Page 1
Safety Data Sheet
Product name: TN-630, TN-660, TN-2340, TN-2370, TN-2310, TN-
2013
2014
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Product Name (Product code)
:
TN-630,TN-660,TN-2340,TN-2370,TN-2310,TN-2320,TN-2335,TN-2375,TN-2330,TN-2350, TN2315,
TN2312 TN
Use of the substance/mixture
:
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers,
multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and
for use in the products stated. Information provided on this SDS is only consiste
specified by Brother
Emergency number
:
CHEMTREC
+1
+1
For France only:
Antipoison Center telephone number: ORFILA +33
EUH phrases
:
EUH208 - Contains Rosin, fumarated(65997-04-8). May produce an allergic reaction
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
SECTION 1: Identification of the substance/mixture and of the compan y/undertaking
1.1. Product identifier
TN-2345,TN-2360,TN-2380,TN-2305,TN-2355,TN-2306,TN-2356,TN-2365, TN-2385,
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Date of issue: 19 November
Revision date: 04 November
SDS No:BPL-01-
-2325 Toner
Version:
1.2.2. Uses advised against
nt with the use
No additional information available
1.3. Details of the supplier of the safety data sheet
Manufacturer Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada) Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe) Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address sds.info@brother.co.jp
1.4. Emergency telephone number
-703-527-3887 (International)
-800-424-9300 (North America)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Not classified
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP]
-1-45-425-959
Page 2
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Product name: TN-630, TN-660, TN-2340, TN-2370, TN-2310, TN-
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Name
Product identifier
%
Classification
67/548/EEC
Classification
1272/2008 [CLP]
N,N-diethyl-N-methyl-2-(2-methyl-1-oxo-2-
ethenylbenzene
133350-42-2
5 - 10
Xi; R36
Eye Irrit. 2, H319
Carbon Black (bound)
(CAS No) 1333-86-4
(EC no) 215-609-9
1 - 5
Not classified
Not classified
Rosin, fumarated
(CAS No) 65997-04-8
1 - 2.5
Xn; R22
Acute Tox. 4 (Oral), H302
Polyester resin
**
(EC no) -
**
Not classified
Not classified
First-aid measures general
:
If symptoms persist, obtain medical attention.
First-aid measures after inhalation
:
Obtain medical attention. In case of accident by inhalation : remove casualty to fresh air and
keep at
First-aid measures after skin contact
:
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap
and water.
First-aid measures after eye contact
:
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.
First-aid measures after ingestion
:
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to
drink.
Symptoms/injuries after inhalation
:
For large quantities: May cause irritation to the respiratory system. Increased difficulty in
breathing. Sneezing. Coughing.
Symptoms/injuries after eye contact
:
May cause eye irritation.
Symptoms/injuries after ingestion
:
May cause stomach ache. Unlikely route of exposure.
Suitable extinguishing media
:
Extinguish preferably with dry chemical, Water spray.
Unsuitable extinguishing media
:
Do not use water jet.
Explosion hazard
:
May form explosible dust clouds in air.
Firefighting instructions
:
Do not use high-pressure water in order to prevent creating a dust cloud and spreading fire dust.
Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self
contained breathi
during cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not
having suitable respiratory protection must leave the area to prevent significant exposure to toxic
combustion gases from any source.
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
SECTION 3: Composition/information on ingredients
3.2. Mixture
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
propenyl)oxyethanaminium salt with 4-methylbenzenesulfonic
acid (1:1) polymer with but yl 2-pr op eno at e an d
** CONFIDENTIAL
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
(CAS No)
(EC no) -
(EC no) 266-040-8
(CAS No)
rest.
4.2. Most important symptoms and effects, both acute and delayed
according to
Directive
Xi; R41
R43
according to
Regulation (EC) No.
Eye Dam. 1, H318
Skin Sens. 1, H317
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
ng apparatus (SCBA) during the attack phase of firefighting operations and
-
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Emergency procedures
:
Avoid generation of dust. Do not breathe dust. A suitable dust mask or dust respirator with filter
type A/P may be appropriate.
Methods for cleaning up
:
Sweep the spilt toner or remove it with a vacuum cleaner and transfer into a sealed container
carefully. Sweep slowly to minimize genera
used, the motor must be rated as dust explosion proof. Potential for very fine particles to be
taken into the vacuum only to be passed back into the environment due to pore size in the bag or
filter.
Precautions for safe handling
:
Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high
concentrations of dust. Avoid contact with eyes.
Storage conditions
:
Keep away from oxidizing agents.
