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Battery pack containing sealed lead acid batteries
MATERIAL SAFETY DATASHEET
SECTION 1: Identification of the Substance/Mixture and of the Company/Undertaking
GHS product
identifier:
Battery pack containing sealed lead acid batteries
Other Names:
Battery pack or accumulator pack with Valve Regulated Lead Acid Battery - Wet, NonSpillable
Model Numbers:
APC-RBCXXX(L)(-AAA) or SYBTXXX(-AAA) (where XXX is 001 through 999 and APC, L, -AAA
are optional and AAA is a two or three letter customer or country code) or YYYY(XXX)BP
(where YYYY is SU, SUA, SCR, SRT, UX, UXA or SURT and XXX is 24, 48 or 192)
Product Type:
Battery pack is a manufactured article consisting of a plastic and metal sealed case
containing one or more sealed lead acid battery connected by wires. Solid.
Supplier/Manufacturer:
Schneider Electric IT USA (formerly APC by Schneider Electric, APC Sales and Service Corp.)
Address:
132 Fairgrounds Road West Kingston, RI 02892
Telephone:
800-788-2208 or 401-789-5735
E-mail:
http: //nam-en.apc.com/app/ask
Website:
www.APC.com
Telecopy:
Not available.
SECTION 2: Hazards identification
Identified uses
Relevant identified use(s): Electric Storage Battery
Use(s) advised against: Transportation
Manufacturer
Version: 1
Review date: November, 2nd, 2015
Emergency telephone number (with hours of operation)
800-788-2208
2.1 Classification of the substance or mixture:
According to CLP No 1272/2008:
Acute Toxicity Oral 4 - H302
Skin Corrosion 1A - H314
Reproductive Toxicity 1A - H360Df
Specific Target Organ Toxicity Repeated Exposure 2 - H373
Hazardous to the aquatic environment Acute 1 - H400
Hazardous to the aquatic environment Chronic 1 - H410
2.2 GHS label elements:
Signal Word: DANGER
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SGH05
SGH08
SGH07
SGH09
H302
Harmful if swallowed.
H314
Causes severe skin burns and eye damage.
H360Df
May damage the unborn child. Suspected of damaging fertility.
H373
May cause damage to organs through prolonged or repeated exposure.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe mist/vapours/spray.
P264
Wash thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P281
Use personal protective equipment as required.
P273
Avoid release to the environment.
P304 + P340
IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
P303 + P361 + P353
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P310
Immediately call a POISON CENTER or doctor/physician.
P321
Specific treatment, see supplemental first aid information.
P363
Wash contaminated clothing before reuse.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301 + P312
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell.
P330
Rinse mouth.
Hazard Statements
Precautionary statements
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Battery pack containing sealed lead acid batteries Page 2 to 11
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P331
Do NOT induce vomiting.
P314
Get medical advice/attention if you feel unwell.
P308 + P313
IF exposed or concerned: Get medical advice/attention.
P391
Collect spillage.
P405
Store locked up.
P501
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
2.3 Other hazards
SECTION 3: Composition/information on ingredients
Chemical Name
CAS Number
EC Number
Composition (%)
Classification
Lead
7439-92-1
231-100-4
55,9 – 63,4 %
Annex VI: Acute Tox. 4, H332;
Acute Tox. 4, H302; Repr. 1A,
H360df; STOT RE 2, H373;
Aquatic Acute 1, H400; Aquatic
Chronic 1, H410
Sulfuric acid
7664-93-9
231-639-5
15,8 – 20,5 %
Annex VI, Table 3.1: Skin Corr.
1A; H314
1-Propene, homopolymer
9003-07-0
--
4,8 – 12,3 %
Not Classified
Amorphous/fused
silica
60676-86-0
--
3,7 – 5,6 %
Not Classified
Polyvinyl Chloride
9002-86-2
--
2,6 %
Not Classified
Copper
7440-50-8
231-159-6
2,6 %
Self Classified: Repr. 2, H361;
Eye Irrit. 2, H319; STOT SE 3:
Resp. Irrit., H335
Steel
--
--
0,4 %
Not Classified
Tin
7440-31-5
231-141-8
0,3 %
Self Classified: STOT SE 3: Resp.
Irrit., H335; STOT RE 2 (Lungs,
Inhalation), H373; STOT RE 1
(CNS, Liver, Kidney), H372
Polycarbonate
27440-31-5
--
0,1 %
Not Classified
According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous.
