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Safety Data Sheet
Date of issue: 21 February 2005
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Product form
:
Mixture
Product name
:
1030, 1230, 1430, 7020, 7220, 7420 Film R bbon, Black
Use of the substance/mixture
:
These products are ink r bbon in cartridge for Brother Industries, Ltd. Typewriters.
Emergency number
:
CHEMTREC
+1
+1
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
SECTION 1: Identification of the substance/mixture and of the compan y/undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
Revision date: 10 February 2016
SDS No: CO-RI-
1.2.1. Relevant identified uses
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Manufacturer Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada) Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe) Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address sds.info@brother.co.jp
1.4. Emergency telephone number
Version: 3
-703-527-3887 (International)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
-800-424-9300 (North America)
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]
No labeling applicable
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
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Safety Data Sheet
Date of issue: 21 February 2005
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Name
Product identifier
CAS No.
w/w%
Classification according to
Regulation (EC) No. 1272/2008 [CLP]
Carbon Black (bound)
1333-86-4
3.36
Not classified
Highly refined Mineral Oil
8012-95-1
4.56
Not classified
Quartz (bound)
14808-60-7
<0.35
Not classified
Cristobalite (bound)
14464-46-1
<0.02
Not classified
Resins
**
6.4-7.4
Not classified
Oils
**
1.15-2.04
Not classified
Filler
**
1.15-2.04
Not classified
Polyethylene film
25213-02-9
83-84
Not classified
First-aid measures general
:
If symptoms persist, obtain medical attention.
First-aid measures after inhalation
:
Not applicable.
First-aid measures after skin contact
:
Wash affected skin with plenty of water or soap and water.
First-aid measures after eye contact
:
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water fo
First-aid measures after ingestion
:
Obtain medical attention. Wash out mouth with water and give 100-200 ml of water to drink.
Symptoms/injuries
:
No specific effects and/or symptoms have been reported or known.
Suitable extinguishing media
:
Extinguish preferably with dry chemical, carbon dioxide, water mist, foam.
Unsuitable extinguishing media
:
None.
Fire hazard
:
No information available.
Firefighting instructions
:
A self contained breathing apparatus and suitable protective clothing should be worn in fire
conditions.
General measures
:
Not normally required.
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
SECTION 3: Composition/information on ingredients
3.2. Mixture
** CONFIDENTIAL
Full text of H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
Revision date: 10 February 2016
Version: 3
SDS No: CO-RI-
r at least 15 minutes.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
No additional information available
6.1.2. For emergency responders
No additional information available
6.2. Environmental precautions
Avoid release to the environment.
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Methods for cleaning up
:
Not applicable.
Precautions for safe handling
:
Avoid contact with skin and eyes.
Storage conditions
:
Keep away from oxidizing agents and extreme heat.
Ingredients
CAS No.
OSHA PEL
ACGIH TLV
Carbon Black
1333-86-4
3.5mg/m3 TWA
3.5mg/m3 TWA
Mineral Oil (mist)
8012-95-1
5.0mg/m3 TWA
5.0mg/m3 TWA
Quartz (respirable quartz)
14808-60-7
0.1mg/m3 TWA
0.1mg/m3 TWA
Cristobalite
14464-46-1
0.025mg/m3 TWA
0.025mg/m3 TWA
Appropriate engineering controls
:
Good general ventilation should be sufficient under normal use.
Personal protective equipment
:
Not normally required. For use other than in normal operating procedures (such as in the event
of large spill), the following should be applied:
Hand protection
:
Protective gloves.
Eye protection
:
Safety goggles.
Skin and body protection
:
Not normally required.
Respiratory protection
:
No special protective equipment required.
Environmental exposure controls
:
Not normally required.
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
These products are ink ribbon in cartridge for Brother Industries, Ltd. Typewriters.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Revision date: 10 February 2016
Version: 3
SDS No: CO-RI-
8.2. Exposure controls
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Physical state
:
Solid
Appearance
:
Film
Color
:
Black.
Odor
:
No information available
Odor threshold
:
No information available
pH : Not applicable
Relative evaporation rate (butyl acetate=1)
:
Not applicable
Relative evaporation rate (ether=1)
:
Not applicable
Melting point
:
Not applicable
Freezing point
:
None
Boiling point
:
Not applicable
Flash point
:
No information available
Auto-ignition temperature
:
No information available
Decomposition temperature
:
No information available
Flammability (solid, gas)
:
No information available
Vapor pressure
:
Not applicable
Relative vapor density at 20 °C
:
Not applicable
Relative density
:
No information available
Solubility
:
Not applicable
Log Pow
:
No information available
Log Kow
:
No information available
Viscosity, kinematic
:
Not applicable
Viscosity, dynamic
:
Not applicable
Explosive properties
:
Not applicable
Oxidizing properties
:
No information available
Explosion limits
:
Not applicable
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Revision date: 10 February 2016
Version: 3
SDS No: CO-RI-
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
No information available.