Carbon Black (bound) (1333-86-4)
Belgium
Local name
Carbone (noir de)
Belgium
Limit value (mg/m³)
3.5 mg/m³
Denmark
Local name
Carbon black
Denmark
Limit (long-term) (mg/m³)
3.5 mg/m³
Denmark
Anmærkninger (DK)
K
Finland
Local name
Nokimusta
Finland
HTP-arvo (8h) (mg/m³)
3.5 mg/m³
Finland
HTP-arvo (15 min)
7 mg/m³
France
Local name
Noir de carbone
France
VME (mg/m³)
3.5 mg/m³
Ireland
Local name
Carbon black
Ireland
OEL (8 hours ref) (mg/m³)
3.5 mg/m³
Ireland
OEL (15 min ref) (mg/m3)
7 mg/m³
Portugal
Local name
Carbono, preto (Negro de fumo)
Portugal
OEL TWA (mg/m³)
3.5 mg/m³
Spain
Local name
Negro de humo
Spain
VLA-ED (mg/m³)
3.5 mg/m³
Spain
Notes
véase Apartado 9
United Kingdom
Local name
Carbon black
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
No additional information available
6.1.2. For emergency responders
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
6.2. Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water drains.
6.3. Methods and material for containment and cleaning up
tion of dust during cleanup. If a vacuum cleaner is
6.4. Reference to other sections
SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. This cartridge should
be used as supplied by Brother and for use in the products stated.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
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Carbon Black (bound) (1333-86-4)
United Kingdom
WEL TWA (mg/m³ )
3.5 mg/m³
United Kingdom
WEL STEL (mg/m³)
7 mg/m³
Norway
Local name
Carbon Black (lampesot)
Norway
TWA (A N) (mg/ m³)
3.5 mg/m³
USA - ACGIH
Local name
Carbon black
USA - ACGIH
ACGIH TWA (mg/m³)
3 mg/m³
USA - ACGIH
Remark (ACGIH)
Bronchitis
USA - OSHA
Local name
Carbon black
USA - OSHA
OSHA PEL (TWA) (mg/m³)
3.5 mg/m³
Additional information
:
USA OSHA PEL (TWA): 15 mg/m³ (Total dust) 5 mg/m³ (Respirable Fraction)
ACGIH TLV (TWA): 10 mg/m³ (Inhalable particles) 3 mg/m³ (Re
Appropriate engineering controls
:
Good general ventilation should be sufficient under normal use.
Personal protective equipment
:
Not normally required. For use other than in normal operating procedures (such as in the event
of large spill), the following should be applied:
Hand protection
:
protective gloves.
Eye protection
:
Safety goggles.
Skin and body protection
:
Long sleeved clothing and long pants.
Respiratory protection
:
Dust mask. (Large spillages: Respirator).
Environmental exposure controls
:
Avoid release to the environment.
Physical state
:
Solid
Appearance
:
Powder
Color
:
Black
Odor
:
odorless
Odor threshold
:
No information available
pH : Not applicable
Relative evaporation rate (butyl acetate=1)
:
Not applicable
Relative evaporation rate (ether=1)
:
Not applicable
Melting point
:
No information available
Freezing point
:
No information available
Boiling point
:
Not applicable
Flash point
:
Not applicable
Auto-ignition temperature
:
No information available
Decomposition temperature
:
No information available
Flammability (solid, gas)
:
Not applicable
Vapor pressure
:
Not applicable
Relative vapor density at 20 °C
:
Not applicable
Relative density
:
1.2 (H2O=1)
Solubility
:
Partially soluble (toluene, chloroform and tetrahydrofuran). Insolubl e in water
Log Pow
:
No information available
Log Kow
:
No information available
Viscosity, kinematic
:
Not applicable
Viscosity, dynamic
:
Not applicable
Explosive properties
:
Explosive limits of toner particles suspended in air approximately equal to that of coal dust
Oxidizing properties
:
No information available
Explosion limits
:
No information available
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
8.2. Exposure controls
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
spirable particles)
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Page 5
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Acute toxicity
:
Not classified
LD50 oral rat
> 5000 mg/kg (OECD 423 method)
LC50 inhalation rat (mg/l)
> 5.24 mg/l/4h (OECD 436 method)
Skin corrosion/irritation
:
Non-irritant. (OECD 404 method)
pH
Serious eye damage/irritation
:
Minimal irritant to the eye. (OECD 405 method)
pH
Respiratory or skin sensitization
:
It is not a skin sensitizer. (OECD 429 method)
Germ cell mutagenicity
:
AMES test : Negative. (OECD 471 method)
Carcinogenicity
:
Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible
human carcinogen). This classification is giv
human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity.
The classification is based upon the development of lung tumors in rats receiving chronic
inhalation exposures to
Studies performed in animal models other than rats did not show any association between
carbon black and lung tumors. Moreover, a two
preparat
tumor development in rats.