2.4 Other information
Acid batteries used in APC by Schneider Electric Replacement Battery Cartridges (RBCs) are contained within
cartridges and are sealed, non-spillable design. Under normal use and handling, there is no contact with the internal
components of the battery or the chemical hazards. Under normal use and handling, these products do not emit
regulated or hazardous substances. Misuse of the product, such as overcharging, may result in a discharge of battery
electrolyte. Classification provided are for the battery electrolyte and are only applicable in the event that the
electrolyte is discharged.
3.1 Substances
The material does not meet the criteria of a substance in accordance with regulation (EC) No 1272/2008
See Section 11 for Toxicological Information. See Section 16 for full text of H-statements and R-phrases.
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SECTION 4: First aid measures
4.1 Description of first aid measures
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. Do
not use mouth-to-mouth method if victim inhaled the substance; give artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical
device.
Skin
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash before
reuse. If signs/symptoms develop, get medical attention.
Eye
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If signs/symptoms develop, get medical attention.
Ingestion
Do NOT induce vomiting. If conscious, drink large quantities of milk or water. Follow with milk of
magnesia, beaten egg, egg whites or vegetable oil. Get medical attention immediately.
SECTION 5: Fire-fighting measures
Suitable Extinguishing Media
Dry chemical or CO2.
Unsuitable Extinguishing
Media
Water should not be used unless from a safe distance due to vigorous and
exothermic reaction which will result.
Unusual Fire and Explosion
Hazards
Hydrogen and oxygen gases are produced during normal battery operation and
charging. These gases escape through the battery vents and may form an
explosive atmosphere around the battery if ventilation is poor. Avoid open flame,
sparks and other ignition sources in areas where batteries are used or stored.
Hazardous Combustion
Products
Acid mists and vapors, toxic fumes from burning plastic.
4.2 Most important symptoms and effects, both acute and delayed
Refer to Section 11 - Toxicological Information
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician: All treatments should be based on observed signs and symptoms of distress in the patient.
Consideration should be given to the possibility that overexposure to materials other than this product may have
occurred.
5.1 Extinguishing media
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Fire fighters should wear complete protective clothing including self-contained breathing apparatus. Wear chemical
protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal
protection. Fire fighters to wear acid-resistant full protective clothing, including rubber footwear and self-contained
breathing apparatus.
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SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions
Do not walk through spilled material. Wear appropriate personal protective
equipment, avoid direct contact. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ventilate enclosed areas.
Do not get in eyes, on skin, or on clothing. Do not breathe dusts or mists.
Emergency Procedures
As an immediate precautionary measure, isolate spill or leak area for at least 50
meters (150 feet) in all directions. Keep unauthorized personnel away. Do not get
water inside container.
Containment/Clean-up
Measures
Stop leak if you can do it without risk. If battery is leaking, place battery in a
heavy duty plastic bag. Contain spill by diking with soda ash, etc. Neutralize spill
area with (soda ash or lime, dilute with acetic acid) Make certain mixture is
neutral then collect residue and place in a drum or other suitable container.
SECTION 7: Handling and storage
SECTION 8: Exposure controls/personal protection
Result
NIOSH
OSHA
Tin (7440-31-5)
TWAs
2 mg/m3 TWA
Not established
Copper (7440-50-8)
TWAs
1 mg/m3 TWA (dust and mist); 0.1
mg/m3 TWA (fume)
0.1 mg/m3 TWA (fume); 1 mg/m3
TWA (dust and mist)
Polyvinyl Chloride
(9002-86-2)
TWAs
Not established
Not established
Sulfuric acid (7664-93-9)
TWAs
1 mg/m3 TWA
1 mg/m3 TWA
Lead as Lead, Inorganic
compounds
TWAs
0.050 mg/m3 TWA
50 μg/m3 TWA
6.2 Environmental precautions
Avoid run off to waterways and sewers.
6.3 Methods and material for containment and cleaning up
6.4 Reference to other sections
Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 – Disposal Considerations
7.1 Precautions for safe handling
Handling: Use only in well ventilated areas. Use caution when combining with water; DO NOT add water to corrosive
liquid, ALWAYS add corrosive liquid to water while stirring to prevent release of heat, steam and fumes. Wear
appropriate personal protective equipment, avoid direct contact. Do not get in eyes, on skin, or on clothing. Do not
breathe mist, vapors, spray. Avoid direct conductive connection across positive and negative terminals to prevent
short circuit. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.