10.4. Conditions to avoid
Keep away from heat. Avoid friction, sparks, or other means of ignition.
10.5. Incompatible ma terials
Strong oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide. Nitrogen oxides.
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Date of issue: 21 February 2005
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Acute toxicity
:
No information available
Skin corrosion/irritation
:
No information available
pH
Serious eye damage/irritation
:
Not classified
pH
Respiratory or skin sensitization
:
No information available
Germ cell mutagenicity
:
No information available
Carcinogenicity
:
Printing inks: IARC Classification: Group 3 (Non-classified Human Carcinogen)
Carbon
human carcinogen). This classification is given to chemicals, for which there is inadequate
human evidence, but sufficient animal evidence on which to base an opinion of
The classification is based upon the development of lung tumors in rats receiving chronic
inhalation exposures to free carbon black at levels that induce particle overload of the lung.
Studies performed in animal models other than rats did
carbon black and lung tumors.
Crystalline silica in the form of quartz or Cristobalite
(
Other ingredients of this product have not been classified as carci
monographs, NTP and OSHA
Reproductive toxicity
:
No information available
Specific target organ toxicity (single exposure)
:
No information available
Specific target organ toxicity (repeated
:
No information available
Aspiration hazard
:
Not classified
Carbon Black (1333-86-4)
EC50 Daphnia
> 5600 mg/l 24 h (Daphnia magna)
Persistence and degradability
No information available.
Log Pow
No information available
Log Kow
No information available
Bioaccumulative potential
No information available.
Ecology - soil
No information available.
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
Other adverse effects
:
No information available.
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
SECTION 11: Toxicological information
11.1. Information on toxicological effects
: Not applicable
: Not applicable
Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible
carcinogenic to humans)
Revision date: 10 February 2016
Version: 3
SDS No: CO-RI-
carcinogenicity.
not show any association between
dust, quartz: IARC Classification: Group 1
nogens according to IARC
exposure)
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
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Date of issue: 21 February 2005
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Waste disposal recommendations
:
Dispose in accordance with federal, state and local regulations.
Proper Shipping Name (ADR/RID)
:
None
Proper Shipping Name (IATA)
:
None
Proper Shipping Name (IMDG)
:
None
Other information
:
None
Special transport precautions
:
None
IBC code
:
Not applicable
Regional legislation
:
USA: All chemical substances contained in this product are and had been listed on the TSCA
Chemical Substances Inventory, and none is subject to any of the following TSCA requirements:
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e)
consent orders; sectio
and safety data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article).
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
In accordance with ADR / IMDG / IATA / DOT / UN
14.1. UN number
Not regulated for transport
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
14.6. Special precautions for user
Revision date: 10 February 2016
Version: 3
SDS No: CO-RI-
14.6.1. Overland transport
No additional information available
14.6.2. Transport by sea
No additional information available
14.6.3. Air transport
No additional information available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2. National regulations
n 8(a) preliminary assessment information rules; and section 8(d) health
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
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Date of issue: 21 February 2005
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Data sources
:
World Health Organization International Agency for Research on Cancer, IARC Monographs on
the Evaluation on the Carcinogenic Risks to Humans, Volume 9
World Health Organization International Agency for Resear
the Evaluation on the Carcinogenic Risks to Humans, Volume
World Health Organization International Agency for Research on Cancer, IARC Monographs on
the Evaluation on the Carcinogenic Risks to Humans, Volume
U.S.
ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
EU Commission Directive 2009/161/EU.
Abbreviations and acronyms
:
IARC (International Agency for Research on Cancer)
IATA (International Air Transport Association)
IMDG (International Maritime Dangerous Goods Code)
REACH (Registration, Evaluation and Authorisation of CHemicals)
WHMIS (Workplace Hazardous Material Information System (Canada))
ACGIH (American Confe
DOT (Department Of Transportation (US))
NTP (National Toxicology Program) (US)
OSHA (Occupational Safety and Health Administration) (US)
PEL (Permissible Exposure Limit)
STEL (Short Term Exposure Limit)
TLV (Thre
TSCA (Toxic Substances Control Act) (US)
TWA (Time Weighted Average).
Other information
:
The information only relates to this specific product. It may not be valid, if used in combination
with any other materials or in any othe
date of preparation (revision).
Product name: 1030, 1230, 1430, 7020, 7220, 7420 Film R bbon,
Black
SECTION 16: Other information
Department of labor, 29CFR Part 1910.
shold Limit Value) (ACGIH)
Revision date: 10 February 2016
Version: 3
SDS No: CO-RI-
3
ch on Cancer, IARC Monographs on
100C
33
rence of Governement Industrial Hygienists)
r process, and it is based on our best knowledge as of the
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