Other ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA
Reproductive toxicity
:
Not classified
Specific target organ toxicity (single exposure)
:
Not classified
Specific target organ toxicity (repeated
:
Not classified
Aspiration hazard
:
Not classified
Carbon Black (bound) (1333-86-4)
EC50 Daphnia
> 5600 mg/l 24 h (Daphnia magna)
Rosin, fumarated (65997-04-8)
LC50 fish
3.2 mg/l 96 h static (Brachydanio rerio)
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
No information available.
10.4. Conditions to avoid
Keep away from heat. Avoid friction, sparks, or other means of ignition.
10.5. Incompatible materials
Strong oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide. Nitrogen oxides.
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
SECTION 11: Toxicological information
11.1. Information on toxicological effects
: Not applicable
: Not applicable
ion containing carbon black demonstrated no association between toner exposure and
exposure)
en to chemicals, for which there is inadequate
free carbon black at levels that induce particle overload of the lung.
-year cancer bioassay using a typical toner
SECTION 12: Ecological information
12.1. Toxicity
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Persistence and degradability
No information available.
Log Pow
No information available
Log Kow
No information available
Ecology - soil
No information available.
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
Results of PBT assessment
Not available
Other adverse effects
:
No information available.
Waste disposal recommendations
:
Do not put toner or toner cartridges into a fire, this can cause fire to spread with the risk of
causing burn injuries. Shred toner cartridges in a dust/explosion controlled enviro
dispersed particles may form explosive mixtures in the air. Dispose in accordance with federal,
state and local regulations.
Proper Shipping Name (ADR/RID)
:
None
Proper Shipping Name (IATA)
:
None
Proper Shipping Name (IMDG)
:
None
Other information
:
None
Special transport precautions
:
None
IBC code
:
Not applicable
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
SECTION 14: Transport information
In accordance with ADR / IMDG / IATA / DOT / UN
14.1. UN number
Not regulated for transport
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
14.6. Special precautions for user
14.6.1. Overland transport
No additional information available
14.6.2. Transport by sea
No additional information available
14.6.3. Air transport
No additional information available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
nment. Finely
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Regional legislation
:
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA: All chem
Chemical Substances Inventory, and none is subject to any of the following TSCA requirements:
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; s
consent orders; section 8(a) preliminary assessment information rules; and section 8(d) health
and safety data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article).
Indication of changes:
Newly issued.
Data sources
:
U.S. 29CFR Part 1910
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Monograp
EU Directive 91/322/EEC and 2000/39/EC
NTP 11th Report on Carcinogens.
Abbreviations and acronyms
:
IARC (International Agency for Research on Cancer)
IATA (International Air Tran
IMDG (International Maritime Dangerous Goods Code)
IOELV (Indicative Occupational Exposure Limit)
REACH (Registration, Evaluation and Authorisation of CHemicals)
WHMIS (Workplace Hazardous Material Information System (Canada))
ACGIH (Ame
DOT (Department Of Transportation (US))
ICAO (International Civil Aviation Organization)
NOHSC (National Occupational Health and Safety Commission (Australia))
NTP (National Toxicology Program) (US)
OS
PEL (Permissible Exposure Limit)
STEL (Short Term Exposure Limit)
TLV (Threshold Limit Value) (ACGIH)
TSCA (Toxic Substances Control Act) (US)
TWA (Time Weighted Average).
Other information
:
The information only relates to this specific product. It may not be valid, if used in combination
with any other materials or in any other process, and it is based on our best knowledge as of the
date of preparation (revision).
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Oral)
Acute toxicity (oral) Category 4
Eye Dam. 1
Serious eye damage/eye irritation Category 1
Eye Irrit. 2
Serious eye damage/eye irritation Category 2
Skin Sens. 1
Skin sensitization Category 1
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2. National regulations
ical substances contained in this product are and had been listed on the TSCA
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
ection 5(e)
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
hs on the Evaluation Carcinogenic Risks to Humans World Health Organization
sport Association)
rican Conference of Governement Industrial Hygienists)
HA (Occupational Safety and Health Administration) (US)
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H302
Harmful if swallowed
H317
May cause an allergic skin reaction
H318
Causes serious eye damage
H319
Causes serious eye irritation
R22
Harmful if swallowed
R36
Irritating to eyes
R41
Risk of serious damage to eyes
R43
May cause sensitization by skin contact
Xi
Irritant
Xn
Harmful
2320, TN-2335, TN-2375, TN-2330, TN-2350, TN-2315, TN-2345, TN2360, TN-2380, TN-2305, TN-2355, TN-2306, TN-2356, TN-2365, TN2385, TN2312, TN-2325 Toner
Date of issue: 19 November
Revision date: 04 November
Version:
SDS No:BPL-01-
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