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Safety Data Sheet
Copyright,2016,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
32-0785-9
Version Number:
4.00
Issue Date:
05/04/16
Supercedes Date:
03/10/15
SECTION 1: Identification
1.1. Product identifier
3M™ Glass Cleaner and Protector, Ready-To-Use
Product Identification Numbers
70-0715-9584-0, 70-0716-5815-0
1.2. Recommended use and restrictions on use
Recommended use
Glass Cleaner and Protector.
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Commercial Solutions Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
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SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 > 99 Trade Secret *
ETHOXYLATED C9-11 ALCOHOLS 68439-46-3 < 1 Trade Secret *
Isopropyl Alcohol 67-63-0 < 1 Trade Secret *
SODIUM LAURYL SULFATE 151-21-3 < 1 Trade Secret *
Non-ionic Surfactants (NJTSRN 04499600-6633) Trade Secret* < 1 Trade Secret *
Fragrance Added Mixture < 0.01 Trade Secret *
NJTS or NJTSRN: New Jersey Trade Secret Registry Number.
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
No need for first aid is anticipated.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Material will not burn. Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
5.3. Special protective actions for fire-fighters
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No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the
container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Isopropyl Alcohol 67-63-0 ACGIH TWA:200 ppm;STEL:400 ppm A4: Not class. as human
carcin
Isopropyl Alcohol 67-63-0 OSHA TWA:980 mg/m3(400 ppm)
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use in a well-ventilated area. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures
to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use
respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
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Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
No protective gloves required.
Respiratory protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Liquid
Odor, Color, Grade:
Clear light blue / apple scent
Odor threshold
No Data Available
pH
6.5 - 8.5
Melting point
No Data Available
Boiling Point
212 ºF
Flash Point
No flash point
Evaporation rate
No Data Available
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
No Data Available
Vapor Density
No Data Available
Density
No Data Available
Specific Gravity
1 g/cm3
Solubility in Water
Complete
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
No Data Available
Decomposition temperature
No Data Available
Viscosity
5 - 10 centipoise
Molecular weight
No Data Available
Volatile Organic Compounds
< 0.1
VOC Less H2O & Exempt Solvents
< 2000
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
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10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Sprayed material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal
discharge, headache, hoarseness, and nose and throat pain.
Skin Contact:
Contact with the skin during product use is not expected to result in significant irritation.
Eye Contact:
Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy
vision.
Ingestion:
No known health effects.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Non-ionic Surfactants (NJTSRN 04499600-6633) Dermal Rabbit LD50 > 11,200 mg/kg
Non-ionic Surfactants (NJTSRN 04499600-6633) Ingestion Rat LD50 3,730 mg/kg
Isopropyl Alcohol Dermal Rabbit LD50 12,870 mg/kg
Isopropyl Alcohol Inhalation-
Vapor (4
hours)
Rat LC50 72.6 mg/l
Isopropyl Alcohol Ingestion Rat LD50 4,710 mg/kg
ETHOXYLATED C9-11 ALCOHOLS Dermal Rabbit LD50 > 2,000 mg/kg
ETHOXYLATED C9-11 ALCOHOLS Ingestion Rat LD50 1,378 mg/kg
SODIUM LAURYL SULFATE Inhalation-
Dust/Mist
LC50 > 0.975 mg/l
SODIUM LAURYL SULFATE Dermal Rabbit LD50 580 mg/kg
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SODIUM LAURYL SULFATE Ingestion Rat LD50 1,650 mg/kg
Fragrance Added Dermal LD50 estimated to be > 5,000 mg/kg
Fragrance Added Ingestion Rat LD50 40,600 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Isopropyl Alcohol Multiple
animal
species
No significant irritation
ETHOXYLATED C9-11 ALCOHOLS Rabbit Irritant
SODIUM LAURYL SULFATE Rabbit Irritant
Serious Eye Damage/Irritation
Name Species Value
Isopropyl Alcohol Rabbit Severe irritant
ETHOXYLATED C9-11 ALCOHOLS Professio
nal
judgeme
nt
Corrosive
SODIUM LAURYL SULFATE Rabbit Corrosive
Skin Sensitization
Name Species Value
Isopropyl Alcohol Guinea
pig
Not sensitizing
ETHOXYLATED C9-11 ALCOHOLS Guinea
pig
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Isopropyl Alcohol In Vitro Not mutagenic
Isopropyl Alcohol In vivo Not mutagenic
ETHOXYLATED C9-11 ALCOHOLS In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
Isopropyl Alcohol Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Isopropyl Alcohol Ingestion Some positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 400
mg/kg/day
during
organogenesi
s
Isopropyl Alcohol Inhalation Some positive developmental data exist,
but the data are not sufficient for
classification
Rat LOAEL 9
mg/l
during
gestation
ETHOXYLATED C9-11 ALCOHOLS Dermal Not toxic to female reproduction Rat NOAEL 250
mg/kg/day
2 generation
ETHOXYLATED C9-11 ALCOHOLS Dermal Not toxic to development Rat NOAEL 250
mg/kg/day
2 generation
ETHOXYLATED C9-11 ALCOHOLS Dermal Some positive male reproductive data Rat NOAEL 100 2 generation
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exist, but the data are not sufficient for
classification
mg/kg/day
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Isopropyl Alcohol Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
Isopropyl Alcohol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Human NOAEL Not
available
Isopropyl Alcohol Inhalation auditory system Some positive data exist, but the
data are not sufficient for
classification
Guinea
pig
NOAEL 13.4
mg/l
24 hours
Isopropyl Alcohol Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Human NOAEL Not
available
poisoning
and/or abuse
ETHOXYLATED C9-11
ALCOHOLS
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
available
not available
SODIUM LAURYL
SULFATE
Inhalation respiratory irritation May cause respiratory irritation similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Isopropyl Alcohol Inhalation kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 12.3
mg/l
24 months
Isopropyl Alcohol Inhalation nervous system All data are negative Rat NOAEL 12
mg/l
13 weeks
Isopropyl Alcohol Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 400
mg/kg/day
12 weeks
ETHOXYLATED C9-11
ALCOHOLS
Dermal kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 125
mg/kg/day
13 weeks
ETHOXYLATED C9-11
ALCOHOLS
Dermal hematopoietic
system
All data are negative Rat NOAEL 125
mg/kg/day
13 weeks
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
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13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. Empty and clean product containers may be disposed as non-hazardous waste. Consult
your specific regulations and service providers to determine available options and requirements.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA. One or more of the
components in this material is not listed on the TSCA inventory, but is approved for specific commercial use(s) under a US
EPA low volume exemption.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 1 Flammability: 0 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: 0 Flammability: 0 Physical Hazard: 0 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
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and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:
32-0785-9
Version Number:
4.00
Issue Date:
05/04/16
Supercedes Date:
03/10/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
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