7.2 Conditions for safe storage, including any incompatibilities
Batteries should be kept in an upright position away from ignition sources. Stack batteries so as to prevent accidental
contact between terminal and/or other damage to terminals or containers. Whenever feasible, store on shipping
pallet or rack. Do not stack loaded pallets or racks on top of other batteries. Store in a cool/low temperature, wellventilated place. Avoid storage in areas exposed to heat or solar buildup
7.3 Specific end use(s)
Refer to Section 1.2 - Relevant identified uses.
8.1 Control parameters
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Key to abbreviations
Respiratory
Follow the European Standard EN 149. Use a European Standard EN 149 approved respirator
if exposure limits are exceeded or symptoms are experienced.
Eye/Face
Wear eye/face protection - Chemical splash goggles, or - Full-face shield with safety glasses.
Skin/Body
Acid resistant clothing with rubber/neoprene boots for major spill clean-up. Acid resistant
gloves such as rubber, neoprene, vinyl coated, PVC.
Environmental
Exposure Controls
Controls should be engineered to prevent release to the environment, including procedures
to prevent spills, atmospheric release and release to waterways. Follow best practice for site
management and disposal of waste.
SECTION 9: Physical and chemical properties
Material Description
Physical Form
Solid
Appearance/Description
Shaped article.
Color
Data lacking
Odor
Data lacking
Odor Threshold
Data lacking
General Properties
Boiling Point
Data lacking
Melting Point
Data lacking
Decomposition
Temperature
Data lacking
pH
Data lacking
Specific Gravity/Relative
Density
Data lacking
Water solubility
Data lacking
Viscosity
Data lacking
Explosive Properties
Not Explosive
Oxidizing Properties :
Not an oxidizer
Volatility
Vapor Pressure
Vapor Density
Evaporation Rate
Flammability
Flash Point
Data lacking
UEL
Data lacking
LEL
Data lacking
Auto ignition
Data lacking
Flammability (solid, gas)
Not flammable.
Environmental
Octanol/Water Partition
coefficient
Data lacking
NIOSH = National Institute of Occupational Safety and Health
OSHA = Occupational Safety and Health Administration
TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures
8.2 Exposure controls
Engineering Measures/Controls: Good general ventilation should be used. Ventilation rates should be matched to
conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain
airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne
levels to an acceptable level.
Personal Protective Equipment
9.1 Information on Physical and Chemical Properties
9.2 Other Information
No additional physical and chemical parameters noted.
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SECTION 10: Stability and reactivity
10.1 Reactivity
SECTION 11: Toxicological information
Components
Sulfuric acid (15.8% to
20.5%)
7664-93-9
Acute Toxicity: Ingestion/Oral-Rat LD50 • 2140 mg/kg; Inhalation-Rat
LC50 • 510 mg/m³ 2 Hour(s); Irritation: Eye-Rabbit • 250 μg • Severe
irritation; Multi-dose Toxicity: Inhalation-Rat TCLo • 1.8 mg/m³ 24
Hour(s) 65 Day(s)-Continuous; Peripheral Nerve and Sensation: Recording
from peripheral motor nerve; Kidney, Ureter, and Bladder: Changes in
both tubules and glomeruli
Polyvinyl Chloride (2.6%)
9002-86-2
Tumorigen / Carcinogen: Ingestion/Oral-Rat TDLo • 210 g/kg 30 Week(s)-
Continuous; Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria; Lungs, Thorax, or Respiration: Tumors; Skin and Appendages:
Other: Tumors
Copper (2.6%)
7440-50-8
Reproductive: Ingestion/Oral-Rat TDLo • 152 mg/kg (22W pre);
Reproductive Effects: Effects on Embryo or Fetus: Fetotoxicity (except
death, e.g., stunted fetus); Reproductive Effects: Specific Developmental
Abnormalities: Central nervous system
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal temperatures and pressures
10.3 Possibility of hazardous reactions
No Data Available
10.4 Conditions to avoid
Use only approved charging methods. Avoid overcharging. Avoid short-circuiting. Avoid sparks and other ignition
sources. Do not open, break or melt the casing.
10.5 Incompatible materials
Strong oxidizing or reducing agents.
10.6 Hazardous decomposition products
Can emit highly toxic fumes when heated. Combustion can produce carbon dioxide and carbon monoxide. Will
release an explosive hydrogen/oxygen gas mixture. Oxides of lead, lead and/or lead compounds may be released.
