code
:
Not applicable
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
In accordance with ADR / IMDG / IATA / DOT / UN
14.1. UN number
Not regulated for transport
14.2. UN proper shipping name
Date of issue: 26 September
Revision date: 1 April 201
SDS No:BHM026–01-
Version: 3
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
14.6. Special precautions for user
14.6.1. Overland transport
No additional information available
14.6.2. Transport by sea
No additional information available
14.6.3. Air transport
No additional information available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
7/8
Regional legislation
:
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA: All chemical substances contained in this product are and had been listed on the TSCA
Chemical Substances Inventory, and none is subject to any of the following TSCA req
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e)
consent orders; section 8(a) preliminary assessment information rules; and section 8(d) health
and safety data reporting rules.
Canada: WHMIS: Not
Indication of changes:
SECTION 1, 2, 3.
Data sources
:
U.S. 29CFR Part 1910
ACGIH Threshold Limi
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU Directive 91/322/EEC and 2000/39/EC
NTP 11th Report on Carcinogens.
Abbreviations and acronyms
:
IARC (International Agency for Research on Cancer)
IATA (International Air Transport Association)
IMDG (International Maritime Dangerous Goods Code)
IOELV (Indicative Occupational Exposure Limit)
REACH (Registration, Evaluation and Autho
WHMIS (Workplace Hazardous Material Information System (Canada))
ACGIH (American Conference of Governement Industrial Hygienists)
DOT (Department Of Transportation (US))
ICAO (International Civil Aviation Organization)
NOHSC (Nationa
NTP (National Toxicology Program) (US)
OSHA (Occupational Safety and Health Administration) (US)
PEL (Permissible Exposure Limit)
TLV (Threshold Limit Value) (ACGIH)
TSCA (Toxic Substances Control Ac
TWA (Time Weighted Average).
Other information
:
The information only relates to this specific product. It may not be valid, if used in combination
with any other materials or in any other process, and it is based on our best knowledge as of the
d
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Oral)
Acute toxicity (oral) Category 4
Eye Dam. 1
Serious eye damage/eye irritation Category 1
Skin Irrit. 2
Skin corrosion/irritation Category 2
Skin Sens. 1
Skin sensitization Category 1
Aquatic Acute 1
Hazardous to the aquatic environment - Acute Hazard, Category 1
Aquatic Chronic 2
Hazardous to the aquatic environment - Chronic Hazard Category 2
H302
Harmful if swallowed
H315
Causes skin irritation
H317
May cause an allergic skin reaction
H318
Causes serious eye damage
H400
Very toxic to aquatic life
H411
Toxic to aquatic life with long lasting effects
R22
Harmful if swallowed
R41
Risk of serious damage to eyes
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
15.1.2. National regulations
Date of issue: 26 September
Revision date: 1 April 201
SDS No:BHM026–01-
Version: 3
uirements:
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
applicable. (Manufactured article).
t Values for Chemical Substances and Physical Agents and Biological
risation of CHemicals)
l Occupational Health and Safety Commission (Australia))
t) (US)
ate of preparation (revision).
Safety Data Sheet
Product name: LC20EM, LC22EM, LC23EM, LC201M, LC203M,
LC645M, LC663M, LC665XLM, LC673M, LC675XLM, LC695XLM Ink
2013
5
.0
EUUSOTHER
EN
8/8
R38
Irritating to skin
R43
May cause sensitization by skin contact
R50
Very toxic to aquatic organisms
R51/53
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
N
Dangerous for the environment
Xi
Irritant
Xn
Harmful
LC205M, LC211M, LC213M, LC215M, LC221M, LC223M,
LC225XLM, LC231M, LC233M, LC235XLM, LC261M, LC263M,
Date of issue: 26 September
Revision date: 1 April 201
SDS No:BHM026–01-
Version: 3
Loading...