3M 62490649209 User Manual

3M™ Multi-Purpose 27 Spray Adhesive 03/30/16

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Safety Data Sheet

Copyright,2016,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

27-1282-6

Version Number:

4.00

Issue Date:

03/30/16

Supercedes Date:

04/29/15

SECTION 1: Identification

1.1. Product identifier

3M™ Multi-Purpose 27 Spray Adhesive

Product Identification Numbers

ID Number UPC ID Number UPC
62-4906-4920-9 62-4906-4925-8

1.2. Recommended use and restrictions on use

Recommended use

Adhesive aerosol, Industrial Use

1.3. Supplier’s details
MANUFACTURER:

3M

DIVISION:

Industrial Adhesives and Tapes Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification

Flammable Aerosol: Category 1.
Gas Under Pressure: Liquefied gas.
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Reproductive Toxicity: Category 2.
Simple Asphyxiant.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (central nervous system): Category 3.

2.2. Label elements

Signal word

Danger

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Symbols

Flame | Gas cylinder | Exclamation mark | Health Hazard |

Pictograms

Hazard Statements

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.

Causes serious eye irritation.
Causes skin irritation.
May cause drowsiness or dizziness.
Suspected of damaging fertility or the unborn child.
May displace oxygen and cause rapid suffocation.

Causes damage to organs:
cardiovascular system |

Precautionary Statements

Prevention:

Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.

Response:

IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see Notes to Physician on this label).

Storage:

Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.
Keep container tightly closed.
Store locked up in a well-ventilated place.

Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

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Notes to Physician:

Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.

2.3. Hazards not otherwise classified

Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

N.J.T.S. Reg No. 4499600-6765 Trade Secret* 20 - 30 Trade Secret *
Acetone 67-64-1 15 - 25 Trade Secret *
Cyclohexane 110-82-7 10 - 20 Trade Secret *
Hydrotreated light Naptha (petroleum) 64742-49-0 10 - 20 Trade Secret *
Isobutane 75-28-5 10 - 20 Trade Secret *
Propane 74-98-6 10 - 20 Trade Secret *
Hexane 110-54-3 < 0.4 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. Get medical attention.

Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:

Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products

Substance Condition

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Carbon monoxide During Combustion
Carbon dioxide During Combustion
Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate
the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust
vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause
flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding
physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or
if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is
available. Contain spill. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal
container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as
possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot
surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do
not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents
(eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities

Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures
exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments

Hexane 110-54-3 ACGIH TWA:50 ppm Skin Notation
Hexane 110-54-3 OSHA TWA:1800 mg/m3(500 ppm)
Cyclohexane 110-82-7 ACGIH TWA:100 ppm
Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm)
Hydrotreated light Naptha 64742-49-0 CMRG TWA:50 ppm

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(petroleum)
Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human

carcin
Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm)
Propane 74-98-6 ACGIH Limit value not established:
Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm)
Isobutane 75-28-5 ACGIH STEL:1000 ppm
Natural gas 75-28-5 ACGIH Limit value not established:

ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray.
If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Nitrile Rubber

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece supplied-air respirator

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
General Physical Form:

Liquid

Specific Physical Form:

Aerosol

Odor, Color, Grade:

White-Tan Color, Mild Solvent Odor

Odor threshold

No Data Available

pH

No Data Available

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Melting point

No Data Available

Flash Point

-137 ºF [Details: Propellant]

Evaporation rate

1.9 [Ref Std: ETHER=1]

Flammability (solid, gas)

Not Applicable

Flammable Limits(LEL)

No Data Available

Flammable Limits(UEL)

No Data Available

Vapor Pressure

No Data Available

Vapor Density

2.97 [Ref Std: AIR=1]

Density

0.81 g/ml

Specific Gravity

0.81 [Ref Std: WATER=1]

Solubility in Water

Nil

Solubility- non-water

No Data Available

Partition coefficient: n-octanol/ water

No Data Available

Autoignition temperature

No Data Available

Decomposition temperature

No Data Available

Viscosity

Not Applicable

Hazardous Air Pollutants

0.4 % weight [Test Method: Calculated]

Molecular weight

No Data Available

Volatile Organic Compounds

<=478 g/l [Test Method: calculated SCAQMD rule 443.1]
[Details: Material VOC]

Volatile Organic Compounds

<=59 % [Test Method: calculated per CARB title 2]

Solids Content

15.9 %

SECTION 10: Stability and reactivity

10.1. Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Heat

10.5. Incompatible materials

Strong oxidizing agents

10.6. Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

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11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

Intentional concentration and inhalation may be harmful or fatal.

Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,

incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose

and throat pain.

May cause additional health effects (see below).