Sulfuric acid may release sulfur dioxide and/or sulfur trioxide.
11.1 Information on toxicological effects
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GHS Properties
Classification EU/CLP
Acute toxicity
Acute Toxicity - Oral 4 - ATEmix = 703.47 mg/kg
Aspiration Hazard
Classification criteria not met
Carcinogenicity
Classification criteria not met
Germ Cell Mutagenicity
Classification criteria not met
Skin corrosion/Irritation
Skin Corrosion 1A
Skin sensitization
Classification criteria not met
STOT-RE
Specific Target Organ Toxicity Repeated Exposure 2
STOT-SE
Classification criteria not met
Toxicity for Reproduction
Toxic to Reproduction 1A
Respiratory sensitization
Classification criteria not met
Serious eye damage/Irritation
Classification criteria not met
Target Organs: Nervous System, Blood, Liver, Kidney
Acute (Immediate)
Lead - For industry, inhalation is much more important than is ingestion. Systemic effects
include loss of appetite, anemia, malaise, insomnia, headache, irritability, muscle and joint
pains, tremors, flaccid paralysis without anesthesia, hallucinations and distorted
perceptions, muscle weakness, gastritis and liver changes. Major organ systems affected
are the nervous system, blood system and kidneys. Experimental evidence suggests that
blood levels of lead below 10 μg/dL can lower the IQ scores of children. Low levels of lead
impair neurotransmission and immune system function and may increase systolic blood
pressure. Reversible kidney damage can occur from acute exposure. Sulfuric Acid Experimental poison by inhalation.
Chronic (Delayed)
Lead - Chronic exposure can lead to irreversible vascular sclerosis, tubular cell atrophy,
interstitial fibrosis, and glomerular sclerosis. Very heavy intoxication can sometimes be
detected by formation of a dark line on the gum margins. Sulfuric acid - Repeated or
prolonged inhalation of sulfuric acid mist can cause inflammation of the upper respiratory
tract, leading to chronic bronchitis. Severe exposure may cause chemical pneumonitis.
Erosion of tooth enamel due to strong acid fume exposure has been observed in industry.
Workers exposed to low concentrations of the vapors gradually lose their sensitivity to its
irritating action. Occupational exposures to strong-acid mists containing sulfuric acid have
been associated with several respiratory tract cancers. However, there is no animal data
supporting the carcinogenicity of sulfuric acid. Sulfuric acid has been found to be nonmutagenic, and in two studies of workers employed in lead acid battery manufacture, no
association between sulfuric acid mist exposure and respiratory tract cancers was
observed.
Acute (Immediate)
Sulfuric Acid - Extremely irritating, corrosive, and toxic to tissue, resulting in rapid
destruction of tissue, causing severe burns. If much skin is involved, exposure is
accompanied by shock, collapse and symptoms similar to those seen in severe burns.
Repeated contact with dilute solutions can cause dermatitis.
Chronic (Delayed)
No Data Available
Acute (Immediate)
Causes serious eye damage.
Chronic (Delayed)
No Data Available
Route(s) of entry/exposure: Inhalation, Skin, Eye, Ingestion
Potential Health Effects
Inhalation
Skin
Eye
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Ingestion
Acute (Immediate)
Lead - Poison by ingestion in large dosages and with prolonged exposure leading to the
same effects as seen in exposure by inhalation. Adults absorb 5-15% of ingested lead and
retain less than 5%. Children absorb about 50% and retain about 30%. Sulfuric Acid Moderately toxic by ingestion.
Chronic (Delayed)
No Data Available
Reproductive
Effects
Lead - Severe toxicity can cause sterility, abortion, and neonatal mortality and morbidity.
Experimental teratogen. Experimental reproductive effects. Pathological lesions have been
found on male gonads. Sulfuric Acid - Experimental teratogen.
Carcinogenic
Effects
Repeated and prolonged exposure may cause cancer.
Carcinogenic Effects
CAS
IARC
NTP
Sulfuric acid
7664-93-9
Group 1-Carcinogenic
Not Listed
Lead
7439-92-1
Group 2A-Probable
Carcinogen
Reasonably Anticipated to be Human
Carcinogen
Lead as Lead
Compounds
NO DATA
AVAILABLE
Not Listed
Reasonably Anticipated to be Human
Carcinogen
Lead as Lead, inorganic
compounds
NO DATA
AVAILABLE
Group 2A-Probable
Carcinogen
Not Listed
SECTION 12: Ecological information
SECTION 13: Disposal considerations
Product waste
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
Packaging waste
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
12.1 Toxicity
Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects
12.2 Persistence and degradability
Material data lacking.