Skin Contact:

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye Contact:

Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Single exposure, above recommended guidelines, may cause:
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.

Reproductive/Developmental Toxicity:

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Dermal No data available; calculated ATE > 5,000 mg/kg
Overall product Inhalation-

Vapor(4 hr)

No data available; calculated ATE > 50 mg/l

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Isobutane Inhalation-

Gas (4
hours)

Rat LC50 276,000 ppm

Propane Inhalation-

Gas (4

Rat LC50 > 200,000 ppm

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hours)
Acetone Dermal Rabbit LD50 > 15,688 mg/kg
Acetone Inhalation-

Vapor (4

hours)

Rat LC50 76 mg/l

Acetone Ingestion Rat LD50 5,800 mg/kg
Cyclohexane Dermal Rat LD50 > 2,000 mg/kg
Cyclohexane Inhalation-

Vapor (4

hours)

Rat LC50 > 32.9 mg/l

Cyclohexane Ingestion Rat LD50 6,200 mg/kg
Hydrotreated light Naptha (petroleum) Dermal Rabbit LD50 > 3,160 mg/kg
Hydrotreated light Naptha (petroleum) Inhalation-

Vapor (4

hours)

Rat LC50 > 14.7 mg/l

Hydrotreated light Naptha (petroleum) Ingestion Rat LD50 > 5,000 mg/kg
N.J.T.S. Reg No. 4499600-6765 Dermal LD50 estimated to be > 5,000 mg/kg

N.J.T.S. Reg No. 4499600-6765 Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Hexane Dermal Rabbit LD50 > 2,000 mg/kg

Hexane Inhalation-

Vapor (4

hours)

Rat LC50 170 mg/l

Hexane Ingestion Rat LD50 > 28,700 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Isobutane Professio

nal
judgeme
nt

No significant irritation

Propane Rabbit Minimal irritation
Acetone Mouse Minimal irritation
Cyclohexane Rabbit Mild irritant
Hydrotreated light Naptha (petroleum) Rabbit Irritant
N.J.T.S. Reg No. 4499600-6765 Professio

nal
judgeme
nt

Minimal irritation

Hexane Human

and
animal

Mild irritant

Serious Eye Damage/Irritation

Name Species Value

Isobutane Professio

nal
judgeme
nt

No significant irritation

Propane Rabbit Mild irritant
Acetone Rabbit Severe irritant
Cyclohexane Rabbit Mild irritant
Hydrotreated light Naptha (petroleum) Rabbit Mild irritant
Hexane Rabbit Mild irritant

Skin Sensitization

Name Species Value

Hydrotreated light Naptha (petroleum) Guinea

pig

Not sensitizing

Hexane Human Not sensitizing

Respiratory Sensitization

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For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

Isobutane In Vitro Not mutagenic
Propane In Vitro Not mutagenic
Acetone In vivo Not mutagenic
Acetone In Vitro Some positive data exist, but the data are not

sufficient for classification
Cyclohexane In Vitro Not mutagenic
Cyclohexane In vivo Some positive data exist, but the data are not

sufficient for classification
Hydrotreated light Naptha (petroleum) In Vitro Not mutagenic
Hexane In Vitro Not mutagenic
Hexane In vivo Not mutagenic

Carcinogenicity

Name Route Species Value

Acetone Not

Specified

Multiple
animal
species

Not carcinogenic

Hydrotreated light Naptha (petroleum) Inhalation Mouse Some positive data exist, but the data are not

sufficient for classification
Hexane Dermal Mouse Not carcinogenic
Hexane Inhalation Mouse Some positive data exist, but the data are not

sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

Acetone Ingestion Some positive male reproductive data

exist, but the data are not sufficient for
classification

Rat NOAEL 1,700

mg/kg/day

13 weeks

Acetone Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 5.2

mg/l

during
organogenesi
s

Cyclohexane Inhalation Not toxic to female reproduction Rat NOAEL 24

mg/l

2 generation

Cyclohexane Inhalation Not toxic to male reproduction Rat NOAEL 24

mg/l

2 generation

Cyclohexane Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 6.9

mg/l

2 generation

Hexane Ingestion Not toxic to development Mouse NOAEL 2,200

mg/kg/day

during
organogenesi
s

Hexane Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 0.7

mg/l

during
gestation

Hexane Ingestion Toxic to male reproduction Rat NOAEL 1,140

mg/kg/day

90 days

Hexane Inhalation Toxic to male reproduction Rat LOAEL 3.52

mg/l

28 days

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Isobutane Inhalation cardiac sensitization Causes damage to organs Multiple

animal

NOAEL Not
available

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species

Isobutane Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Isobutane Inhalation respiratory irritation All data are negative Mouse NOAEL Not

available

Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not

available

Propane Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Propane Inhalation respiratory irritation All data are negative Human NOAEL Not

available

Acetone Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

Acetone Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL Not

available

Acetone Inhalation immune system Some positive data exist, but the

data are not sufficient for
classification

Human NOAEL 1.19

mg/l

6 hours

Acetone Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Guinea
pig

NOAEL Not
available

Acetone Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

poisoning
and/or abuse

Cyclohexane Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Cyclohexane Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Human
and
animal

NOAEL Not
available

Cyclohexane Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Professio
nal
judgeme
nt

NOAEL Not
available

Hydrotreated light Naptha
(petroleum)

Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human
and
animal

NOAEL Not
available

Hydrotreated light Naptha
(petroleum)

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

Hydrotreated light Naptha
(petroleum)

Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Professio
nal
judgeme
nt

NOAEL Not
available

Hexane Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

not available

Hexane Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Rabbit NOAEL Not

available

8 hours

Hexane Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 24.6

mg/l

8 hours

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Isobutane Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL

4,500 ppm

13 weeks

Acetone Dermal eyes Some positive data exist, but the

data are not sufficient for
classification

Guinea
pig

NOAEL Not
available

3 weeks

Acetone Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL 3

mg/l

6 weeks

Acetone Inhalation immune system Some positive data exist, but the Human NOAEL 1.19 6 days

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data are not sufficient for
classification

mg/l

Acetone Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Guinea
pig

NOAEL 119
mg/l

not available

Acetone Inhalation heart | liver All data are negative Rat NOAEL 45

mg/l

8 weeks

Acetone Ingestion kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 900

mg/kg/day

13 weeks

Acetone Ingestion heart Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL

2,500
mg/kg/day

13 weeks

Acetone Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 200

mg/kg/day

13 weeks

Acetone Ingestion liver Some positive data exist, but the

data are not sufficient for
classification

Mouse NOAEL

3,896
mg/kg/day

14 days

Acetone Ingestion eyes All data are negative Rat NOAEL

3,400
mg/kg/day

13 weeks

Acetone Ingestion respiratory system All data are negative Rat NOAEL

2,500
mg/kg/day

13 weeks

Acetone Ingestion muscles All data are negative Rat NOAEL

2,500 mg/kg

13 weeks

Acetone Ingestion skin | bone, teeth,

nails, and/or hair

All data are negative Mouse NOAEL

11,298
mg/kg/day

13 weeks

Cyclohexane Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 24

mg/l

90 days

Cyclohexane Inhalation auditory system Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL 1.7

mg/l

90 days

Cyclohexane Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rabbit NOAEL 2.7

mg/l

10 weeks

Cyclohexane Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 24

mg/l

14 weeks

Cyclohexane Inhalation peripheral nervous

system

All data are negative Rat NOAEL 8.6

mg/l

30 weeks

Hexane Inhalation peripheral nervous

system

Causes damage to organs through
prolonged or repeated exposure

Human NOAEL Not

available

occupational
exposure

Hexane Inhalation respiratory system Some positive data exist, but the

data are not sufficient for
classification

Mouse LOAEL 1.76

mg/l

13 weeks

Hexane Inhalation liver Some positive data exist, but the

data are not sufficient for
classification

Rat NOAEL Not

available

6 months

Hexane Inhalation kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat LOAEL 1.76

mg/l

6 months

Hexane Inhalation hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Mouse NOAEL 35.2

mg/l

13 weeks

Hexane Inhalation auditory system |

immune system |
eyes

Some positive data exist, but the
data are not sufficient for
classification

Human NOAEL Not

available

occupational
exposure

Hexane Inhalation heart | skin |

endocrine system

All data are negative Rat NOAEL 1.76

mg/l

6 months

Hexane Ingestion peripheral nervous

system

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL

1,140
mg/kg/day

90 days

Hexane Ingestion endocrine system |

hematopoietic

Some positive data exist, but the
data are not sufficient for

Rat NOAEL Not

available

13 weeks

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system | liver |
immune system |
kidney and/or
bladder

classification

Aspiration Hazard

Name Value

Cyclohexane Aspiration hazard
Hydrotreated light Naptha (petroleum) Aspiration hazard
Hexane Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal
alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and
handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable
regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

3M™ Multi-Purpose 27 Spray Adhesive 03/30/16

__________________________________________________________________________________________

Page 13 of 13

Ingredient C.A.S. No % by Wt

Cyclohexane 110-82-7 Trade Secret 10 - 20

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 4 Instability: 0 Special Hazards: None

Aerosol Storage Code: 3

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification

Health: *2 Flammability: 4 Physical Hazard: 0 Personal Protection: X - See PPE section.

Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group:

27-1282-6

Version Number:

4.00

Issue Date:

03/30/16

Supercedes Date:

04/29/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com