12.3 Bioaccumulative potential
Material data lacking.
12.4 Mobility in Soil
Material data lacking.
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment has not been conducted for this material.
12.6 Other adverse effects
No studies have been found.
13.1 Waste treatment methods
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SECTION 14: Transport information
14.1 UN
number
14.2 UN proper shipping
name
14.3 Transport hazard
class(es)
14.4 Packing
group
14.5 Environmental
hazards
DOT
UN2800
Batteries, Wet, Nonspillable
Hazard Class 8
Packing
Group II
TDG
UN2800
Batteries, Wet, Nonspillable
Hazard Class 8
Packing
Group II
IMO/IMDG
UN2800
Batteries, Wet, Nonspillable
Hazard Class 8
Packing
Group II
IATA/ICAO
UN2800
Batteries, Wet, Nonspillable
Hazard Class 8
Packing
Group II
SECTION 15: Regulatory information
Component
CAS
EU EINECS
EU ENICS
1-Propene, homopolymer
9003-07-0
No
No
Amorphous/fused
silica
60676-86-0
Yes
Yes
Calcium
7440-70-2
Yes
No
Copper
7440-50-8
Yes
No
Lead
7439-92-1
Yes
No
Polycarbonate
25037-45-0
No
No
Polyvinyl Chloride
9002-86-2
No
Yes
Sulfuric Acid
7664-93-9
Yes
No
Tin
7440-31-5
Yes
No
The non-spillable lead acid batteries used in these battery packs are:
- Certified by their manufacturers as capable of withstanding the IATA/ICAO Vibration and Pressure
Differential Test and that at a temperature of 55 degrees Centigrade, the electrolyte will not flow from a
ruptured or cracked case and there is no free liquid to flow. Schneider Electric only authorizes the use of
batteries that meet these criteria. Applicable certifications and test reports are available upon request.
- Packaged in accordance with the requirements of ADR/RID special provision 598, IMDG special provision
238 and IATA-DGR special provision A67 when shipped inside a UPS or packaged in accordance with the
requirements of ADR/RID special provision 598, IMDG special provision 238 and IATA-DGR special provision
A67 when shipped inside a UPS or shipped in their original battery pack packaging. When they are shipped
inside the UPS or in their original packaging, then they are:
o Secured in such a way that they cannot slip, fall or be damaged;
o When weighing greater than 2.5 kg, provided with carrying devices, unless they are suitably
stacked, e.g. on pallets;
o Free of dangerous traces of alkalis or acids on the outside; and protected against short circuits.
o Outer packaging may be marked “NONSPILLABLE” or “NONSPILLABLE BATTERY.” When not
marked, the outer packaging needs to be marked with one of these two phrases.
o Shipment by air requires on Master Air Waybill the following endorsement in the “Nature and
Quantity of Good” box: “Not Restricted as per Special Provision A67”
Please note that if the Battery Pack or UPS containing the Battery pack is not shipped in the original packaging or no
longer meets any of the referenced requirements above, then the package must be shipped as follows:
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
SARA Hazard Classifications: Acute Chronic
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15.2 Chemical Safety Assessment
SECTION 16: Other information
No Chemical Safety Assessment has been carried out.
Review date: November, 2nd, 2015
Version: 1
Relevant Phrases (code & full text)
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
H335 - May cause respiratory irritation
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
R36/37 - Irritating to eyes and respiratory system.
R38 - Irritating to skin.
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 - Possible risk of harm to the unborn child.
Every endeavor has been made to ensure that the information contained in this publication is reliable and offered in
good faith. It is meant to describe the safety requirements of our products and should not be construed as
guaranteeing specific properties. Customers are encouraged to conduct their own tests as end user suitability of the
product for particular uses is beyond our control. The information is not intended as an inducement to bargain and
no warranty expressed or implied is made as to its accuracy, reliability or completeness. Schneider Electric
Incorporated accepts no liability for loss, injury or damage arising from reliance upon the information contained in
this data sheet except in conjunction with the proper use of the product to which it refers. Due care should be taken
that the use and disposal of this product is in compliance with appropriate Federal, State and Local Government
regulations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above -named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the
user. All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee that these are the only hazards that exist.
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